An obvious trend shift in the annual mean and winter mixed layer depth(MLD)in the Antarctic Circumpolar Current(ACC)region was detected during the 1960–2021 period.Shallowing trends stopped in mid-1980s,followed by a...An obvious trend shift in the annual mean and winter mixed layer depth(MLD)in the Antarctic Circumpolar Current(ACC)region was detected during the 1960–2021 period.Shallowing trends stopped in mid-1980s,followed by a period of weak trends.The MLD deepening trend difference between the two periods were mainly distributed in the western areas in the Drake Passage,the areas north to Victoria Land and Wilkes Land,and the central parts of the South Indian sector.The newly formed ocean current shear due to the meridional shift of the ACC flow axis between the two periods is the dominant driver for the MLD trends shift distributed in the western areas in the Drake Passage and the central parts of the South Indian sector.The saltier trends in the regions north to Victoria Land and Wilkes Land could be responsible for the strengthening mixing processes in this region.展开更多
Magnesium(Mg)is a widely used and attractive metal,known for its unique physical and chemical properties,and it has been employed in the manufacture of many practical materials.Layered Double Hydroxides(LDHs),particul...Magnesium(Mg)is a widely used and attractive metal,known for its unique physical and chemical properties,and it has been employed in the manufacture of many practical materials.Layered Double Hydroxides(LDHs),particularly Mg-based LDHs,rank among the most prevalent two-dimensional materials utilized in separation processes,which include adsorption,extraction,and membrane technology.The high popularity of Mg-based LDHs in separation applications can be attributed to their properties,such as excellent hydrophilicity,high surface area,ion exchangeability,and adjustable interlayer space.Currently,polymer membranes play a pivotal role in semi-industrial and industrial separation processes.Consequently,the development of polymer membranes and the mitigation of their limitations have emerged as compelling topics for researchers.Several methods exist to enhance the separation performance and anti-fouling properties of polymer membranes.Among these,incorporating additives into the membrane polymer matrix stands out as a cost-effective,straightforward,readily available,and efficient approach.The use of Mg-based LDHs,either in combination with other materials or as a standalone additive in the polymer membrane matrix,represents a promising strategy to bolster the separation and anti-fouling efficacy of flat sheet mixed matrix polymer membranes.This review highlights Mg-based LDHs as high-potential additives designed to refine flat sheet mixed matrix polymer membranes for applications in wastewater treatment and brackish water desalination.展开更多
Based on the Ocean Reanalysis System version 5(ORAS5)and the fifth-generation reanalysis datasets derived from European Centre for Medium-Range Weather Forecasts(ERA5),we investigate the different impacts of the centr...Based on the Ocean Reanalysis System version 5(ORAS5)and the fifth-generation reanalysis datasets derived from European Centre for Medium-Range Weather Forecasts(ERA5),we investigate the different impacts of the central Pacific(CP)El Niño and the eastern Pacific(EP)El Niño on the Southern Ocean(SO)mixed layer depth(MLD)during austral winter.The MLD response to the EP El Niño shows a dipole pattern in the South Pacific,namely the MLD dipole,which is the leading El Niño-induced MLD variability in the SO.The tropical Pacific warm sea surface temperature anomaly(SSTA)signal associated with the EP El Niño excites a Rossby wave train propagating southeastward and then enhances the Amundsen Sea low(ASL).This results in an anomalous cyclone over the Amundsen Sea.As a result,the anomalous southerly wind to the west of this anomalous cyclone advects colder and drier air into the southeast of New Zealand,leading to surface cooling through less total surface heat flux,especially surface sensible heat(SH)flux and latent heat(LH)flux,and thus contributing to the mix layer(ML)deepening.The east of the anomalous cyclone brings warmer and wetter air to the southwest of Chile,but the total heat flux anomaly shows no significant change.The warm air promotes the sea ice melting and maintains fresh water,which strengthens stratification.This results in a shallower MLD.During the CP El Niño,the response of MLD shows a separate negative MLD anomaly center in the central South Pacific.The Rossby wave train triggered by the warm SSTA in the central Pacific Ocean spreads to the Amundsen Sea,which weakens the ASL.Therefore,the anomalous anticyclone dominates the Amundsen Sea.Consequently,the anomalous northerly wind to the west of anomalous anticyclone advects warmer and wetter air into the central and southern Pacific,causing surface warming through increased SH,LH,and longwave radiation flux,and thus contributing to the ML shoaling.However,to the east of the anomalous anticyclone,there is no statistically significant impact on the MLD.展开更多
The upper mixed layer depth(h)has a significant seasonal variation in the real ocean and the low-order statistics of Langmuir turbulence are dramatically influenced by the upper mixed layer depth.To explore the influe...The upper mixed layer depth(h)has a significant seasonal variation in the real ocean and the low-order statistics of Langmuir turbulence are dramatically influenced by the upper mixed layer depth.To explore the influence of the upper mixed layer depth on Langmuir turbulence under the condition of the wind and wave equilibrium,the changes of Langmuir turbulence characteristics with the idealized variation of the upper mixed layer depth from very shallow(h=5 m)to deep enough(h=40 m)are studied using a non-hydrostatic large eddy simulation model.The simulation results show that there is a direct entrainment depth induced by Langmuir turbulence(h_(LT))within the thermocline.The normalized depthaveraged vertical velocity variance is smaller and larger than the downwind velocity variance for the ratio of the upper mixed layer to a direct entrainment depth induced by Langmuir turbulence h/h_(LT)<1 and h/h_(LT)>1,respectively,indicating that turbulence characteristics have the essential change(i.e.,depth-averaged vertical velocity variance(DAVV)DADV for Langmuir turbulence)between h/h_(LT)<1 and h/h_(LT)>1.The rate of change of the normalized depth-averaged low-order statistics for h/h_(LT)<1 is much larger than that for h/h_(LT)>1.The reason is that the downward pressure perturbation induced by Langmuir cells is strongly inhibited by the upward reactive force of the strong stratified thermocline for h/h_(LT)<1 and the eff ect of upward reactive force on the downward pressure perturbation becomes weak for h/h_(LT)>1.Hence,the upper mixed layer depth has significant influences on Langmuir turbulence characteristics.展开更多
Intraseasonal oscillation of the mixed layer and upper ocean temperature has been found to occur over the South China Sea(SCS)in the summer monsoon season based on the multiple reanalysis and observational data in thi...Intraseasonal oscillation of the mixed layer and upper ocean temperature has been found to occur over the South China Sea(SCS)in the summer monsoon season based on the multiple reanalysis and observational data in this study.The method of composite analysis and an upper ocean temperature equation assisted the analysis of physical mechanisms.The results show that the mixed layer depth(MLD)in the SCS has a significant oscillation with a 30-60 d period over the SCS region,which is closely related to boreal summer intraseasonal oscillation(BSISO)activities.The MLD can increase(decrease)during the positive(negative)phase of the BSISO and usually lags behind by approximately one-eighth of the lifecycle(5 days)of the BSISO-related convection.The BSISO may cause periodic anomalies at the air-sea boundary,such as wind stress and heat flux,so it can play a dominant role in modulating the variation in MLD.There also are significant intraseasonal seawater temperature anomalies in both the surface and subsurface layers of the SCS.In addition,during the initial phase of the BSISO,the temperature anomaly signals of the thermocline are obviously opposite to the sea surface temperature(SST),especially in the southern SCS.According to the results from the analysis of the temperature equation,the vertical entrainment term caused by BSISO-related wind stress is stronger than the thermal forcing during the initial stage of convection,and it is more significant in the southern SCS.展开更多
