The relationship between trace elements in coal and organic functional groups of coal, also some of aromatic structure, was investigated by using curve fitting of infrared spectra. Cluster analysis was also performed ...The relationship between trace elements in coal and organic functional groups of coal, also some of aromatic structure, was investigated by using curve fitting of infrared spectra. Cluster analysis was also performed according to the degree of affinity of organic groups to the trace elements. The results show that there is a possibility that trace elements, especially LREE, were bound to peripheral organic functional groups of middle rank coal macromolecule. The most possible functional group that binds trace element is the hydroxyl, and to the less degree, the asymmetric -CH3 and 〉CH2 stretching, -CH3 stretching, etc. The degree of affinity of trace elements to different functional groups varies. The tendency obeys the natural structural changing law of trace elements-- the periodic law. The deviation of some trace elements from this regular trend is attributed to the deviation of intrinsic ＂confusion degree＂ （conventional molar entropy） of the matter system of coal basin, which is affected by the inner and outer factors during the evolution.展开更多
According to the influence of the combination of short-distance coal seam group on mining roadway, using numerical simulation software FLAG2D to draw the abutment pressure distribution ahead the working face and the a...According to the influence of the combination of short-distance coal seam group on mining roadway, using numerical simulation software FLAG2D to draw the abutment pressure distribution ahead the working face and the area of influence in fully-mechanized mining conditions, the variation rules of surrounding rock supporting pressure of floor roadway and the deformation rules were summarized. GYS-300 anchor dynamometer was used to measure the roadway surface displacement, and the conclusions of numerical simulation were verified.展开更多
In light of the severe deformation and destruction of the district raise tunnel in the mining area at the northern part of the Lubanshan colliery, by the theoretic analysis and numerical simulation, both the mining st...In light of the severe deformation and destruction of the district raise tunnel in the mining area at the northern part of the Lubanshan colliery, by the theoretic analysis and numerical simulation, both the mining stress distribution in seams group and the deformation and destruction mechanism of floor district raise were investigated. The results show that, at the maximum vertical distance of 40 m, the abutment stress has an influence on the recovery of 2# and 3# coal seam and 8# coal seam at distance of 30 m. As a result, the recovery of 8# is rather than those of 2# or 3# coal seam, which contributes to the deformation and destruction of the district raise surrounding rock. The major factors affecting the abutment stress include the mining depth, mining height, residual gob space, adjacent working faces and short spacing coal seam recovery.展开更多
针对中近距离松软低透气性突出煤层群抽采防突难题,以皖北矿区任楼煤矿突出煤层群瓦斯地质条件为工程背景,在对松软煤层水力割缝卸压增透机制、首采层割缝工艺参数等研究的基础上,提出了首采层煤巷条带水力割缝卸压增透、煤层群瓦斯联...针对中近距离松软低透气性突出煤层群抽采防突难题,以皖北矿区任楼煤矿突出煤层群瓦斯地质条件为工程背景,在对松软煤层水力割缝卸压增透机制、首采层割缝工艺参数等研究的基础上,提出了首采层煤巷条带水力割缝卸压增透、煤层群瓦斯联合抽采的综合治理技术,优化了钻孔布置方式,并进行了工程应用。结果表明:割缝实施后钻孔的瓦斯抽采浓度、单孔日均抽采纯量分别是常规钻孔的4.27倍、3.94倍,煤层透气性提高了22~31倍,首采层72号煤层割缝后的防突有效半径可提高至5 m以上,检验抽采半径5 m处的瓦斯含量指标为4.13 m 3/t,在有效解决首采层煤巷条带瓦斯灾害的同时,钻孔工程量降低了2/3以上。展开更多
基金supported by the National Science Foundation of China(Nos.41172143 and 40872101)Developmental Plan of Basic Research on Natural Science of Shanxi Province(20012JM5005)Science Research Plan of Shanxi education department(12JK0483)
文摘The relationship between trace elements in coal and organic functional groups of coal, also some of aromatic structure, was investigated by using curve fitting of infrared spectra. Cluster analysis was also performed according to the degree of affinity of organic groups to the trace elements. The results show that there is a possibility that trace elements, especially LREE, were bound to peripheral organic functional groups of middle rank coal macromolecule. The most possible functional group that binds trace element is the hydroxyl, and to the less degree, the asymmetric -CH3 and 〉CH2 stretching, -CH3 stretching, etc. The degree of affinity of trace elements to different functional groups varies. The tendency obeys the natural structural changing law of trace elements-- the periodic law. The deviation of some trace elements from this regular trend is attributed to the deviation of intrinsic ＂confusion degree＂ （conventional molar entropy） of the matter system of coal basin, which is affected by the inner and outer factors during the evolution.
文摘According to the influence of the combination of short-distance coal seam group on mining roadway, using numerical simulation software FLAG2D to draw the abutment pressure distribution ahead the working face and the area of influence in fully-mechanized mining conditions, the variation rules of surrounding rock supporting pressure of floor roadway and the deformation rules were summarized. GYS-300 anchor dynamometer was used to measure the roadway surface displacement, and the conclusions of numerical simulation were verified.
基金Project(51104176)supported by the National Natural Science Foundation of China
文摘In light of the severe deformation and destruction of the district raise tunnel in the mining area at the northern part of the Lubanshan colliery, by the theoretic analysis and numerical simulation, both the mining stress distribution in seams group and the deformation and destruction mechanism of floor district raise were investigated. The results show that, at the maximum vertical distance of 40 m, the abutment stress has an influence on the recovery of 2# and 3# coal seam and 8# coal seam at distance of 30 m. As a result, the recovery of 8# is rather than those of 2# or 3# coal seam, which contributes to the deformation and destruction of the district raise surrounding rock. The major factors affecting the abutment stress include the mining depth, mining height, residual gob space, adjacent working faces and short spacing coal seam recovery.
文摘针对中近距离松软低透气性突出煤层群抽采防突难题,以皖北矿区任楼煤矿突出煤层群瓦斯地质条件为工程背景,在对松软煤层水力割缝卸压增透机制、首采层割缝工艺参数等研究的基础上,提出了首采层煤巷条带水力割缝卸压增透、煤层群瓦斯联合抽采的综合治理技术,优化了钻孔布置方式,并进行了工程应用。结果表明:割缝实施后钻孔的瓦斯抽采浓度、单孔日均抽采纯量分别是常规钻孔的4.27倍、3.94倍,煤层透气性提高了22~31倍,首采层72号煤层割缝后的防突有效半径可提高至5 m以上,检验抽采半径5 m处的瓦斯含量指标为4.13 m 3/t,在有效解决首采层煤巷条带瓦斯灾害的同时,钻孔工程量降低了2/3以上。
