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Metallogenic Age and Ore-forming Material Sources of the Dahongshan Fe-Cu Deposit,Yunnan Province:Insights from Molybdenite Re-Os Dating and H-O-S-Pb Isotopes
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作者 YE Zifeng YANG Guangshu +2 位作者 YU Wenxiu CHEN Aibing JIA Fuju 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2023年第6期1698-1718,共21页
The Dahongshan Fe-Cu(-Au)deposit is a superlarge deposit in the Kangdian metallogenic belt,southwestern China,comprising approximately 458 Mt of Fe ores(40%Fe)and 1.35 Mt Cu.Two main types of Fe-Cu(-Au)mineralization ... The Dahongshan Fe-Cu(-Au)deposit is a superlarge deposit in the Kangdian metallogenic belt,southwestern China,comprising approximately 458 Mt of Fe ores(40%Fe)and 1.35 Mt Cu.Two main types of Fe-Cu(-Au)mineralization are present in the Dahongshan deposit:(1)early submarine volcanic exhalation and sedimentary mineralization characterized by strata-bound fine-grained magnetite and banded Fe-Cu sulfide(pyrite and chalcopyrite)hosted in the Na-rich metavolcanic rocks;(2)late hydrothermal(-vein)type mineralization characterized by Fe-Cu sulfide veins in the hosted strata or massive coarse-grained magnetite orebodies controlled by faults.While previous studies have focused primarily on the early submarine volcanic and sedimentary mineralization of the deposit,data related to late hydrothermal mineralization is lacking.In order to establish the metallogenic age and ore-forming material source of the late hydrothermal(-vein)type mineralization,this paper reports the Re-Os dating of molybdenite from the late hydrothermal vein Fe-Cu orebody and H,O,S,and Pb isotopic compositions of the hydrothermal quartz-sulfide veins.The primary aim of this study was to establish the metallogenic age and ore-forming material source of the hydrothermal type orebody.Results show that the molybdenite separated from quartz-sulfide veins has a Re-Os isochron age of 831±11 Ma,indicating that the Dahongshan Fe-Cu deposit experienced hydrothermal superimposed mineralization in Neoproterozoic.The molybdenite has a Re concentration of 99.7-382.4 ppm,indicating that the Re of the hydrothermal vein ores were primarily derived from the mantle.The δ^(34)S values of sulfides from the hydrothermal ores are 2‰-8‰ showing multi-peak tower distribution,suggesting that S in the ore-forming period was primarily derived from magma and partially from calcareous sedimentary rock.Furthermore,the abundance of radioactive Pb increased significantly from ore-bearing strata to layered and hydrothermal vein ores,which may be related to the later hydrothermal transformation.The composition of H and O isotopes within the hydrothermal quartz indicates that the ore-forming fluid is a mixture of magmatic water and a small quantity of water.These results further indicate that the late hydrothermal orebodies were formed by the Neoproterozoic magmatic hydrothermal event,which might be related to the breakup of the Rodinia supercontinent.Mantle derived magmatic hydrothermal fluid extracted ore-forming materials from the metavolcanic rocks of Dahongshan Group and formed the hydrothermal(-vein)type Fe-Cu orebodies by filling and metasomatism. 展开更多
关键词 stable isotopes re-os dating ore-forming material Dahongshan Fe-Cu deposit Kangdian region
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Re-Os Dating of Molybdenite from the Nannihu Mo (-W) Orefield in the East Qinling and Its Geodynamic Significance 被引量:27
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作者 LIYongfeng MAOJingwen GUOBaojian SHAOYongjun FEIHongcai HUHuabin 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2004年第2期463-470,共8页