The southeastern Indian Ocean is characterized by the warm barrier layer(BL)underlying the cool mixed layer water in austral winter.This phenomenon lasts almost half a year and thus provides a unique positive effect o...The southeastern Indian Ocean is characterized by the warm barrier layer(BL)underlying the cool mixed layer water in austral winter.This phenomenon lasts almost half a year and thus provides a unique positive effect on the upper mixed layer heat content through the entrainment processes at the base of the mixed layer,which has not been well evaluated due to the lack of proper method and dataset.Among various traditional threshold methods,here it is shown that the 5 m fixed depth difference can produce a reliable and accurate estimate of the entrainment heat flux(EHF)in this BL region.The comparison between the daily and monthly EHF warming indicates that the account for high-frequency EHF variability almost doubles the warming effect in the BL period,which can compensate for or even surpass the surface heat loss.This increased warming is a result of stronger relative rate of the mixed layer deepening and larger temperature differences between the mixed layer and its immediate below in the daily-resolving data.The interannual EHF shows a moderately increasing trend and similar variabilities to the Southern Annular Mode(SAM),likely because the mixed layer deepening under the positive SAM trend is accompanied by enhanced turbulent entrainment and thus increases the BL warming.展开更多
To investigate the spatiotemporal variations in the mixed layer depth(MLD)in the Arctic basins,a new criterion to determine the MLD,called the improved maximum angle method(IMAM),was developed.A total of 45123 potenti...To investigate the spatiotemporal variations in the mixed layer depth(MLD)in the Arctic basins,a new criterion to determine the MLD,called the improved maximum angle method(IMAM),was developed.A total of 45123 potential density profiles collected using Ice-Tethered Profilers(ITPs)in the Arctic basins during 2005-2021 were used to demonstrate the method’s effectiveness.By comparing the results obtained by the fixed threshold method(FTM),percentage threshold method(PTM),and maximum gradient method(MGM)for profiles in the Canada Basin,Makarov Basin,and Eurasian Basin,we determined that the quality index(1.0 for perfect identification of the MLD)of the IMAM regarding the assessment of the MLD determination method reached 0.94,which is much greater than those of other criteria.Moreover,two types of the density profiles were identified based on the mixed layer development stage.The MLDs of the typical profiles determined using the IMAM were found to have better consistency with the original definition.By utilizing the new mixed layer criterion,the seasonal variations and regional differences in the MLD in the Arctic basins were analyzed.Spatially,the summer and winter MLDs in the Canada Basin were the shallowest(13.55 m in summer,26.76 m in winter)than those in the Makarov(29.51 m in summer,49.08 m in winter)and Eurasian(20.36 m in summer,46.81 m in winter)basins due to the stable stratification in the upper ocean and the subsequent small effects of dynamic and thermodynamic processes(wind-driven stirring and brine rejection)in the Canada Basin.Seasonally,in the three Arctic basins,the average MLD was shallowest(22.77 m)in summer;it deepened through autumn and reached a winter maximum(41.12 m).展开更多
ZnO/NiO/ZnAl2O4 mixed-metal oxides were successfully synthesized through a hydrotalcite-like precursor route, in which appropriate amounts of metal salts solutions were mixed to obtain a new series of ZnNiAl layered d...ZnO/NiO/ZnAl2O4 mixed-metal oxides were successfully synthesized through a hydrotalcite-like precursor route, in which appropriate amounts of metal salts solutions were mixed to obtain a new series of ZnNiAl layered double hydroxides（LDHs） as precursors, followed by calcination under different temperatures. The as-obtained samples were characterized by SEM, HRTEM, TEM, XRD, BET, TG-DTA, and UV-Vis spectra techniques. The photocatalytic activities of the samples were evaluated by degradation of methyl orange（MO） under the simulated sunlight irradiation. The effects of Zn/Ni/Al mole ratio and calcination temperature on the composition, morphology and photocatalytic activity of the samples were investigated in detail. The results indicated that compared with ZnNiAl-LDHs, the mixed-metal oxide showed superior photocatalytic performance for the degradation of MO. A maximum of 97.3% photocatalytic decoloration rate within 60 min was achieved from the LDH with the Zn/Ni/Al mole ratio of 2：1：1 and the calcination temperature of 500 ℃, which much exceeded that of Degussa P25 under the same conditions. The possible mechanism of photocatalytic degradation over ZnO/NiO/ZnAl2O4 was discussed.展开更多
High-performance lithium-ion batteries(LIB)are important in powering emerging technologies.Cathodes are regarded as the bottleneck of increasing battery energy density,among which layered oxides are the most promising...High-performance lithium-ion batteries(LIB)are important in powering emerging technologies.Cathodes are regarded as the bottleneck of increasing battery energy density,among which layered oxides are the most promising candidates for LIB.However,a limitation with layered oxides cathodes is the transition metal and Li site mixing,which significantly impacts battery capacity and cycling stability.Despite recent research on Li/Ni mixing,there is a lack of comprehensive understanding of the origin of cation mixing between the transition metal and Li;therefore,practical means to address it.Here,a critical review of cation mixing in layered cathodes has been provided,emphasising the understanding of cation mixing mechanisms and their impact on cathode material design.We list and compare advanced characterisation techniques to detect cation mixing in the material structure;examine methods to regulate the degree of cation mixing in layered oxides to boost battery capacity and cycling performance,and critically assess how these can be applied practically.An appraisal of future research directions,including superexchange interaction to stabilise structures and boost capacity retention has also been concluded.Findings will be of immediate benefit in the design of layered cathodes for high-performance rechargeable LIB and,therefore,of interest to researchers and manufacturers.展开更多
Previously, most ocean circulation models have overlooked the role of the surface waves. As a result, these models have produced insufficient vertical mixing, with an under - prediction of the ,nixing layer （ML） dep...Previously, most ocean circulation models have overlooked the role of the surface waves. As a result, these models have produced insufficient vertical mixing, with an under - prediction of the ,nixing layer （ML） depth and an over - prediction of the sea surface temperature （SST）, particularly during the summer season. As the ocean surface layer determines the lower boundary conditions of the atmosphere, this deficiency has severely limited the performance of the coupled ocean - atmospheric models and hence the climate studies. To overcome this shortcoming, a new parameterization for the wave effects in the ML model that will correct this systematic error of insufficient mixing. The new scheme has enabled the mixing layer to deepen, the surface excessive heating to be corrected, and an excellent agreement with observed global climatologic data. The study indicates that the surface waves are essential for ML formation, and that they are the primer drivers of the upper ocean dynamics; therefore, they are critical for climate studies.展开更多
