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Evaluation of threading dislocation density of strained Ge epitaxial layer by high resolution x-ray diffraction 被引量:1
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作者 苗渊浩 胡辉勇 +3 位作者 李鑫 宋建军 宣荣喜 张鹤鸣 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第12期511-515,共5页
The analysis of threading dislocation density(TDD)in Ge-on-Si layer is critical for developing lasers,light emitting diodes(LEDs),photodetectors(PDs),modulators,waveguides,metal oxide semiconductor field effect transi... The analysis of threading dislocation density(TDD)in Ge-on-Si layer is critical for developing lasers,light emitting diodes(LEDs),photodetectors(PDs),modulators,waveguides,metal oxide semiconductor field effect transistors(MOS-FETs),and also the integration of Si-based monolithic photonics.The TDD of Ge epitaxial layer is analyzed by etching or transmission electron microscope(TEM).However,high-resolution x-ray diffraction(HR-XRD)rocking curve provides an optional method to analyze the TDD in Ge layer.The theory model of TDD measurement from rocking curves was first used in zinc-blende semiconductors.In this paper,this method is extended to the case of strained Ge-on-Si layers.The HR-XRD 2θ/ωscan is measured and Ge(004)single crystal rocking curve is utilized to calculate the TDD in strained Ge epitaxial layer.The rocking curve full width at half maximum(FWHM)broadening by incident beam divergence of the instrument,crystal size,and curvature of the crystal specimen is subtracted.The TDDs of samples A and B are calculated to be 1.41×10~8cm^(-2)and 6.47×10~8cm^(-2),respectively.In addition,we believe the TDDs calculated by this method to be the averaged dislocation density in the Ge epitaxial layer. 展开更多
关键词 HR-XRD RPCVD threading dislocation density(TDD) etching pit density(EPD)
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Microstructure, Dislocation Density and Thermal Expansion Behavior Using Thermo Elastic Models of Zircon Sand Reinforced as Cast ZA-27 Composites
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作者 G. R. Gurunagendra V. Bharat +3 位作者 B. R. Raju D. G. Amith Vijayakumar Pujar C. Ravi Keerthi 《Journal of Minerals and Materials Characterization and Engineering》 2021年第1期100-115,共16页
In the present work stir casting route is used to fabricate the ZA27 Metal matrix composites containing 3 wt%, 6 wt%, 9 wt%, and 12 wt%. Zircon sand particulates of size 100 mesh. Microstructure studies using Optical ... In the present work stir casting route is used to fabricate the ZA27 Metal matrix composites containing 3 wt%, 6 wt%, 9 wt%, and 12 wt%. Zircon sand particulates of size 100 mesh. Microstructure studies using Optical Microscopy, SEM-EDAX are carried out to ascertain the distribution and morphology of particulates in the composites. Effect of zircon sand as reinforcement on bulk density, porosity, of the fabricated composites is studied. SEM studies are carried out to understand the behavior of as-cast ZA27 alloy reinforced with zircon sand. The dislocation density of the fabricated composite affects the strength of the composites and depends on the strain due to thermal mismatch and is found to increase with increase in weight% of zircon sand. However, it does not consider casting defects of voids/clustering observed in micrographs of the fabricated composite. Porosity in composites does not have influence on Coefficient of thermal expansion (CTE) of the ZA27 composites studied using thermoelastic models like Kerner and turner model and rule of mixtures of composite. 展开更多
关键词 density POROSITY dislocation density Thermoelastic Models Rule of Mixtures
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Comparison and analysis of dislocation density, morphology and evolution in microstructure of low-carbon steel produced using different technologies 被引量:5
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作者 YU Hao~ 1) , KANG Yonglin~ 1) , DONG Hongbo~ 2) 1) Materials Science and Engineering School, University of Science and Technology Beijing, Beijing 100083, China 2) Jinan Iron & Steel Group Co., Jinan 250101, China 《北京科技大学学报》 EI CAS CSCD 北大核心 2006年第11期1018-1018,共1页