Located in the East Qinling molybdenum metallogenic belt on the southern margin of the North China craton, the Nannihu Mo (-W) orefield comprising Nannihu, Sandaozhuang, and Shangfanggou deposits is a superlarge skarn... Located in the East Qinling molybdenum metallogenic belt on the southern margin of the North China craton, the Nannihu Mo (-W) orefield comprising Nannihu, Sandaozhuang, and Shangfanggou deposits is a superlarge skarn-porphyry Mo (-W) orefield in the world. Re-Os dating was performed of six molybdenite samples from the Mo deposits in the Nannihu Mo orefield with inductively coupled plasma mass spectrometry (ICP-MS). The results show that the Re-Os model ages are 145.8±2.1-141.8±2.1 Ma for the Nannihu deposit, 145.4±2.0-144.5±2.2 Ma (averaging 145.0±2.2 Ma) for the Sandaozhuang deposit and 145.8±2.1-143.8±2.1 Ma (averaging 144.8±2.1 Ma) for the Shangfanggou deposit; dating of the six samples yields an isochron age of 141.5±7.8 Ma (2σ), which accurately determines the timing of mineralization. The results also suggest that the ore-forming materials were mainly derived from the lower crust, mixed with minor mantle components. These Mo deposits were formed during the transition of the Mesozoic tectonic regime in eastern China, and its mineralization was a part of the Late Mesozoic large-scale mineralization in that region. 展开更多
关键词 Mo deposit re-os dating East Qinling Nannihu China
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Re-Os Dating of the Pulang Porphyry Copper Deposit in Zhongdian,NW Yunnan, and Its Geological Significance 被引量:11
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作者 ZENGPusheng HOUZengqian +4 位作者 WANGHaiping QUWenjun MENGYifeng YANGZhusen LIWenchang 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2004年第2期604-609,共6页
The Pulang porphyry copper deposit is located in the Zhongdian island arc belt, NW Yunnan, in the central part of the Sanjiang area, SW China, belonging to the southern segment of the Yidun island arc belt on the west... The Pulang porphyry copper deposit is located in the Zhongdian island arc belt, NW Yunnan, in the central part of the Sanjiang area, SW China, belonging to the southern segment of the Yidun island arc belt on the western margin of the Yangtze Platform. In the Yidun island arc, there occur well-known 'Gacun-style' massive sulfide deposits in the northern segment and plenty of porphyry copper deposits in the southern segment, of which the Pulang porphyry copper deposit is one of the representatives. Like the Yulong porphyry copper deposit, this porphyry copper deposit is also one of the most important porphyry copper deposits in the eastern Qinghai-Tibet Plateau. But it is different from other porphyry copper deposits in the eastern Qinghai-Tibet Plateau (e.g. those in the Gangdise porphyry copper belt and Yulong porphyry copper belt) in that it formed in the Indosinian period, while others in the Himalayan period. Because of its particularity among the porphyry copper deposits of China, this porphyry copper deposit is of great significance for the study of the basic geology and the evaluation and prediction of mineral resources in the Zhongdian island arc belt. However, no accurate chronological data are available for determining the timing of mineralization of the porphyry copper deposit. By field observation in the study area and Re-Os dating of molybdenite and K-Ar dating of hydrothermal minerals and whole rock from the typical geological bodies, the timing of mineralization of the porphyry copper deposit has systematically been determined for the first time. The K-Ar age for the hydrothermal mineralization of biotite-quartz monzonitic porphyry that has undergone patassic silicate (biotite and K-feldspar) alteration ranges from 235.4±2.4 to 221.5±2.0 Ma and the Re-Os age for molybdenite in the quartz-molybdenite stage is ~213±3.8 Ma. These data are very close to each other, suggesting that the ore-forming processes of the Pulang porphyry copper deposit was completed in the Indosinian. But the K-feldspar K-Ar age of the main orebodies suggests that the hydrothermal activity related to porphyry copper mineralization continued till ~182.5±1.8 Ma. This indicates that the lifespan of the hydrothermal system related to porphyry copper mineralization may have lasted at least 40 Ma. This hydrothermal thermal system with such a long lifespan may be one of the necessary conditions for forming large porphyry copper deposits with a high grade. No late Yanshanian and/or Himalayan magmatism (mineralization) were superimposed in the Pulang porphyry copper deposit. 展开更多
