Fouling caused by excess metal ions in hard water can negatively impact the performance of the circulating cooling water system(CCWS)by depositing ions on the heat exchanger's surface.Currently,the operation optim...Fouling caused by excess metal ions in hard water can negatively impact the performance of the circulating cooling water system(CCWS)by depositing ions on the heat exchanger's surface.Currently,the operation optimization of CCWS often prioritizes short-term flow velocity optimization for minimizing power consumption,without considering fouling.However,low flow velocity promotes fouling.Therefore,it's crucial to balance fouling and energy/water conservation for optimal CCWS long-term operation.This study proposes a mixed-integer nonlinear programming(MINLP)model to achieve this goal.The model considers fouling in the pipeline,dynamic concentration cycle,and variable frequency drive to optimize the synergy between heat transfer,pressure drop,and fouling.By optimizing the concentration cycle of the CCWS,water conservation and fouling control can be achieved.The model can obtain the optimal operating parameters for different operation intervals,including the number of pumps,frequency,and valve local resistance coefficient.Sensitivity experiments on cycle and environmental temperature reveal that as the cycle increases,the marginal benefits of energy/water conservation decrease.In periods with minimal impact on fouling rate,energy/water conservation can be achieved by increasing the cycle while maintaining a low fouling rate.Overall,the proposed model has significant energy/water saving effects and can comprehensively optimize the CCWS through its incorporation of fouling and cycle optimization.展开更多
In the process of production or processing of materials by various methods,there is a need for a large volume of water of the required quality.Today in many regions of the world,there is an acute problem of providing ...In the process of production or processing of materials by various methods,there is a need for a large volume of water of the required quality.Today in many regions of the world,there is an acute problem of providing industry with water of a required quality.Its solution is an urgent and difficult task.The water quality of surface water bodies is formed by a combination of a large number of both natural and anthropogenic factors,and is often significantly heterogeneous not only in the water area,but also in depth.As a rule,the water supply of large industrial enterprises is located along the river network.Mergers are the most important nodes of river systems.Understanding the mechanism of transport of pollutants at the confluence of rivers is critical for assessing water quality.In recent years,thanks to the data of satellite images,the interest of researchers in the phenomenon of mixing the waters of merging rivers has increased.The nature of the merger is influenced by the formation of transverse circulation.Within the framework of this work,a study of vorticity,as well as the width of the mixing zone,depending on the distance from the confluence,the speeds of the merging rivers and the angle of confluence was carried out.Since the consumer properties of water are largely determined by its chemical and physical indicators,the intensity of mixing,determined largely by the nature of the secondary circulation,is of fundamental importance for assessing the distribution of hydrochemical indicators of water quality in the mixing zone.These characteristics are important not only for organizing water intake for drinking and technical purposes with the best consumer properties,but also for organizing an effective monitoring system for confluence zones.展开更多
Aniline is a vital industrial raw material.However,highly-toxic aniline wastewater usually deteriorated effluent quality,posed a threat to human health and ecosystem safety.Therefore,this study reported a novel intern...Aniline is a vital industrial raw material.However,highly-toxic aniline wastewater usually deteriorated effluent quality,posed a threat to human health and ecosystem safety.Therefore,this study reported a novel internal circulation iron-carbon micro-electrolysis(ICE)reactor to treat aniline wastewater.The effects of reaction time,pH,aeration rate and iron-carbon(Fe/C)ratio on the removal rate of aniline and the chemical oxygen demand were investigated using single-factor experiments.This process exhibited high aniline degradation performance of approximately 99.86% under optimal operating conditions(reaction time=20 min,pH=3,aeration rate=0.5 m3·h^(-1),and Fe/C=1:2).Based on the experimental results,the response surface method was applied to optimize the aniline removal rate.The Box–Behnken method was used to obtain the interaction effects of three main factors.The result showed that the reaction time had a dominant effect on the removal rate of aniline.The highest aniline removal rate was obtained at pH of 2,aeration rate of 0.5 m^(3)·h^(-1)and reaction time of 30 min.Under optional experimental conditions,the aniline content of effluent was reduced to 3 mg·L^(-1)and the removal rate was as high as 98.24%,within the 95% confidence interval(97.84%-99.32%)of the predicted values.The solution was treated and the reaction intermediates were identified by high-performance liquid chromatography,ultraviolet-visible spectroscopy,Fourier-transform infrared spectroscopy,gas chromatography-mass spectrometry,and ion chromatography.The main intermediates were phenol,benzoquinone,and carboxylic acid.These were used to propose the potential mechanism of aniline degradation in the ICE reactor.The results obtained in this study provide optimized conditions for the treatment of industrial wastewater containing aniline and can strengthen the understanding of the degradation mechanism of iron-carbon micro-electrolysis.展开更多
