The recovery of metals from a multi-component alloy obtained by crushing, melting and anodic dissolution of waste from electric and electronic equipment（WEEE） was investigated. The anodic dissolution of the alloy wa...The recovery of metals from a multi-component alloy obtained by crushing, melting and anodic dissolution of waste from electric and electronic equipment（WEEE） was investigated. The anodic dissolution of the alloy was carried out in an electrolysis cell with one copper cathode and a central cast anode, immersed in the electrolyte formed by choline chloride-ethylene glycol-iodine. The temperature of the electrolyte during the process was 343 K. Depending on the electrolysis parameters（current density and cell voltage）, cathodic deposits of Sn, Pb and Zn of 〉99% purity were obtained. Cyclic voltammetry was used in order to determine the deposition potentials of the studied metals. The obtained metallic deposits were subject of determination of XRD, SEM/EDX and AFM in order to evidence the deposits structure and morphology. The experiments performed demonstrated the possibility of separating/selective recovery of metals from the multi-component alloy resulted from the waste from electrical and electronic equipment by anodic dissolution in ionic liquids.展开更多
A comparison of three hydrometallurgical methods for selective recovery of copper from low-grade electric and electronic wastes was reported. Scraps were smelted to produce Cu？Zn？Sn？Ag alloy. Multiphase material wa...A comparison of three hydrometallurgical methods for selective recovery of copper from low-grade electric and electronic wastes was reported. Scraps were smelted to produce Cu？Zn？Sn？Ag alloy. Multiphase material was analyzed by SEM？EDS and XRD. The alloy was dissolved anodically with simultaneous metal electrodeposition using ammoniacal and sulfuric acid solutions or leached in ammonia？ammonium sulfate solution and then copper electrowinning was carried out. This resulted in the separation of metals, where lead, silver and tin accumulated mainly in the slimes, while copper was transferred to the electrolyte and then recovered on the cathode. The best conditions of the alloy treatment were obtained in the sulfuric acid, where the final product was metal of high purity （99% Cu） at the current efficiency of 90%. Ammoniacal leaching of the alloy led to the accumulation of copper ions in the electrolyte and further metal electrowinning, but the rate of the spontaneous dissolution was low. Anodic dissolution of the alloy in the ammonia？ammonium sulfate solution led to the unfavorable distribution of metals among the slime, electrolyte and cathodic deposit.展开更多
In addition to maximizing economic benefits, reverse supply chains should further seek to maximize social benefits by increasing the quantity of waste electrical and electronic equipment （WEEE）. The paper investigat...In addition to maximizing economic benefits, reverse supply chains should further seek to maximize social benefits by increasing the quantity of waste electrical and electronic equipment （WEEE）. The paper investigates cooperative models with different parties in a three-echelon reverse supply chain for WEEE consisting of a single collector, a single remanufacturer, and two retailers based on complete information. In acldition, the optimal decisions of four cooperative models and the effect of the market demand of remanufactured WEEE products and the market share of two retailers on the optimal decisions are discussed. The results indicate that optimal total channel profit and recycle quantity in a reverse supply chain are maximized in a centralized model. The optimal total channel profit and recycle quantity increase with an increase in the market demand of remanufactured WEEE products. The three-echelon reverse supply chain consisting of duopolistic retailers maximizes total channel profit and recycle quantity in a reverse supply chain fbr WEEE.展开更多
Given the challenge of estimating or calculating quantities of waste electrical and electronic equipment(WEEE)in developing countries,this article focuses on predicting the WEEE generated by Cameroonian small and medi...Given the challenge of estimating or calculating quantities of waste electrical and electronic equipment(WEEE)in developing countries,this article focuses on predicting the WEEE generated by Cameroonian small and medium enterprises(SMEs)that are engaged in ISO 14001:2015 initiatives and consume electrical and electronic equipment(EEE)to enhance their performance and profitability.The methodology employed an exploratory approach involving the application of general equilibrium theory(GET)to contextualize the study and generate relevant parameters for deploying the random forest regression learning algorithm for predictions.Machine learning was applied to 80%of the samples for training,while simulation was conducted on the remaining 20%of samples based on quantities of EEE utilized over a specific period,utilization rates,repair rates,and average lifespans.The results demonstrate that the model’s predicted values are significantly close to the actual quantities of generated WEEE,and the model’s performance was evaluated using the mean squared error(MSE)and yielding satisfactory results.Based on this model,both companies and stakeholders can set realistic objectives for managing companies’WEEE,fostering sustainable socio-environmental practices.展开更多