关键词 re-os dating porphyry copper Pulang Zhongdian YUNNAN China
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LA-ICP-MS Zircon U-Pb Dating of Intermediate-Acidic Intrusive Rocks and Molybdenite Re-Os Dating from the Bangpu Mo (Cu) Deposit, Tibet and its Geological Implication 被引量:13
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作者 WANG Liqiang CHEN Yuchuan +5 位作者 TANG Juxing LU Pengrui LUO Maocheng WANG Huan CHEN Wei LENG Qiufeng 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2012年第5期1225-1240,共16页
The multi-stage intrusions of intermediate-acid magma occur in the Bangpu mining district, the petrogenic ages of which have been identified. The times and sequences of their emplacement have been collated and stipula... The multi-stage intrusions of intermediate-acid magma occur in the Bangpu mining district, the petrogenic ages of which have been identified. The times and sequences of their emplacement have been collated and stipulated in detail in this paper by using the laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) zircon U-Pb dating method. The ages of biotite monzogranite that were formed before mineralization in the southwest of this mining district are 70±1 Ma (mean square of weighted deviates (MSWD) =9.5, n=8) and 60.60±0.31 Ma (MSWD=3.8, n=16), which belong to the late Cretaceous-early Paleocene in age. That means, they are products of an early tectonicmagmatic event of the collision between the Indian and Asian continentals. The ages of ore-bearing monzogranite porphyry and ore-bearing diorite porphyrite are 16.23±0.19 Ma (MSWD=2.0, n=26) and 15.16±0.09 Ma (MSWD=3.9, n=5) separately, which belong to the middle Miocene in age; namely, they are products of the Gangdese post-collision extensional stage when crust-mantle materials melted and mixed as well as magmatic intrusion simultaneously occurred. Some zircons with ages of 203.6±2.2 Ma (MSWD=1.18, n=7) were captured in the ore-bearing diorite porphyrite, which shows that there had been tectono-magmatic events in the late Triassic-early Jurassic. Molybdenum (copper) ore-bodies produced in the monzogranite porphyry and copper (molybdenum) ore-bodies produced in the diorite porphyrite are the main ore types in this ore deposit. The model ages of Re-Os isotopic dating for the 11 molybdenite are 13.97-15.84 Ma, while isochron ages are 14.09±0.49 Ma (MSWD=26). The isochron ages of seven molybdenite from molybdenum (copper) ore with monzogranite porphyry type are 14.11±0.31 Ma (MSWD=5.2). There is great error in the isochron ages of four molybdenite from copper (molybdenum) ore with diorite porphyrite type, and their weighted average model ages of 14.6±1.2 Ma (MSWD=41), which generally represent the mineralization age. The results about the Re-Os isotopic dating of molybdenite in the ore of different types have limited exactly that, the minerlazation age of this ore deposits is about 14.09 Ma, which belongs to the middle Miocene mineralization. The Bangpu deposit has a uniform metallogenic dynamics background with the porphyry type and skarn-type deposits such as Jiama, Qulong and others. 展开更多
关键词 LA-ICP-MS zircon U-Pb dating molybdenite re-os dating metallogenic dynamics background Bangpu TIBET
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LA-ICP-MS Zircon U-Pb Geochronology of the Fine-grained Granite and Molybdenite Re-Os Dating in the Wurinitu Molybdenum Deposit,Inner Mongolia,China 被引量:10