In order to investigate the effect of sampling frequency and time on pressure fluctuations, the three-dimensional unsteady numerical simulations were conducted in a circulating water pump. Through comparison of turbul...In order to investigate the effect of sampling frequency and time on pressure fluctuations, the three-dimensional unsteady numerical simulations were conducted in a circulating water pump. Through comparison of turbulence models with hydraulic performance experiment, SST k-co model was confirmed to study the rational determination of sampling frequency and time better. The Fast Fourier Transform （FFT） technology was then adopted to process those fluctuating pressure signals obtained. On these bases, the characteristics of pressure fluctuations acting on the tongue were discussed. It is found that aliasing errors decrease at higher sampling frequency of 17 640 Hz, but not at a lower sampling frequency of 1 764 Hz. Correspondingly, an output frequency range ten-times wider is obtained at 17 640 Hz. Compared with 8R, when the sampling time is shorter, the amplitudes may be overvalued, and the frequencies and amplitudes of low-frequency fluctuations can not be well predicted. The frequencies at the tongue are in good agreement with the values calculated by formula and the frequency compositions less than the blade passing frequency are accurately predicted.展开更多
The corrosion inhibition performance of co-immobilized lysozyme and lipase was investigated in a recirculating cooling water system. Four methods were carried out in co-immobilization, and the operating parameters wer...The corrosion inhibition performance of co-immobilized lysozyme and lipase was investigated in a recirculating cooling water system. Four methods were carried out in co-immobilization, and the operating parameters were optimized by using the respond surface methodology(RSM). The corrosion inhibition performance of co-immobilized lipase and lysozyme was evaluated by weight loss measurements and electrochemical measurements. The results revealed that the optimal co-immobilization method should be the sequential immobilization of lysozyme and then lipase. The inhibition efficiency was 86.10% under the optimal co-immobilized conditions. Electrochemical data showed that co-immobilized lysozyme and lipase was a mixed-type inhibitor and the corrosion inhibition efficiency was 81%.展开更多
Recent research on deterministic methods for circulating cooling water systems optimization has been well developed. However, the actual operating conditions of the system are mostly variable, so the system obtained u...Recent research on deterministic methods for circulating cooling water systems optimization has been well developed. However, the actual operating conditions of the system are mostly variable, so the system obtained under deterministic conditions may not be stable and economical. This paper studies the optimization of circulating cooling water systems under uncertain circumstance. To improve the reliability of the system and reduce the water and energy consumption, the influence of different uncertain parameters is taken into consideration. The chance constrained programming method is used to build a model under uncertain conditions, where the confidence level indicates the degree of constraint violation. Probability distribution functions are used to describe the form of uncertain parameters. The objective is to minimize the total cost and obtain the optimal cooling network configuration simultaneously.An algorithm based on Monte Carlo method is proposed, and GAMS software is used to solve the mixed integer nonlinear programming model. A case is optimized to verify the validity of the model. Compared with the deterministic optimization method, the results show that when considering the different types of uncertain parameters, a system with better economy and reliability can be obtained(total cost can be reduced at least 2%).展开更多
This paper presents a systematic model test program to assess the uncertainty of the ship-bank interaction forces,using the planar motion mechanism(PMM)system in a circulating water channel(CWC).Therefore,the uncertai...This paper presents a systematic model test program to assess the uncertainty of the ship-bank interaction forces,using the planar motion mechanism(PMM)system in a circulating water channel(CWC).Therefore,the uncertainties due to ship-bank distance and water depth are considered,and they are calculated via the partial differentials of the regression formulae based on the test data.The general part of the uncertainty analysis(UA)is performed according to the ITTC recommended procedure 7.5-02-06.04,while the uncertainty of speed is identified as the bias limit due to the flow velocity maldistribution in the CWC.In each example test for the UA of ship-bank interaction forces,12 repeated measurements were conducted.Results from the UA show that the contribution of water depth error and flow velocity maldistribution to the total uncertainty is noticeable,and the paper explains how they increase with the change of the test conditions.The present study will be useful in understanding the uncertainty regarding the ship-bank interaction force measurement in a CWC.展开更多
MIC is one of the main problems of circulating cooling water system. The direct economic loss by MIC is about 300 to 500 billion dollars. It is good to understand MIC in order to control MIC. Source and species of mic...MIC is one of the main problems of circulating cooling water system. The direct economic loss by MIC is about 300 to 500 billion dollars. It is good to understand MIC in order to control MIC. Source and species of microorganisms was introduced firstly. There are three kinds of microorganisms in the system, including bacteria, fungi and algae. Species of these microorganisms are shown in the paper. Then, mechanisms of MIC are analysed. Although there is no universal mechanism of MIC, MIC is still mainly an electrochemical corrosion in nature. Meanwhile, the mechanisms on SRB and iron bacteria are introduced in details. At last, several methods of microorganisms control are put forward in the paper.展开更多
