As a high-performance material with great application potential,the application of carbon nanotubes has been limited by their production volume.A distributor-less conical fluidized bed is the main equipment used in th...As a high-performance material with great application potential,the application of carbon nanotubes has been limited by their production volume.A distributor-less conical fluidized bed is the main equipment used in the industrial production of carbon nanotubes.To improve the production volume and product quality of carbon nanotubes,the study of fluidized-bed-diameter scaling is important.Three different diameters of distributor-less conical fluidized beds were established,and then the particle behavior and bubble characteristics of carbon nanotube clusters at these bed diameters were investigated.Time-series and wavelet analysis methods were used to analyze the pressure-fluctuation signals inside the fluidized beds.Results showed that the distributor-less design caused the airflow to break through the middle of the bed,which did not change with the change in bed diameter.The powder-bridging phenomenon of carbon nanotube clusters in a 100-mm-diameter fluidized bed was related to the special microstructure of carbon nanotube clusters.The frequency of pressure fluctuations in the bed decreased nonlinearly with increasing bed diameter.This study can guide the design and scale-up of distributor-less conical fluidized beds,especially for the scale-up of carbon nanotube production equipment,which can contribute to the improvement of carbon nanotubes’capacity and quality in industrial production.展开更多
The fixed-gas drag force from a model calculation method that stabilizes the agitation capabilities of different gas ratios was used to explore the influence of temperature and hydrogen concentration on fluidizing dur...The fixed-gas drag force from a model calculation method that stabilizes the agitation capabilities of different gas ratios was used to explore the influence of temperature and hydrogen concentration on fluidizing duration, metallization ratio, utilization rate of reduction gas, and sticking behavior. Different hydrogen concentrations from 5vol%to 100vol%at 1073 and 1273 K were used while the drag force with the flow of N2 and H2 （N2：2 L·min^-1;H2：2 L·min^-1） at 1073 K was chosen as the standard drag force. The metallization ratio, mean reduc-tion rate, and utilization rate of reduction gas were observed to generally increase with increasing hydrogen concentration. Faster reduction rates and higher metallization ratios were obtained when the reduction temperature decreased from 1273 to 1073 K. A numerical relation among particle diameter, particle drag force, and fluidization state was plotted in a diagram by this model.展开更多
A Markov chain-based stochastic model （MCM） is developed to simulate the movement of particles in a 2D bubbling fluidized bed （BFB）. The state spaces are determined by the discretized physical cells of the bed, an...A Markov chain-based stochastic model （MCM） is developed to simulate the movement of particles in a 2D bubbling fluidized bed （BFB）. The state spaces are determined by the discretized physical cells of the bed, and the transition probability matrix is directly calculated by the results of a discrete element method （DEM） simulation. The Markov property of the BFB is discussed by the comparison results calculated from both static and dynamic transition probability matrices. The static matrix is calculated based on the Markov chain while the dynamic matrix is calculated based on the memory property of the particle movement. Results show that the difference in the trends of particle movement between the static and dynamic matrix calculation is very small. Besides, the particle mixing curves of the MCM and DEM have the same trend and similar numerical values, and the details show the time averaged characteristic of the MCM and also expose its shortcoming in describing the instantaneous particle dynamics in the BFB.展开更多
A heat pump assisted fluidized bed grain drying experimental system wasdeveloped. Based on this system, a serial of experiments was performed under four kinds of air cycleconditions. According to the experimental anal...A heat pump assisted fluidized bed grain drying experimental system wasdeveloped. Based on this system, a serial of experiments was performed under four kinds of air cycleconditions. According to the experimental analysis, an appropriate drying medium-air cycle for theheat pump assisted fluidized bed drying equipment was decided, which is different from the commonlyused heat pump assisted drying system. The experimental results concerning the drying operationperformance of the new system show that the averaged coefficient of performance (COP) can reach morethan 2.5. The economical evaluation was performed and the power consumption for removing a kilogramwater from grains was about 0.485 kW-h/kg (H_2O), which shows its reasonable commercial efficiencyand great application potentiality in future market.展开更多
In most industrial fluidization units, two- or three-stage cyclone systems are used to clean the product gases. To return the solids to the bed, these cyclones are fitted with diplegs. By pass of gas from the bed thro...In most industrial fluidization units, two- or three-stage cyclone systems are used to clean the product gases. To return the solids to the bed, these cyclones are fitted with diplegs. By pass of gas from the bed through the dipleg is partially overcome by the back pressure build-up in the dipleg and by adding a trickle valve at the bottom of the dipleg. Diplegs of primary cyclones, operating at a high solid loading behave differently from diplegs of secondary and tertiary cyclones which operate at low solid loading. Both types have been investigated by pressure drop measurements, visual observation and by measurements of the air flow rate flowing up the riser. The primary dipleg was also studied using electrical capacitance tomography. The results are reported hereafter and will give a first indication towards the right design of the dipleg and the selection of the trickle valve. The influence of gas flow in the dipleg on the conversion in a catalytic fluidized bed reactor is found to be negligible.展开更多