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作者 Cui LIU Jinfu DENG +4 位作者 Weiqiong KONG Liquan XU Guochun ZHAO Zhaohua LUO Ning LI 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2011年第5期1057-1066,共10页
The Wurinitu molybdenum deposit,located in Honggor,Sonid Left Banner of Inner Mongolia,China,is recently discovered and is considered to be associated with a concealed fine-grained granite impregnated with molybdenite... The Wurinitu molybdenum deposit,located in Honggor,Sonid Left Banner of Inner Mongolia,China,is recently discovered and is considered to be associated with a concealed fine-grained granite impregnated with molybdenite.The wall rocks are composed of Variscan porphyritic-like biotite granite and the Lower Ordovician Wubin'aobao Formation.LA-ICP-MS zircon U-Pb dating of the fine-grained granite reveals two stages of zircons,one were formed at 181.7±7.4 Ma and the other at 133.6±3.3 Ma.The latter age is believed to be the formation age of the fine-grained granite,while the former may reflect the age of inherited zircons,based on the morphological study of the zircon and regional geological setting.The Re-Os model age of molybdenite is 142.2±2.5 Ma,which is older than the diagenetic age of the fine-grained granite.Therefore the authors believe that the metallogenic age of the Wurinitu molybdenum deposit should be nearly 133.6±3.3 Ma or slightly later,i.e.,Early Cretaceous.Combined with regional geological background research,it is speculated that the molybdenum deposits were formed at the late Yanshanian orogenic cycle in the Hingganling-Mongolian orogenic belt,belonging to the relaxation epoch posterior to the compression and was associated with the closure of the Mongolia-Okhotsk Sea. 展开更多
关键词 fine-grained granite LA-ICP-MS zircon U-Pb geochronology molybdenite re-os dating Wurinitu molybdenum deposit Inner Mongolia
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Re-Os Dating of Chalcopyrite from the Lala IOCG Deposit in the Kangdian Copper Belt,China 被引量:3
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作者 SONG Hao SONG Shiwei 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2015年第2期689-690,共2页
This study focused on the typical Precambrian copper- iron-gold-uranium deposits in the southwestern margin of the Yangtze block, such as the Lala in Huili, Dahongshan in Xinping, Yinachang in Wuding, and Chahe in Yua... This study focused on the typical Precambrian copper- iron-gold-uranium deposits in the southwestern margin of the Yangtze block, such as the Lala in Huili, Dahongshan in Xinping, Yinachang in Wuding, and Chahe in Yuanjiang. Through systematically sampling of rocks, mineral and single mineral samples, this study discussed the continental geodynamics, age of magmatic rocks and metallogenic epoch, coupling relationship between polymetallic elements and ore-forming fluid, and the coupling relationship between magma evolution and polymetallic mineralization based on the latest metallogenic theory and modern analytical techniques. 展开更多
关键词 re-os dating of Chalcopyrite from the Lala IOCG Deposit in the Kangdian Copper Belt China OS
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Re-Os Dating of Molybdenite from the Yaogangxian Tungsten Deposit,South China,and Its Geological Significance 被引量:9
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作者 WANG Yonglei PEI Rongfu +4 位作者 LI Jinwen QU Wenjun LI Li WANG Haolin DU Andao 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2008年第4期820-825,共6页