In order to solve the problems including pipe corrosion, scaling and microbial growth, which severely threat safe op-eration of circulating cooling water system, this paper proposes ion exchange softening and alkaliza...In order to solve the problems including pipe corrosion, scaling and microbial growth, which severely threat safe op-eration of circulating cooling water system, this paper proposes ion exchange softening and alkalization process to solve these problems and carries out a series of studies to study the feasibility of ion exchange softening and alkaliza-tion process in the simulation process of circulating cooling water system. The studies include product water quality of ion exchange softening and alkalization process, effect on the performance of carbon steel and brass, and the inhibition that suppresses microbial growth. The results indicate that ion exchange softening and alkalization process is feasible to prevent the circulating cooling water system from scaling, pipe corrosion, and microbial growth without any other chemicals. Thus circulating cooling water system can achieve zerodischarge of wastewater.展开更多
Mesoporous SiO_2 microspheres were synthesized using the sol-gel method and were characterized by TEM, FT-IR and BET techniques. The diameter of the microspheres is about 100—150 nm, and the average mesopore diameter...Mesoporous SiO_2 microspheres were synthesized using the sol-gel method and were characterized by TEM, FT-IR and BET techniques. The diameter of the microspheres is about 100—150 nm, and the average mesopore diameter is 2.55 nm, while the specific surface area is 1 088.9 m2/g. Mesoporous SiO_2 microspheres adsorb glutaraldehyde and immobilize laccase by means of the aldehyde group in glutaral which can react with the amidogen of laccase. The immobilization conditions were optimized at a glutaraldehyde concentration of 0.75%, a crosslinking time of 8 h, a laccase concentration of 0.04 L/L and an immobilization time of 10 h. When diesel leakage concentration was 80 mg/L, the highest corrosion inhibition efficiency of immobilized laccase reached 49.23%, which was slightly lower than the corrosion inhibition efficiency of free laccase(59%). The diesel degradation ratio could reach up to 45%. It has been proved that the immobilized laccase could degrade diesel to inhibit corrosion.展开更多
In the past 20 a, the gulf-scale circulation in the Beibu Gulf has been commonly accepted to be driven by a wind stress or density gradient. However, using three sensitive experiments based on a three-dimensional baro...In the past 20 a, the gulf-scale circulation in the Beibu Gulf has been commonly accepted to be driven by a wind stress or density gradient. However, using three sensitive experiments based on a three-dimensional baroclinic model that was verified by observations, the formation mechanisms were revealed： the circula- tion in the northern Beibu Gulf was triggered by the monsoon wind throughout a year; whereas the southern gulf circulation was driven by the monsoon wind and South China Sea （SCS） circulation in winter and sum- mer, respectively. The force of heat flux and tidal harmonics had a strong effect on the circulation strength and range, as well as the local circulation structures, but these factors did not influence the major circulation structure in the Beibu Gulf. On the other hand, the Beibu Gulf Cold Water Mass （BGCWM） would disappear without the force of heat flux because the seasonal thermocline layer was generated by the input of heat so that the vertical mixing between the upper hot water and lower cold water was blocked. In addition, the wind-induced cyclonic gyre in the northern gulf was favorable to the existence of the BGCWM. However, the coverage area of the BGCWM was increased slightly without the force of the tidal harmonics. When the model was driven by the monthly averaged surface forcing, the circulation structure was changed to some extent, and the coverage area of the BGCWM almost extended outwards 100%, implying the circulation and water mass in the Beibu Gulf had strong responses to the temporal resolution of the surface forces.展开更多
The hybrid finite analytic(HFA) method is a kind of numerical scheme in rectangular element. In order to simulate the shallow circulation in irregular bathymetry by HFA scheme, the model in sigma coordinate system was...The hybrid finite analytic(HFA) method is a kind of numerical scheme in rectangular element. In order to simulate the shallow circulation in irregular bathymetry by HFA scheme, the model in sigma coordinate system was obtained. The model has been tested against three cases: 1) Wind induced circulation; 2) Density driven circulation and 3) Seiche oscillation. The results obtained in the present study compare well with those obtained from the corresponding analytical solutions under idealized for the above three cases. The hybrid finite analytic method and the circulation model in sigma coordinate system can be used calculate the flow and water quality in estuaries and coastal waters.展开更多
Using hydrographic data covering large areas of ocean for the period from June 21 to July 5 in 2009, we studied the circulation structure in the Luzon Strait area, examined the routes of water exchange between the Sou...Using hydrographic data covering large areas of ocean for the period from June 21 to July 5 in 2009, we studied the circulation structure in the Luzon Strait area, examined the routes of water exchange between the South China Sea （SCS） and the Philippine Sea, and estimated the volume transport through Luzon Strait. We found that the Kuroshio axis follows a e-shaped path slightly east of 121°E in the upper layer. With an increase in depth, the Kuroshio axis became gradually farther from the island of Luzon. To study the water exchange between the Philippine Sea and the SCS, identification of inflows and outflows is necessary. We first identified which flows contributed to the water exchange through Luzon Strait, which differs from the approach taken in previous studies. We determined that the obvious water exchange is in the section of 121°E. The westward inflow from the Philippine Sea into the SCS is 6.39 Sv in volume, and mainly in the 100-500 m layer at 19.5°-20°N （accounting for 4.40 Sv）, while the outflow from the SCS into the Philippine Sea is concentrated in the upper 100 m at 19°-20°N and upper 400 m at 21°-21.5°N, and below 240 m at 19°-19.5°N, accounting for 1.07, 3.02 and 3.43 Sv in volume transport, respectively.展开更多
