Based on the charge storage mode,it is important to investigate the scaling dependence of memory performance in silicon nanocrystal（Si-NC） nonvolatile memory（NVM） devices for its scaling down limit.In this work,we...Based on the charge storage mode,it is important to investigate the scaling dependence of memory performance in silicon nanocrystal（Si-NC） nonvolatile memory（NVM） devices for its scaling down limit.In this work,we made eight kinds of test key cells with different gate widths and lengths by 0.13-μm node complementary metal oxide semiconductor（CMOS） technology.It is found that the memory windows of eight kinds of test key cells are almost the same of about1.64 V @ ±7 V/1 ms,which are independent of the gate area,but mainly determined by the average size（12 nm） and areal density（1.8×10^（11）/cm^2） of Si-NCs.The program/erase（P/E） speed characteristics are almost independent of gate widths and lengths.However,the erase speed is faster than the program speed of test key cells,which is due to the different charging behaviors between electrons and holes during the operation processes.Furthermore,the data retention characteristic is also independent of the gate area.Our findings are useful for further scaling down of Si-NC NVM devices to improve the performance and on-chip integration.展开更多
The micro modeling for electric vehicle and its solution were investigated. A new car-following model for electric vehicle was proposed based on the existing car-following models. The impacts of the electric vehicle&#...The micro modeling for electric vehicle and its solution were investigated. A new car-following model for electric vehicle was proposed based on the existing car-following models. The impacts of the electric vehicle's charging electricity were studied from the numerical perspective. The numerical results show that the electric vehicle's charging electricity will destroy the stability of uniform flow and produce some prominent queues and these traffic phenomena are directly related to the initial headway, the distance between two adjacent charging stations and the number of charging stations. The above results can help traffic engineer to choose the position of charging station and the electric vehicle's driver to adjust his/her driving behavior in the traffic system with charging station.展开更多
This study addresses a new charging station network planning problem for smart connected electric vehicles.We embed a charging station choice model into a charging network planning model that explicitly considers the ...This study addresses a new charging station network planning problem for smart connected electric vehicles.We embed a charging station choice model into a charging network planning model that explicitly considers the heterogeneity of the charging behavior in a data-driven manner.To cope with the deficiencies from a small size and sparse behavioral data,we propose a robust charging demand prediction method that can significantly reduce the impact of sample errors and missing data.On the basis of these two building blocks,we form and solve a new optimal charging station location and capacity problem by minimizing the construction and charging costs while considering the charging service level,construction budget,and limit to the number of chargers.We use a case study of planning charging stations in Shanghai to validate our contributions and provide managerial insight in this area.展开更多
Band engineering based on the construction of solid solutions is an effective approach to enhance the efficiency of semiconductor photocatalysts, via which the balance between light absorption and driving force can be...Band engineering based on the construction of solid solutions is an effective approach to enhance the efficiency of semiconductor photocatalysts, via which the balance between light absorption and driving force can be well achieved by continuously tuning the band structure. Here the ZnS1–xSex nanobelt solid solutions have been prepared via thermal treatment of ZnS1–xSex(en)0.5 precursors. The compositions are adjusted by changing the mole ratio of Se to S powder in the starting materials, resulting in continuously modulating the alignment of energy levels of the obtained solid solutions. The band structure is also studied via theoretical calculation. Accordingly, the light harvesting can be tuned too, as confirmed by the UV-vis absorption spectra. XPS valence spectra are used to determine the valence band maximum. Transient photoluminescence spectra are employed to study the separation of photogenerated charge carriers. BET specific surface area and CO2 adsorption isotherms of different catalysts are measured. The obtained ZnS1–xSex nanobelts exhibit different photocatalytic activity for solar-fuel production, dependent on many factors like the light harvesting and alignment of energy levels. The related mechanism is studied in detail.展开更多