A one-dimensional mixed-layer model, including a Mellor- Yamada level 2.5 turbulence closure scheme, was implemented to investi- gate the dynamical and thermal structures of the ocean surface mixed layer in the northe...A one-dimensional mixed-layer model, including a Mellor- Yamada level 2.5 turbulence closure scheme, was implemented to investi- gate the dynamical and thermal structures of the ocean surface mixed layer in the northern South China Sea. The turbulent kinetic ener- gy released through wave breaking was incorporated into the model as a source of energy at the ocean surface, and the influence of the breaking waves on the mixed layer was studied. The numerical simulations show that the simulated SST is overestimated in summer without the breaking waves. However, the cooler SST is simulated when the effect of the breaking waves is considered, the corre- sponding discrepancy with the observed data decreases up to 20% and the MLD calculated averagely deepens 3.8 m. Owing to the wave-enhanced turbulence mixing in the summertime, the stratification at the bottom of the mixed layer was modified and the tempera- ture gradient spread throughout the whole thermocline compared with the concentrated distribution without wave breaking.展开更多
Multiple linear regression （MLR） method was applied to quantify the effects of the net heat flux （NHF）, the net freshwater flux （NFF） and the wind stress on the mixed layer depth （MLD） of the South China Sea ...Multiple linear regression （MLR） method was applied to quantify the effects of the net heat flux （NHF）, the net freshwater flux （NFF） and the wind stress on the mixed layer depth （MLD） of the South China Sea （SCS） based on the simple ocean data assimilation （SODA） dataset. The spatio-temporal distributions of the MLD, the buoyancy flux （combining the NHF and the NFF） and the wind stress of the SCS were presented. Then using an oceanic vertical mixing model, the MLD after a certain time under the same initial conditions but various pairs of boundary conditions （the three factors） was simulated. Applying the MLR method to the results, regression equations which modeling the relationship between the simulated MLD and the three factors were calculated. The equations indicate that when the NHF was negative, it was the primary driver of the mixed layer deepening; and when the NHF was positive, the wind stress played a more important role than that of the NHF while the NFF had the least effect. When the NHF was positive, the relative quantitative effects of the wind stress, the NHF, and the NFF were about i0, 6 and 2. The above conclusions were applied to explaining the spatio-temporal distributions of the MLD in the SCS and thus proved to be valid.展开更多
The aquatic eco-environment is significantly affected by temporal and spatial variation of the mixed layer depth （MLD） in large shallow lakes. In the present study, we simulated the three-dimensional water temperatu...The aquatic eco-environment is significantly affected by temporal and spatial variation of the mixed layer depth （MLD） in large shallow lakes. In the present study, we simulated the three-dimensional water temperature of Taihu Lake with an unstructured grid with a finite-volume coastal ocean model （FVCOM） using wind speed, wind direction, short-wave radiation and other meteorological data measured during 13-18 August 2008. The simulated results were consistent with the measurements. The temporal and spatial distribution of the MLD and the possible relevant mechanisms were analyzed on the basis of the water temperature profile data of Taihu Lake. The results indicated that diurnal stratification might be established through the combined effect of the hydrodynamic conditions induced by wind and the heat exchange between air and water. Compared with the net heat flux, the changes of the MLD were delayed approximately two hours. Furthermore, there were significant spatial differences of the MLD in Taihu Lake due to the combined impact of thermal and hydrodynamic forces. Briefly, diurnal stratification formed relatively easily in Gonghu Bay, Zhushan Bay, Xukou Bay and East Taihu Bay, and the surface mixed layer was thin. The center of the lake region had the deepest surface mixed layer due to the strong mixing process. In addition, Meiliang Bay showed a medium depth of the surface mixed layer. Our analysis indicated that the spatial difference in the hydrodynamic action was probably the major cause for the spatial variation of the MLD in Taihu Lake.展开更多
The present climate simulations of the mixed layer depth（MLD） and the subduction rate in the subtropical Northeast Pacific are investigated based on nine of the CMIP5 models. Compared with the observation data,spati...The present climate simulations of the mixed layer depth（MLD） and the subduction rate in the subtropical Northeast Pacific are investigated based on nine of the CMIP5 models. Compared with the observation data,spatial patterns of the MLD and the subduction rate are well simulated in these models. The spatial pattern of the MLD is nonuniform, with a local maximum MLD（〉140 m） region centered at（28°N, 135°W） in late winter. The nonuniform MLD pattern causes a strong MLD front on the south of the MLD maximum region, controls the lateral induction rate pattern, and then decides the nonuniform distribution of the subduction rate. Due to the inter-regional difference of the MLD, we divide this area into two regions. The relatively uniform Ekman pumping has little effect on the nonuniform subduction spatial pattern, though it is nearly equal to the lateral induction in values. In the south region, the northward warm Ekman advection（–1.75×10–7 K/s） controls the ocean horizontal temperature advection（–0.85×10–7 K/s）, and prevents the deepening of the MLD. In the ensemble mean, the contribution of the ocean advection to the MLD is about –29.0 m/month, offsetting the sea surface net heat flux contribution（33.9 m/month）. While in the north region, the southward cold advection deepens the MLD（21.4 m/month） as similar as the heat flux（30.4 m/month）. In conclusion, the nonuniform MLD pattern is dominated by the nonuniform ocean horizontal temperature advection. This new finding indicates that the upper ocean current play an important role in the variability of the winter MLD and the subduction rate.展开更多
By using the upper layer data(downloaded from the web of the Scripps Institution of Oceanography),the interannual variability of the heat storage of upper layer(from surface to 400 m depth) and the mixed layer depth i...By using the upper layer data(downloaded from the web of the Scripps Institution of Oceanography),the interannual variability of the heat storage of upper layer(from surface to 400 m depth) and the mixed layer depth in the tropical Pacific Ocean are investigated. The abnormal signal of the warm event comes from the central and west Pacific Ocean, whereas it is regarded that the abnormal signal of the warm event comes from the east Pacific Ocean in the popular viewpoint. From the viewpoint on the evolution of the interannual variability of the mixed layer depth and the heat storage of the whole upper layer, the difference between the two types of El Nino is so small that it can be neglected. During these two El Nino/La Nina events(1972/1973 and 1997/1998), other than the case of the heat storage or for the mixed layer depth, the abnormal signal propagates from the central and west Pacific Ocean to the east usually by the path along the equator whereas the abnormal signal propagates from the east to the west by the path northern to the equator. For the interannual variability, the evolution of the mixed layer depth corresponds to that of the heat storage in the upper layer very well. This is quite different from the evolution of seasonality.展开更多