After water is impounded in a reservoir, rock mass in the hydro-fluctuation belt of the reservoir bank slope is subject to water saturation- dehydration circulation （WSDC）. To quantify the rate of change of rock mec...After water is impounded in a reservoir, rock mass in the hydro-fluctuation belt of the reservoir bank slope is subject to water saturation- dehydration circulation （WSDC）. To quantify the rate of change of rock mechanical properties, samples from the Longtan dam area were measured with uniaxial compression tests after different numbers （1, 5, 10, 15, and 20） of simulated WSDC cycles. Based on the curves derived from these tests, a modified Hock- Brown failure criterion was proposed, in which a new parameter was introduced to model the cumulative damage to rocks after WSDC. A case of an engineering application was analyzed, and the results showed that the modified Hock-Brown failure criterion is useful. Under similar WSDC-influenced engineering and geological conditions, rock mass strength parameters required for analysis and evaluation of rock slope stability can be estimated according to this modified Hoek-Brown failure criterion.展开更多
A lattice Boltzmann (LB) model with overall second-order accuracy is applied to the 1.5-layer shallow water equation for a wind-driven double-gyre ocean circulation. By introducing the second-order integral approximat...A lattice Boltzmann (LB) model with overall second-order accuracy is applied to the 1.5-layer shallow water equation for a wind-driven double-gyre ocean circulation. By introducing the second-order integral approximation for the collision operator, the model becomes fully explicit. In this case, any iterative technique is not needed. The Coriolis force and other external forces are included in the model with second-order accuracy, which is consistent with the discretized accuracy of the LB equation. The numerical results show correct physics of the ocean circulation driven by the double-gyre wind stress with different Reynolds numbers and different spatial resolutions. An intrinsic low-frequency variability of the shallow water model is also found. The wind-driven ocean circulation exhibits subannual and interannual oscillations, which are comparable to those of models in which the conventional numerical methods are used.展开更多
The circulation of Yellow Sea Cold Water Mass （YSCWM） in the Southern Yellow Sea is investigated using a diagnostic 2D MITgcm model. The resolution of the computational grid is 900 m in the horizontal and 2 m in the...The circulation of Yellow Sea Cold Water Mass （YSCWM） in the Southern Yellow Sea is investigated using a diagnostic 2D MITgcm model. The resolution of the computational grid is 900 m in the horizontal and 2 m in the vertical where an initial tem- perature distribution corresponding to a typical measured Yellow Sea Cold Water Mass was applied. The existence of YSCWM that causes fluid density difference, is shown to produce counter-rotating cyclonic horizontal eddies in the surface layer： the inner one is anti-cyclonic （clockwise） and relatively weaker （8-10cms-1） while the outer one is cyclonic （anti-clockwise） and much stronger （15-20cms-~）. This result is consistent with the surface pattern observed by Pang et al. （2004）, who has shown that a mesoscale anti-cyclonic eddy （clockwise） exists in the upper layer of central southern Yellow Sea, and a basin-scale cyclonic （anticlockwise） gyre lies outside of the anti-cyclonic eddy, based on the trajectories and drifting velocities of 23 drifters. Below the thermocline, there is an anti-cyclonic （clockwise） circulation. This complex current eddy system is considered to be capable of trapping suspended sediments and depositing them near the front between YSCWM and the coastal waters off the Subei coast, providing an explanation on the sediment depth and size distribution of mud patches in the Southern Yellow Sea. Moreover, sensitive test scenarios indicate that variations of bottom friction do not substantially change the main features of the circulation structure, but will reduce the bottom current velocity, increase the surface current velocity and weaken the upwelling around the frontal area.展开更多
Data obtained from a comprehensive multidisciplinary oceanographic survey in the central and northern parts of the Taiwan Strait, 24°20′-26°00′N, 118°45°-121°00′E by the Fujian Institute of...Data obtained from a comprehensive multidisciplinary oceanographic survey in the central and northern parts of the Taiwan Strait, 24°20′-26°00′N, 118°45°-121°00′E by the Fujian Institute of Oceanology during the period May, 1983 through May, 1984, showed that the distributions of dissolved oxygen (DO), nitrate, dissolved inorganic phosphate and silicate concentrations here had obvious areal and seasonal characteristics that were mainly influenced by the seasonal circulation ofthree major water systems in the Taiwan Strait-- the Taiwan Strait Warm Water (TSWW), theZhejiang-Fujian Coastal Water (ZFCW), and the Northeastern Strait Warm Water (NESWW).展开更多
In order to solve water resources problems in the North China Plain, this paper explored human-nature compound water circulation system from three aspects including urban flood control, surface drainage and saline wat...In order to solve water resources problems in the North China Plain, this paper explored human-nature compound water circulation system from three aspects including urban flood control, surface drainage and saline water in the central and eastern of the North China Plain. Results show that:(1) The technical methods have achieved zero increase in rainwater runoff in urban areas,(2) surface drainage depletion problems can be solved through abandoned water and river water separation method,(3) and technical method through promoting rainwater infiltration would be used to solve problem of saline water in the central and eastern parts. This research provides a new perspective to the ultimate solutions to water resources problems in the North China Plain, and a fresh research direction for the development of hydro-geological science.展开更多
Based on the characteristic of ‘one river one oasis’ in the arid areas, the Yerqiang River Basin, which is the largest irrigated area of Xinjiang, is taken as an example in this paper, and the regional water circula...Based on the characteristic of ‘one river one oasis’ in the arid areas, the Yerqiang River Basin, which is the largest irrigated area of Xinjiang, is taken as an example in this paper, and the regional water circulation pattern is investigated through the analysis of 60 groups of isotope data in the basin. From the phreatic evaporation data analysis of different soils, we study the law of phreatic evaporation, complete the research of the main consumption path of the groundwater, and improve the assessment precision of water resources. The transformation mount of regional water resources are predicted by calculation, which provides a scientific basis for water resources assessment and allocation in arid regions, and offers a new method for the study of regional water circulation patterns.展开更多