Three kinds of specimens were produced from hot strips of similar composition and same thickness (nominal gauge 4.0mm) but produced using different technologies, and the dislocation density of these strips was quantit... Three kinds of specimens were produced from hot strips of similar composition and same thickness (nominal gauge 4.0mm) but produced using different technologies, and the dislocation density of these strips was quantitatively measured by positron annihilation technique test. The dislocation morphology and evolution in microstructure of each pass for producing the 1.9mm hot strip using CSP (compact strip production) technology were observed under an H-800 transmission electron microscope; its density was also quantitatively measured using the positron annihilation technique test, and the factors influencing the dislocation density during the production process were analyzed. The experimental results show that the dislocation density in the microstructure produced using CSP technology is higher than that in the microstructure produced using conventional technology. This result was discussed and confirmed on the basis of the finite element simulation and the theory relevant to dislocations. 展开更多
关键词 compact strip production (CSP) MICROSTRUCTURE dislocation positron annihilation technique finite element simulation
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Evaluation of mobile dislocation density based on distribution function of dislocation segments
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作者 周志敏 孙艳蕊 周海涛 《中国有色金属学会会刊:英文版》 CSCD 2004年第5期977-980,共4页
A function is offered to represent the distribution of reduced length of dislocation segments. The segment distribution of materials, e.g., MgO and Cu, can be well described by taking appropriate values of parameters ... A function is offered to represent the distribution of reduced length of dislocation segments. The segment distribution of materials, e.g., MgO and Cu, can be well described by taking appropriate values of parameters m and n. Based on this function, a model for evaluating the mobile dislocation density is developed. Provided the total dislocation density and applied stress are known, the mobile dislocation density could be readily assessed by using this model. For pure copper the mobile dislocation density and strain rates at deferent strains are evaluated. The calculated results are consistent with the known experimental data. 展开更多
关键词 位错密度 塑性材料 金属 晶体 MGO 氧化镁
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Comparison and analysis of dislocation density,morphology and evolution in mi-crostructure of low-carbon steel produced using different technologies
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作者 Hao Yu Yonglin Kang Hongbo Dong 《Journal of University of Science and Technology Beijing》 CSCD 2006年第5期406-410,共5页
Three kinds of specimens were produced from hot strips of similar composition and same thickness (nominal gauge 4.0 mm) but produced using different technologies, and the dislocation density of these strips was quanti... Three kinds of specimens were produced from hot strips of similar composition and same thickness (nominal gauge 4.0 mm) but produced using different technologies, and the dislocation density of these strips was quantitatively measured by positron annihila- tion technique test. The dislocation morphology and evolution in microstructure of each pass for producing the 1.9 mm hot strip using CSP (compact strip production) technology were observed under an H-800 transmission electron microscope; its density was also quantitatively measured using the positron annihilation technique test, and the factors influencing the dislocation density during the production process were analyzed. The experimental results show that the dislocation density in the microstructure produced using CSP technology is higher than that in the microstructure produced using conventional technology. This result was discussed and confirmed on the basis of the finite element simulation and the theory relevant to dislocations. 展开更多
关键词 紧凑型带钢生产 CSP生产线 显微结构 断层 正电子湮灭术 有限元模拟
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An iterative blending integrating grinding force model considering grain size and dislocation density evolution
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作者 Zi-Shan Ding Yun-Hui Zhao +3 位作者 Miao-Xian Guo Wei-Cheng Guo Chong-Jun Wu Steven Y.Liang 《Advances in Manufacturing》 SCIE EI CAS CSCD 2023年第3期428-443,共16页
The dynamic force load in grinding process is considered as a crucial factor affecting the quality of parts,and a better understanding of the mechanism of force generation is conducive to revealing the evolution of ma... The dynamic force load in grinding process is considered as a crucial factor affecting the quality of parts,and a better understanding of the mechanism of force generation is conducive to revealing the evolution of material microstructure more precisely.In this study,an iterative blending integrating grinding force model that comprehensively considers the impact of grain size and dislocation density evolution of the material is proposed.According to the grinding kinematics,the interaction of grit-workpiece is divided into rubbing,plowing,and chip formation stages in each grinding zone.On this basis,the