The mechanisms behind the seasonal deepening of the mixed layer （ML） in the subtropical Southeast Pacific were investigated using the monthly Argo data from 2004 to 2012. The region with a deep ML （more than 175 m...The mechanisms behind the seasonal deepening of the mixed layer （ML） in the subtropical Southeast Pacific were investigated using the monthly Argo data from 2004 to 2012. The region with a deep ML （more than 175 m） was found in the region of （22°-30°S, 105°-90°W）, reaching its maximum depth （-200 m） near （27°-28°S, 100°W） in September. The relative importance of horizontal density advection in determining the maximum ML location is discussed qualitatively. Downward Ekman pumping is key to determining the eastern boundary of the deep ML region. In addition, zonal density advection by the subtropical countercurrent （STCC） in the subtropical Southwest Pacific determines its western boundary, by carrying lighter water to strengthen the stratification and form a ＂shallow tongue＂ of ML depth to block the westward extension of the deep ML in the STCC region. The temperature advection by the STCC is the main source for large heat loss from the subtropical Southwest Pacific. Finally, the combined effect of net surface heat flux and meridional density advection by the subtropical gyre determines the northern and southern boundaries of the deep ML region： the ocean heat loss at the surface gradually increases from 22~S to 35~S, while the meridional density advection by the subtropical gyre strengthens the strat- ification south of the maximum ML depth and weakens the stratification to the north. The freshwater flux contribution to deepening the ML during austral winter is limited. The results are useful for understanding the role of ocean dynamics in the ML formation in the subtropical Southeast Pacific.展开更多
It has been noted that when the convective Richardson number Ri* is used to characterize the depth of the entrainment zone, various parameterization schemes can be obtained. This situation is often attributed to the i...It has been noted that when the convective Richardson number Ri* is used to characterize the depth of the entrainment zone, various parameterization schemes can be obtained. This situation is often attributed to the invalidity of parcel theory. However, evidence shows that the convective Richardson number Ri* might be an improper characteristic scaling parameter for the entrainment process. An attempt to use an innovative parameter to parameterize the entrainment-zone thickness has been made in this paper. Based on the examination of the data of water-tank experiments and atmospheric measurements, it is found that the total lapse rate of potential temperature across the entrainment zone is proportional to that of the capping inversion layer. Inserting this relationship into the so-called parcel theory, it thus gives a new parameterization scheme for the depth of the entrainment zone. This scheme includes the lapse rate of the capping inversion layer that plays an important role in the entrainment process. Its physical representation is reasonable. The new scheme gives a better ordering of the data measured in both water-tank and atmosphere as compared with the traditional method using Ri*. These indicate that the parcel theory can describe the entrainment process suitably and that the new parameter is better than Ri*.展开更多
Large eddy simulation （LES） is used to investigate contrasting dynamic characteristics of shear turbulence （ST） and Langmuir circulation （LC） in the surface mixed layer （SML）. ST is usually induced by wind for...Large eddy simulation （LES） is used to investigate contrasting dynamic characteristics of shear turbulence （ST） and Langmuir circulation （LC） in the surface mixed layer （SML）. ST is usually induced by wind forcing in SML. LC can be driven by wave-current interaction that includes the roles of wind, wave and vortex forcing. The LES results show that LC suppresses the horizontal velocity and greatly modifies the downwind velocity profile, but increases the vertical velocity. The strong downweUing jets of LC accelerate and increase the downward transport of energy as compared to ST. The vertical eddy viscosity Km of LC is much larger than that of ST. Strong mixing induced by LC has two locations. They are located in the 26s-36s （Stokes depth scale） and the lower layer of the SML, respectively. Its value and position change periodically with time. In contrast, maximum Km induced by ST is located in the middle depth of the SML. The turbulent kinetic energy （TKE） generated by LC is larger than that by ST. The differences in vertical distributions of TKE and Krn are evident. Therefore, the parameterization of LC cannot be solely based on TKE. For deep SML, the convection of large-scale eddies in LC plays a main role in downward transport of energy and LC can induce stronger velocity shear （S2） near the SML base. In addition, the large-scale eddies and Sz induced by LC is changing all the time, which needs to be fully considered in the parameterization of LC.展开更多
Catalytic oxidation is regarded as one of the most promising strategies for volatile organic compounds(VOCs)purification.Mixed metal oxides(MMOs),after topological transformation using layered double hydroxides(LDHs)a...Catalytic oxidation is regarded as one of the most promising strategies for volatile organic compounds(VOCs)purification.Mixed metal oxides(MMOs),after topological transformation using layered double hydroxides(LDHs)as precursors,are extensively used as catalysts for VOCs oxidation due to their uniformity advantage.This review summarizes the developments in the LDH-derived VOCs heterogeneous catalytic oxidation over the last 10 years.Particularly,it addresses the VOCs abatement performance over MMO,noble metal/MMO,core-shell structured MMO,and integral MMO film catalysts originating from LDHs.Moreover,it highlights the water vapor effect and oxidation mechanism.This review indicates that LDH-based catalysts are a category of important VOCs oxidation materials.展开更多
As an important physical process at the air-sea interface, wave movement and breaking have a significant effect on the ocean surface mixed layer (OSML). When breaking waves occur at the ocean surface, turbulent kineti...As an important physical process at the air-sea interface, wave movement and breaking have a significant effect on the ocean surface mixed layer (OSML). When breaking waves occur at the ocean surface, turbulent kinetic energy (TKE) is input downwards, and a sublayer is formed near the surface and turbulence vertical mixing is intensively enhanced. A one-dimensional ocean model including the Mellor-Yamada level 2.5 turbulence closure equations was employed in our research on variations in turbulent energy budget within OSML. The influence of wave breaking could be introduced into the model by modifying an existing surface boundary condition of the TKE equation and specifying its input. The vertical diffusion and dissipation of TKE were effectively enhanced in the sublayer when wave breaking was considered. Turbulent energy dissipated in the sublayer was about 92.0% of the total depth-integrated dissipated TKE, which is twice higher than that of non-wave breaking. The shear production of TKE decreased by 3.5% because the mean flow fields tended to be uniform due to wave-enhanced turbulent mixing. As a result, a new local equilibrium between diffusion and dissipation of TKE was reached in the wave-enhanced layer. Below the sublayer, the local equilibrium between shear production and dissipation of TKE agreed with the conclusion drawn from the classical law-of-the-wall (Craig and Banner, 1994).展开更多
基金The National Natural Science Foundation of China under contract No.41605052。
文摘An obvious trend shift in the annual mean and winter mixed layer depth(MLD)in the Antarctic Circumpolar Current(ACC)region was detected during the 1960–2021 period.Shallowing trends stopped in mid-1980s,followed by a period of weak trends.The MLD deepening trend difference between the two periods were mainly distributed in the western areas in the Drake Passage,the areas north to Victoria Land and Wilkes Land,and the central parts of the South Indian sector.The newly formed ocean current shear due to the meridional shift of the ACC flow axis between the two periods is the dominant driver for the MLD trends shift distributed in the western areas in the Drake Passage and the central parts of the South Indian sector.The saltier trends in the regions north to Victoria Land and Wilkes Land could be responsible for the strengthening mixing processes in this region.