基金Financial support from the National Natural Science Foundation of China (22022816 and 22078358)
文摘Fouling caused by excess metal ions in hard water can negatively impact the performance of the circulating cooling water system(CCWS)by depositing ions on the heat exchanger's surface.Currently,the operation optimization of CCWS often prioritizes short-term flow velocity optimization for minimizing power consumption,without considering fouling.However,low flow velocity promotes fouling.Therefore,it's crucial to balance fouling and energy/water conservation for optimal CCWS long-term operation.This study proposes a mixed-integer nonlinear programming(MINLP)model to achieve this goal.The model considers fouling in the pipeline,dynamic concentration cycle,and variable frequency drive to optimize the synergy between heat transfer,pressure drop,and fouling.By optimizing the concentration cycle of the CCWS,water conservation and fouling control can be achieved.The model can obtain the optimal operating parameters for different operation intervals,including the number of pumps,frequency,and valve local resistance coefficient.Sensitivity experiments on cycle and environmental temperature reveal that as the cycle increases,the marginal benefits of energy/water conservation decrease.In periods with minimal impact on fouling rate,energy/water conservation can be achieved by increasing the cycle while maintaining a low fouling rate.Overall,the proposed model has significant energy/water saving effects and can comprehensively optimize the CCWS through its incorporation of fouling and cycle optimization.
基金financial support from the Government of the Perm Territory within the Framework of Scientific Project No.S-26/828the Ministry of Science and High Education of Russia(Theme No.121031700169-1).
文摘In the process of production or processing of materials by various methods,there is a need for a large volume of water of the required quality.Today in many regions of the world,there is an acute problem of providing industry with water of a required quality.Its solution is an urgent and difficult task.The water quality of surface water bodies is formed by a combination of a large number of both natural and anthropogenic factors,and is often significantly heterogeneous not only in the water area,but also in depth.As a rule,the water supply of large industrial enterprises is located along the river network.Mergers are the most important nodes of river systems.Understanding the mechanism of transport of pollutants at the confluence of rivers is critical for assessing water quality.In recent years,thanks to the data of satellite images,the interest of researchers in the phenomenon of mixing the waters of merging rivers has increased.The nature of the merger is influenced by the formation of transverse circulation.Within the framework of this work,a study of vorticity,as well as the width of the mixing zone,depending on the distance from the confluence,the speeds of the merging rivers and the angle of confluence was carried out.Since the consumer properties of water are largely determined by its chemical and physical indicators,the intensity of mixing,determined largely by the nature of the secondary circulation,is of fundamental importance for assessing the distribution of hydrochemical indicators of water quality in the mixing zone.These characteristics are important not only for organizing water intake for drinking and technical purposes with the best consumer properties,but also for organizing an effective monitoring system for confluence zones.
基金supported by the National Natural Science Foundation of China(21677018)the Joint Fund of the Beijing Municipal Natural Science Foundation and Beijing Municipal Education Commission(KZ201810017024)the Cross-Disciplinary Science Foundation from Beijing Institute of Petrochemical Technology(BIPTCSF–22032205003/014)。
文摘Aniline is a vital industrial raw material.However,highly-toxic aniline wastewater usually deteriorated effluent quality,posed a threat to human health and ecosystem safety.Therefore,this study reported a novel internal circulation iron-carbon micro-electrolysis(ICE)reactor to treat aniline wastewater.The effects of reaction time,pH,aeration rate and iron-carbon(Fe/C)ratio on the removal rate of aniline and the chemical oxygen demand were investigated using single-factor experiments.This process exhibited high aniline degradation performance of approximately 99.86% under optimal operating conditions(reaction time=20 min,pH=3,aeration rate=0.5 m3·h^(-1),and Fe/C=1:2).Based on the experimental results,the response surface method was applied to optimize the aniline removal rate.The Box–Behnken method was used to obtain the interaction effects of three main factors.The result showed that the reaction time had a dominant effect on the removal rate of aniline.The highest aniline removal rate was obtained at pH of 2,aeration rate of 0.5 m^(3)·h^(-1)and reaction time of 30 min.Under optional experimental conditions,the aniline content of effluent was reduced to 3 mg·L^(-1)and the removal rate was as high as 98.24%,within the 95% confidence interval(97.84%-99.32%)of the predicted values.The solution was treated and the reaction intermediates were identified by high-performance liquid chromatography,ultraviolet-visible spectroscopy,Fourier-transform infrared spectroscopy,gas chromatography-mass spectrometry,and ion chromatography.The main intermediates were phenol,benzoquinone,and carboxylic acid.These were used to propose the potential mechanism of aniline degradation in the ICE reactor.The results obtained in this study provide optimized conditions for the treatment of industrial wastewater containing aniline and can strengthen the understanding of the degradation mechanism of iron-carbon micro-electrolysis.
