In terms of special geological conditions of the Western Route of South-to-North Water Transfer Project, the classification method for surrounding rocks is discussed by combining with the construction method of tunnel...In terms of special geological conditions of the Western Route of South-to-North Water Transfer Project, the classification method for surrounding rocks is discussed by combining with the construction method of tunnel boring machine （TBM）. The classification standard of surrounding rocks is put forward on the basis of physical simulations and engineering practices. Damage, deformation and evolution of surrounding rocks induced by TBM excavation are discussed. Meanwhile, the long-term deformation mechanisms and stability of surrounding rocks are also studied. On this basis, a three-dimensional constitutive model for interbedded sandstone slate and a fiat shell-joint element-foundation system for calculating internal forces of segment lining are established. The deformation features of surrounding rocks of deep and steep interbedded sandstone slate and their influences on internal forces of segment lining are presented. Finally, the design methods of segment lining constructed in deep and steep flysch are proposed.展开更多
This paper assess the eco-environmental benefits that may come from the middle route project of China's South-North Water Transfer Scheme(SNWT) with principles and methods of eco-economics and planning reports of ...This paper assess the eco-environmental benefits that may come from the middle route project of China's South-North Water Transfer Scheme(SNWT) with principles and methods of eco-economics and planning reports of SNWT's middle route project. Some benefits were calculated in monetary units. To make sure that the results can be comparable with normal monetary indices, concrete assessment objects and the parameters are prudently selected according to the major characteristics of the project and its water import region. Primary assessment revealed that in different project construction stages, the benefit could be more than 13 07 billion RMB Yuan in 2010 and 19 79 billion RMB Yuan in 2030, respectively. The monetary value tends to increase with social-economic development. To realize these potential benefits, however, calls for more endeavors.展开更多
It is well known that there is abundant water resources in basin of the Yangtze River, the first largest river in China, which is mainly located in Southern China. However, water resources is very scarce in the basin ...It is well known that there is abundant water resources in basin of the Yangtze River, the first largest river in China, which is mainly located in Southern China. However, water resources is very scarce in the basin of the Yellow River, which is mainly located in Northern China. So the western route project of south-north water transfer scheme （WRP-SNWTS） aims to transfer water from the Yangtze River to the Yellow River. The area of WRP-SNWT, located in the upper reaches of the Yangtze River and the main areas of Sichuan and the marginal areas of the Qinghai-Tibet Plateau, has sufficient water resources but fragile ecology and environment. Therefore, it is necessary for WRP-SNWT to analyze the ecology water required. Based on the planning principles of from low elevation to high elevation, from small to large, from short to long and from easy to difficulty, the WRP-SNWT will be constructed through three stage projects. The western route first stage project of the south-north water transfer scheme （WRFST-SNWTS） is planned to transfer 4×10^9m^3/a from six tributaries of the Yalong river and from Dadu river to Jiaqu of Yellow River.. Daqu river and Niqu river are the branches of Xianshui river. Sequ river, Duke river, Make river and Ake river are the branches of Dadu river, which account for 65-70% of the total river run-off. It need more research and the rest run-off can satisfy channel ecology water required. According to analysis ecological water required which mainly satisfy for aquicolous biology in water-exporting region, such as low air temperature. Fish and aquicolous biology main living from May to August, and rivers are iced up from December to March of next year, ecology water required mainly for fish and aquicolous biology. The flow criterion of Tennant method is modified. The ecology water required of WRFSP-SNWTS is estimated by the flow data of Zhuwo gauging station, Zhuba gauging station, Chuosijia gauging station and Zumuzu gauging station. The result show that the ecology water required calculated by modified Tennant less 1 l percent than that of Tennant. This estimating result can supply more water resources for transferring to Yellow River. Meanwhile, this can supply gist for research transferring water of WRFSP-SNWTS.展开更多
The unsteady flow in the Middle Route South-to-North Water Transfer Channel was simulated numerically using an implicit solution procedure for the Saint Venant equations. An equivalent roughness was used to simulate t...The unsteady flow in the Middle Route South-to-North Water Transfer Channel was simulated numerically using an implicit solution procedure for the Saint Venant equations. An equivalent roughness was used to simulate the effect of many transfer structures on the water levels in the main channel. Various gate operating and control methods were analyzed to study the response to disturbances produced by varying the flow rates through the Tianjin outlet. The results show that when the inflow at the head changes in the same way as the sum of the flow rates through all the outlets, the transition time and the fluctuation of the water levels using the timed gate operation method are less than when using the simultaneous gate operation method, but the variations of the gate openings and flow rates through each control gate are much larger. The flow disturbances produced by the Tianjin outlet can be rectified within several channel sections and the transition time can be greatly shortened by allowing the water levels immediately upstream of the control gates to vary within proscribed ranges, rather than being held constant.展开更多
