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Electrophoretic Deposition of TiO2/Nb2O5 Composite Electrode Thin Films for Photovoltaic Application 被引量:1
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作者 John Njagi Nguu Bernard Odhiambo Aduda Francis Wanjala Nyongesa Robinson Juma Musembi 《Journal of Energy and Power Engineering》 2014年第4期757-764,共8页
Nano sized powders of TiO2 (titanium dioxide) and Nb2O5 (Niobium (V) oxide) were used to fabricate TiO2/Nb2O5 composites thin films by EPD (electrophoretic deposition) technique. The metal oxide powders, toget... Nano sized powders of TiO2 (titanium dioxide) and Nb2O5 (Niobium (V) oxide) were used to fabricate TiO2/Nb2O5 composites thin films by EPD (electrophoretic deposition) technique. The metal oxide powders, together with magnesium nitrate hexahydrate pellets, were suspended in propan-2-ol inside an EPD cell. The electrodes, placed 1.2 cm apart, were partially immersed in the suspension and a DC potential applied across them. Key EPD process parameters, which include applied DC electric field, deposition time and solid concentration in suspension, were optimized through visual inspection and from UV-Vis-NIR spectrophotometer spectra. The highest (55%) transmittance was obtained for films with deposition time of 90 s, powder concentration of 0.01 g/40 mL, and 35 V DC (direct current) voltage. XRD micrographs confirmed that TiO2 and Nb2O5 particles were presented in the composite film. SEM (scanning electron microscope) micrographs of the composite electrode thin films showed that porous films of high quality with well controlled morphology were deposited by using the EPD technique. 展开更多
关键词 Electrophoretic deposition tio2/Nb2O5 composite electrode thin films.
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Electrically enhanced photodegradation of an azodye(Acid Orange II) using a Pt/TiO_2 film electrode irradiating with an UV lamp
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作者 SUJing CHENGuo-hua 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2003年第1期60-64,共5页
A photoelectrochemical process in the degradation of an azodye (Acid Orange II) on a Pt/TiO 2 film electrode was investigated. By using the glass device and the voltage stabilized source of direct current, decoloriza... A photoelectrochemical process in the degradation of an azodye (Acid Orange II) on a Pt/TiO 2 film electrode was investigated. By using the glass device and the voltage stabilized source of direct current, decolorization ratios higher than 78% were observed during a period of 5h. Comparing this value with the sum of the decolorization ratios obtained by a sole application of electrochemical(lower than 3%) and photochemical(about 23%) procedures, a significant synergic effect between both processes was observed. The effects of adscititious voltage and pH value on the decolorization ratios were obvious while the effect of the amount of aeration was minor. 展开更多
关键词 photoelectrochemical process Pt/TiO 2 film electrode synergic effect
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