基金Project supported by the Priority Academic Development Program of Jiangsu Higher Education Institutions, ChinaProject(CXZZ12_0680) supported by Postgraduate Innovation Foundation of Jiangsu Province, ChinaProject(12JDG082) supported by the Advanced Talent Foundation of Jiangsu University, China
文摘In order to investigate the effect of sampling frequency and time on pressure fluctuations, the three-dimensional unsteady numerical simulations were conducted in a circulating water pump. Through comparison of turbulence models with hydraulic performance experiment, SST k-co model was confirmed to study the rational determination of sampling frequency and time better. The Fast Fourier Transform （FFT） technology was then adopted to process those fluctuating pressure signals obtained. On these bases, the characteristics of pressure fluctuations acting on the tongue were discussed. It is found that aliasing errors decrease at higher sampling frequency of 17 640 Hz, but not at a lower sampling frequency of 1 764 Hz. Correspondingly, an output frequency range ten-times wider is obtained at 17 640 Hz. Compared with 8R, when the sampling time is shorter, the amplitudes may be overvalued, and the frequencies and amplitudes of low-frequency fluctuations can not be well predicted. The frequencies at the tongue are in good agreement with the values calculated by formula and the frequency compositions less than the blade passing frequency are accurately predicted.
基金financially supported by the National Natural Science Foundation of China (project 21077133)the Natural Foundation of Shandong Province and the Top Talent Project of China University of Petroleum (16RC17040003)
文摘The corrosion inhibition performance of co-immobilized lysozyme and lipase was investigated in a recirculating cooling water system. Four methods were carried out in co-immobilization, and the operating parameters were optimized by using the respond surface methodology(RSM). The corrosion inhibition performance of co-immobilized lipase and lysozyme was evaluated by weight loss measurements and electrochemical measurements. The results revealed that the optimal co-immobilization method should be the sequential immobilization of lysozyme and then lipase. The inhibition efficiency was 86.10% under the optimal co-immobilized conditions. Electrochemical data showed that co-immobilized lysozyme and lipase was a mixed-type inhibitor and the corrosion inhibition efficiency was 81%.
基金Financial support from the National Natural Science Foundation of China (22022816, 22078358)。
文摘Recent research on deterministic methods for circulating cooling water systems optimization has been well developed. However, the actual operating conditions of the system are mostly variable, so the system obtained under deterministic conditions may not be stable and economical. This paper studies the optimization of circulating cooling water systems under uncertain circumstance. To improve the reliability of the system and reduce the water and energy consumption, the influence of different uncertain parameters is taken into consideration. The chance constrained programming method is used to build a model under uncertain conditions, where the confidence level indicates the degree of constraint violation. Probability distribution functions are used to describe the form of uncertain parameters. The objective is to minimize the total cost and obtain the optimal cooling network configuration simultaneously.An algorithm based on Monte Carlo method is proposed, and GAMS software is used to solve the mixed integer nonlinear programming model. A case is optimized to verify the validity of the model. Compared with the deterministic optimization method, the results show that when considering the different types of uncertain parameters, a system with better economy and reliability can be obtained(total cost can be reduced at least 2%).
基金This study is financially supported by the China Ministry of Education Key Research Project“KSHIP-II Project”(Grant No.GKZY010004).
文摘This paper presents a systematic model test program to assess the uncertainty of the ship-bank interaction forces,using the planar motion mechanism(PMM)system in a circulating water channel(CWC).Therefore,the uncertainties due to ship-bank distance and water depth are considered,and they are calculated via the partial differentials of the regression formulae based on the test data.The general part of the uncertainty analysis(UA)is performed according to the ITTC recommended procedure 7.5-02-06.04,while the uncertainty of speed is identified as the bias limit due to the flow velocity maldistribution in the CWC.In each example test for the UA of ship-bank interaction forces,12 repeated measurements were conducted.Results from the UA show that the contribution of water depth error and flow velocity maldistribution to the total uncertainty is noticeable,and the paper explains how they increase with the change of the test conditions.The present study will be useful in understanding the uncertainty regarding the ship-bank interaction force measurement in a CWC.
文摘MIC is one of the main problems of circulating cooling water system. The direct economic loss by MIC is about 300 to 500 billion dollars. It is good to understand MIC in order to control MIC. Source and species of microorganisms was introduced firstly. There are three kinds of microorganisms in the system, including bacteria, fungi and algae. Species of these microorganisms are shown in the paper. Then, mechanisms of MIC are analysed. Although there is no universal mechanism of MIC, MIC is still mainly an electrochemical corrosion in nature. Meanwhile, the mechanisms on SRB and iron bacteria are introduced in details. At last, several methods of microorganisms control are put forward in the paper.
文摘In order to solve the problems including pipe corrosion, scaling and microbial growth, which severely threat safe op-eration of circulating cooling water system, this paper proposes ion exchange softening and alkalization process to solve these problems and carries out a series of studies to study the feasibility of ion exchange softening and alkaliza-tion process in the simulation process of circulating cooling water system. The studies include product water quality of ion exchange softening and alkalization process, effect on the performance of carbon steel and brass, and the inhibition that suppresses microbial growth. The results indicate that ion exchange softening and alkalization process is feasible to prevent the circulating cooling water system from scaling, pipe corrosion, and microbial growth without any other chemicals. Thus circulating cooling water system can achieve zerodischarge of wastewater.