evolution of material microstructure in the current chip formation stage will affect the rubbing force in the next grinding arc through flow stresses,which in turn will influence the total grinding force.Therefore,the flow stress models in rubbing and chip formation stages are firstly established,and then the dislocation density prediction model is established experimentally based on the characteristics of grain size.The effects of the evolution of grain size and dislocation density on the grinding forces during the grinding process are studied by means of iterative cycles.The results indicate that the implementation of an iterative blending scheme is instrumental in obtaining a higher accurate prediction of the grinding force and a deeper insight of the influence mechanisms of materials microstructure on grinding process. 展开更多
关键词 Grinding force Grain size dislocation density Iterative loop
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Elbow Dislocation in Children: About Two Cases and Review of the Literature
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作者 Nyanit Bob Dorcas Atangana Cédric Paterson +10 位作者 Mantho Fopa Pauline Kouna TsalaIrène Nadine Mvouni Bob Thérèse Raissa Bekima King Francis Ateaze Chrisantus Dikongue Diwondi Audrey Ndongo Réné Akoa Manga Ismael Evoni Molo Tatiana Choupo Guetchuin Stéphane Handy Eone Daniel 《Open Journal of Pediatrics》 2024年第2期218-226,共9页
Background: Elbow dislocations in pediatric patients are rare injuries. This is a therapeutic emergency because a delay in treatment can have disastrous consequences on the functional level of the upper limb. Objectiv... Background: Elbow dislocations in pediatric patients are rare injuries. This is a therapeutic emergency because a delay in treatment can have disastrous consequences on the functional level of the upper limb. Objective: To present the management of elbow dislocation in children in cases of limited resources. Presentation of the Cases: These were 2 older male children aged 7 and 9 years old, admitted to the emergency room for painful functional impotence of the right elbow after a fall and landing on the right hand. Clinical and radiological examinations were in favor of posterior elbow dislocations. The reductions were carried out under sedation and immobilization in Jersey. According to Robert’s criteria, the functional result was excellent in both patients. Conclusion: Emergency reduction and immobilization whatever the means ensure an excellent functional prognosis even in cases of limited resources. 展开更多
关键词 Elbow dislocation CHILD DIAGNOSIS TREATMENT Limited Resources
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Electron density measurement by the three boundary channels of HCOOH laser interferometer on the HL-3 tokamak
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作者 牟俊任 李永高 +5 位作者 李远 王再宏 丁宝钢 王浩西 易江 石中兵 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第3期88-93,共6页
Far-infrared(FIR)interferometer is widely used to measure the electron density in the magnetically confined fusion plasma devices.A new FIR laser interferometer with a total of 13 channels(8 horizontal channels and 5 ... Far-infrared(FIR)interferometer is widely used to measure the electron density in the magnetically confined fusion plasma devices.A new FIR laser interferometer with a total of 13 channels(8 horizontal channels and 5 oblique channels)is under development on the HL-3tokamak by using the formic-acid laser(HCOOH,f=694 GHz).In order to investigate the boundary electron density activity during the divertor discharge,three horizontal interferometry channels located at Z=-97,-76,76.5 cm have been successfully developed on HL-3 in 2023,and put into operation in recent experimental campaign,with a time resolution of<1.0μs and lineintegrated electron density resolution of~7.0×10^(16) m^(-2).This paper mainly focuses on the optical design of the three-channel interferometry system,as well as optical elements and recent experimental result on HL-3. 展开更多
关键词 electron density INTERFEROMETER HL-3
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Comparison of Surgical Techniques Used in Treating Acromioclavicular Dislocation in Patients Participating in Sports: A Systematic Review
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作者 Walter Hugo Brandão Nascimento Paulo Renan Matos Sucupira Cunha +3 位作者 João Pedro Pimentel Abreu Lethycia Pereira Rosa Kamilly Iêda Silva Veigas Rodrigo Martins Silva Caetano 《Open Journal of Orthopedics》 2024年第1期41-52,共12页