针对现有保有量废弃电器电子产品(waste electrical and electronic equipment,WEEE)预测模型的不足,给出了基于中等区域尺度下考虑梯次利用影响的WEEE预测模型,预测模型中家用电器电子产品(electrical and electronic equipment,EEE)...针对现有保有量废弃电器电子产品(waste electrical and electronic equipment,WEEE)预测模型的不足,给出了基于中等区域尺度下考虑梯次利用影响的WEEE预测模型,预测模型中家用电器电子产品(electrical and electronic equipment,EEE)的废弃规律采用Weilbull分布函数并按照实际修正,使得预测结果更加贴合实际。开展上海市“四机一脑”废弃量实证分析,采用现有模型验证,结果表明该WEEE预测模型可较好地预测中等区域尺度下WEEE的废弃量,为WEEE后续管理提供科学依据。展开更多
China stands as one of the leading producers of waste electrical and electronic equipment(WEEE),facing significant challenges in managing the substantial volumes generated.Despite existing regulations,the informal tre...China stands as one of the leading producers of waste electrical and electronic equipment(WEEE),facing significant challenges in managing the substantial volumes generated.Despite existing regulations,the informal treatment of WEEE persists in some areas due to inadequate recycling networks at the city level.Consequently,there is a critical need for a detailed geographical mapping of WEEE generation to address improper disposal practices effectively.This study introduces the cMAC–EEEs(city Material Cycles and Manufactured Capital–EEEs)database,providing estimates of WEEE generation across approximately 300 prefecture-level cities from 1978 to 2017.It focuses on five commonly used types of electrical and electronic equipment(refrigerators,air conditioners,washing machines,computers,TVs)originating from three key sources(urban residents,rural residents,enterprises).The findings reveal(1)significant spatial variation in WEEE generation within China,with eastern and central city clusters identified as hotspots,particularly for urban residents and enterprises,while the western region exhibits the highest growth rate in WEEE generation,notably among rural residents.(2)The growth in obsolete computers and air conditioners is prominent,especially in rural areas and among enterprises,whereas the generation of obsolete TVs,washing machines,and refrigerators is leveling off and expected to decrease in some urban areas.(3)Enterprises account for a substantial portion of WEEE generation,though uncertainties exist,necessitating further refinement.The study highlights that less developed regions lack adequate recycling facilities,with specific limitations in refrigerators and air conditioners recycling capabilities.To enhance WEEE management,it advocates for increased interregional collaboration and capacity building in less developed areas.Additionally,the regulation of WEEE from private enterprises requires improvement.At the product level,a greater focus on recycling practices for refrigerators and air conditioners is recommended.展开更多
文摘The recovery of metals from a multi-component alloy obtained by crushing, melting and anodic dissolution of waste from electric and electronic equipment（WEEE） was investigated. The anodic dissolution of the alloy was carried out in an electrolysis cell with one copper cathode and a central cast anode, immersed in the electrolyte formed by choline chloride-ethylene glycol-iodine. The temperature of the electrolyte during the process was 343 K. Depending on the electrolysis parameters（current density and cell voltage）, cathodic deposits of Sn, Pb and Zn of 〉99% purity were obtained. Cyclic voltammetry was used in order to determine the deposition potentials of the studied metals. The obtained metallic deposits were subject of determination of XRD, SEM/EDX and AFM in order to evidence the deposits structure and morphology. The experiments performed demonstrated the possibility of separating/selective recovery of metals from the multi-component alloy resulted from the waste from electrical and electronic equipment by anodic dissolution in ionic liquids.
基金Project(NNOTECH-2/IN2/18/181960/NCBR)supported by the National Centre for Research and Development,Poland
文摘A comparison of three hydrometallurgical methods for selective recovery of copper from low-grade electric and electronic wastes was reported. Scraps were smelted to produce Cu？Zn？Sn？Ag alloy. Multiphase material was analyzed by SEM？EDS and XRD. The alloy was dissolved anodically with simultaneous metal electrodeposition using ammoniacal and sulfuric acid solutions or leached in ammonia？ammonium sulfate solution and then copper electrowinning was carried out. This resulted in the separation of metals, where lead, silver and tin accumulated mainly in the slimes, while copper was transferred to the electrolyte and then recovered on the cathode. The best conditions of the alloy treatment were obtained in the sulfuric acid, where the final product was metal of high purity （99% Cu） at the current efficiency of 90%. Ammoniacal leaching of the alloy led to the accumulation of copper ions in the electrolyte and further metal electrowinning, but the rate of the spontaneous dissolution was low. Anodic dissolution of the alloy in the ammonia？ammonium sulfate solution led to the unfavorable distribution of metals among the slime, electrolyte and cathodic deposit.