基金supported by the Foundation for Top Talents Program of China University of Petroleum
文摘Mesoporous SiO_2 microspheres were synthesized using the sol-gel method and were characterized by TEM, FT-IR and BET techniques. The diameter of the microspheres is about 100—150 nm, and the average mesopore diameter is 2.55 nm, while the specific surface area is 1 088.9 m2/g. Mesoporous SiO_2 microspheres adsorb glutaraldehyde and immobilize laccase by means of the aldehyde group in glutaral which can react with the amidogen of laccase. The immobilization conditions were optimized at a glutaraldehyde concentration of 0.75%, a crosslinking time of 8 h, a laccase concentration of 0.04 L/L and an immobilization time of 10 h. When diesel leakage concentration was 80 mg/L, the highest corrosion inhibition efficiency of immobilized laccase reached 49.23%, which was slightly lower than the corrosion inhibition efficiency of free laccase(59%). The diesel degradation ratio could reach up to 45%. It has been proved that the immobilized laccase could degrade diesel to inhibit corrosion.
基金The Guangxi Natural Science Foundation under contract No.2012GXNSFEA053001the program of"The Beibu Gulf forecast circulation system construction and its application to the coastal pollution transport"
文摘In the past 20 a, the gulf-scale circulation in the Beibu Gulf has been commonly accepted to be driven by a wind stress or density gradient. However, using three sensitive experiments based on a three-dimensional baroclinic model that was verified by observations, the formation mechanisms were revealed： the circula- tion in the northern Beibu Gulf was triggered by the monsoon wind throughout a year; whereas the southern gulf circulation was driven by the monsoon wind and South China Sea （SCS） circulation in winter and sum- mer, respectively. The force of heat flux and tidal harmonics had a strong effect on the circulation strength and range, as well as the local circulation structures, but these factors did not influence the major circulation structure in the Beibu Gulf. On the other hand, the Beibu Gulf Cold Water Mass （BGCWM） would disappear without the force of heat flux because the seasonal thermocline layer was generated by the input of heat so that the vertical mixing between the upper hot water and lower cold water was blocked. In addition, the wind-induced cyclonic gyre in the northern gulf was favorable to the existence of the BGCWM. However, the coverage area of the BGCWM was increased slightly without the force of the tidal harmonics. When the model was driven by the monthly averaged surface forcing, the circulation structure was changed to some extent, and the coverage area of the BGCWM almost extended outwards 100%, implying the circulation and water mass in the Beibu Gulf had strong responses to the temporal resolution of the surface forces.
文摘The hybrid finite analytic(HFA) method is a kind of numerical scheme in rectangular element. In order to simulate the shallow circulation in irregular bathymetry by HFA scheme, the model in sigma coordinate system was obtained. The model has been tested against three cases: 1) Wind induced circulation; 2) Density driven circulation and 3) Seiche oscillation. The results obtained in the present study compare well with those obtained from the corresponding analytical solutions under idealized for the above three cases. The hybrid finite analytic method and the circulation model in sigma coordinate system can be used calculate the flow and water quality in estuaries and coastal waters.
基金Supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (No. KZCX1-YW-12)the National Natural Science Foundation of China (Nos. 41030855,41006013)
文摘Using hydrographic data covering large areas of ocean for the period from June 21 to July 5 in 2009, we studied the circulation structure in the Luzon Strait area, examined the routes of water exchange between the South China Sea （SCS） and the Philippine Sea, and estimated the volume transport through Luzon Strait. We found that the Kuroshio axis follows a e-shaped path slightly east of 121°E in the upper layer. With an increase in depth, the Kuroshio axis became gradually farther from the island of Luzon. To study the water exchange between the Philippine Sea and the SCS, identification of inflows and outflows is necessary. We first identified which flows contributed to the water exchange through Luzon Strait, which differs from the approach taken in previous studies. We determined that the obvious water exchange is in the section of 121°E. The westward inflow from the Philippine Sea into the SCS is 6.39 Sv in volume, and mainly in the 100-500 m layer at 19.5°-20°N （accounting for 4.40 Sv）, while the outflow from the SCS into the Philippine Sea is concentrated in the upper 100 m at 19°-20°N and upper 400 m at 21°-21.5°N, and below 240 m at 19°-19.5°N, accounting for 1.07, 3.02 and 3.43 Sv in volume transport, respectively.
基金supported by the National Natural Science Foundation of China under No. 41630639the National Basic Research Program of China (2014CB744703)+1 种基金Natural Science Basic Research Plan in Shaanxi Province of China (No. 2016JQ4014)China Postdoctoral Science Foundation (2016M602743)
文摘After water is impounded in a reservoir, rock mass in the hydro-fluctuation belt of the reservoir bank slope is subject to water saturation- dehydration circulation （WSDC）. To quantify the rate of change of rock mechanical properties, samples from the Longtan dam area were measured with uniaxial compression tests after different numbers （1, 5, 10, 15, and 20） of simulated WSDC cycles. Based on the curves derived from these tests, a modified Hock- Brown failure criterion was proposed, in which a new parameter was introduced to model the cumulative damage to rocks after WSDC. A case of an engineering application was analyzed, and the results showed that the modified Hock-Brown failure criterion is useful. Under similar WSDC-influenced engineering and geological conditions, rock mass strength parameters required for analysis and evaluation of rock slope stability can be estimated according to this modified Hoek-Brown failure criterion.