Introduction: The acromioclavicular joint is a superficial diarthrodial joint that surrounds the medial articular facet of the acromion and the distal portion of the clavicle. Due to its anatomy and biomechanics, it i... Introduction: The acromioclavicular joint is a superficial diarthrodial joint that surrounds the medial articular facet of the acromion and the distal portion of the clavicle. Due to its anatomy and biomechanics, it is highly susceptible to trauma and in young men who play contact sports, acromioclavicular dislocation is common. This article aimed to systematically review the literature and compare the surgical techniques used in the treatment of acromioclavicular dislocation in patients who practice sports. Methods: This systematic review was conducted according to the International Preferred Reporting Items for Systematic Review and Meta-Analyses guidelines. Eligible studies for this systematic review included articles in English or Spanish published between 2013 and 2023, which mention the occurrence of acromioclavicular dislocation during sports practices. Additionally, only studies that addressed the surgical treatment of acromion-clavicular dislocation and contained original data on the topic were included. Results: We found 144 eligible studies after searching the LILACS and PubMed databases. Based on the inclusion and exclusion criteria and the reviewers’ consensus, we selected four studies for the systematic review. 133 patients with AC joint displacement were evaluated. Mean Age: approximately 31.90 years. 81.92 of these injuries occurred during sports practice. Surgical Procedures Used: titanium plates fixation (49 patients), arthroscopy (24), single tunnel technique (30) and coracoid sling technique (30). The results of the visual analog scale and Constant-Murley scores varied between the techniques used. Twenty-two complications after surgical treatment were identified. Conclusion: A significant variability of operative techniques can be used in the surgical approach of acromioclavicular dislocation, such as arthroscopy, single tunnel, coracoid sling and titanium plates. Although it presented excellent functional results compared to the other three techniques evaluated by this review, using titanium plates is not the gold standard since other techniques not assessed by this work may be more effective. 展开更多
关键词 Acromioclavicular Joint Shoulder dislocation Surgical Procedure Postoperative Complications Postoperative Care
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Evolutionary history shapes variation of wood density of tree species across the world
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作者 Fangbing Li Hong Qian +7 位作者 Jordi Sardans Dzhamal Y.Amishev Zixuan Wang Changyue Zhang Tonggui Wu Xiaoniu Xu Xiao Tao Xingzhao Huang 《Plant Diversity》 SCIE CAS CSCD 2024年第3期283-293,共11页
The effect of evolutionary history on wood density variation may play an important role in shaping variation in wood density,but this has largely not been tested.Using a comprehensive global dataset including 27,297 m... The effect of evolutionary history on wood density variation may play an important role in shaping variation in wood density,but this has largely not been tested.Using a comprehensive global dataset including 27,297 measurements of wood density from 2621 tree species worldwide,we test the hypothesis that the legacy of evolutionary history plays an important role in driving the variation of wood density among tree species.We assessed phylogenetic signal in different taxonomic(e.g.,angiosperms and gymnosperms)and ecological(e.g.,tropical,temperate,and boreal)groups of tree species,explored the biogeographical and phylogenetic patterns of wood density,and quantified the relative importance of current environmental factors(e.g.,climatic and soil variables)and evolutionary history(i.e.,phylogenetic relatedness among species and lineages)in driving global wood density variation.We found that wood density displayed a significant phylogenetic signal.Wood density differed among different biomes and climatic zones,with higher mean values of wood density in relatively drier regions(highest in subtropical desert).Our study revealed that at a global scale,for angiosperms and gymnosperms combined,phylogeny and species(representing the variance explained by taxonomy and not direct explained by long-term evolution process)explained 84.3%and 7.7%of total wood density variation,respectively,whereas current environment explained 2.7%of total wood density variation when phylogeny and species were taken into account.When angiosperms and gymnosperms were considered separately,the three proportions of explained variation are,respectively,84.2%,7.5%and 6.7%for angiosperms,and 45.7%,21.3%and 18.6%for gymnosperms.Our study shows that evolutionary history outpaced current environmental factors in shaping global variation in wood density. 展开更多
关键词 Wood density PHYLOGENY ANGIOSPERMS GYMNOSPERMS Climate factors Biophysical parameters
