The environmental concerns resulting from coal-fired power generation that produces large amounts of CO_(2)and fly ash are of great interest.To mitigate,this study aims to develop a novel carbonated CO_(2)-fly ash-bas...The environmental concerns resulting from coal-fired power generation that produces large amounts of CO_(2)and fly ash are of great interest.To mitigate,this study aims to develop a novel carbonated CO_(2)-fly ash-based backfill(CFBF)material under ambient conditions.The performance of CFBF was investigated for different fly ash-cement ratios and compared with non-CO_(2)reacted samples.The fresh CFBF slurry conformed to the Herschel-Bulkley model with shear thinning characteristics.After carbonation,the yield stress of the fresh slurry increased significantly by lowering fly ash ratio due to gel formation.The setting times were accelerated,resulting in approximately 40.6%of increased early strength.The final strength decreased when incorporating a lower fly ash ratio(50%and 60%),which was related to the existing heterogeneous pores caused by rapid fluid loss.The strength increased with fly ash content above 70%because additional C-S(A)-H and silica gels were characterized to precipitate on the grain surface,so the binding between particles increased.The C-S(A)-H gel was developed through the pozzolanic reaction,where CaCO_(3)was the prerequisite calcium source obtained in the CO_(2)-fly ash reaction.Furthermore,the maximum CO_(2)uptake efficiency was 1.39 mg-CO_(2)/g-CFBF.The CFBF material is feasible to co-dispose CO_(2)and fly ash in the mine goaf as negative carbon backfill materials,and simultaneously mitigates the strata movement and water lost in post-subsurface mining.展开更多
As a kind of green concrete,the mechanical properties and durability of cemented gangue backfill material(CGBM)will be affected if they are in acid mine water with sulfate ions in the long term.To improve the performa...As a kind of green concrete,the mechanical properties and durability of cemented gangue backfill material(CGBM)will be affected if they are in acid mine water with sulfate ions in the long term.To improve the performance of CGBM in acid mine water with sulfate ions,CGBM specimens with different doses of barium hydroxide were immersed in sulfuric acid solutions of different concentrations for 270 days.The changes of mass,ultrasonic pulse velocity(UPV)and compressive strength of the specimens at different ages were analyzed.Scanning electron microscopy(SEM)and X-ray diffraction(XRD)were used to analyze the microstructure and composition of the specimens.The results show that incorporation of barium hydroxide into CGBM specimen can promote the formation of barium sulfate precipitation and inhibit the generation of corrosion products such as ettringite.Meanwhile,barium sulfate precipitation blocks the pore channel invaded by sulfuric acid solution,delaying the progress of corrosion reaction and making the interior of CGBM specimen more complete.And the specimen with 2.0 kg/m^(3)barium hydroxide was more effective in improving performance.This study provides a basis for the ratio design of CGBM in acid mine water with sulfate ions.展开更多
The backfill-mining mass ratio is the ratio of the mass of the backfill materials in the goaf to the mass of the produced raw coal during solid backfill mining and it is regarded as a direct control index of the backf...The backfill-mining mass ratio is the ratio of the mass of the backfill materials in the goaf to the mass of the produced raw coal during solid backfill mining and it is regarded as a direct control index of the backfill effect in solid backfill mining. To design the backfill-mining mass ratio in a solid backfill mining panel, the backfill-mining mass ratio was defined on the basis of the basic principle of solid backfill mining. In addition, the density-stress relationship of backfill materials under compaction was obtained for five types of materials to derive a design formula for backfill-mining mass ratio. Moreover, the 6304-1 backfill panel under the large-scale dam of Ji′ning No. 3 coal mine was taken as an engineering case to design the backfill-mining mass ratio. In this way, it is found that the designed backfill-mining mass ratio is 1.22, while the mean value of the measured backfill-mining mass ratio is 1.245. Besides, the maximum roof subsidence is only 340 mm which effectively guarantees the backfill effect in the panel and control of strata movement and surface subsidence.展开更多
The use of materials from waste in buildings compensates for the lack of natural resources, solves the problem of waste management and provides an altern<span style="font-family:Verdana;">ative techniq...The use of materials from waste in buildings compensates for the lack of natural resources, solves the problem of waste management and provides an altern<span style="font-family:Verdana;">ative technique for protection of the environment. There are a lar</span><span style="font-family:Verdana;">ge number of industrial wastes that are used for full or partial replacement of raw materials in some construction materials. This review assesses mining waste in concrete as a substitute for aggregates and cement;in fired bricks as a substitute for soil;and in road backfill as a substitute for soil. This paper reviews some mining tailings, mine waste rocks and some slags obtained in the exploitation and/or processing of some ores including iron, gold, lead, phosphate, copper, coal, etc. Different physical properties, mechanical properties, chemical properties, heavy metal content, mineralogic composition, geotechnical properties and environmental properties (leaching test) of the mine wastes were examined. The physical, mechanical and environmental properties of the materials obtained by substitution of raw materials by mine waste were examined and compared to reference materials. Mining waste in cementitious materials offers good compressive strengths, while the porosity of the concrete and/or mortar is a factor influencing its toxicity. As for the waste in fired bricks, fired at a temperature of 900°</span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;">C</span><span style="font-family:Verdana;"> or more, it offers convincing compressive and flexural strengths. The few research studies obtained on the use of mining waste in road embankments have shown that mining waste can be used as a sub-base layer and backfill as long as it is not toxic. In addition, several other mining wastes require special attention as substitutes for raw materials in construction materials, such as coltan, cobalt.</span></span></span></span>展开更多