The Yaogangxian tungsten deposit is located in the central part of the Nanling polymetailic metallogenic province. The orebodies occur as veins. Wolframite and molybdenite are the dominant ore minerals. Two samples we... The Yaogangxian tungsten deposit is located in the central part of the Nanling polymetailic metallogenic province. The orebodies occur as veins. Wolframite and molybdenite are the dominant ore minerals. Two samples were selected for molybdenite Re-Os dating in order to elucidate the timing of mineralization. Re-Os datings of molybdenite from quartz-woiframite veins and disseminated in granite yield ages of 153±7 Ma and 163.2±4.2 Ma respectively. The results indicate that the Yaogangxian tungsten deposit is the product of large-scale metallogenesis in the middle Yanshanian period in South China, and that the evolution from late magmatic to postmagmatic hypothermal mineralization occurred at about 10 Ma. The rhenium content of molybdenite in the Yaogangxian tungsten deposit suggests that the ore materials originated from the crust. 展开更多
关键词 re-os isotopes MOLYBDENITE tungsten deposit South China
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Timing of carbonatite-hosted U-polymetallic mineralization in the supergiant Huayangchuan deposit,Qinling Orogen:Constraints from titanite U-Pb and molybdenite Re-Os dating 被引量:9
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作者 Hui Zheng Huayong Chen +3 位作者 Dengfeng Li Chao Wu Xi Chen Chun-kit Lai 《Geoscience Frontiers》 SCIE CAS CSCD 2020年第5期1581-1592,共12页
The newly-discovered supergiant Huayangchuan uranium(U)-polymetallic(Sr,Se,REEs,Ba,Nb and Pb)deposit is located in the Qinling Orogen,central China.The deposit underwent multistage mineralization,with the main carbona... The newly-discovered supergiant Huayangchuan uranium(U)-polymetallic(Sr,Se,REEs,Ba,Nb and Pb)deposit is located in the Qinling Orogen,central China.The deposit underwent multistage mineralization,with the main carbonatite ore stage being the most important for the U,Nb,REE,Sr and Ba endowments.According to the mineral assemblages,the main carbonatite ore stage can be divided into three substages,i.e.,sulfate(Ba-Sr),alkali-rich U and REE-U mineralization.Main-stage titanite from the Huayangchuan igneous carbonatite are rich in high field strength elements(HFSEs,e.g.,Zr,Nb and REEs),and show clear elemental substitutions(e.g.,Ti vs.Nb+Fe+Al and Ca+Ti vs.Fe+Al+REE).High-precision LA-ICP-MS titanite dating yielded a U-Pb age of 209.0±2.9 Ma,which represents the mainstage mineralization age at Huayangchuan,and is coeval with the local carbonatite dyke intrusion.This mineralization age is further constrained by the Re-Os dating of molybdenite from the Huayangchuan carbonatite,which yielded a weighted mean age of 196.8±2.4 Ma.Molybdenite Re contents(337.55-392.75 ppm)and C-OSr-Nd-Pb isotopic evidence of the Huayangchuan carbonatite both suggest a mantle origin for the carbonatite.Our study supports that the Late Triassic carbonatite magmatism was responsible for the world-class U-Mo-REE mineralization in the Qinling Orogen,and that the regional magmatism and ore formation was likely caused by the closure of the Mianlue ocean and the subsequent North China-South China continent-continent collision. 展开更多
关键词 Carbonatite-hosted U-Polymetallic deposits Titanite U–Pb dating Molybdenite Re–Os dating Huayangchuan deposit Qinling orogen
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SHRIMP Zircon U-Pb and Molybdenite Re-Os Datings of the Superlarge Donggou Porphyry Molybdenum Deposit in the East Qinling,China,and Its Geological Implications 被引量:7
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作者 YE Huishou MAO Jingwen +5 位作者 LI Yongfeng GUO Baojian ZHANG Changqing LIU Jun YAN Quanren LIU Guoyin 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2008年第1期134-145,共12页