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A detailed rock density model of the Hong Kong territories
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作者 Albertini Nsiah Ababio Robert Tenzer 《Geodesy and Geodynamics》 EI CSCD 2024年第1期75-81,共7页
We used the geological map and published rock density measurements to compile the digital rock density model for the Hong Kong territories.We then estimated the average density for the whole territory.According to our... We used the geological map and published rock density measurements to compile the digital rock density model for the Hong Kong territories.We then estimated the average density for the whole territory.According to our result,the rock density values in Hong Kong vary from 2101 to 2681 kg·m^(-3).These density values are typically smaller than the average density of 2670 kg·m^(-3),often adopted to represent the average density of the upper continental crust in physical geodesy and gravimetric geophysics applications.This finding reflects that the geological configuration in Hong Kong is mainly formed by light volcanic formations and lava flows with overlying sedimentary deposits at many locations,while the percentage of heavier metamorphic rocks is very low(less than 1%).This product will improve the accuracy of a detailed geoid model and orthometric heights. 展开更多
关键词 density model Rock types Gravimetric modeling Hong Kong
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Local thermal conductivity of inhomogeneous nano-fluidic films:A density functional theory perspective
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作者 孙宗利 康艳霜 康艳梅 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期594-603,共10页
Combining the mean field Pozhar-Gubbins(PG)theory and the weighted density approximation,a novel method for local thermal conductivity of inhomogeneous fluids is proposed.The correlation effect that is beyond the mean... Combining the mean field Pozhar-Gubbins(PG)theory and the weighted density approximation,a novel method for local thermal conductivity of inhomogeneous fluids is proposed.The correlation effect that is beyond the mean field treatment is taken into account by the simulation-based empirical correlations.The application of this method to confined argon in slit pore shows that its prediction agrees well with the simulation results,and that it performs better than the original PG theory as well as the local averaged density model(LADM).In its further application to the nano-fluidic films,the influences of fluid parameters and pore parameters on the thermal conductivity are calculated and investigated.It is found that both the local thermal conductivity and the overall thermal conductivity can be significantly modulated by these parameters.Specifically,in the supercritical states,the thermal conductivity of the confined fluid shows positive correlation to the bulk density as well as the temperature.However,when the bulk density is small,the thermal conductivity exhibits a decrease-increase transition as the temperature is increased.This is also the case in which the temperature is low.In fact,the decrease-increase transition in both the small-bulk-density and low-temperature cases arises from the capillary condensation in the pore.Furthermore,smaller pore width and/or stronger adsorption potential can raise the critical temperature for condensation,and then are beneficial to the enhancement of the thermal conductivity.These modulation behaviors of the local thermal conductivity lead immediately to the significant difference of the overall thermal conductivity in different phase regions. 展开更多
关键词 thermal conductivity nano-fluidic films density functional theory
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Density functional theory study of B- and Si-doped carbons and their adsorption interactions with sulfur compounds
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作者 Peng Guo Hong Zhang +1 位作者 Shuliang Dong Libao An 《Carbon Energy》 SCIE EI CAS CSCD 2024年第2期195-208,共14页