Three kinds of metal atoms with different valence electronic configurations,Bi(6s^(2)6p^(3)),Y(4d^(1)5s^(2)),and Ce(4f^(1)5d^(1)6s^(2)),were selected to investigate the effect of A-site(La^(3+))doping on electronic ba...Three kinds of metal atoms with different valence electronic configurations,Bi(6s^(2)6p^(3)),Y(4d^(1)5s^(2)),and Ce(4f^(1)5d^(1)6s^(2)),were selected to investigate the effect of A-site(La^(3+))doping on electronic band structure,photoelectric properties,and photocatalytic performance of LaFeO_(3) perovskite.It was identified that the Bi doped LaFeO_(3) presented significantly improved photocatalytic activity towards the reduction of CO_(2),while the Y or Ce doped LaFeO_(3) displayed decreased photocatalytic activity compared to the pristine LaFeO_(3).It was revealed that doping of all the three metal atoms resulted in narrowed band gap and thus extended light absorption of LaFeO_(3) by lowering its conduction band minimum(CBM).The recombination rate and mobility of the charge carriers were represented by the relative effective mass(D)between holes and electrons for pristine and A-site doped LaFeO_(3).The doping of Bi resulted in increased D value,attributed to the Bi 6s electron states at the valence band maximum(VBM),and thus promoted separation and transfer of the charge carriers and improved photocatalytic activity of LaFeO_(3).In contrast,the doping of Ce resulted in significantly decreased D value,induced by the highly localized Ce 4f hole states at the CBM,and thus higher recombination rate of the charge carriers and decreased photocatalytic activity of LaFeO_(3).Furthermore,the Y doped LaFeO_(3) with a slightly decreased D value presented slightly increased recombination rate of the charge carriers and thus decreased photocatalytic activity.Such a work provides new insights into the A-site doping in LaFeO_(3) perovskite,which should be helpful for optimizing the electronic band structure and activity of perovskite-type photocatalysts at atomic level.展开更多
We studied cycle time （0.01-10 s with triangular input waves） and poling history （continuous versus fresh poling） dependent electric energy storage and discharge behaviors in poly（vinylidene fluoride-co-hexafluor...We studied cycle time （0.01-10 s with triangular input waves） and poling history （continuous versus fresh poling） dependent electric energy storage and discharge behaviors in poly（vinylidene fluoride-co-hexafluoropropylene） [P（VDF- HFP）] films using the electric displacement -- the electric field （D-E） hysteresis loop measurements. Since the permanent dipoles in PVDF are orientational in nature, it is generally considered that both charging and discharging processes should be time and poling history dependent. Intriguingly, our experimental results showed that the charging process depended heavily on the cycle time and the prior poling history, and thus the D-E hysteresis loops had different shapes accordingly. However, the discharged energy density did not change no matter how the D-E loop shape varied due to different measurements. This experimental result could be explained in terms of reversible and irreversible polarizations. The reversible polarization could be charged and discharged fairly quickly （〈 5 ms for each process）, while the irreversible polarization depended heavily on the poling time and the prior poling history. This study suggests that it is only meaningful to compare the discharged energy density for PVDF and its copolymer films when different cycle times and poling histories are used.展开更多
Due to their fast response and strong short-term power throughput capacity, electric vehicles(EVs) are promising for providing primary frequency support to power grids. However, due to the complicated charging demands...Due to their fast response and strong short-term power throughput capacity, electric vehicles(EVs) are promising for providing primary frequency support to power grids. However, due to the complicated charging demands of drivers, it is challenging to efficiently utilize the regulation capacity of EV clusters for providing stable primary frequency support to the power grid. Accordingly, this paper proposes an adaptive primary frequency support strategy for EV clusters constrained by the charging-behavior-defined operation area. First, the forced charging boundary of the EV is determined according to the driver's charging behavior, and based on this, the operation area is defined. This ensures full utilization of the available frequency support capacity of the EV. An adaptive primary frequency support strategy of EV clusters is then proposed. The output power of EV is adaptively regulated according to the real-time distance from the EV operating point to the forced charging boundary. With the proposed strategy, when the EV approaches the forced charging boundary, its output power is gradually reduced to zero. Then, the rapid state-of-charge declines of EVs and sudden output power reductions in EV clusters caused by forced charging to meet the driver's charging demands can be effectively avoided. EV clusters can then provide sustainable frequency support to the power grid without violating the driver's charging demands. Simulation results validate the proposed operation-area-constrained adaptive primary frequency support strategy, which outperforms the average strategy in terms of stable output maintenance and the optimal utilization of regulation capacities of EV clusters.展开更多