Through changing the axial load on backfilling material compaction test to reflect different overlying strata pressure on backfilling material, the stress-strain relations in the compaction process of backfilling mate...Through changing the axial load on backfilling material compaction test to reflect different overlying strata pressure on backfilling material, the stress-strain relations in the compaction process of backfilling material under the geological condition can be obtained. Based on the characteristic of overlying strata movement in backfill mining, a model of roof thin plate is established. By introducing the stress-strain relation in compaction process into the model and using RIZT method to analyze the bending deformation of roof, the bending deflection and stress distribution can be obtained. The results show that the maximum roof subsidence and maximum tensile stress occurring at the center are 255 mm and5 MPa, respectively. Tensile fracture of roof under the geological condition of Dongping Mine did not occur. The dynamic measurement results of roof in Dongping Mine verify the theoretical result from the aforementioned model, thereby suggesting the roof mechanical model is reliable. The roof thin plate model based on the compaction characteristic of backfilling material in this study is of importance to research on backfill mining theories and application of backfilling material characteristics.展开更多
A methodology for identifying and calibrating the material parameters for a coupled hydro-mechanical problem is presented in this pape r.For validation purpose,a laboratory-based water infiltration test was numericall...A methodology for identifying and calibrating the material parameters for a coupled hydro-mechanical problem is presented in this pape r.For validation purpose,a laboratory-based water infiltration test was numerically simulated using finite element method(FEM).The test was conducted using a self-designed column-type experimental device,which mimicked the wetting process of a candidate backfill material in a nuclear waste repository.The real-time measurements of key state variables(e.g.water content,relative humidity,temperature,and total stresses)were performed with the monitoring sensors along the height of cylindrical soil sample.For numerical simulation,the modified Barcelona Basic Model(BBM)along with soil-water retention model for compacted bentonite was used.It shows that the identified model parameters successfully captured the moisture migration process under an applied hydraulic gradient in a bentonite-based compacted soil sample.A comparison between the measured and predicted values of total stresses both in axial and lateral directions along with other state variables revealed that heterogeneous moisture content was distributed along the hydration-path,resulting in non-uniform stress-deformation characteristics of soil.展开更多
基金The authors would like to make an appreciation to the National Natural Science Foundation of China(No.51874280)the Fundamental Research Funds of the Central Universities(No.2021ZDPY0211)for financial support.
文摘The environmental concerns resulting from coal-fired power generation that produces large amounts of CO_(2)and fly ash are of great interest.To mitigate,this study aims to develop a novel carbonated CO_(2)-fly ash-based backfill(CFBF)material under ambient conditions.The performance of CFBF was investigated for different fly ash-cement ratios and compared with non-CO_(2)reacted samples.The fresh CFBF slurry conformed to the Herschel-Bulkley model with shear thinning characteristics.After carbonation,the yield stress of the fresh slurry increased significantly by lowering fly ash ratio due to gel formation.The setting times were accelerated,resulting in approximately 40.6%of increased early strength.The final strength decreased when incorporating a lower fly ash ratio(50%and 60%),which was related to the existing heterogeneous pores caused by rapid fluid loss.The strength increased with fly ash content above 70%because additional C-S(A)-H and silica gels were characterized to precipitate on the grain surface,so the binding between particles increased.The C-S(A)-H gel was developed through the pozzolanic reaction,where CaCO_(3)was the prerequisite calcium source obtained in the CO_(2)-fly ash reaction.Furthermore,the maximum CO_(2)uptake efficiency was 1.39 mg-CO_(2)/g-CFBF.The CFBF material is feasible to co-dispose CO_(2)and fly ash in the mine goaf as negative carbon backfill materials,and simultaneously mitigates the strata movement and water lost in post-subsurface mining.
基金sponsored by the National Natural Science Foundation of China(Grant No.51974192)the Distinguished Youth Funds of National Natural Science Foundation of China(Grant No.51925402)Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Project(2021SX-TD001).
文摘As a kind of green concrete,the mechanical properties and durability of cemented gangue backfill material(CGBM)will be affected if they are in acid mine water with sulfate ions in the long term.To improve the performance of CGBM in acid mine water with sulfate ions,CGBM specimens with different doses of barium hydroxide were immersed in sulfuric acid solutions of different concentrations for 270 days.The changes of mass,ultrasonic pulse velocity(UPV)and compressive strength of the specimens at different ages were analyzed.Scanning electron microscopy(SEM)and X-ray diffraction(XRD)were used to analyze the microstructure and composition of the specimens.The results show that incorporation of barium hydroxide into CGBM specimen can promote the formation of barium sulfate precipitation and inhibit the generation of corrosion products such as ettringite.Meanwhile,barium sulfate precipitation blocks the pore channel invaded by sulfuric acid solution,delaying the progress of corrosion reaction and making the interior of CGBM specimen more complete.And the specimen with 2.0 kg/m^(3)barium hydroxide was more effective in improving performance.This study provides a basis for the ratio design of CGBM in acid mine water with sulfate ions.