Understanding the adsorption interactions between carbon materials and sulfur compounds has far-reaching impacts,in addition to their well-known important role in energy storage and conversion,such as lithium-ion batt... Understanding the adsorption interactions between carbon materials and sulfur compounds has far-reaching impacts,in addition to their well-known important role in energy storage and conversion,such as lithium-ion batteries.In this paper,properties of intrinsic B or Si single-atom doped,and B-Si codoped graphene(GR)and graphdiyne(GDY)were investigated by using density functional theory-based calculations,in which the optimal doping configurations were explored for potential applications in adsorbing sulfur compounds.Results showed that both B or Si single-atom doping and B-Si codoping could substantially enhance the electron transport properties of GR and GDY,improving their surface activity.Notably,B and Si atoms displayed synergistic effects for the codoped configurations,where B-Si codoped GR/GDY exhibited much better performance in the adsorption of sulfurcontaining chemicals than single-atom doped systems.In addition,results demonstrated that,after B-Si codoping,the adsorption energy and charge transfer amounts of GDY with sulfur compounds were much larger than those of GR,indicating that B-Si codoped GDY might be a favorable material for more effectively interacting with sulfur reagents. 展开更多
关键词 ADSORPTION density functional theory DOPING graphdiyne GRAPHENE sulfur compounds
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Synergistic effects of planting density and nitrogen fertilization on chlorophyll degradation and leaf senescence after silking in maize
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作者 Tianqiong Lan Lunjing Du +9 位作者 Xinglong Wang Xiaoxu Zhan Qinlin Liu Gui Wei Chengcheng Lyu Fan Liu Jiaxu Gao Dongju Feng Fanlei Kong Jichao Yuan 《The Crop Journal》 SCIE CSCD 2024年第2期605-613,共9页
Regulating planting density and nitrogen(N)fertilization could delay chlorophyll(Chl)degradation and leaf senescence in maize cultivars.This study measured changes in ear leaf green area(GLA_(ear)),Chl content,the act... Regulating planting density and nitrogen(N)fertilization could delay chlorophyll(Chl)degradation and leaf senescence in maize cultivars.This study measured changes in ear leaf green area(GLA_(ear)),Chl content,the activities of Chl a-degrading enzymes after silking,and the post-silking dry matter accumulation and grain yield under multiple planting densities and N fertilization rates.The dynamic change of GLA_(ear)after silking fitted to the logistic model,and the GLA_(ear) duration and the GLAearat 42 d after silking were affected mainly by the duration of the initial senescence period(T_(1))which was a key factor of the leaf senescence.The average chlorophyllase(CLH)activity was 8.3 times higher than pheophytinase activity and contributed most to the Chl content,indicating that CLH is a key enzyme for degrading Chl a in maize.Increasing density increased the CLH activity and decreased the Chl content,T1,GLAear,and GLA_(ear) duration.Under high density,appropriate N application reduced CLH activity,increased Chl content,prolonged T1,alleviated high-density-induced leaf senescence,and increased post-silking dry matter accumulation and grain yield. 展开更多
关键词 density Nitrogen fertilization Leaf senescence Chlorophyll-degrading enzyme Logistic model
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Correlation between DKK-1 Level and Bone Density Status in Children on Maintenance Haemodialysis
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作者 Manal Abd El-Salam Marwa Mohamed Anwar +2 位作者 Rasha Mahmoud Gouda Naglaa Abou El Fattah Nadia Youssef Riad 《Open Journal of Nephrology》 2024年第1期48-61,共14页
Background: Renal osteodystrophy (ROD) is a bone disorder resulting from chronic kidney disease (CKD) and related metabolic diseases. Dickkopf-related protein-1 (DKK-1) is critical in regulating bone biology. This stu... Background: Renal osteodystrophy (ROD) is a bone disorder resulting from chronic kidney disease (CKD) and related metabolic diseases. Dickkopf-related protein-1 (DKK-1) is critical in regulating bone biology. This study aimed to evaluate the serum DKK-1 level as a bone marker in children with CKD who undergo regular hemodialysis (HD). Subjects and Methods: This case-control study involved 40 children with CKD on HD and 40 healthy children as controls. The study measured serum DKK-1 levels and performed a dual-energy X-ray absorptiometry scan (DEXA) in line with routine laboratory investigations. Results: There was a significant increase in the serum level of DKK-1 in the patient group compared to the control group. The DKK-1 levels were 2540.65 (2215.4 - 2909.2) pg/ml and 1110.45 (885.45 - 1527.65) pg/ml, respectively, with a p-value of less than 0.001. In the hemodialysis group, 25 patients (62.5%) had low bone mineral density (BMD) with a Z-score of under -2.0. Eighteen of these patients had low BMD in both the neck of the femur and lumbar spines. Additionally, there was a significant increase in serum DKK-1 level in patients with low BMD (2567.35 (2303.8 - 3108.1) pg/ml) compared to patients with normal BMD (2454 (1859 - 2820) pg/ml) (p = 0.041). There was also a significant positive correlation between DKK1 level and phosphorus, alkaline phosphatase, and Parathormone serum levels. In conclusion, the study indicates a clear correlation between DKK-1 and BMD in children undergoing maintenance hemodialysis. DKK1 is a promising biomarker for CKD-MBD. 展开更多