基金Project supported by the State Key Development Program for Basic Research of China(Grant No.2010CB934402)the National Natural Science Foundation of China(Grant Nos.11374153,61571221,and 61071008)
文摘Based on the charge storage mode,it is important to investigate the scaling dependence of memory performance in silicon nanocrystal（Si-NC） nonvolatile memory（NVM） devices for its scaling down limit.In this work,we made eight kinds of test key cells with different gate widths and lengths by 0.13-μm node complementary metal oxide semiconductor（CMOS） technology.It is found that the memory windows of eight kinds of test key cells are almost the same of about1.64 V @ ±7 V/1 ms,which are independent of the gate area,but mainly determined by the average size（12 nm） and areal density（1.8×10^（11）/cm^2） of Si-NCs.The program/erase（P/E） speed characteristics are almost independent of gate widths and lengths.However,the erase speed is faster than the program speed of test key cells,which is due to the different charging behaviors between electrons and holes during the operation processes.Furthermore,the data retention characteristic is also independent of the gate area.Our findings are useful for further scaling down of Si-NC NVM devices to improve the performance and on-chip integration.
基金Project(71271016)supported the National Natural Science Foundation of China
文摘The micro modeling for electric vehicle and its solution were investigated. A new car-following model for electric vehicle was proposed based on the existing car-following models. The impacts of the electric vehicle's charging electricity were studied from the numerical perspective. The numerical results show that the electric vehicle's charging electricity will destroy the stability of uniform flow and produce some prominent queues and these traffic phenomena are directly related to the initial headway, the distance between two adjacent charging stations and the number of charging stations. The above results can help traffic engineer to choose the position of charging station and the electric vehicle's driver to adjust his/her driving behavior in the traffic system with charging station.
基金the National Natural Science Founda-tion of China(Nos.72171175,and 72021102)。
文摘This study addresses a new charging station network planning problem for smart connected electric vehicles.We embed a charging station choice model into a charging network planning model that explicitly considers the heterogeneity of the charging behavior in a data-driven manner.To cope with the deficiencies from a small size and sparse behavioral data,we propose a robust charging demand prediction method that can significantly reduce the impact of sample errors and missing data.On the basis of these two building blocks,we form and solve a new optimal charging station location and capacity problem by minimizing the construction and charging costs while considering the charging service level,construction budget,and limit to the number of chargers.We use a case study of planning charging stations in Shanghai to validate our contributions and provide managerial insight in this area.
文摘Band engineering based on the construction of solid solutions is an effective approach to enhance the efficiency of semiconductor photocatalysts, via which the balance between light absorption and driving force can be well achieved by continuously tuning the band structure. Here the ZnS1–xSex nanobelt solid solutions have been prepared via thermal treatment of ZnS1–xSex(en)0.5 precursors. The compositions are adjusted by changing the mole ratio of Se to S powder in the starting materials, resulting in continuously modulating the alignment of energy levels of the obtained solid solutions. The band structure is also studied via theoretical calculation. Accordingly, the light harvesting can be tuned too, as confirmed by the UV-vis absorption spectra. XPS valence spectra are used to determine the valence band maximum. Transient photoluminescence spectra are employed to study the separation of photogenerated charge carriers. BET specific surface area and CO2 adsorption isotherms of different catalysts are measured. The obtained ZnS1–xSex nanobelts exhibit different photocatalytic activity for solar-fuel production, dependent on many factors like the light harvesting and alignment of energy levels. The related mechanism is studied in detail.
基金supported by the National Natural Science Foundation of China(No.21773089).