The HCl emission characteristics of typical municipal solid waste(MSW) components and their mixtures have been investigated in a Φ150 mm fluidized bed. Some influencing factors of HCl emission in MSW fluidized bed in...The HCl emission characteristics of typical municipal solid waste(MSW) components and their mixtures have been investigated in a Φ150 mm fluidized bed. Some influencing factors of HCl emission in MSW fluidized bed incinerator was found in this study. The HCl emission is increasing with the growth of bed temperature, while it is decreasing with the increment of oxygen concentration at furnace exit. When the weight percentage of auxiliary coal is increased, the conversion rate of Cl to HCl is increasing. The HCl emission is decreased, if the sorbent(CaO) is added during the incineration process. Based on these experimental results, a 14×6×1 three-layer BP neural networks prediction model of HCl emission in MSW/coal co-fired fluidized bed incinerator was built. The numbers of input nodes and hidden nodes were fixed on by canonical correlation analysis technique and dynamic construction method respectively. The prediction results of this model gave good agreement with the experimental results, which indicates that the model has relatively high accuracy and good generalization ability. It was found that BP neural network is an effectual method used to predict the HCl emission of MSW/coal co-fired fluidized bed incinerator.展开更多
This study is devoted to gas-solid mass transfer behavior inheterogeneous two-phase flow. Experiments were carried out in a coldcirculating fluidized bed of 3.0 m in height and 72 mm in diameterwith naphthalene partic...This study is devoted to gas-solid mass transfer behavior inheterogeneous two-phase flow. Experiments were carried out in a coldcirculating fluidized bed of 3.0 m in height and 72 mm in diameterwith naphthalene particles. Axial and radial distributions ofsublimated naphthalene concentration in air were measured with an on-line concentration monitoring system HP GC-MS. Mass transfercoefficients were obtained under various operating conditions,showing that heterogeneous flow structure strongly influences theaxial and radial profiles of mass transfer coefficients.展开更多
The settling behavior of coarse particles in a gas-solid fluidized bed was experimentally studied by using magnetic tracer. It is well known that the calculation of terminal velocity is of interest in dense medium sep...The settling behavior of coarse particles in a gas-solid fluidized bed was experimentally studied by using magnetic tracer. It is well known that the calculation of terminal velocity is of interest in dense medium separation. However, this problem has not been completely solved up to now. In this work, the terminal velocity of an object mov-ing in a gas-solid fluidized bed was experimentally measured and theoretically calculated. The experimental results in-dicated that the plastic viscosity and yield stress of the bed increase as the size of fluidized particles increases, but it varies little when some coarser particles are mixed with the fluidized particles. The resistance to a rising object was an order magnitude greater than that to a settling object. The efficient buoyancy on a flaky object, which lies flatly on the gas distributor, was much less than that calculated by the Archimedes principle. The object does not always rise or set-tle with minimal projective area owing to radial motion of the fluidized particles. But in the lower part of the bed, the bar-shaped objects were likely with minimal projective area rising or settling.展开更多
An experimental verification is reported on the early predicting index of agglomeration in bubbling fluidized bed. Coarse quartz sand, which has the same density but larger diameter than the bed material, was used to ...An experimental verification is reported on the early predicting index of agglomeration in bubbling fluidized bed. Coarse quartz sand, which has the same density but larger diameter than the bed material, was used to simulate the initial agglomerated particle. Wigner distribution was used to analyze the pressure fuctuation of the tested bed, and the average amplitude of local domain frequency （LDF） and local peak weighted average frequency （LPWA） under different operating conditions were measured and compared. The results showed that the LDF is sensitive to the agglomeration phenomena and had quick response to the incipient agglomeration in fluidized beds. It can be concluded from the results that these two parameters could be taken as the characteristic indexes to the agglomeration in fuidized beds.展开更多