文摘Magnesium(Mg)is a widely used and attractive metal,known for its unique physical and chemical properties,and it has been employed in the manufacture of many practical materials.Layered Double Hydroxides(LDHs),particularly Mg-based LDHs,rank among the most prevalent two-dimensional materials utilized in separation processes,which include adsorption,extraction,and membrane technology.The high popularity of Mg-based LDHs in separation applications can be attributed to their properties,such as excellent hydrophilicity,high surface area,ion exchangeability,and adjustable interlayer space.Currently,polymer membranes play a pivotal role in semi-industrial and industrial separation processes.Consequently,the development of polymer membranes and the mitigation of their limitations have emerged as compelling topics for researchers.Several methods exist to enhance the separation performance and anti-fouling properties of polymer membranes.Among these,incorporating additives into the membrane polymer matrix stands out as a cost-effective,straightforward,readily available,and efficient approach.The use of Mg-based LDHs,either in combination with other materials or as a standalone additive in the polymer membrane matrix,represents a promising strategy to bolster the separation and anti-fouling efficacy of flat sheet mixed matrix polymer membranes.This review highlights Mg-based LDHs as high-potential additives designed to refine flat sheet mixed matrix polymer membranes for applications in wastewater treatment and brackish water desalination.
基金The Oceanic Interdisciplinary Program of Shanghai Jiao Tong University under contract No.SL2021ZD204the Sino-German Mobility Program under contract No.M0333the grant of Shanghai Frontiers Science Center of Polar Science(SCOPS).
文摘Based on the Ocean Reanalysis System version 5(ORAS5)and the fifth-generation reanalysis datasets derived from European Centre for Medium-Range Weather Forecasts(ERA5),we investigate the different impacts of the central Pacific(CP)El Niño and the eastern Pacific(EP)El Niño on the Southern Ocean(SO)mixed layer depth(MLD)during austral winter.The MLD response to the EP El Niño shows a dipole pattern in the South Pacific,namely the MLD dipole,which is the leading El Niño-induced MLD variability in the SO.The tropical Pacific warm sea surface temperature anomaly(SSTA)signal associated with the EP El Niño excites a Rossby wave train propagating southeastward and then enhances the Amundsen Sea low(ASL).This results in an anomalous cyclone over the Amundsen Sea.As a result,the anomalous southerly wind to the west of this anomalous cyclone advects colder and drier air into the southeast of New Zealand,leading to surface cooling through less total surface heat flux,especially surface sensible heat(SH)flux and latent heat(LH)flux,and thus contributing to the mix layer(ML)deepening.The east of the anomalous cyclone brings warmer and wetter air to the southwest of Chile,but the total heat flux anomaly shows no significant change.The warm air promotes the sea ice melting and maintains fresh water,which strengthens stratification.This results in a shallower MLD.During the CP El Niño,the response of MLD shows a separate negative MLD anomaly center in the central South Pacific.The Rossby wave train triggered by the warm SSTA in the central Pacific Ocean spreads to the Amundsen Sea,which weakens the ASL.Therefore,the anomalous anticyclone dominates the Amundsen Sea.Consequently,the anomalous northerly wind to the west of anomalous anticyclone advects warmer and wetter air into the central and southern Pacific,causing surface warming through increased SH,LH,and longwave radiation flux,and thus contributing to the ML shoaling.However,to the east of the anomalous anticyclone,there is no statistically significant impact on the MLD.
基金Supported by the National Key Research and Development Program of China(No.2018YFC1405701)the National Natural Science Foundation of China(Nos.92158204,41506001,42076026,41876017,42176027)+2 种基金the Project supported by Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)(No.GML2019ZD0304)the Open Research Project Programme of the State Key Laboratory of Internet of Things for Smart City(University of Macao)(No.SKL-IoTSC(UM)-2021-2023/ORPF/A20/2022)the State Key Laboratory of Tropical Oceanography(No.LTOZZ2101)。
文摘The upper mixed layer depth(h)has a significant seasonal variation in the real ocean and the low-order statistics of Langmuir turbulence are dramatically influenced by the upper mixed layer depth.To explore the influence of the upper mixed layer depth on Langmuir turbulence under the condition of the wind and wave equilibrium,the changes of Langmuir turbulence characteristics with the idealized variation of the upper mixed layer depth from very shallow(h=5 m)to deep enough(h=40 m)are studied using a non-hydrostatic large eddy simulation model.The simulation results show that there is a direct entrainment depth induced by Langmuir turbulence(h_(LT))within the thermocline.The normalized depthaveraged vertical velocity variance is smaller and larger than the downwind velocity variance for the ratio of the upper mixed layer to a direct entrainment depth induced by Langmuir turbulence h/h_(LT)<1 and h/h_(LT)>1,respectively,indicating that turbulence characteristics have the essential change(i.e.,depth-averaged vertical velocity variance(DAVV)DADV for Langmuir turbulence)between h/h_(LT)<1 and h/h_(LT)>1.The rate of change of the normalized depth-averaged low-order statistics for h/h_(LT)<1 is much larger than that for h/h_(LT)>1.The reason is that the downward pressure perturbation induced by Langmuir cells is strongly inhibited by the upward reactive force of the strong stratified thermocline for h/h_(LT)<1 and the eff ect of upward reactive force on the downward pressure perturbation becomes weak for h/h_(LT)>1.Hence,the upper mixed layer depth has significant influences on Langmuir turbulence characteristics.
基金supported by the National Natural Science Foundation of China(No.41830964)。
文摘Intraseasonal oscillation of the mixed layer and upper ocean temperature has been found to occur over the South China Sea(SCS)in the summer monsoon season based on the multiple reanalysis and observational data in this study.The method of composite analysis and an upper ocean temperature equation assisted the analysis of physical mechanisms.The results show that the mixed layer depth(MLD)in the SCS has a significant oscillation with a 30-60 d period over the SCS region,which is closely related to boreal summer intraseasonal oscillation(BSISO)activities.The MLD can increase(decrease)during the positive(negative)phase of the BSISO and usually lags behind by approximately one-eighth of the lifecycle(5 days)of the BSISO-related convection.The BSISO may cause periodic anomalies at the air-sea boundary,such as wind stress and heat flux,so it can play a dominant role in modulating the variation in MLD.There also are significant intraseasonal seawater temperature anomalies in both the surface and subsurface layers of the SCS.In addition,during the initial phase of the BSISO,the temperature anomaly signals of the thermocline are obviously opposite to the sea surface temperature(SST),especially in the southern SCS.According to the results from the analysis of the temperature equation,the vertical entrainment term caused by BSISO-related wind stress is stronger than the thermal forcing during the initial stage of convection,and it is more significant in the southern SCS.
