Reinforcement of slopes using soil nailing can effectively improve slope stability, and it has been widely used in upgrading cut slopes. Based on the assumptions of stresses on the slip surface, a new method for analy...Reinforcement of slopes using soil nailing can effectively improve slope stability, and it has been widely used in upgrading cut slopes. Based on the assumptions of stresses on the slip surface, a new method for analyzing the stability of a slope reinforced with soil nails was established in the limit equilibrium theory framework, by considering that slope sliding occurs owing to shear failure of the slip surface, which subjects to Mohr–Coulomb(M–C) strength criterion. Meanwhile, in order to easily analyze the stability of a soil nailed slope in actual engineering and facilitate optimum design of parameters for soil nailing, factor of safety(FOS) contour curve charts were drawn on the basis of the established linear proportional relationship between the spacing of soil nails and slope height, and the length of soil nails and slope height. Then, by analyzing and verifying the results obtained from classic examples, some conclusions can be got as follows: 1) The results obtained from the current method are close to those obtained from the traditional limit equilibrium methods, and the current method can provide a strict solution for the slope FOS as it satisfies all the static equilibrium conditions of a sliding body, thus confirming the feasibility of the current method; 2) The slope FOS contour curve charts can be used not only to reliably analyze the stability of a soil nailed slope, but also to design optimally the parameters of soil nailing for the slope with a certain safety requirement.展开更多
This paper summarizes the results of a study of adsorption of sulfur compounds from a high-sulfur feed on improved spherical-shaped nano-AgX zeolite. For this purpose, the nano-AgX zeolite was initially synthesized an...This paper summarizes the results of a study of adsorption of sulfur compounds from a high-sulfur feed on improved spherical-shaped nano-AgX zeolite. For this purpose, the nano-AgX zeolite was initially synthesized and improved with silver compounds such as silver nitrate, and then it was utilized in the adsorption process. In order to investigate the equilibrium and dynamics of the adsorption process, adsorptive desulfurization of real feed(i.e., sour gas condensate from the South Pars gas field) was carried out in batch and continuous processes under several operating conditions; a temperature-dependent Langmuir isotherm model was used to fit the equilibrium data. The value of monolayer adsorption capacity(q_m) and adsorption enthalpy(ΔH) were calculated to be 1.044 mmol/g and 16.8 kJ/mol, respectively. Furthermore, a detailed theoretical model was employed in order to model the breakthrough experiments. The results revealed that an increase in the feed flow rate and 1/T values will cause linear and exponential increase in the total mass transfer coefficient(ks). Isotherm and dynamic breakthrough models were found to be in agreement with the experimental data.展开更多
The adsorption of the bentonite toward Ni(II) from aqueous solution was studied to obtain optimum conditions,equilibrium model,thermodynamic and kinetic parameters.Statistical method was used to evaluate maximum amoun...The adsorption of the bentonite toward Ni(II) from aqueous solution was studied to obtain optimum conditions,equilibrium model,thermodynamic and kinetic parameters.Statistical method was used to evaluate maximum amount of adsorbed Ni(II).In this work,p H of solution during stirring,contact time,initial Ni(II) concentration,particle size of bentonite and amount of bentonite were considered as effective parameters which should be examined.The increase of temperature has negative effect on the Ni(II) adsorption.The equilibrium data were correlated well with Freundlich and Dubinin–Radushkevich isotherm models the correlation coefficients of which are(R^2) 0.994 and 0.971,respectively.This model indicates heterogeneous and chemical absorption or ion exchange process.The values of thermodynamic parameters such as ΔH°,ΔS° and ΔG° of nickel adsorption reveal that it is a spontaneous,exothermic and associative process.The experimental data fit the pseudo-second-order kinetic very well with correlation coefficient(R^2) more than 0.995.展开更多
基金Project(2015M580702)supported by the Postdoctoral Science Foundation of ChinaProject(51608541)supported by the National Natural Science Foundation of ChinaProject(2014122066)supported by the Guizhou Provincial Department of Transportation Foundation,China
文摘Reinforcement of slopes using soil nailing can effectively improve slope stability, and it has been widely used in upgrading cut slopes. Based on the assumptions of stresses on the slip surface, a new method for analyzing the stability of a slope reinforced with soil nails was established in the limit equilibrium theory framework, by considering that slope sliding occurs owing to shear failure of the slip surface, which subjects to Mohr–Coulomb(M–C) strength criterion. Meanwhile, in order to easily analyze the stability of a soil nailed slope in actual engineering and facilitate optimum design of parameters for soil nailing, factor of safety(FOS) contour curve charts were drawn on the basis of the established linear proportional relationship between the spacing of soil nails and slope height, and the length of soil nails and slope height. Then, by analyzing and verifying the results obtained from classic examples, some conclusions can be got as follows: 1) The results obtained from the current method are close to those obtained from the traditional limit equilibrium methods, and the current method can provide a strict solution for the slope FOS as it satisfies all the static equilibrium conditions of a sliding body, thus confirming the feasibility of the current method; 2) The slope FOS contour curve charts can be used not only to reliably analyze the stability of a soil nailed slope, but also to design optimally the parameters of soil nailing for the slope with a certain safety requirement.
文摘This paper summarizes the results of a study of adsorption of sulfur compounds from a high-sulfur feed on improved spherical-shaped nano-AgX zeolite. For this purpose, the nano-AgX zeolite was initially synthesized and improved with silver compounds such as silver nitrate, and then it was utilized in the adsorption process. In order to investigate the equilibrium and dynamics of the adsorption process, adsorptive desulfurization of real feed(i.e., sour gas condensate from the South Pars gas field) was carried out in batch and continuous processes under several operating conditions; a temperature-dependent Langmuir isotherm model was used to fit the equilibrium data. The value of monolayer adsorption capacity(q_m) and adsorption enthalpy(ΔH) were calculated to be 1.044 mmol/g and 16.8 kJ/mol, respectively. Furthermore, a detailed theoretical model was employed in order to model the breakthrough experiments. The results revealed that an increase in the feed flow rate and 1/T values will cause linear and exponential increase in the total mass transfer coefficient(ks). Isotherm and dynamic breakthrough models were found to be in agreement with the experimental data.
文摘The adsorption of the bentonite toward Ni(II) from aqueous solution was studied to obtain optimum conditions,equilibrium model,thermodynamic and kinetic parameters.Statistical method was used to evaluate maximum amount of adsorbed Ni(II).In this work,p H of solution during stirring,contact time,initial Ni(II) concentration,particle size of bentonite and amount of bentonite were considered as effective parameters which should be examined.The increase of temperature has negative effect on the Ni(II) adsorption.The equilibrium data were correlated well with Freundlich and Dubinin–Radushkevich isotherm models the correlation coefficients of which are(R^2) 0.994 and 0.971,respectively.This model indicates heterogeneous and chemical absorption or ion exchange process.The values of thermodynamic parameters such as ΔH°,ΔS° and ΔG° of nickel adsorption reveal that it is a spontaneous,exothermic and associative process.The experimental data fit the pseudo-second-order kinetic very well with correlation coefficient(R^2) more than 0.995.