关键词 DKK-1 CHILDREN HAEMODIALYSIS Bone density Status
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Solvent effects on Diels-Alder reaction in ionic liquids:A reaction density functional study
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作者 Zijiang Dou Weiqiang Tang +1 位作者 Peng Xie Shuangliang Zhao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期180-188,共9页
Extensive experimental studies have been performed on the Diels-Alder(DA)reactions in ionic liquids(ILs),which demonstrate that the IL environment can significantly influence the reaction rates and selectivity.However... Extensive experimental studies have been performed on the Diels-Alder(DA)reactions in ionic liquids(ILs),which demonstrate that the IL environment can significantly influence the reaction rates and selectivity.However,the underlying microscopic mechanism remains ambiguous.In this work,the multiscale reaction density functional theory is applied to explore the effect of 1-butyl-3-methylimidazolium hexafluorophosphate([BMIM][PF_(6)])solvent on the reaction of cyclopentadiene(CP)with acrolein,methyl acrylate,or acrylonitrile.By analyzing the free energy landscape during the reaction,it is found that the polarization effect has a relatively small influence,while the solvation effect makes both the activation free energy and reaction free energy decrease.In addition,the rearrangement of local solvent structure shows that the cation spatial distribution responds more evidently to the reaction than the anion,and this indicates that the cation plays a dominant role in the solvation effect and so as to affect the reaction rates and selectivity of the DA reactions. 展开更多
关键词 Solvent effect Ionic liquids Diels-Alder reaction Reaction density functional theory
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Influence of Current Density on the Photocatalytic Activity of Nd:TiO_(2) Coatings
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作者 施渊吉 ZHANG Zhen +2 位作者 DAI Yunzhong LI Jingxiao CHEN Zeyu 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第1期32-38,共7页
The Nd:TiO_(2 )PEO coatings were formed in a phosphate-based electrolyte with the addition of Nd_(2)O_(3 )under the current density of 150,200,250 and 300 m A/cm^(2).SEM results showed that the micropores decreased on... The Nd:TiO_(2 )PEO coatings were formed in a phosphate-based electrolyte with the addition of Nd_(2)O_(3 )under the current density of 150,200,250 and 300 m A/cm^(2).SEM results showed that the micropores decreased on quantity and increased on scale with the increasing current density.AFM results revealed that the roughness of the coatings increased with the increasing current density.Phase and composition analysis showed that the Nd:TiO_(2) coatings were mainly composed of anatase and rutile phase.And the anatase phase content has reached the maximum value at the current density of 250 m A/cm^(2).XPS results indicated that Ti2p spin-orbit components of the Nd:TiO_(2) coatings are shifted towards higher binding energy,compared with the pure TiO_(2) coating,suggesting that some of the Nd^(3+)ions are combined with TiO_(2) lattice and led to dislocation.Photocatalytic test showed that the photocatalytic activity of Nd:TiO_(2) coatings varied in the same pattern with the anatase content variation in Nd:TiO_(2) coatings.The photocatalytic experiment results show that the photocatalytic activity of Nd:TiO_(2) coatings can be greatly enhanced with moderate amount of Nd^(3+).However,excessive amount of Nd^(3+)does not have an effective impact on the photoctalytic activity improvement. 展开更多
关键词 PEO current density AFM XPS Nd:TiO_(2) PHOTOCATALYTIC
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A Weakly-Supervised Crowd Density Estimation Method Based on Two-Stage Linear Feature Calibration
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作者 Yong-Chao Li Rui-Sheng Jia +1 位作者 Ying-Xiang Hu Hong-Mei Sun 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2024年第4期965-981,共17页