The combination of SiC quantum dots sensitized inverse opal TiO_(2) photocatalyst is designed in this work and then applied in wastewater purification under simulated sunlight.From various spectroscopic techniques,it ...The combination of SiC quantum dots sensitized inverse opal TiO_(2) photocatalyst is designed in this work and then applied in wastewater purification under simulated sunlight.From various spectroscopic techniques,it is found that electrons transfer directionally from SiC quantum dots to inverse opal TiO_(2),and the energy difference between their conduction/valence bands can reduce the recombination rate of photogenerated carriers and provide a pathway with low interfacial resistance for charge transfer inside the composite.As a result,a typical type-II mechanism is proved to dominate the photoinduced charge transfer process.Meanwhile,the composite achieves excellent photocatalytic performances(the highest apparent kinetic constant of 0.037 min^(-1)),which is 6.2 times(0.006 min^(-1))and 2.1 times(0.018 min^(-1))of the bare inverse opal TiO_(2) and commercial P25 photocatalysts.Therefore,the stability and non-toxicity of SiC quantum dots sensitized inverse opal TiO_(2) composite enables it with great potential in practical photocatalytic applications.展开更多
The low separation/migration efficiency is a major obstacle that limits the practical application of semiconductor-photocatalysts. Constructing S-scheme heterojunction is an ideal strategy for providing high photocata...The low separation/migration efficiency is a major obstacle that limits the practical application of semiconductor-photocatalysts. Constructing S-scheme heterojunction is an ideal strategy for providing high photocatalytic activity via accelerating charge separation. Herein, an AgPO/CNcomposite was synthesized by coupling AgPOparticle with CNhollow spheres in-situ via a precipitation method. The S-scheme hete-rojunction between AgPOand CNcould accelerate the charge separation and retain high photoredox ability, which synchronously realized high photocatalytic oxygen production and hexavalent chromium reduction. The optimized Ag3PO4/CNcomposite shows a high oxygen production rate up to 803.31 μmol·g·hand a high conversion(87.9%) of Cr(Ⅵ) to Cr(Ⅲ). In addition, CNhollow spheres affords higher reaction efficiency than that of CNtube, CNbulk and CNsheet, which indicates that the hollow sphere structure can provide more active sites and adsorption sites in the photocatalytic process. This work offers an effective way in developing a dual-function S-scheme heterojunction for clean energy production and environmental protection.展开更多
The operation of reservoir(s) has a certain impact on the downstream hydrologic regime,and even endangers the ecological water safety of river corridor and ecosystems which interact with river system.Therefore,ecologi...The operation of reservoir(s) has a certain impact on the downstream hydrologic regime,and even endangers the ecological water safety of river corridor and ecosystems which interact with river system.Therefore,ecological operation needs to be carried out in order to ensure ecological water use of downstream zone.The key technological support is the estimation and integrated calculation of ecological water demand.The connotation of the integrated calculation on ecological water demand lies on that the ecological water demand of different ecosystems is integrated to meet the requirements of water allocation and operation on watershed scale in terms of hydrological cycle.Considering the practical requirement of ecological operation of reservoir(s),this study proposed an integrated calculation approach of ecological water demand according to the ecological water demand in various ecosystems as well as the hydraulic connection among them;it established an integrated calculation model of regional ecological water demand by means of the distributed hydrological model,and studied the integrated calculation in Yalong River basin which is the source area of the west route of South-North Water Transfer Project as an example.The results indicated that the integrated calculation model more effectively combined the ecological water demand and hydraulic connection of ecosystems in time and space,compared with the lumped water balance analysis,since the former conquered the defect of insufficient ecological water source and supplement on multiple spatial and temporal scales,and met the demand of ecological operation of reservoir(s).展开更多
基金Supported by the National Key Technology R&D Program in the 11th Five-year Plan of China (2006BAB04A06)
文摘In terms of special geological conditions of the Western Route of South-to-North Water Transfer Project, the classification method for surrounding rocks is discussed by combining with the construction method of tunnel boring machine （TBM）. The classification standard of surrounding rocks is put forward on the basis of physical simulations and engineering practices. Damage, deformation and evolution of surrounding rocks induced by TBM excavation are discussed. Meanwhile, the long-term deformation mechanisms and stability of surrounding rocks are also studied. On this basis, a three-dimensional constitutive model for interbedded sandstone slate and a fiat shell-joint element-foundation system for calculating internal forces of segment lining are established. The deformation features of surrounding rocks of deep and steep interbedded sandstone slate and their influences on internal forces of segment lining are presented. Finally, the design methods of segment lining constructed in deep and steep flysch are proposed.