文摘Three kinds of metal atoms with different valence electronic configurations,Bi(6s^(2)6p^(3)),Y(4d^(1)5s^(2)),and Ce(4f^(1)5d^(1)6s^(2)),were selected to investigate the effect of A-site(La^(3+))doping on electronic band structure,photoelectric properties,and photocatalytic performance of LaFeO_(3) perovskite.It was identified that the Bi doped LaFeO_(3) presented significantly improved photocatalytic activity towards the reduction of CO_(2),while the Y or Ce doped LaFeO_(3) displayed decreased photocatalytic activity compared to the pristine LaFeO_(3).It was revealed that doping of all the three metal atoms resulted in narrowed band gap and thus extended light absorption of LaFeO_(3) by lowering its conduction band minimum(CBM).The recombination rate and mobility of the charge carriers were represented by the relative effective mass(D)between holes and electrons for pristine and A-site doped LaFeO_(3).The doping of Bi resulted in increased D value,attributed to the Bi 6s electron states at the valence band maximum(VBM),and thus promoted separation and transfer of the charge carriers and improved photocatalytic activity of LaFeO_(3).In contrast,the doping of Ce resulted in significantly decreased D value,induced by the highly localized Ce 4f hole states at the CBM,and thus higher recombination rate of the charge carriers and decreased photocatalytic activity of LaFeO_(3).Furthermore,the Y doped LaFeO_(3) with a slightly decreased D value presented slightly increased recombination rate of the charge carriers and thus decreased photocatalytic activity.Such a work provides new insights into the A-site doping in LaFeO_(3) perovskite,which should be helpful for optimizing the electronic band structure and activity of perovskite-type photocatalysts at atomic level.
基金supported by ONR(N00014-05-1-0338)NSF(DMR-0907580)
文摘We studied cycle time （0.01-10 s with triangular input waves） and poling history （continuous versus fresh poling） dependent electric energy storage and discharge behaviors in poly（vinylidene fluoride-co-hexafluoropropylene） [P（VDF- HFP）] films using the electric displacement -- the electric field （D-E） hysteresis loop measurements. Since the permanent dipoles in PVDF are orientational in nature, it is generally considered that both charging and discharging processes should be time and poling history dependent. Intriguingly, our experimental results showed that the charging process depended heavily on the cycle time and the prior poling history, and thus the D-E hysteresis loops had different shapes accordingly. However, the discharged energy density did not change no matter how the D-E loop shape varied due to different measurements. This experimental result could be explained in terms of reversible and irreversible polarizations. The reversible polarization could be charged and discharged fairly quickly （〈 5 ms for each process）, while the irreversible polarization depended heavily on the poling time and the prior poling history. This study suggests that it is only meaningful to compare the discharged energy density for PVDF and its copolymer films when different cycle times and poling histories are used.
基金supported by the Science and Technology Project of State Grid Corporation of China (No.5100-202199274A-0-0-00)。
文摘Due to their fast response and strong short-term power throughput capacity, electric vehicles(EVs) are promising for providing primary frequency support to power grids. However, due to the complicated charging demands of drivers, it is challenging to efficiently utilize the regulation capacity of EV clusters for providing stable primary frequency support to the power grid. Accordingly, this paper proposes an adaptive primary frequency support strategy for EV clusters constrained by the charging-behavior-defined operation area. First, the forced charging boundary of the EV is determined according to the driver's charging behavior, and based on this, the operation area is defined. This ensures full utilization of the available frequency support capacity of the EV. An adaptive primary frequency support strategy of EV clusters is then proposed. The output power of EV is adaptively regulated according to the real-time distance from the EV operating point to the forced charging boundary. With the proposed strategy, when the EV approaches the forced charging boundary, its output power is gradually reduced to zero. Then, the rapid state-of-charge declines of EVs and sudden output power reductions in EV clusters caused by forced charging to meet the driver's charging demands can be effectively avoided. EV clusters can then provide sustainable frequency support to the power grid without violating the driver's charging demands. Simulation results validate the proposed operation-area-constrained adaptive primary frequency support strategy, which outperforms the average strategy in terms of stable output maintenance and the optimal utilization of regulation capacities of EV clusters.