In a crowd density estimation dataset,the annotation of crowd locations is an extremely laborious task,and they are not taken into the evaluation metrics.In this paper,we aim to reduce the annotation cost of crowd dat... In a crowd density estimation dataset,the annotation of crowd locations is an extremely laborious task,and they are not taken into the evaluation metrics.In this paper,we aim to reduce the annotation cost of crowd datasets,and propose a crowd density estimation method based on weakly-supervised learning,in the absence of crowd position supervision information,which directly reduces the number of crowds by using the number of pedestrians in the image as the supervised information.For this purpose,we design a new training method,which exploits the correlation between global and local image features by incremental learning to train the network.Specifically,we design a parent-child network(PC-Net)focusing on the global and local image respectively,and propose a linear feature calibration structure to train the PC-Net simultaneously,and the child network learns feature transfer factors and feature bias weights,and uses the transfer factors and bias weights to linearly feature calibrate the features extracted from the Parent network,to improve the convergence of the network by using local features hidden in the crowd images.In addition,we use the pyramid vision transformer as the backbone of the PC-Net to extract crowd features at different levels,and design a global-local feature loss function(L2).We combine it with a crowd counting loss(LC)to enhance the sensitivity of the network to crowd features during the training process,which effectively improves the accuracy of crowd density estimation.The experimental results show that the PC-Net significantly reduces the gap between fullysupervised and weakly-supervised crowd density estimation,and outperforms the comparison methods on five datasets of Shanghai Tech Part A,ShanghaiTech Part B,UCF_CC_50,UCF_QNRF and JHU-CROWD++. 展开更多
关键词 Crowd density estimation linear feature calibration vision transformer weakly-supervision learning
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Asymptotic normality of error density estimator in stationary and explosive autoregressive models
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作者 WU Shi-peng YANG Wen-zhi +1 位作者 GAO Min HU Shu-he 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2024年第1期140-158,共19页
In this paper,we consider the limit distribution of the error density function estima-tor in the rst-order autoregressive models with negatively associated and positively associated random errors.Under mild regularity... In this paper,we consider the limit distribution of the error density function estima-tor in the rst-order autoregressive models with negatively associated and positively associated random errors.Under mild regularity assumptions,some asymptotic normality results of the residual density estimator are obtained when the autoregressive models are stationary process and explosive process.In order to illustrate these results,some simulations such as con dence intervals and mean integrated square errors are provided in this paper.It shows that the residual density estimator can replace the density\estimator"which contains errors. 展开更多
关键词 explosive autoregressive models residual density estimator asymptotic distribution association sequence
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High-dimensional uncertainty quantification of projectile motion in the barrel of a truck-mounted howitzer based on probability density evolution method
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作者 Mingming Wang Linfang Qian +3 位作者 Guangsong Chen Tong Lin Junfei Shi Shijie Zhou 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第2期209-221,共13页
This paper proposed an efficient research method for high-dimensional uncertainty quantification of projectile motion in the barrel of a truck-mounted howitzer.Firstly,the dynamic model of projectile motion is establi... This paper proposed an efficient research method for high-dimensional uncertainty quantification of projectile motion in the barrel of a truck-mounted howitzer.Firstly,the dynamic model of projectile motion is established considering the flexible deformation of the barrel and the interaction between the projectile and the barrel.Subsequently,the accuracy of the dynamic model is verified based on the external ballistic projectile attitude test platform.Furthermore,the probability density evolution method(PDEM)is developed to high-dimensional uncertainty quantification of projectile motion.The engineering example highlights the results of the proposed method are consistent with the results obtained by the Monte Carlo Simulation(MCS).Finally,the influence of parameter uncertainty on the projectile disturbance at muzzle under different working conditions is analyzed.The results show that the disturbance of the pitch angular,pitch angular velocity and pitch angular of velocity decreases with the increase of launching angle,and the random parameter ranges of both the projectile and coupling model have similar influence on the disturbance of projectile angular motion at muzzle. 展开更多
关键词 Truck-mounted howitzer Projectile motion Uncertainty quantification Probability density evolution method
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