基金The work was supported by the One Hundred Talents Project of the Chinese Academy of Sciences(Grant No.KCL14014)the Impacts of Ocean-Land-Atmosphere Interactions over the East Asian Mon soon Region on the Climate in China(EAMOLA)(Grant No:ZKCX2-SW-210)the National Outstanding Youth Science Foundation of China(Grant No.40325016).
文摘A lattice Boltzmann (LB) model with overall second-order accuracy is applied to the 1.5-layer shallow water equation for a wind-driven double-gyre ocean circulation. By introducing the second-order integral approximation for the collision operator, the model becomes fully explicit. In this case, any iterative technique is not needed. The Coriolis force and other external forces are included in the model with second-order accuracy, which is consistent with the discretized accuracy of the LB equation. The numerical results show correct physics of the ocean circulation driven by the double-gyre wind stress with different Reynolds numbers and different spatial resolutions. An intrinsic low-frequency variability of the shallow water model is also found. The wind-driven ocean circulation exhibits subannual and interannual oscillations, which are comparable to those of models in which the conventional numerical methods are used.
基金funded by the National Natural Science Foundation of China (NSFC) (Grant Nos. 41030856, 51479182 and 51425901)the Open Fund of State Key Laboratory of Hydraulics and Mountain River Engineering (Grant No. SKHL1428)The financial support through a PhD grant awarded to Chunyan Zhou by the University of Dundee, UK is gratefully acknowledged
文摘The circulation of Yellow Sea Cold Water Mass （YSCWM） in the Southern Yellow Sea is investigated using a diagnostic 2D MITgcm model. The resolution of the computational grid is 900 m in the horizontal and 2 m in the vertical where an initial tem- perature distribution corresponding to a typical measured Yellow Sea Cold Water Mass was applied. The existence of YSCWM that causes fluid density difference, is shown to produce counter-rotating cyclonic horizontal eddies in the surface layer： the inner one is anti-cyclonic （clockwise） and relatively weaker （8-10cms-1） while the outer one is cyclonic （anti-clockwise） and much stronger （15-20cms-~）. This result is consistent with the surface pattern observed by Pang et al. （2004）, who has shown that a mesoscale anti-cyclonic eddy （clockwise） exists in the upper layer of central southern Yellow Sea, and a basin-scale cyclonic （anticlockwise） gyre lies outside of the anti-cyclonic eddy, based on the trajectories and drifting velocities of 23 drifters. Below the thermocline, there is an anti-cyclonic （clockwise） circulation. This complex current eddy system is considered to be capable of trapping suspended sediments and depositing them near the front between YSCWM and the coastal waters off the Subei coast, providing an explanation on the sediment depth and size distribution of mud patches in the Southern Yellow Sea. Moreover, sensitive test scenarios indicate that variations of bottom friction do not substantially change the main features of the circulation structure, but will reduce the bottom current velocity, increase the surface current velocity and weaken the upwelling around the frontal area.
文摘Data obtained from a comprehensive multidisciplinary oceanographic survey in the central and northern parts of the Taiwan Strait, 24°20′-26°00′N, 118°45°-121°00′E by the Fujian Institute of Oceanology during the period May, 1983 through May, 1984, showed that the distributions of dissolved oxygen (DO), nitrate, dissolved inorganic phosphate and silicate concentrations here had obvious areal and seasonal characteristics that were mainly influenced by the seasonal circulation ofthree major water systems in the Taiwan Strait-- the Taiwan Strait Warm Water (TSWW), theZhejiang-Fujian Coastal Water (ZFCW), and the Northeastern Strait Warm Water (NESWW).
基金funded by National Key Basic Research Program of China(2010CB428800),Geological Survey(20023064)(12120113102400)
文摘In order to solve water resources problems in the North China Plain, this paper explored human-nature compound water circulation system from three aspects including urban flood control, surface drainage and saline water in the central and eastern of the North China Plain. Results show that:(1) The technical methods have achieved zero increase in rainwater runoff in urban areas,(2) surface drainage depletion problems can be solved through abandoned water and river water separation method,(3) and technical method through promoting rainwater infiltration would be used to solve problem of saline water in the central and eastern parts. This research provides a new perspective to the ultimate solutions to water resources problems in the North China Plain, and a fresh research direction for the development of hydro-geological science.
文摘Based on the characteristic of ‘one river one oasis’ in the arid areas, the Yerqiang River Basin, which is the largest irrigated area of Xinjiang, is taken as an example in this paper, and the regional water circulation pattern is investigated through the analysis of 60 groups of isotope data in the basin. From the phreatic evaporation data analysis of different soils, we study the law of phreatic evaporation, complete the research of the main consumption path of the groundwater, and improve the assessment precision of water resources. The transformation mount of regional water resources are predicted by calculation, which provides a scientific basis for water resources assessment and allocation in arid regions, and offers a new method for the study of regional water circulation patterns.