文摘This paper assess the eco-environmental benefits that may come from the middle route project of China's South-North Water Transfer Scheme(SNWT) with principles and methods of eco-economics and planning reports of SNWT's middle route project. Some benefits were calculated in monetary units. To make sure that the results can be comparable with normal monetary indices, concrete assessment objects and the parameters are prudently selected according to the major characteristics of the project and its water import region. Primary assessment revealed that in different project construction stages, the benefit could be more than 13 07 billion RMB Yuan in 2010 and 19 79 billion RMB Yuan in 2030, respectively. The monetary value tends to increase with social-economic development. To realize these potential benefits, however, calls for more endeavors.
文摘It is well known that there is abundant water resources in basin of the Yangtze River, the first largest river in China, which is mainly located in Southern China. However, water resources is very scarce in the basin of the Yellow River, which is mainly located in Northern China. So the western route project of south-north water transfer scheme （WRP-SNWTS） aims to transfer water from the Yangtze River to the Yellow River. The area of WRP-SNWT, located in the upper reaches of the Yangtze River and the main areas of Sichuan and the marginal areas of the Qinghai-Tibet Plateau, has sufficient water resources but fragile ecology and environment. Therefore, it is necessary for WRP-SNWT to analyze the ecology water required. Based on the planning principles of from low elevation to high elevation, from small to large, from short to long and from easy to difficulty, the WRP-SNWT will be constructed through three stage projects. The western route first stage project of the south-north water transfer scheme （WRFST-SNWTS） is planned to transfer 4×10^9m^3/a from six tributaries of the Yalong river and from Dadu river to Jiaqu of Yellow River.. Daqu river and Niqu river are the branches of Xianshui river. Sequ river, Duke river, Make river and Ake river are the branches of Dadu river, which account for 65-70% of the total river run-off. It need more research and the rest run-off can satisfy channel ecology water required. According to analysis ecological water required which mainly satisfy for aquicolous biology in water-exporting region, such as low air temperature. Fish and aquicolous biology main living from May to August, and rivers are iced up from December to March of next year, ecology water required mainly for fish and aquicolous biology. The flow criterion of Tennant method is modified. The ecology water required of WRFSP-SNWTS is estimated by the flow data of Zhuwo gauging station, Zhuba gauging station, Chuosijia gauging station and Zumuzu gauging station. The result show that the ecology water required calculated by modified Tennant less 1 l percent than that of Tennant. This estimating result can supply more water resources for transferring to Yellow River. Meanwhile, this can supply gist for research transferring water of WRFSP-SNWTS.
基金Supported by China Postdoctoral Science Foundation (No. 20060390078)
文摘The unsteady flow in the Middle Route South-to-North Water Transfer Channel was simulated numerically using an implicit solution procedure for the Saint Venant equations. An equivalent roughness was used to simulate the effect of many transfer structures on the water levels in the main channel. Various gate operating and control methods were analyzed to study the response to disturbances produced by varying the flow rates through the Tianjin outlet. The results show that when the inflow at the head changes in the same way as the sum of the flow rates through all the outlets, the transition time and the fluctuation of the water levels using the timed gate operation method are less than when using the simultaneous gate operation method, but the variations of the gate openings and flow rates through each control gate are much larger. The flow disturbances produced by the Tianjin outlet can be rectified within several channel sections and the transition time can be greatly shortened by allowing the water levels immediately upstream of the control gates to vary within proscribed ranges, rather than being held constant.
