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Analysis and Prospect of Waste Heat Utilization from Blast Furnace Slag Flushing
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作者 Shenqin Zhang Junyi Qing 《Frontiers of Metallurgical Industry》 2024年第2期15-20,共6页
Estimating the residual heat of blast furnace slag flushing in China,classifying and introducing the current proposed methods of slag flushing waste heat utilization,and listing existing cases.In order to better save ... Estimating the residual heat of blast furnace slag flushing in China,classifying and introducing the current proposed methods of slag flushing waste heat utilization,and listing existing cases.In order to better save energy and water in the slag flushing process of blast furnaces,an ideal comprehensive cascade utilization system scheme for annual recovery of waste heat is proposed.Based on the measured waste heat data of a steel plant,design calculations are carried out to further analyze the economic feasibility of the new scheme and provide reference for its promotion and application. 展开更多
关键词 blast furnace slag flushing waste heat utilization comprehensive cascade utilization energy saving and water-saving
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Formation cause,composition analysis and comprehensive utilization of rare earth solid wastes 被引量:9
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作者 许涛 彭会清 《Journal of Rare Earths》 SCIE EI CAS CSCD 2009年第6期1096-1102,共7页
Based on practical situation of rare earth industrial chain,production process and rare earth materials that could produce solid wastes on batch were discussed.Formation cause,formation volume,composition analysis and... Based on practical situation of rare earth industrial chain,production process and rare earth materials that could produce solid wastes on batch were discussed.Formation cause,formation volume,composition analysis and comprehensive utilization of the solid wastes of rare earth hydrometallurgy slag,electrolysis slag,Fe-based rare earth permanent magnetic materials,Co-based rare earth permanent magnetic materials,rare earth hydrogen storage materials,rare earth polishing powders and rare earth catalysts were ... 展开更多
关键词 rare earths solid wastes comprehensive utilization
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Technology of comprehensive disposal and utilization of municipal solid waste (MSW) 被引量:1
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作者 Liu Xiao\|feng, Liao Yin\|zhang, Liu Ke\|xin Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu\ 610041, China 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 1999年第3期378-380,共3页
The project for treating MSW of 200 tons each day was built in Yibin, Sichuan Province of China. The disposal processes are: separation and selection of usable resources; compost and fermentation of “heavy” organic ... The project for treating MSW of 200 tons each day was built in Yibin, Sichuan Province of China. The disposal processes are: separation and selection of usable resources; compost and fermentation of “heavy” organic waste (kitchen, garden composting rubbish); incineration of “light” waste (plastic, paper, wood and bamboo etc.) and landfill of inorganic waste. The thermal energy generated in the process can be used as 1/3 of the whole energy for drying fertilizers. In the process, there is no wastewater drainage, and air emissions can be effectively controlled by a series of measures. The sanitary and environmental indicators of disposal site meet the national standards. This project has worked well for two years. It not only disposes of and reduces the MSW, but also retrieves the resource effectively. The organic fertilizer has been applied in the ten thousand acres of fields, with productivity increase by more than 10%. 展开更多
关键词 municipal solid waste (MSW) comprehensive utilization composted fertilizer.