Located in the eastern part of the East Qinling molybdenum belt, the Donggou deposit is a superlarge porphyry molybdenum deposit discovered in recent years. The authors performed highly precise dating of the mineraliz... Located in the eastern part of the East Qinling molybdenum belt, the Donggou deposit is a superlarge porphyry molybdenum deposit discovered in recent years. The authors performed highly precise dating of the mineralized porphyry and ores in the Donggou molybdenum deposit. A SHRIMP U-Pb zircon dating of the Donggou aluminous A-type granite-porphyry gave a rock-forming age of 112±1 Ma, and the ICP-MS Re-Os analyses of molybdenite from the molybdenum deposit yielded ReOs model ages ranging from 116.5±1.7 to 115.5±1.7 Ma for the deposit. The ages obtained by the two methods are quite close, suggesting that the rocks and ores formed approximately at the same time. The Donggou molybdenum deposit formed at least 20 Ma later than the Jinduicheng, Nannihu, Shangfanggou and Leimengou porphyry molybdenum deposits in the same molybdenum belt, implying that these deposits were formed in different tectonic settings. 展开更多
关键词 SHRIMP U-Pb zircon age aluminous A-type granite-porphyry molybdenite re-os age Donggou molybdenum deposit East Qinling
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Re-Os dating,and Pb-H-O isotope characteristics,of the Abra Cu-Ag-Pb-Au polymetallic deposit in Western Australia
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作者 Chaozhuang Xi Minghong Zheng +1 位作者 Ling He Haodong Xia 《Acta Geochimica》 EI CAS CSCD 2021年第5期739-751,共13页
The Abra deposit,a large lead-silver-copper–gold polymetallic deposit in Western Australia,is located at the eastern of the metallogenic belt of the Jillawarra basin in the Bangemall basin.The 4 th to the 6 th rock s... The Abra deposit,a large lead-silver-copper–gold polymetallic deposit in Western Australia,is located at the eastern of the metallogenic belt of the Jillawarra basin in the Bangemall basin.The 4 th to the 6 th rock section of the Irrigully Group of Edmund Series are the principal ore-host strata,composed mainly of sandstone and fine sandstone.The orebody in Abra can be classified into two types as upper layer-like lead-silver and lower veins or netvein copper–gold.The metal minerals are mainly galena,chalcopyrite,and pyrite,while the gangue minerals are mainly quartz,dolomite,and barite.Both ReOs isotopic age of the pyrite(1329.5±98 Ma)with the initial(187Os/188Os)=5.0±3.8 and Pb isotopic compositions(206 Pb/204 Pb=15.914–15.967,207Pb/204Pb=15.425–15.454,208Pb/204Pb=35.584–35.667)suggests that the metal minerals were sourced from the wall-rocks.d DV-SMOWvalues of quartz range from-35%to-17%whereas d18 OV-SMOWvalue range from 12%to 16%which indicates that the ore-forming fluids of Abra were mediumlow temperature and medium–low salinity,and were mainly metamorphic water and secondary atmospheric precipitation.When the medium–low temperature oreforming fluids are mixed with oxidizing reducing fluids carrying a large number of metal substances,a large number of ore-forming substances will be precipitated when the physical and chemical conditions change,thus it can be considered that the Abra deposit is a medium–low temperature hydrothermal polymetallic deposit. 展开更多
关键词 re-os isotope Pb–H-O isotope Abra cu-ag-pb-au polymetallic deposit AUSTRALIA
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青海东昆仑三通沟北锰矿成矿时代与物质来源:来自Re-Os同位素年代学与地球化学的约束
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作者 李文 刘永乐 +4 位作者 李文君 高炳宇 董志国 朱明田 张连昌 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第4期1231-1248,共18页
东昆仑三通沟北锰矿床是近年来青海省发现的规模最大的海相沉积型锰矿。该矿床位于东昆南构造带的北缘,成矿地质背景与原特提斯洋的演化密切相关。但目前该矿床研究程度较低,尤其是成矿时代存在中-新元古代与奥陶-志留纪的争议,成矿物... 东昆仑三通沟北锰矿床是近年来青海省发现的规模最大的海相沉积型锰矿。该矿床位于东昆南构造带的北缘,成矿地质背景与原特提斯洋的演化密切相关。但目前该矿床研究程度较低,尤其是成矿时代存在中-新元古代与奥陶-志留纪的争议,成矿物质来源存在海底热液为主还是海底热液与陆源风化共同来源的不同认识。为了解决这些问题,本文在对三通沟北锰矿进行详细野外地质调查和钻孔岩芯编录的基础上,选择11件锰矿石进行Re-Os同位素分析,获得了442±15Ma的Re-Os等时线年龄,说明三通沟北锰矿带形成于晚奥陶世,不是前人认为的中-新元古代,这一成矿年龄与区域上的奥陶纪纳赤台群沉积岩的形成时代一致。同时Re-Os同位素分析获得的^(187)Os/^(188)Os初始值为0.67±0.02,该值明显低于同期海水的Os同位素组成(0.72),初步表明三通沟北锰矿的锰质来源以海底热液为主。矿石在SiO_(2)-Al_(2)O_(3)、Al/(Al+Fe+Mn)-Fe/Ti、Fe-Mn-(Ni+Cu+Co)×10和lgU-lgTh等图解上主要位于热水沉积区,矿石稀土元素配分型式也具有海底热液来源的特征。可见三通沟北锰矿的成矿物质来源主要与海底热液活动有关。 展开更多
关键词 东昆仑 沉积型锰矿 纳赤台群 re-os同位素年龄 地球化学