基金Project(51421003)supported by the Foundation for Innovative Research Groups of the National Natural Science Foundation of ChinaProject(2014ZDPY02)supported by the Fundamental Research Funds for the Central Universities,China
文摘The backfill-mining mass ratio is the ratio of the mass of the backfill materials in the goaf to the mass of the produced raw coal during solid backfill mining and it is regarded as a direct control index of the backfill effect in solid backfill mining. To design the backfill-mining mass ratio in a solid backfill mining panel, the backfill-mining mass ratio was defined on the basis of the basic principle of solid backfill mining. In addition, the density-stress relationship of backfill materials under compaction was obtained for five types of materials to derive a design formula for backfill-mining mass ratio. Moreover, the 6304-1 backfill panel under the large-scale dam of Ji′ning No. 3 coal mine was taken as an engineering case to design the backfill-mining mass ratio. In this way, it is found that the designed backfill-mining mass ratio is 1.22, while the mean value of the measured backfill-mining mass ratio is 1.245. Besides, the maximum roof subsidence is only 340 mm which effectively guarantees the backfill effect in the panel and control of strata movement and surface subsidence.
文摘The use of materials from waste in buildings compensates for the lack of natural resources, solves the problem of waste management and provides an altern<span style="font-family:Verdana;">ative technique for protection of the environment. There are a lar</span><span style="font-family:Verdana;">ge number of industrial wastes that are used for full or partial replacement of raw materials in some construction materials. This review assesses mining waste in concrete as a substitute for aggregates and cement;in fired bricks as a substitute for soil;and in road backfill as a substitute for soil. This paper reviews some mining tailings, mine waste rocks and some slags obtained in the exploitation and/or processing of some ores including iron, gold, lead, phosphate, copper, coal, etc. Different physical properties, mechanical properties, chemical properties, heavy metal content, mineralogic composition, geotechnical properties and environmental properties (leaching test) of the mine wastes were examined. The physical, mechanical and environmental properties of the materials obtained by substitution of raw materials by mine waste were examined and compared to reference materials. Mining waste in cementitious materials offers good compressive strengths, while the porosity of the concrete and/or mortar is a factor influencing its toxicity. As for the waste in fired bricks, fired at a temperature of 900°</span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;">C</span><span style="font-family:Verdana;"> or more, it offers convincing compressive and flexural strengths. The few research studies obtained on the use of mining waste in road embankments have shown that mining waste can be used as a sub-base layer and backfill as long as it is not toxic. In addition, several other mining wastes require special attention as substitutes for raw materials in construction materials, such as coltan, cobalt.</span></span></span></span>
基金financial assistance provided by the National Natural Science Foundation of China(No.51304206)China Postdoctoral Science Foundation funded project(No.2015M580492)
文摘Through changing the axial load on backfilling material compaction test to reflect different overlying strata pressure on backfilling material, the stress-strain relations in the compaction process of backfilling material under the geological condition can be obtained. Based on the characteristic of overlying strata movement in backfill mining, a model of roof thin plate is established. By introducing the stress-strain relation in compaction process into the model and using RIZT method to analyze the bending deformation of roof, the bending deflection and stress distribution can be obtained. The results show that the maximum roof subsidence and maximum tensile stress occurring at the center are 255 mm and5 MPa, respectively. Tensile fracture of roof under the geological condition of Dongping Mine did not occur. The dynamic measurement results of roof in Dongping Mine verify the theoretical result from the aforementioned model, thereby suggesting the roof mechanical model is reliable. The roof thin plate model based on the compaction characteristic of backfilling material in this study is of importance to research on backfill mining theories and application of backfilling material characteristics.
基金the German Research Foundation(DFG)for the financial support(Grant No.SCHA 675/17-1)。
文摘A methodology for identifying and calibrating the material parameters for a coupled hydro-mechanical problem is presented in this pape r.For validation purpose,a laboratory-based water infiltration test was numerically simulated using finite element method(FEM).The test was conducted using a self-designed column-type experimental device,which mimicked the wetting process of a candidate backfill material in a nuclear waste repository.The real-time measurements of key state variables(e.g.water content,relative humidity,temperature,and total stresses)were performed with the monitoring sensors along the height of cylindrical soil sample.For numerical simulation,the modified Barcelona Basic Model(BBM)along with soil-water retention model for compacted bentonite was used.It shows that the identified model parameters successfully captured the moisture migration process under an applied hydraulic gradient in a bentonite-based compacted soil sample.A comparison between the measured and predicted values of total stresses both in axial and lateral directions along with other state variables revealed that heterogeneous moisture content was distributed along the hydration-path,resulting in non-uniform stress-deformation characteristics of soil.