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Advances in Research on Comprehensive Utilization of Tea Waste 被引量:7
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作者 谢枫 金玲莉 +2 位作者 涂娟 乐美旺 王璠 《Agricultural Science & Technology》 CAS 2015年第7期1552-1557,1564,共7页
China is a big producer and consumer of tea. A huge amount of tea waste is produced in China every year, resulting in environmental pollution and enormous natural resources waste. From the perspective of utilization w... China is a big producer and consumer of tea. A huge amount of tea waste is produced in China every year, resulting in environmental pollution and enormous natural resources waste. From the perspective of utilization way, this pa- per summarized the research progresses in tea waste as a raw material for ex- tracting active ingredients and preparing absorbent, activated carbon, bio-organic fer- tilizer, animal feed and nutrients for edible fungi cultivation. In addition, the develop- ment trend of comprehensive utilization of tea waste was prospected. It is found that the comprehensive utilization of tea waste using a variety of techniques can im- prove the utilization efficiency of tea waste and reduce production costs. Finally, a simple and practical comprehensive utilization program was proposed to provide a reference for practical application. 展开更多
关键词 Tea waste comprehensive utilization Tea residue
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CO_(2) mineralization by typical industrial solid wastes for preparing ultrafine CaCO_(3): A review
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作者 Run Xu Fuxia Zhu +8 位作者 Liang Zou Shuqing Wang Yanfang Liu Jili Hou Chenghao Li Kuntong Song Lingzhao Kong Longpeng Cui Zhiqiang Wang 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第11期1679-1697,共19页
Mineral carbonation is a promising CO_(2) sequestration strategy that can utilize industrial wastes to convert CO_(2) into high-value CaCO_(3).This review summarizes the advancements in CO_(2) mineralization using typ... Mineral carbonation is a promising CO_(2) sequestration strategy that can utilize industrial wastes to convert CO_(2) into high-value CaCO_(3).This review summarizes the advancements in CO_(2) mineralization using typical industrial wastes to prepare ultrafine CaCO_(3).This work surveys the mechanisms of CO_(2) mineralization using these wastes and its capacities to synthesize CaCO_(3),evaluates the effects of carbonation pathways and operating parameters on the preparation of CaCO_(3),analyzes the current industrial application status and economics of this technology.Due to the large amount of impurities in solid wastes,the purity of CaCO_(3) prepared by indirect methods is greater than that prepared by direct methods.Crystalline CaCO_(3) includes three polymorphs.The polymorph of CaCO_(3) synthesized by carbonation process is determined the combined effects of various factors.These parameters essentially impact the nucleation and growth of CaCO_(3) by altering the CO_(2) supersaturation in the reaction system and the surface energy of CaCO_(3) grains.Increasing the initial pH of the solution and the CO_(2)flow rate favors the formation of vaterite,but calcite is formed under excessively high pH.Vaterite formation is favored at lower temperatures and residence time.With increased temperature and prolonged residence time,it passes through aragonite metastable phase and eventually transforms into calcite.Moreover,polymorph modifiers can decrease the surface energy of CaCO_(3) grains,facilitating the synthesis of vaterite.However,the large-scale application of this technology still faces many problems,including high costs,high energy consumption,low calcium leaching rate,low carbonation efficiency,and low product yield.Therefore,it is necessary to investigate ways to accelerate carbonation,optimize operating parameters,develop cost-effective agents,and understand the kinetics of CaCO_(3) nucleation and crystallization to obtain products with specific crystal forms.Furthermore,more studies on life cycle assessment(LCA)should be conducted to fully confirm the feasibility of the developed technologies. 展开更多