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新疆东天山黄滩金铜锌矿成矿时代——来自白云母^(40)Ar-^(39)Ar年龄和黄铁矿Re-Os年龄约束
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作者 耿新霞 张志欣 +4 位作者 张振龙 李宁 杨富全 杨成栋 成曦晖 《大地构造与成矿学》 EI CAS CSCD 北大核心 2024年第2期368-379,共12页
卡拉塔格是东天山十分重要的铜矿集区,发育5个不同时代和成矿类型的成矿系统。近年来新发现了黄滩(包括金岭)金铜锌矿床,赋存于火山岩系中,发育层状矿化、脉状矿化和黄铁绢英岩化,但层状矿化和黄铁绢英岩化形成时代不清楚,制约了进一步... 卡拉塔格是东天山十分重要的铜矿集区,发育5个不同时代和成矿类型的成矿系统。近年来新发现了黄滩(包括金岭)金铜锌矿床,赋存于火山岩系中,发育层状矿化、脉状矿化和黄铁绢英岩化,但层状矿化和黄铁绢英岩化形成时代不清楚,制约了进一步找矿勘查工作。本文基于野外调查和室内研究,开展白云母^(40)Ar-^(39)Ar年龄和黄铁矿Re-Os年代学研究,获得黄铁绢英岩中白云母^(40)Ar-^(39)Ar坪年龄为429.46±3.91 Ma,7件层状矿化中黄铁矿Re-Os等时线年龄为436.5±4.2 Ma。层状矿化年龄与前人获得含矿岩系英安岩和英安质凝灰岩年龄(434~438 Ma)、脉状矿化年龄(432~438 Ma)一致,表明层状矿化、脉状矿化和黄铁绢英岩化是同一成矿事件的产物,黄滩为富金火山成因块状硫化物(VMS)型矿床。因此,尽管黄滩和红海‒黄土坡为VMS型矿床,红石为火山热液脉状矿床,但它们均为同一VMS成矿系统,形成于430~439 Ma,受控矿因素的差异,造成了成因类型、矿化类型和成矿元素组合的多样性。 展开更多
关键词 白云母^(40)Ar-^(39)Ar年龄 黄铁矿re-os年龄 VMS矿床 金铜锌 黄滩 东天山
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原油组分Re-Os放射性同位素体系特征及其定年机理与应用启示
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作者 刘俊杰 殷启春 +3 位作者 龚赞 李作生 龙晓平 李杰 《大地构造与成矿学》 EI CAS CSCD 北大核心 2024年第3期557-565,共9页
Re-Os放射性同位素体系可用于含油气系统关键地质过程的定年与示踪研究。不过,Re-Os定年的精度仍受到有关科学问题的制约,如原油组分的Re-Os体系特征、沥青质渐进散失对原油Re-Os体系特征与定年应用的影响等。本研究通过二元溶液直接分... Re-Os放射性同位素体系可用于含油气系统关键地质过程的定年与示踪研究。不过,Re-Os定年的精度仍受到有关科学问题的制约,如原油组分的Re-Os体系特征、沥青质渐进散失对原油Re-Os体系特征与定年应用的影响等。本研究通过二元溶液直接分离原油次组分的实验,揭示了原油组分的Re-Os体系特征,模拟了实际地质情况中沥青质渐进散失对原油Re-Os体系特征与定年应用的影响,并通过重复实验验证相关实验流程对所取得的结果和认识的影响。研究发现,根据沉淀的先后顺序,原油次组分的Re和Os元素丰度总体上呈下降趋势,但有起伏变化,Re-Os同位素比值则单调下降。因此,沥青质的渐进散失将导致原油Re和Os元素丰度以及Re-Os同位素比值降低,进而对原油和低成熟度沥青Re-Os定年与示踪的应用产生影响。重复实验表明,实验室分离次组分的操作结果具有一定的随机性,但不影响Re-Os体系的总体性质。 展开更多
关键词 RM8505原油 次组分 re-os放射性同位素体系 re-os定年
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西秦岭加甘滩金矿成因研究:毒砂Re-Os定年、载金矿物原位微量元素和硫同位素限定
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作者 陈炳翰 张勇 李康宁 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第6期1767-1783,共17页
西秦岭加甘滩金矿是夏河-合作地区最大的金矿,但其矿床成因存在争议,其中主要问题在于该矿床成矿时代缺乏研究。通过野外工作和镜下观察,识别出两种毒砂和黄铁矿:毒砂Apy1(较为常见,在矿石中呈浸染状产出)和毒砂Apy2(数量较少,围绕黄铁... 西秦岭加甘滩金矿是夏河-合作地区最大的金矿,但其矿床成因存在争议,其中主要问题在于该矿床成矿时代缺乏研究。通过野外工作和镜下观察,识别出两种毒砂和黄铁矿:毒砂Apy1(较为常见,在矿石中呈浸染状产出)和毒砂Apy2(数量较少,围绕黄铁矿Py1产出),黄铁矿Py1(浸染状黄铁矿)和黄铁矿Py2(黄铁矿脉)。本次工作对毒砂进行Re-Os定年,以期确定加甘滩金矿的成矿时代:通过对Apy1进行了Re-Os定年,获得毒砂的Re-Os等时线年龄243.1±8.7Ma,该年龄与夏河-合作区域岩浆作用(232~249Ma)相对应。利用LA-ICP-MS和LA-MC-ICP-MS对成矿期毒砂和黄铁矿进行了微量元素和硫同位素测定。微量元素测试结果显示加甘滩金矿硫化物内的不可见金以固溶体形式赋存,Apy2的不可见金含量最高可达521×10^(-6),其他毒砂和黄铁矿不可见金含量最高为119×10^(-6)。加甘滩金矿的平均品位为2~3g/t,依据质量平衡计算,如果毒砂和黄铁矿内不可见金发生再活化,不可见金含量需要达到20~30g/t,但实际金含量远低于所需,需要额外的岩浆热液来源。Py1、Py2、Apy1和Apy2的原位硫同位素结果分别为-14.3‰~-7.70‰(平均-10.0‰)、-14.5‰~-9.60‰(平均-12.5‰)、-13.0‰~-6.40‰(平均-8.54‰),-11.2‰~-9.00‰(平均-10.1‰),反映其硫同位素发生了分馏。将加甘滩金矿成矿期硫化物的硫同位素与成岩期和典型岩浆热液型黄铁矿硫同位素进行对此,指示其成矿流体为岩浆热液来源。综上,本文研究指示加甘滩金矿属于岩浆热液成因。 展开更多
关键词 毒砂 re-os定年 微量元素 硫同位素 加甘滩金矿
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新疆西天山智博铁矿成矿时代——来自锆石U-Pb年龄和黄铁矿Re-Os年龄的证据
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作者 宋雪龙 段士刚 蒋宗胜 《大地构造与成矿学》 EI CAS CSCD 北大核心 2024年第5期1060-1077,共18页
智博铁矿是新疆西天山阿吾拉勒铁成矿带的大型富铁矿床,在区域成矿规律研究和找矿勘查方面极具代表性。本文选择能限定铁矿体时代的围岩火山岩、侵入围岩地层的石英闪长岩开展锆石U-Pb测年,并挑选与磁铁矿共生的黄铁矿开展Re-Os同位素定... 智博铁矿是新疆西天山阿吾拉勒铁成矿带的大型富铁矿床,在区域成矿规律研究和找矿勘查方面极具代表性。本文选择能限定铁矿体时代的围岩火山岩、侵入围岩地层的石英闪长岩开展锆石U-Pb测年,并挑选与磁铁矿共生的黄铁矿开展Re-Os同位素定年,试图厘定其成矿时代。本文获得5件铁矿石样品中黄铁矿的Re-Os等时线年龄为307±12Ma,围岩绿帘石化安山岩的锆石U-Pb年龄为312.0±3.4 Ma,安山质集块岩年龄为317.8±2.5 Ma,两件石英闪长岩的年龄分别为317.0±2.2 Ma和315.4±0.9 Ma,据此认为智博铁矿成矿于晚石炭世,该时期火山喷发-岩浆侵入-铁矿近乎同时形成,是同一岩浆-热液事件的不同体现,并推测“晚石炭世火山机构+岩浆侵位+热液蚀变”区是铁矿就位的场所,应当作为重要勘查目标。 展开更多
关键词 阿吾拉勒铁成矿带 智博铁矿 年代学 锆石U-PB年龄 黄铁矿re-os年龄
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吉林省敦化市松江河金(钼)矿床辉钼矿Re-Os年龄及其地质意义
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作者 陈诗戈 顾尚义 +3 位作者 陈原林 徐爱军 郑朝阳 杨晓明 《矿物学报》 CAS CSCD 北大核心 2024年第2期242-252,共11页