基金The National Natural Science Foundation of China under contract No.42276003the Oceanic Interdisciplinary Program of Shanghai Jiao Tong University under contract No.SL2021MS021.
文摘The southeastern Indian Ocean is characterized by the warm barrier layer(BL)underlying the cool mixed layer water in austral winter.This phenomenon lasts almost half a year and thus provides a unique positive effect on the upper mixed layer heat content through the entrainment processes at the base of the mixed layer,which has not been well evaluated due to the lack of proper method and dataset.Among various traditional threshold methods,here it is shown that the 5 m fixed depth difference can produce a reliable and accurate estimate of the entrainment heat flux(EHF)in this BL region.The comparison between the daily and monthly EHF warming indicates that the account for high-frequency EHF variability almost doubles the warming effect in the BL period,which can compensate for or even surpass the surface heat loss.This increased warming is a result of stronger relative rate of the mixed layer deepening and larger temperature differences between the mixed layer and its immediate below in the daily-resolving data.The interannual EHF shows a moderately increasing trend and similar variabilities to the Southern Annular Mode(SAM),likely because the mixed layer deepening under the positive SAM trend is accompanied by enhanced turbulent entrainment and thus increases the BL warming.
基金Supported by the National Key R&D Program of China(Nos.2018 YFA 0605903,2019 YFC 1509101)the National Natural Science Foundation of China(No.41976218)the Fundamental Research Funds for the Central Universities(No.202165005)。
文摘To investigate the spatiotemporal variations in the mixed layer depth(MLD)in the Arctic basins,a new criterion to determine the MLD,called the improved maximum angle method(IMAM),was developed.A total of 45123 potential density profiles collected using Ice-Tethered Profilers(ITPs)in the Arctic basins during 2005-2021 were used to demonstrate the method’s effectiveness.By comparing the results obtained by the fixed threshold method(FTM),percentage threshold method(PTM),and maximum gradient method(MGM)for profiles in the Canada Basin,Makarov Basin,and Eurasian Basin,we determined that the quality index(1.0 for perfect identification of the MLD)of the IMAM regarding the assessment of the MLD determination method reached 0.94,which is much greater than those of other criteria.Moreover,two types of the density profiles were identified based on the mixed layer development stage.The MLDs of the typical profiles determined using the IMAM were found to have better consistency with the original definition.By utilizing the new mixed layer criterion,the seasonal variations and regional differences in the MLD in the Arctic basins were analyzed.Spatially,the summer and winter MLDs in the Canada Basin were the shallowest(13.55 m in summer,26.76 m in winter)than those in the Makarov(29.51 m in summer,49.08 m in winter)and Eurasian(20.36 m in summer,46.81 m in winter)basins due to the stable stratification in the upper ocean and the subsequent small effects of dynamic and thermodynamic processes(wind-driven stirring and brine rejection)in the Canada Basin.Seasonally,in the three Arctic basins,the average MLD was shallowest(22.77 m)in summer;it deepened through autumn and reached a winter maximum(41.12 m).
基金Project(21306041)supported by the National Natural Science Young Foundation of ChinaProject(21271071)supported by the National Natural Science Foundation of ChinaProject(15A076)supported by the Scientific Research Foundation of Hunan Provincial Education Department of China
文摘ZnO/NiO/ZnAl2O4 mixed-metal oxides were successfully synthesized through a hydrotalcite-like precursor route, in which appropriate amounts of metal salts solutions were mixed to obtain a new series of ZnNiAl layered double hydroxides（LDHs） as precursors, followed by calcination under different temperatures. The as-obtained samples were characterized by SEM, HRTEM, TEM, XRD, BET, TG-DTA, and UV-Vis spectra techniques. The photocatalytic activities of the samples were evaluated by degradation of methyl orange（MO） under the simulated sunlight irradiation. The effects of Zn/Ni/Al mole ratio and calcination temperature on the composition, morphology and photocatalytic activity of the samples were investigated in detail. The results indicated that compared with ZnNiAl-LDHs, the mixed-metal oxide showed superior photocatalytic performance for the degradation of MO. A maximum of 97.3% photocatalytic decoloration rate within 60 min was achieved from the LDH with the Zn/Ni/Al mole ratio of 2：1：1 and the calcination temperature of 500 ℃, which much exceeded that of Degussa P25 under the same conditions. The possible mechanism of photocatalytic degradation over ZnO/NiO/ZnAl2O4 was discussed.
基金the Australian Institute of Nuclear Science and Engineering (AINSE) Limited for providing financial assistance in the form of a Post Graduate Research Award (PGRA) to carry out this worksupported by the Australian Research Council under grants DP200101862, DP210101486, and FL210100050
文摘High-performance lithium-ion batteries(LIB)are important in powering emerging technologies.Cathodes are regarded as the bottleneck of increasing battery energy density,among which layered oxides are the most promising candidates for LIB.However,a limitation with layered oxides cathodes is the transition metal and Li site mixing,which significantly impacts battery capacity and cycling stability.Despite recent research on Li/Ni mixing,there is a lack of comprehensive understanding of the origin of cation mixing between the transition metal and Li;therefore,practical means to address it.Here,a critical review of cation mixing in layered cathodes has been provided,emphasising the understanding of cation mixing mechanisms and their impact on cathode material design.We list and compare advanced characterisation techniques to detect cation mixing in the material structure;examine methods to regulate the degree of cation mixing in layered oxides to boost battery capacity and cycling performance,and critically assess how these can be applied practically.An appraisal of future research directions,including superexchange interaction to stabilise structures and boost capacity retention has also been concluded.Findings will be of immediate benefit in the design of layered cathodes for high-performance rechargeable LIB and,therefore,of interest to researchers and manufacturers.
基金The National Natural Science Foundation of China No.40730842the"973"project of China under contract No.2006CB403605
文摘Previously, most ocean circulation models have overlooked the role of the surface waves. As a result, these models have produced insufficient vertical mixing, with an under - prediction of the ,nixing layer （ML） depth and an over - prediction of the sea surface temperature （SST）, particularly during the summer season. As the ocean surface layer determines the lower boundary conditions of the atmosphere, this deficiency has severely limited the performance of the coupled ocean - atmospheric models and hence the climate studies. To overcome this shortcoming, a new parameterization for the wave effects in the ML model that will correct this systematic error of insufficient mixing. The new scheme has enabled the mixing layer to deepen, the surface excessive heating to be corrected, and an excellent agreement with observed global climatologic data. The study indicates that the surface waves are essential for ML formation, and that they are the primer drivers of the upper ocean dynamics; therefore, they are critical for climate studies.