关键词 Industrial solid wastes Resource utilization Mineral carbonation Ultrafine CaCO_(3) Carbon emission reduction
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Analysis of Comprehensive Utilization of Coconut Waste
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作者 Kan ZHENG Dong LIANG Xirui ZHANG 《Asian Agricultural Research》 2013年第10期84-87,共4页
This paper describes and analyzes the coconut cultivation in China,and the current comprehensive utilization of waste resources generated during cultivation and processing of coconut.The wastes generated in the proces... This paper describes and analyzes the coconut cultivation in China,and the current comprehensive utilization of waste resources generated during cultivation and processing of coconut.The wastes generated in the process of cultivation include old coconut tree trunk,roots,withered coconut leaves,coconut flower and fallen cracking coconut,mainly used for biogas extraction,direct combustion and power generation,brewing,pharmacy,and processing of building materials;the wastes generated during processing include coconut water,coconut coat,coconut shell and coconut meal,mainly used for processing beverages,pharmaceutical products,activated carbon,medium and feed.This paper analyzes and explores some problems in the process of comprehensive utilization of coconut waste in China,such as insufficient understanding,inadequate development and lack of research efforts,and finally puts forth the corresponding development countermeasures. 展开更多
关键词 COCONUT waste comprehensive utilization
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Review of the fabrication and application of porous materials from silicon-rich industrial solid waste 被引量:17
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作者 Chao Miao Lixing Liang +5 位作者 Fan Zhang Shumei Chen Kaixuan Shang Jinlong Jiang Yi Zhang Jing Ouyang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2022年第3期424-438,共15页
Porous materials have promise as sound insulation, heat barrier, vibration attenuation, and catalysts. Most industrial solid wastes, such as tailings, coal gangue, and fly ash are rich in silicon. Additionally, a high... Porous materials have promise as sound insulation, heat barrier, vibration attenuation, and catalysts. Most industrial solid wastes, such as tailings, coal gangue, and fly ash are rich in silicon. Additionally, a high silicon content waste is a potential raw material for the syn- thesis of silicon-based, multi-porous materials such as zeolites, mesoporous silica, glass-ceramics, and geopolymer foams. Representative sil- icon-rich industrial solid wastes (SRISWs) are the focus of this mini review of the processing and application of porous silicon materials with respect to the physical and chemical properties of the SRISW. The transformation methods of preparing porous materials from SRISWs are summarized, and their research status in micro-, meso-, and macro-scale porous materials are described. Possible problems in the application of SRISWs and in the preparation of functional porous materials are analyzed, and their development prospects are discussed. This review should provide a typical reference for the recycling and use of industrial solid wastes to develop sustainable “green materials.” 展开更多
关键词 silicon-rich industrial solid waste porous materials physicochemical properties material utilization of solid wastes
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The New Understanding of Potash Development Scale and the Comprehensive Utilization of Resources in Chaerhan Salt lake 被引量:1
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作者 WANG Xingfu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2014年第S1期437-437,共1页
This paper briefly introduces resources characteristics and development advantages for Charhan salt lake;and elaborated the technology progress to increase potassium mining scale systematically,the impact of the
关键词 salt lake Science and technology progress solid-liquid conversion potassium devepmont comprehensive utilization