松江河金(钼)矿是近十年来发现的产在韧性变形带内的一座中型金矿床(Au资源储量达9 t)。近年来,在松江河矿区五中段至八中段发现大量辉钼矿分布,至少延深至九中段,从五中至八中段钼矿化具有明显的增强趋势。为确定钼成矿时代,文章利用... 松江河金(钼)矿是近十年来发现的产在韧性变形带内的一座中型金矿床(Au资源储量达9 t)。近年来,在松江河矿区五中段至八中段发现大量辉钼矿分布,至少延深至九中段,从五中至八中段钼矿化具有明显的增强趋势。为确定钼成矿时代,文章利用高精度ICP-MS辉钼矿Re-Os同位素测年技术,首次获得了松江河矿床的辉钼矿Re-Os同位素加权平均模式年龄和等时线年龄分别为(167±2.4) Ma和(158±10)Ma,该年龄与前人报道的松江河矿区黄泥河岩体的年龄(164~162 Ma)和五道溜河岩体的年龄(174~172 Ma)误差范围内基本一致,证实了该矿床成矿与成岩作用近于同时发生,且主要在燕山早期的中、晚侏罗世。结合吉林省中东部地区已发表的成岩与成矿年代学资料,文章认为,区内钼多金属矿床形成于燕山期古太平洋板块向欧亚大陆岩石圈俯冲的活动大陆边缘的地球动力学背景。矿床中辉钼矿的ω(Re)为142.74×10^(-6)~217.67×10^(-6),均值为196.58×10^(-6),结合矿床地质特征和成矿岩体及矿石O、S、Pb同位素等证据,文章认为该矿床的成矿物质主要为地幔来源,来自深部的流体可能对该矿床的成矿作用起了重要作用。 展开更多
关键词 辉钼矿 re-os等时线年龄 松江河金(钼)矿床 吉林省中东部
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赣北石门寺钨铜多金属矿床辉钼矿Re-Os同位素年龄及其地质意义
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作者 刘更更 吴颖宸 +2 位作者 魏文凤 严冰 邹志超 《矿物岩石地球化学通报》 CAS CSCD 北大核心 2024年第1期192-210,共19页
为了解赣北石门寺钨铜多金属矿床的钨富集机理及矿床成因,对该矿床中的辉钼矿开展了Re-Os同位素年代学研究。结果显示,6件辉钼矿样品的Re-Os模式年龄为140.2~142.5 Ma,加权平均年龄为(141.37±0.84)Ma(MSWD=0.84),等时线年龄为(141.... 为了解赣北石门寺钨铜多金属矿床的钨富集机理及矿床成因,对该矿床中的辉钼矿开展了Re-Os同位素年代学研究。结果显示,6件辉钼矿样品的Re-Os模式年龄为140.2~142.5 Ma,加权平均年龄为(141.37±0.84)Ma(MSWD=0.84),等时线年龄为(141.79±0.97)Ma(MSWD=1.10),二者在误差范围内一致,可以代表辉钼矿的矿化年龄,指示该矿床的成矿时间为141 Ma左右。对赣北、赣中和赣南地区的成岩成矿年龄进行对比,发现三地的成岩成矿事件在时间上具有连续性。结合区域构造演化历程,本文认为石门寺钨铜多金属矿形成于早白垩世时期的伸展减薄环境。 展开更多
关键词 石门寺钨铜多金属矿床 re-os同位素 成矿年龄 赣北、赣中和赣南
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Pt-Re-Os同位素体系分析技术研究进展
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作者 鲍厚银 李杰 《地球化学》 CAS CSCD 北大核心 2024年第4期595-610,共16页
Pt-Os和Re-Os同位素体系(统称Pt-Re-Os同位素体系)在壳–幔和核–幔相互作用、矿床成因、陨石成因、太阳系早期演化等地球科学研究中具有重要应用潜力。由于地质样品中Pt-Re-Os含量极低(pg/g~ng/g级),对其元素含量和同位素组成进行高精... Pt-Os和Re-Os同位素体系(统称Pt-Re-Os同位素体系)在壳–幔和核–幔相互作用、矿床成因、陨石成因、太阳系早期演化等地球科学研究中具有重要应用潜力。由于地质样品中Pt-Re-Os含量极低(pg/g~ng/g级),对其元素含量和同位素组成进行高精度的分析测试极具挑战。本文对Pt-Re-Os同位素化学前处理和质谱测定方法研究进展进行综述。化学前处理方法包括酸溶法、碱熔法、火试金法、Carius管溶样法和HPA-S高温高压釜溶样法等常用的样品消解方法以及Pt-Re-Os的化学分离与纯化技术。重点介绍了负离子热电离质谱法(N-TIMS)和(多接收器)电感耦合等离子体质谱法(ICP-MS和MC-ICP-MS)测试Pt-Re-Os元素含量及同位素组成的原理、标准物质和测量精度,以及近年来高精度Os同位素质谱测定中O同位素校正、质量分馏校正、多原子干扰和提高灵敏度等质谱分析技术研究进展。与Re-Os同位素分析技术相比,Pt-Os同位素分析技术还存在困难,国内Pt-Os同位素分析技术仍处于起步阶段。本综述可为Pt-Re-Os同位素分析方法研究提供参考,从而推动国内Pt-Re-Os同位素地球化学研究的发展。 展开更多
关键词 re-os同位素 Pt-Os同位素 消解 化学分离 质谱测量
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缅甸Wunto-Popa岩浆弧Shangalon铜金矿床辉钼矿Re-Os同位素测年及其地质意义
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作者 冷秋锋 吴松洋 +2 位作者 刘书生 聂飞 张彬 《沉积与特提斯地质》 CAS CSCD 北大核心 2024年第2期411-420,共10页
Shangalon铜金矿床位于缅甸Wunto-Popa岩浆弧北段,研究工作薄弱,其成矿地质背景和矿床成因尚缺乏高精度同位素成矿年代学数据的制约。本文选取典型矿石中5件辉钼矿样品通过Re-Os同位素定年方法厘定成矿时代,获得的模式年龄集中变化于38.... Shangalon铜金矿床位于缅甸Wunto-Popa岩浆弧北段,研究工作薄弱,其成矿地质背景和矿床成因尚缺乏高精度同位素成矿年代学数据的制约。本文选取典型矿石中5件辉钼矿样品通过Re-Os同位素定年方法厘定成矿时代,获得的模式年龄集中变化于38.5±0.6至38.3±0.5 Ma,加权平均年龄为38.4±0.2 Ma,对应的等时线年龄为38.0±1.6 Ma(MSWD=0.17),二者在误差范围内基本保持一致,指示Shangalon铜金矿床的成矿时限为始新世,该年龄数据与矿区的含矿闪长岩和花岗闪长岩锆石U-Pb年龄38~40 Ma相吻合,表明Shangalon Cu-Au-Mo成矿作用与始新世闪长岩–花岗闪长岩侵入体密切相关,为始新世岩浆活动的产物。Shangalon铜金矿床辉钼矿样品的Re含量为82.4~111.2μg·g-1,平均值为98.88μg·g-1,指示成矿物质具有壳幔混源的特征。通过综合分析区域成矿动力学背景,认为Shangalon地区始新世铜金成矿作用可能形成于印度与欧亚大陆碰撞背景下的新特提斯洋板片撕裂和断裂,诱发软流圈上涌,新生下地壳部分熔融。 展开更多
关键词 辉钼矿 re-os同位素定年 Shangalon铜金矿床 Wunto-Popa岩浆弧 缅甸
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马达加斯加Maevatanana金矿床Re-Os同位素年龄及其地质意义
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作者 杨喜安 许德如 《岩石矿物学杂志》 CAS CSCD 北大核心 2024年第5期1302-1312,共11页
马达加斯加Maevatanana金矿床是一个产在绿岩带中的石英脉型金矿床,其成因备受争议。本文对其进行了元素地球化学分析和测年,探讨了金矿床的成矿时代和成矿过程。马达加斯加Maevatanana片麻岩金含量为1.11×10^(-9)~80.8×10^(-... 马达加斯加Maevatanana金矿床是一个产在绿岩带中的石英脉型金矿床,其成因备受争议。本文对其进行了元素地球化学分析和测年,探讨了金矿床的成矿时代和成矿过程。马达加斯加Maevatanana片麻岩金含量为1.11×10^(-9)~80.8×10^(-9),平均值19.55×10^(-9);片麻岩中黄铁矿为主要载金矿物,黄铁矿Re-Os同位素等时线年龄为752±27 Ma。含金石英脉金品位26.44×10^(-6)~132.22×10^(-6),黄铁矿为主要载金矿物,含金石英脉中黄铁矿Re-Os同位素等时线年龄为535±26 Ma,代表了Maevatanana金矿床的成矿年龄。两期黄铁矿Re-Os同位素等时线年龄与泛非造山事件两次碰撞的时间相对应。片麻岩金含量远远高于地壳平均品位,在黄铁矿中可见包裹金,黄铁矿Re-Os同位素等时线年龄表明752±27 Ma花岗岩、辉长岩侵入,马达加斯加地体发生了广泛的绿片岩相到角闪岩相的变质作用,火山沉积岩中的金被活化、迁移、富集形成矿源层。含金石英脉的成矿年龄535±26 Ma和马达加斯加中北部寒武纪后碰撞A型花岗岩的年龄一致,野外证据和地球化学数据表明Maevatanana金矿床和寒武纪后碰撞A型花岗岩有密切的成因联系。在岩浆上升过程中,岩浆逐渐演化形成成矿流体,这些成矿流体进入容矿构造,富集成矿。 展开更多
关键词 黄铁矿 re-os同位素 成矿年龄 Maevatanana金矿床 马达加斯加
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