基金supported by the cooperative project of the Chinese Academy of Sciencesthe China National Offshore Oil Corporation+1 种基金the National Natural Science Foundation of China under contract Nos 40376008 and 40476008Open Projects of the Key Laboratory of Physical Oceanography of Ministry of Education of China under contract No.200310.
文摘A one-dimensional mixed-layer model, including a Mellor- Yamada level 2.5 turbulence closure scheme, was implemented to investi- gate the dynamical and thermal structures of the ocean surface mixed layer in the northern South China Sea. The turbulent kinetic ener- gy released through wave breaking was incorporated into the model as a source of energy at the ocean surface, and the influence of the breaking waves on the mixed layer was studied. The numerical simulations show that the simulated SST is overestimated in summer without the breaking waves. However, the cooler SST is simulated when the effect of the breaking waves is considered, the corre- sponding discrepancy with the observed data decreases up to 20% and the MLD calculated averagely deepens 3.8 m. Owing to the wave-enhanced turbulence mixing in the summertime, the stratification at the bottom of the mixed layer was modified and the tempera- ture gradient spread throughout the whole thermocline compared with the concentrated distribution without wave breaking.
基金The National Natural Science Foundation of China under contract No.11174235the Science and Technology Development Project of Shaanxi Province of China under contract No.2010KJXX-02+2 种基金the Program for New Century Excellent Talents in University of China under contract No. NCET-08-0455the Science and Technology Innovation Foundation of Northwestern Polytechnical University of Chinathe Doctorate Foundation of Northwestern Polytechnical University of China under contract No.CX201226.
文摘Multiple linear regression （MLR） method was applied to quantify the effects of the net heat flux （NHF）, the net freshwater flux （NFF） and the wind stress on the mixed layer depth （MLD） of the South China Sea （SCS） based on the simple ocean data assimilation （SODA） dataset. The spatio-temporal distributions of the MLD, the buoyancy flux （combining the NHF and the NFF） and the wind stress of the SCS were presented. Then using an oceanic vertical mixing model, the MLD after a certain time under the same initial conditions but various pairs of boundary conditions （the three factors） was simulated. Applying the MLR method to the results, regression equations which modeling the relationship between the simulated MLD and the three factors were calculated. The equations indicate that when the NHF was negative, it was the primary driver of the mixed layer deepening; and when the NHF was positive, the wind stress played a more important role than that of the NHF while the NFF had the least effect. When the NHF was positive, the relative quantitative effects of the wind stress, the NHF, and the NFF were about i0, 6 and 2. The above conclusions were applied to explaining the spatio-temporal distributions of the MLD in the SCS and thus proved to be valid.
基金supported by the National Natoral Science Foundation of Ghina (Grant Nos.41071070.41165001.and 41171368)the Special Scientific Research Project of the China Commonwealth Trade(meteorology)(GYHY201006054)
文摘The aquatic eco-environment is significantly affected by temporal and spatial variation of the mixed layer depth （MLD） in large shallow lakes. In the present study, we simulated the three-dimensional water temperature of Taihu Lake with an unstructured grid with a finite-volume coastal ocean model （FVCOM） using wind speed, wind direction, short-wave radiation and other meteorological data measured during 13-18 August 2008. The simulated results were consistent with the measurements. The temporal and spatial distribution of the MLD and the possible relevant mechanisms were analyzed on the basis of the water temperature profile data of Taihu Lake. The results indicated that diurnal stratification might be established through the combined effect of the hydrodynamic conditions induced by wind and the heat exchange between air and water. Compared with the net heat flux, the changes of the MLD were delayed approximately two hours. Furthermore, there were significant spatial differences of the MLD in Taihu Lake due to the combined impact of thermal and hydrodynamic forces. Briefly, diurnal stratification formed relatively easily in Gonghu Bay, Zhushan Bay, Xukou Bay and East Taihu Bay, and the surface mixed layer was thin. The center of the lake region had the deepest surface mixed layer due to the strong mixing process. In addition, Meiliang Bay showed a medium depth of the surface mixed layer. Our analysis indicated that the spatial difference in the hydrodynamic action was probably the major cause for the spatial variation of the MLD in Taihu Lake.
基金The National Natural Science Foundation of China under contract Nos 41606217,41675064 and 41406214the Scientific Research Foundation for the Talent Start-Up of University of Information Science and Technology under contract No.2015r043+1 种基金the Open Fund of the Key Laboratory of Research on Marine Hazards Forecasting under contract No.LOMF1702the China Scholarship Council under contract No.201708320046
文摘The present climate simulations of the mixed layer depth（MLD） and the subduction rate in the subtropical Northeast Pacific are investigated based on nine of the CMIP5 models. Compared with the observation data,spatial patterns of the MLD and the subduction rate are well simulated in these models. The spatial pattern of the MLD is nonuniform, with a local maximum MLD（〉140 m） region centered at（28°N, 135°W） in late winter. The nonuniform MLD pattern causes a strong MLD front on the south of the MLD maximum region, controls the lateral induction rate pattern, and then decides the nonuniform distribution of the subduction rate. Due to the inter-regional difference of the MLD, we divide this area into two regions. The relatively uniform Ekman pumping has little effect on the nonuniform subduction spatial pattern, though it is nearly equal to the lateral induction in values. In the south region, the northward warm Ekman advection（–1.75×10–7 K/s） controls the ocean horizontal temperature advection（–0.85×10–7 K/s）, and prevents the deepening of the MLD. In the ensemble mean, the contribution of the ocean advection to the MLD is about –29.0 m/month, offsetting the sea surface net heat flux contribution（33.9 m/month）. While in the north region, the southward cold advection deepens the MLD（21.4 m/month） as similar as the heat flux（30.4 m/month）. In conclusion, the nonuniform MLD pattern is dominated by the nonuniform ocean horizontal temperature advection. This new finding indicates that the upper ocean current play an important role in the variability of the winter MLD and the subduction rate.
基金This project is supported by the National Natural Science Foundation of China under contract No.59021 1004,40005007,49975021,and 40376039.
文摘By using the upper layer data(downloaded from the web of the Scripps Institution of Oceanography),the interannual variability of the heat storage of upper layer(from surface to 400 m depth) and the mixed layer depth in the tropical Pacific Ocean are investigated. The abnormal signal of the warm event comes from the central and west Pacific Ocean, whereas it is regarded that the abnormal signal of the warm event comes from the east Pacific Ocean in the popular viewpoint. From the viewpoint on the evolution of the interannual variability of the mixed layer depth and the heat storage of the whole upper layer, the difference between the two types of El Nino is so small that it can be neglected. During these two El Nino/La Nina events(1972/1973 and 1997/1998), other than the case of the heat storage or for the mixed layer depth, the abnormal signal propagates from the central and west Pacific Ocean to the east usually by the path along the equator whereas the abnormal signal propagates from the east to the west by the path northern to the equator. For the interannual variability, the evolution of the mixed layer depth corresponds to that of the heat storage in the upper layer very well. This is quite different from the evolution of seasonality.