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Recent Advances in the Synthesis of Zeolites from Solid Wastes
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作者 LIU Pei WU Qinming +1 位作者 CHEN Zhenghai XIAO Feng-Shou 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2024年第4期646-656,共11页
With the rapid development of industrialization,it is inevitable to produce solid wastes in the fields of energy petrochemical industry.However,the storage and utilization of these solid wastes have become a considera... With the rapid development of industrialization,it is inevitable to produce solid wastes in the fields of energy petrochemical industry.However,the storage and utilization of these solid wastes have become a considerable challenge.Due to the main element composition of these solid wastes including silicon and aluminum,it has attracted extensive attention for synthesizing zeolites.This review summarized the properties of major solid wastes including coal fly ash,coal gangue,spent fluid catalytic cracking(FCC)catalyst,lithium slag,bauxite residue,and waste glass.Then,the preparation of LTA,FAU,ZSM-5,SSZ-13,Beta,and MOR zeolites from these solid wastes were introduced.Finally,the current challenges and perspectives were discussed. 展开更多
关键词 solid waste ZEOLITE utilization Sustainable route APPLICATION
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Solid State Reaction Yielding a Mineral Utilizing Silica Obtained from an Agricultural Waste 被引量:5
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作者 M.S.Nizami M.K.Farooq K.Hussain and M.Z.Iqbal(PCSIR Laboratories Complex, Lahore, Pakistan) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1999年第3期276-280,共5页
Wollastonite, a mineral of wide industrial applications was synthesised from rice husk ash silica and limestone. A number of raw batches consisting of these starting materials, in 1:1 molar ratio, were heat treated to... Wollastonite, a mineral of wide industrial applications was synthesised from rice husk ash silica and limestone. A number of raw batches consisting of these starting materials, in 1:1 molar ratio, were heat treated to produce it through solid state reaction from 900℃ to 1300℃. The conducted reaction was monitored by XRD step by step. Amount of Wollastonite formed at every temperature was also studied to some extent. Analyses of the obtained data indicated that the target mineral formation was quite effective and almost proportional to a rise in temperature up to 1200℃. The results from both, XRD and chemical analysis were found in fair agreement with one another 展开更多
关键词 OO CAO Co solid State Reaction Yielding a Mineral Utilizing Silica Obtained from an Agricultural waste SIO
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Thermodynamic data calculation for iron phases in sulfoaluminate cementitious materials prepared using solid wastes
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作者 WenlongWang Guolin Li +1 位作者 Lizhi Zhou Changzai Ren 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第12期2989-2993,共5页
The preparation of sulfoaluminate cementitious materials(SCM)is a promising way to massively utilize solid wastes.Iron phases are significant in SCM system but the thermodynamic data of some key minerals,such as6 CaO&... The preparation of sulfoaluminate cementitious materials(SCM)is a promising way to massively utilize solid wastes.Iron phases are significant in SCM system but the thermodynamic data of some key minerals,such as6 CaO·Al2 O3·2 Fe2 O3(C6 AF2)and 6 CaO·2 Al2 O3·Fe2 O3(C6 A2 F),are missing,which greatly hinders the SCM optimization in a theoretical way.This work,for the first time,calculated the standard formation enthalpy,Gibbs free energy of formation,entropy and molar heat capacity for C6 AF2 and C6 A2 F and lowered the errors to the least with the reference of C4 AF data in the literature.By building the function diagram of Gibbs free energy changes with temperature for the basic iron phase formation reactions with the obtained thermodynamic data,it is proved that the formation likeliness of C6 AF2 is higher than that of C6 A2 F,as is accordant to the literatures and verifies the correctness of obtained data.This work provides a good theoretical foundation to optimize SCM mineral system and to study relevant mechanism deeply. 展开更多