基金partially supported by the National Natural Science Foundation of China(Grant Nos.51402161,51373086,21606140,and 21776147)the Natural Science Foundation of Shandong Province(Grant No.ZR2021YQ32)the Taishan Scholar Project of Shandong Province(tsqn201909117).
文摘The combination of SiC quantum dots sensitized inverse opal TiO_(2) photocatalyst is designed in this work and then applied in wastewater purification under simulated sunlight.From various spectroscopic techniques,it is found that electrons transfer directionally from SiC quantum dots to inverse opal TiO_(2),and the energy difference between their conduction/valence bands can reduce the recombination rate of photogenerated carriers and provide a pathway with low interfacial resistance for charge transfer inside the composite.As a result,a typical type-II mechanism is proved to dominate the photoinduced charge transfer process.Meanwhile,the composite achieves excellent photocatalytic performances(the highest apparent kinetic constant of 0.037 min^(-1)),which is 6.2 times(0.006 min^(-1))and 2.1 times(0.018 min^(-1))of the bare inverse opal TiO_(2) and commercial P25 photocatalysts.Therefore,the stability and non-toxicity of SiC quantum dots sensitized inverse opal TiO_(2) composite enables it with great potential in practical photocatalytic applications.
基金supported by the National Natural Science Foundation of China(21975110,21972058 and 22102064)the financial support from Taishan Youth Scholar Program of Shandong Province。
文摘The low separation/migration efficiency is a major obstacle that limits the practical application of semiconductor-photocatalysts. Constructing S-scheme heterojunction is an ideal strategy for providing high photocatalytic activity via accelerating charge separation. Herein, an AgPO/CNcomposite was synthesized by coupling AgPOparticle with CNhollow spheres in-situ via a precipitation method. The S-scheme hete-rojunction between AgPOand CNcould accelerate the charge separation and retain high photoredox ability, which synchronously realized high photocatalytic oxygen production and hexavalent chromium reduction. The optimized Ag3PO4/CNcomposite shows a high oxygen production rate up to 803.31 μmol·g·hand a high conversion(87.9%) of Cr(Ⅵ) to Cr(Ⅲ). In addition, CNhollow spheres affords higher reaction efficiency than that of CNtube, CNbulk and CNsheet, which indicates that the hollow sphere structure can provide more active sites and adsorption sites in the photocatalytic process. This work offers an effective way in developing a dual-function S-scheme heterojunction for clean energy production and environmental protection.
基金supported by the Foundation for Innovative Research Groups of the National Natural Science Foundation of China (Grant No. 51021066)the State Key Development Program for Basic Research of China (Grant No. 2010CB951102)
文摘The operation of reservoir(s) has a certain impact on the downstream hydrologic regime,and even endangers the ecological water safety of river corridor and ecosystems which interact with river system.Therefore,ecological operation needs to be carried out in order to ensure ecological water use of downstream zone.The key technological support is the estimation and integrated calculation of ecological water demand.The connotation of the integrated calculation on ecological water demand lies on that the ecological water demand of different ecosystems is integrated to meet the requirements of water allocation and operation on watershed scale in terms of hydrological cycle.Considering the practical requirement of ecological operation of reservoir(s),this study proposed an integrated calculation approach of ecological water demand according to the ecological water demand in various ecosystems as well as the hydraulic connection among them;it established an integrated calculation model of regional ecological water demand by means of the distributed hydrological model,and studied the integrated calculation in Yalong River basin which is the source area of the west route of South-North Water Transfer Project as an example.The results indicated that the integrated calculation model more effectively combined the ecological water demand and hydraulic connection of ecosystems in time and space,compared with the lumped water balance analysis,since the former conquered the defect of insufficient ecological water source and supplement on multiple spatial and temporal scales,and met the demand of ecological operation of reservoir(s).