基金supported by the National Basic Research Program of China (Grant No. 2012CB955603)the National Natural Science Foundation of China (Grant Nos. 41176006 and 41490643)the Shandong Joint Fund for Marine Science Research Centers (Grant No. U1406401)
文摘The mechanisms behind the seasonal deepening of the mixed layer （ML） in the subtropical Southeast Pacific were investigated using the monthly Argo data from 2004 to 2012. The region with a deep ML （more than 175 m） was found in the region of （22°-30°S, 105°-90°W）, reaching its maximum depth （-200 m） near （27°-28°S, 100°W） in September. The relative importance of horizontal density advection in determining the maximum ML location is discussed qualitatively. Downward Ekman pumping is key to determining the eastern boundary of the deep ML region. In addition, zonal density advection by the subtropical countercurrent （STCC） in the subtropical Southwest Pacific determines its western boundary, by carrying lighter water to strengthen the stratification and form a ＂shallow tongue＂ of ML depth to block the westward extension of the deep ML in the STCC region. The temperature advection by the STCC is the main source for large heat loss from the subtropical Southwest Pacific. Finally, the combined effect of net surface heat flux and meridional density advection by the subtropical gyre determines the northern and southern boundaries of the deep ML region： the ocean heat loss at the surface gradually increases from 22~S to 35~S, while the meridional density advection by the subtropical gyre strengthens the strat- ification south of the maximum ML depth and weakens the stratification to the north. The freshwater flux contribution to deepening the ML during austral winter is limited. The results are useful for understanding the role of ocean dynamics in the ML formation in the subtropical Southeast Pacific.
基金This paper was supported by the National Natural Science Foundation of China under Grant Nos.40105002 and 40333027.
文摘It has been noted that when the convective Richardson number Ri* is used to characterize the depth of the entrainment zone, various parameterization schemes can be obtained. This situation is often attributed to the invalidity of parcel theory. However, evidence shows that the convective Richardson number Ri* might be an improper characteristic scaling parameter for the entrainment process. An attempt to use an innovative parameter to parameterize the entrainment-zone thickness has been made in this paper. Based on the examination of the data of water-tank experiments and atmospheric measurements, it is found that the total lapse rate of potential temperature across the entrainment zone is proportional to that of the capping inversion layer. Inserting this relationship into the so-called parcel theory, it thus gives a new parameterization scheme for the depth of the entrainment zone. This scheme includes the lapse rate of the capping inversion layer that plays an important role in the entrainment process. Its physical representation is reasonable. The new scheme gives a better ordering of the data measured in both water-tank and atmosphere as compared with the traditional method using Ri*. These indicate that the parcel theory can describe the entrainment process suitably and that the new parameter is better than Ri*.
基金The National Basic Research Program of China(973 Program)under contract No.2011CB403504the China Postdoctoral Science Foundation under contract No.2013M542216the National Natural Science Foundation of China under contract No.41206011
文摘Large eddy simulation （LES） is used to investigate contrasting dynamic characteristics of shear turbulence （ST） and Langmuir circulation （LC） in the surface mixed layer （SML）. ST is usually induced by wind forcing in SML. LC can be driven by wave-current interaction that includes the roles of wind, wave and vortex forcing. The LES results show that LC suppresses the horizontal velocity and greatly modifies the downwind velocity profile, but increases the vertical velocity. The strong downweUing jets of LC accelerate and increase the downward transport of energy as compared to ST. The vertical eddy viscosity Km of LC is much larger than that of ST. Strong mixing induced by LC has two locations. They are located in the 26s-36s （Stokes depth scale） and the lower layer of the SML, respectively. Its value and position change periodically with time. In contrast, maximum Km induced by ST is located in the middle depth of the SML. The turbulent kinetic energy （TKE） generated by LC is larger than that by ST. The differences in vertical distributions of TKE and Krn are evident. Therefore, the parameterization of LC cannot be solely based on TKE. For deep SML, the convection of large-scale eddies in LC plays a main role in downward transport of energy and LC can induce stronger velocity shear （S2） near the SML base. In addition, the large-scale eddies and Sz induced by LC is changing all the time, which needs to be fully considered in the parameterization of LC.
基金supported by the National Key R&D Program of China(2017YFC0211503,2016YFC0207100)the Strategic Priority Research Program(A)of the Chinese Academy of Sciences(XDA23030300)+2 种基金the National Natural Science Foundation of China(21401200,51672273)the Open Research Fund of State Key Laboratory of Multi-phase Complex Systems(MPCS-2017-D-06)the Young Talent Project of the Center for Excellence in Regional Atmospheric Environment,CAS(CERAE201805)~~
文摘Catalytic oxidation is regarded as one of the most promising strategies for volatile organic compounds(VOCs)purification.Mixed metal oxides(MMOs),after topological transformation using layered double hydroxides(LDHs)as precursors,are extensively used as catalysts for VOCs oxidation due to their uniformity advantage.This review summarizes the developments in the LDH-derived VOCs heterogeneous catalytic oxidation over the last 10 years.Particularly,it addresses the VOCs abatement performance over MMO,noble metal/MMO,core-shell structured MMO,and integral MMO film catalysts originating from LDHs.Moreover,it highlights the water vapor effect and oxidation mechanism.This review indicates that LDH-based catalysts are a category of important VOCs oxidation materials.
基金Supported by the NSFC (No. 40476008)Knowledge Innovation Programs of the Chinese Academy of Sciences (No. KZCX3-SW-222)the NSFDYS (No. 40425015)
文摘As an important physical process at the air-sea interface, wave movement and breaking have a significant effect on the ocean surface mixed layer (OSML). When breaking waves occur at the ocean surface, turbulent kinetic energy (TKE) is input downwards, and a sublayer is formed near the surface and turbulence vertical mixing is intensively enhanced. A one-dimensional ocean model including the Mellor-Yamada level 2.5 turbulence closure equations was employed in our research on variations in turbulent energy budget within OSML. The influence of wave breaking could be introduced into the model by modifying an existing surface boundary condition of the TKE equation and specifying its input. The vertical diffusion and dissipation of TKE were effectively enhanced in the sublayer when wave breaking was considered. Turbulent energy dissipated in the sublayer was about 92.0% of the total depth-integrated dissipated TKE, which is twice higher than that of non-wave breaking. The shear production of TKE decreased by 3.5% because the mean flow fields tended to be uniform due to wave-enhanced turbulent mixing. As a result, a new local equilibrium between diffusion and dissipation of TKE was reached in the wave-enhanced layer. Below the sublayer, the local equilibrium between shear production and dissipation of TKE agreed with the conclusion drawn from the classical law-of-the-wall (Craig and Banner, 1994).