关键词 Sulfoaluminate CEMENT IRON phase THERMODYNAMIC data Gibbs free energy solid waste utilization
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New Advanced Technology on Waste Resourcelization of the Black Pulping Liquor
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作者 周毅 韩园园 张东翔 《Journal of Beijing Institute of Technology》 EI CAS 2007年第3期363-368,共6页
Combining the characteristics of the black pulping liquor that contains a lot of lignin and other biomass resources, the technology of comprehensive waste utilization is employed. The reconstructive preparation of mod... Combining the characteristics of the black pulping liquor that contains a lot of lignin and other biomass resources, the technology of comprehensive waste utilization is employed. The reconstructive preparation of modified urea-formaldehyde glue by adding black pulping liquor and the application in extruding the medium density fibre board using this modified urea-formaldehyde glue is researched. Results show that when applying the preparation technology that alkaline reaction and then weak acid reaction, the appropriate preparation process is as follows: the adding urea process is divided into three stages (proportion 2 : 1 : 1) ; the pH value is 8.0, and the reaction time is 40 min in the addition reaction stage; the pH value will be naturally reduced to 3.5 -5.0, and the reaction time is 45 min in the aggregation reaction stage; the pH value is 8.0 in the urea complement stage. And the optimal condition of the reconstructive preparation the modified ureaformaldehyde glue is adding the condensed black pulping liquor after hydroxymethylation in the beginning of polycondensation reaction by 5% proportion. The application in extruding medium density fibre board with this modified urea-fosmaldehyde glue is proved feasible. 展开更多
关键词 pulping black liquor comprehensive utilization of the waste pH effect to urea-formaldehyde glueproduction
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Field Utilization of Dried Water Hyacinth for Phosphorous Recovery from Source-Separated Human Urine
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作者 Boqi Weng Junli Zhou +3 位作者 Siping Zheng Xiuxia Chen Weiguang Zhang Qin Huang 《Journal of Environmental Protection》 2012年第8期715-721,共7页
This research demonstrated the feasibility of converting source-separated human urine into a solid fertilizer by means of continuous absorption and solar thermal evaporation using dried water hyacinth as adsorbent. In... This research demonstrated the feasibility of converting source-separated human urine into a solid fertilizer by means of continuous absorption and solar thermal evaporation using dried water hyacinth as adsorbent. In a preliminary experiment, the dried petioles of water hyacinth (DWH) absorbed urine in a mean rate of 18.78 ml·g-1 within 7 d, retrieving about 3.46% urine dissolved solids (UDS). In an advanced experiment, the DWH’s capacity of urine absorption declined from an initial 2.73 L·kg-1·d-1 to 0.68 L·kg-1·d-1, with a requirement of material change in about 25 effective days and an average ratio of 25 (L) to 1 (kg). Phosphorus (P2O5) concentration in the adsorbent increased from 0.46% (material baseline) to 3.14% (end product), suggesting a satisfactory recovery of the element. In field application, the urine was discharged, not in wet weather, onto the DWH via a tube connected to a waterless urinal. There are several ways to use the UDS-DWH as P(K)-rich fertilizer, e.g., making soluble fertilizer for foliage spraying to encourage prolific flowering and fruiting. Apparently, utilization of water hyacinth waste to recover dissolved plant nutrient elements from source-separated urine will benefit the environment in a wide range of perspectives. The herein innovative use of water hyacinth is also expected to be useful in the recycling of certain dissolved hazardous materials. 展开更多