基金This work was supported by the National Natural Science Foundation of China （Grant No. 71471105）.
文摘In addition to maximizing economic benefits, reverse supply chains should further seek to maximize social benefits by increasing the quantity of waste electrical and electronic equipment （WEEE）. The paper investigates cooperative models with different parties in a three-echelon reverse supply chain for WEEE consisting of a single collector, a single remanufacturer, and two retailers based on complete information. In acldition, the optimal decisions of four cooperative models and the effect of the market demand of remanufactured WEEE products and the market share of two retailers on the optimal decisions are discussed. The results indicate that optimal total channel profit and recycle quantity in a reverse supply chain are maximized in a centralized model. The optimal total channel profit and recycle quantity increase with an increase in the market demand of remanufactured WEEE products. The three-echelon reverse supply chain consisting of duopolistic retailers maximizes total channel profit and recycle quantity in a reverse supply chain fbr WEEE.
文摘Given the challenge of estimating or calculating quantities of waste electrical and electronic equipment(WEEE)in developing countries,this article focuses on predicting the WEEE generated by Cameroonian small and medium enterprises(SMEs)that are engaged in ISO 14001:2015 initiatives and consume electrical and electronic equipment(EEE)to enhance their performance and profitability.The methodology employed an exploratory approach involving the application of general equilibrium theory(GET)to contextualize the study and generate relevant parameters for deploying the random forest regression learning algorithm for predictions.Machine learning was applied to 80%of the samples for training,while simulation was conducted on the remaining 20%of samples based on quantities of EEE utilized over a specific period,utilization rates,repair rates,and average lifespans.The results demonstrate that the model’s predicted values are significantly close to the actual quantities of generated WEEE,and the model’s performance was evaluated using the mean squared error(MSE)and yielding satisfactory results.Based on this model,both companies and stakeholders can set realistic objectives for managing companies’WEEE,fostering sustainable socio-environmental practices.
文摘针对现有保有量废弃电器电子产品(waste electrical and electronic equipment,WEEE)预测模型的不足,给出了基于中等区域尺度下考虑梯次利用影响的WEEE预测模型,预测模型中家用电器电子产品(electrical and electronic equipment,EEE)的废弃规律采用Weilbull分布函数并按照实际修正,使得预测结果更加贴合实际。开展上海市“四机一脑”废弃量实证分析,采用现有模型验证,结果表明该WEEE预测模型可较好地预测中等区域尺度下WEEE的废弃量,为WEEE后续管理提供科学依据。
基金supported by the Strategic Pilot Science and Technology Projects of Chinese Academy of Sciences(XDA23030304)the National Natural Science Foundation of China(Grant Nos.52200214,71961147003,and 52070178)+1 种基金Key Program of Frontier Science of the Chinese Academy of Sciences(QYZDB-SSW-DQC012)the China Scholarship Council(Grant No.201904910422).
文摘China stands as one of the leading producers of waste electrical and electronic equipment(WEEE),facing significant challenges in managing the substantial volumes generated.Despite existing regulations,the informal treatment of WEEE persists in some areas due to inadequate recycling networks at the city level.Consequently,there is a critical need for a detailed geographical mapping of WEEE generation to address improper disposal practices effectively.This study introduces the cMAC–EEEs(city Material Cycles and Manufactured Capital–EEEs)database,providing estimates of WEEE generation across approximately 300 prefecture-level cities from 1978 to 2017.It focuses on five commonly used types of electrical and electronic equipment(refrigerators,air conditioners,washing machines,computers,TVs)originating from three key sources(urban residents,rural residents,enterprises).The findings reveal(1)significant spatial variation in WEEE generation within China,with eastern and central city clusters identified as hotspots,particularly for urban residents and enterprises,while the western region exhibits the highest growth rate in WEEE generation,notably among rural residents.(2)The growth in obsolete computers and air conditioners is prominent,especially in rural areas and among enterprises,whereas the generation of obsolete TVs,washing machines,and refrigerators is leveling off and expected to decrease in some urban areas.(3)Enterprises account for a substantial portion of WEEE generation,though uncertainties exist,necessitating further refinement.The study highlights that less developed regions lack adequate recycling facilities,with specific limitations in refrigerators and air conditioners recycling capabilities.To enhance WEEE management,it advocates for increased interregional collaboration and capacity building in less developed areas.Additionally,the regulation of WEEE from private enterprises requires improvement.At the product level,a greater focus on recycling practices for refrigerators and air conditioners is recommended.
