Fabrication of Gd2O2S：Pr scintillation ceramics by 2Gd2O3.（Gd,Pr）2（SO4）3.mH2O precursor was made Gd2O3, Pr6O11 and H2SO4 as the starting materials pressureless reaction sintering was investigated. The by hydrothe...Fabrication of Gd2O2S：Pr scintillation ceramics by 2Gd2O3.（Gd,Pr）2（SO4）3.mH2O precursor was made Gd2O3, Pr6O11 and H2SO4 as the starting materials pressureless reaction sintering was investigated. The by hydrothermal reaction using commercially available Then single phase Gd2O2SO4：Pr powder was obtained by calcining the precursor at 750℃ for 2 h. The Gd2O2SO4：Pr powder compacts can be sintered to single phase Gd2O2S：Pr ceramics with a relative density of 99% and mean grain size of 30um at 1750℃ for 2 h in flowing hydrogen atmosphere. Densification and microstructural development of the Gd2O2S：Pr ceramics were examined. Luminescence spectra of the Gd2O2S：Pr ceramic under 309 nm UV excitation and X-ray excitation show a green emission at 511 nm as the most prominent peak, which corresponds to the ^3p0-3H4 transition of Pr^3＋ ions.展开更多
Tailoring of the composition of the scintillation ceramics Gd_(x)Ce_(0.03)Al_(2)Ga_(3)O_(12)(x=2.89-3.07) heavily doped with Ce was performed.The co-precipitation is found to be quite a useful method to provide a purp...Tailoring of the composition of the scintillation ceramics Gd_(x)Ce_(0.03)Al_(2)Ga_(3)O_(12)(x=2.89-3.07) heavily doped with Ce was performed.The co-precipitation is found to be quite a useful method to provide a purpo seful deviation of Gd content from the stoichio metric ratio in powders for their further compacting and sintering in the air.The effect of the composition variations on microstructure,phase composition,luminescent and scintillation characteristics is demonstrated.It is shown that Gd content below the stoichiometric composition leads to increasing the grain size but,quenching of the photoluminescence and the scintillation,whereas excess Gd leads to higher luminosity;the maximum value is obtained for the composition with an excess of Gd ~2%.Ceramics possess a light yield of -50000 ph/MeV,effective scintillation kinetics of 50 ns,and is a good candidate for application in a new generation of scanners utilizing pulsed X-ray sources.展开更多
基金supported by the National Natural Sci-ence Foundation of China (Grant. No. 50672014)the National Science Fund for Distinguished Young Scholars,China (Grant No. 50425413)
文摘Fabrication of Gd2O2S：Pr scintillation ceramics by 2Gd2O3.（Gd,Pr）2（SO4）3.mH2O precursor was made Gd2O3, Pr6O11 and H2SO4 as the starting materials pressureless reaction sintering was investigated. The by hydrothermal reaction using commercially available Then single phase Gd2O2SO4：Pr powder was obtained by calcining the precursor at 750℃ for 2 h. The Gd2O2SO4：Pr powder compacts can be sintered to single phase Gd2O2S：Pr ceramics with a relative density of 99% and mean grain size of 30um at 1750℃ for 2 h in flowing hydrogen atmosphere. Densification and microstructural development of the Gd2O2S：Pr ceramics were examined. Luminescence spectra of the Gd2O2S：Pr ceramic under 309 nm UV excitation and X-ray excitation show a green emission at 511 nm as the most prominent peak, which corresponds to the ^3p0-3H4 transition of Pr^3＋ ions.
基金Project supported by the NRC"Kurchatov Institute"(No.2834 dated 09.11.2021)the Russian Federation represented by the Ministry of Education and Science of Russia (Agreement No.075-11-2021-070 dated 19.08.2021)。
文摘Tailoring of the composition of the scintillation ceramics Gd_(x)Ce_(0.03)Al_(2)Ga_(3)O_(12)(x=2.89-3.07) heavily doped with Ce was performed.The co-precipitation is found to be quite a useful method to provide a purpo seful deviation of Gd content from the stoichio metric ratio in powders for their further compacting and sintering in the air.The effect of the composition variations on microstructure,phase composition,luminescent and scintillation characteristics is demonstrated.It is shown that Gd content below the stoichiometric composition leads to increasing the grain size but,quenching of the photoluminescence and the scintillation,whereas excess Gd leads to higher luminosity;the maximum value is obtained for the composition with an excess of Gd ~2%.Ceramics possess a light yield of -50000 ph/MeV,effective scintillation kinetics of 50 ns,and is a good candidate for application in a new generation of scanners utilizing pulsed X-ray sources.