关键词 DRIED Water Hyacinth URINE Dissolved solidS Phosphorus Recovery waste utilization Source-Separated Human URINE
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Site Selection of Waste Slag Yard and Design of Protective Measures in Water Supply Project of Drawing from the Songhua River in Central Cities of Jilin
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作者 Hongchao LIU Jun LV 《Meteorological and Environmental Research》 CAS 2021年第4期49-51,共3页
Water supply project of drawing from the Songhua River in central cities of Jilin is taken as research object.On the basis of analyzing project characteristics and natural conditions of the project area,site selection... Water supply project of drawing from the Songhua River in central cities of Jilin is taken as research object.On the basis of analyzing project characteristics and natural conditions of the project area,site selection of waste slag yard of water diversion project and design of water and soil conservation measures are discussed.Rationality of site selection of waste slag yard and pertinence of prevention and control measures of water and soil loss in waste slag yard are analyzed,and comprehensive utilization of waste slag in large-scale production and construction projects is explored. 展开更多
关键词 waste slag yard Layout principle Prevention and control measures comprehensive utilization of waste slag Water supply project of drawing from the Songhua River Jilin
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Analysis and Economic Evaluation of Hourly Operation Strategy Based on MSW Classification and LNG Multi-Generation System
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作者 Xueqing Lu Yuetao Shi Jinsong Li 《Energy Engineering》 EI 2023年第6期1325-1352,共28页
In this study,a model of combined cooling,heating and power system with municipal solid waste(MSW)and liquefied natural gas(LNG)as energy sources was proposed and developed based on the energy demand of a large commun... In this study,a model of combined cooling,heating and power system with municipal solid waste(MSW)and liquefied natural gas(LNG)as energy sources was proposed and developed based on the energy demand of a large community,andMSW was classified and utilized.The systemoperated by determining power by heating load,and measures were taken to reduce operating costs by purchasing and selling LNG,natural gas(NG),cooling,heating,and power.Based on this system model,three operation strategies were proposed based on whether MSW was classified and the length of kitchen waste fermentation time,and each strategy was simulated hourly throughout the year.The results showed that the strategy of MSW classified and centralized fermentation of kitchen waste in summer(i.e.,strategy 3)required the least total amount of LNG for the whole year,which was 47701.77 t.In terms of total annual cost expenditure,strategy 3 had the best overall economy,with the lowest total annual expenditure of 2.7730×108 RMB at LNG and NG unit prices of 4 and 4.2 RMB/kg,respectively.The lower heating value of biogas produced by fermentation of kitchen waste from MSW being classified was higher than that of MSW before being classified,so the average annual thermal economy of the operating strategy of MSW being classified was better than that of MSW not being classified.Among the strategies in which MSW was classified and utilized,strategy 3 could better meet the load demand of users in the corresponding season,and thus this strategy had better thermal economy than the strategy of year-round fermentation of kitchen waste(i.e.,strategy 2).The hourly analysis data showed that the net electrical efficiency of the system varies in the same trend as the cooling,heating and power loads in all seasons,while the relationship between the energy utilization efficiency and load varied from season to season.This study can provide guidance for the practical application of MSW being classified in the system. 展开更多
关键词 Municipal solid waste liquefied natural gas energy recovery combined power heating and cooling determining power by heating load net electrical efficiency energy utilization efficiency
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煤电化基地大宗固废“三化”协同利用基础与技术 被引量:1
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作者 杨科 何淑欣 +6 位作者 何祥 初茉 周伟 袁宁 陈登红 龚鹏 张元春 《煤炭科学技术》 EI CAS CSCD 北大核心 2024年第4期69-82,共14页
我国14个大型煤炭基地及89个大宗固体废弃物综合利用示范基地建设,标志着矿区大宗固废利用已被纳入全国战略发展布局。长期以来煤炭资源高强度的开发与利用,造成矿区浅埋煤层资源临近枯竭,煤电化基地大规模固废堆积及地表沉陷,已成为制... 我国14个大型煤炭基地及89个大宗固体废弃物综合利用示范基地建设,标志着矿区大宗固废利用已被纳入全国战略发展布局。长期以来煤炭资源高强度的开发与利用,造成矿区浅埋煤层资源临近枯竭,煤电化基地大规模固废堆积及地表沉陷,已成为制约矿区绿色低碳、高质量发展的难题。大宗煤基固废协同利用与绿色充填是解放“三下一上”压煤,延长矿井服务年限,实现固废无害化、资源化、规模化“三化”利用的有效途径。基于产煤大省山西省、“华东能源粮仓”安徽两淮基地及宁东能源化工基地的煤基固废种类和产量,详细阐述了以煤矸石、粉煤灰、炉底渣、气化渣和脱硫石膏等为主要材料的煤基固废通过重金属吸附解吸和络合钝化技术实现无害化处置,列举煤基固废分类应用于低热值煤基固废发电、制备建筑材料如水泥、砖瓦等资源化利用途径,对比分析煤基固废采煤沉陷区复垦回填及井下充填规模化利用途径,突出煤基固废井下充填的优越性。基于煤电化基地深部煤炭资源,提出绿色充填开采理论与关键技术,包括深部煤矸石源头减量与采选充协同技术、充填材料高效制备与深部井下输送技术及煤基固废充填材料深部多场耦合机理,探究多源煤基固废从源头、过程到终端的深部充填开采全过程的技术原理与方法,以解决矿区深部井下充填的技术难题。根据宁东基地任家庄煤矿、山西省霍尔辛赫煤矿及淮北矿区地质条件和充填目的,分别提出超前钻孔注充低位充填方案、关键层非典型特征条件下多离层梯级注浆方案和煤基固废协同利用关键技术,综合矿山固废处置与利用、深部煤炭资源开发利用、地表沉陷控制、生态环境保护等优势,形成煤电化基地大宗固废协同利用与绿色开采模式,为煤炭开采高质量化和环境低损伤化提供参考。 展开更多
关键词 煤电化基地 煤基固废 协同利用 深部开采 源头减量 采选充一体化
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固体废物的工业窑炉协同处置进展 被引量:2
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作者 竹涛 范诗晗 +1 位作者 李芙蓉 刘海兵 《化工环保》 CAS CSCD 北大核心 2024年第1期1-10,共10页
工业窑炉协同处置固体废物是降低碳排放的重要途径。将固体废物作为替代燃料或原料在现有高温窑炉中进行处置,不仅可以减少污染物排放,还可实现固体废物的减量化、无害化和资源化利用。本文介绍了水泥窑、电厂燃煤锅炉、钢铁冶炼窑炉、... 工业窑炉协同处置固体废物是降低碳排放的重要途径。将固体废物作为替代燃料或原料在现有高温窑炉中进行处置,不仅可以减少污染物排放,还可实现固体废物的减量化、无害化和资源化利用。本文介绍了水泥窑、电厂燃煤锅炉、钢铁冶炼窑炉、煤气化炉等工业窑炉协同处置固体废物技术的现状,分析了多氯代二苯并-对-二口恶英/多氯代二苯并呋喃(PCDD/Fs)和重金属两类典型污染物的排放特征,指出了该技术当前存在的问题,并对其发展方向进行了展望。 展开更多
关键词 固体废物 工业窑炉 环境污染 资源化
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赤泥提铁研究进展 被引量:1
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作者 孙涛涛 荣嵘 +2 位作者 洪亚军 朱美庆 彭昌盛 《中国有色冶金》 CAS 北大核心 2024年第2期22-33,共12页
我国赤泥堆存量已超过10亿t,主要类型为拜耳法赤泥,该赤泥中含铁量高达30%以上,是经济价值较高的铁资源。目前回收赤泥中铁资源的方法主要是高温还原焙烧-磁选,还原剂以固态碳基还原剂和气基还原剂为主,需大量能耗和成本。我国是农业大... 我国赤泥堆存量已超过10亿t,主要类型为拜耳法赤泥,该赤泥中含铁量高达30%以上,是经济价值较高的铁资源。目前回收赤泥中铁资源的方法主要是高温还原焙烧-磁选,还原剂以固态碳基还原剂和气基还原剂为主,需大量能耗和成本。我国是农业大国,主要农作物秸秆年产量在7亿t以上,这些生物质具有碳中性、反应活性高、灰分含量低、储量高、可再生等优点,而且热解温度远远低于固态碳质还原剂,其还原三价铁的温度仅为300~800℃,属于低温热解,采用生物质还原焙烧赤泥可大幅降低能耗和成本。本文重点对固态碳质还原剂、气基还原剂和生物质还原剂还原三价铁的参数进行对比,并详细阐述了生物质热解过程及还原赤泥中Fe_(2)O_(3)的机理,认为生物质还原焙烧-磁选技术可以实现赤泥和农业秸秆等固体废弃物的减量化和高值化利用,具有极高的经济价值和环境效益。最后对未来研究赤泥中铁资源回收提出以下建议:加强探究技术耦合实现赤泥产业化处置;回收利用生物质热解产气及热量;探究尾渣综合利用途径;增强对铁铝矿物的分离研究,以实现铁精矿的连续动态化生产。 展开更多
关键词 赤泥 生物质 低温热解 低温还原 高值化利用 铁资源回收 农业秸秆 固废协同处理
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粉煤灰矿化电厂烟气CO_(2)技术及关键科学问题 被引量:1
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作者 秦波涛 冯乐乐 邵旭 《煤炭学报》 EI CAS CSCD 北大核心 2024年第2期1161-1173,共13页
燃煤发电是我国能源安全的重要保障,但烟气中会排放大量CO_(2),同时,也会产生大量粉煤灰。利用粉煤灰矿化封存电厂烟气CO_(2),并将矿化产物进行综合利用,可达到大宗固废处置与CO_(2)长效封存的双重目的。目前,粉煤灰矿化电厂烟气CO_(2)... 燃煤发电是我国能源安全的重要保障,但烟气中会排放大量CO_(2),同时,也会产生大量粉煤灰。利用粉煤灰矿化封存电厂烟气CO_(2),并将矿化产物进行综合利用,可达到大宗固废处置与CO_(2)长效封存的双重目的。目前,粉煤灰矿化电厂烟气CO_(2)技术仍存在矿化效率低、反应时间长、CO_(2)处理量小等不足,其对应的关键科学问题和技术瓶颈亟待解决。简要介绍了粉煤灰矿化烟气CO_(2)的基本原理,分析了不同反应条件对粉煤灰碱土金属离子浸出和CO_(2)矿化反应效率的影响机制,对比了CO_(2)直接矿化反应工艺、碱土金属预浸出工艺、CO_(2)预吸收工艺等3种流程的优缺点,提出了包含粉煤灰碱土金属离子高效浸出、CO_(2)矿化反应过程强化、粉煤灰矿化CO_(2)智能装备、矿化效果综合评价等方面的粉煤灰高效矿化烟气CO_(2)技术体系,总结了粉煤灰矿化CO_(2)产物的物理化学性质,提出了粉煤灰矿化CO_(2)产物高值化综合利用的构想。最后,凝练出了粉煤灰碱土金属离子快速浸出与CO_(2)高效矿化特性、粉煤灰矿化CO_(2)大型反应器中多相混合与反应规律、粉煤灰浆液矿化CO_(2)产物性质的调控机制等3个关键科学问题,指明了基础研究-关键技术与装备研发-工程应用全链条的攻关方向,为粉煤灰高效矿化烟气CO_(2)及产物综合利用提供了参考,对于双碳目标实现和固废综合利用具有重要意义。 展开更多
关键词 电厂烟气 粉煤灰 二氧化碳 矿化 固废利用
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植物茎秆纤维结构及其沥青胶浆流变特性 被引量:1
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作者 李祖仲 熊乔扬 +3 位作者 刘卫东 曾金海 马晨杨 杨佳桦 《材料科学与工程学报》 CAS CSCD 北大核心 2024年第1期35-41,51,共8页
本研究将棉秸秆、玉米秸秆、废竹、蔗渣制备出植物纤维。采用相关分析和试验评价各植物纤维沥青胶浆的物化特性。结果表明:在微米级结构层面上,棉秸秆纤维、玉米秸秆纤维和蔗渣纤维呈现出空腔管状结构,竹纤维、木质素纤维为实心结构;各... 本研究将棉秸秆、玉米秸秆、废竹、蔗渣制备出植物纤维。采用相关分析和试验评价各植物纤维沥青胶浆的物化特性。结果表明:在微米级结构层面上,棉秸秆纤维、玉米秸秆纤维和蔗渣纤维呈现出空腔管状结构,竹纤维、木质素纤维为实心结构;各纤维的化学成分存在差异,且影响其热解速率。掺入纤维后,沥青胶浆高温稳定性改善明显,在初始试验温度下各纤维沥青胶浆车辙因子提升了23.8%~75.7%,弹性恢复率提高了9.4%~18.5%。掺加纤维后,沥青胶浆低温抗裂性能略有下降,但植物纤维类型对其影响并不显著。 展开更多
关键词 植物纤维 沥青胶浆 茎秆固废利用 微观结构 流变特性
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