A CFD code has been developed based on the conservation principles describing gas and solid flow in fluidized beds. This code is employed to simulate not only the spatiotemporal gas and solid phase velocities and v...A CFD code has been developed based on the conservation principles describing gas and solid flow in fluidized beds. This code is employed to simulate not only the spatiotemporal gas and solid phase velocities and voidage profiles in a two dimensional bed but also fluid dynamics in the jet region. The computational results show that gas flow direction is upward in the entire bed accompanied with random local circulations, whilst solid flow direction is upward at the center and downward near the wall. The radical reason of strong back mixing of solid particles and good transfer behavior between two phases is that the jet entrains solid particles. Numerical calculation indicates that gas velocity, solid velocity and pressure profile have a significant change when the voidage is 0 8. The simulated time averaged voidage profiles agree with the experimental results and simulated data reported by Gidaspow and Ettehadieh(1983). Therefore, CFD model can be regarded as a useful tool to study the jet characteristics in dense gas solid fluidized beds.展开更多
The chaotic scale-up approach by matching the Kolmogorov entropy(E_K) proposed by Schouten et al.(1996) was assessed in two geometrically similar gas–solid fluidized bed columns of 0.14 and 0.44 m diameter.We used fo...The chaotic scale-up approach by matching the Kolmogorov entropy(E_K) proposed by Schouten et al.(1996) was assessed in two geometrically similar gas–solid fluidized bed columns of 0.14 and 0.44 m diameter.We used four conditions of our validated new mechanistic scale-up method based on matching the radial profiles of gas holdup where the local dimensionless hydrodynamic parameters were similar as measured by advanced measurement techniques.These experimental conditions were used to evaluate the validity of the chaotic scale-up method,which were selected based on our new mechanistic scale-up methodology.Pressure gauge transducer measurements at the wall and inside the bed at various local radial locations and at three axial heights were used to estimate KE.It was found that the experimental conditions with similar or close radial profiles of the Kolmogorov entropy and with similar or close radial profiles of the gas holdup achieve the similarity in local dimensionless hydrodynamic parameters,and vice versa.展开更多
It is found analytically that the parabolic radial profile of liquid velocity in cylindrical liquid-solid fluidized bed (LSFB) causes particles to circulate around some radial position. This is the main reason for liq...It is found analytically that the parabolic radial profile of liquid velocity in cylindrical liquid-solid fluidized bed (LSFB) causes particles to circulate around some radial position. This is the main reason for liquid-phase axial dispersions. The liquid-phase axial dispersion is depressed as the liquid velocity presents a flatter Bessel radial profile in a converging taper LSFB. The void fraction increases with axial distance in converging taper LSFB. The behavior produces less liquid-phase axial dispersion. Experimental results show good coincidence.展开更多
Experiments of biomass pyrolysis were carried out in a fluidized bed, and dynamic signals of pressure and temperature were recorded. Correlation dimension was employed to characterize the chaotic behavior of pressure ...Experiments of biomass pyrolysis were carried out in a fluidized bed, and dynamic signals of pressure and temperature were recorded. Correlation dimension was employed to characterize the chaotic behavior of pressure and temperature signals. Both pressure and temperature signals exhibit chaotic behavior, and the chaotic behavior of temperature signals is always weaker than that of pressure signals. Chaos transfer theory was advanced to explain the above phenomena. The discussion on the algorithm of the correlation dimension shows that the distance definition based on rhombic neighborhood is a better choice than the traditional one based on spherical neighborhood. The former provides a satisfactory result in a much shorter time.展开更多
A model is proposed to predict boiling heat transfer coefficient in a three-phase circulating fluidized bed (CFB), which is a new type of evaporation boiling means for enhancing heat transfer and preventing fouling. T...A model is proposed to predict boiling heat transfer coefficient in a three-phase circulating fluidized bed (CFB), which is a new type of evaporation boiling means for enhancing heat transfer and preventing fouling. To verify the model, experiments are conducted in a stainless steel column with 39mm ID and 2.0m height, in which the heat transfer coefficient is measured for different superficial velocities, steam pressures, particle concentrations and materials of particle. As the steam pressure and particle concentrations increase, the heat transfer coefficient in the bed increases. The heat transfer coefficient increases with the liquid velocity but it exhibits a local minimum.The heat transfer coefficient is correlated with cluster renewed model and two-mechanism method. The prediction of the model is in good agreement with experimental data.展开更多
The axial concentration distribution of both particles with betterwetting (forming non-attached system) and poorer wetting (formingattached system) was investigated in a vertical gas-liquid-solidfluidized bed of 4.2 c...The axial concentration distribution of both particles with betterwetting (forming non-attached system) and poorer wetting (formingattached system) was investigated in a vertical gas-liquid-solidfluidized bed of 4.2 cm in diameters and 130 cm in height with thesolids holdup less than 0.05. The one-dimensionalsedimentation-dispersion model could be used satisfactorily todescribe the axial distribution of solids holdup by modifying only amodel parameter, i.e. by means of the terminal settling velocityminus a certain value, which is a functions of gas velocity andconsiders the effect of an additional drag force resulted fromattached rising bubbles.展开更多
Fluidized beds are nonlinear dynamic systems that exchange mass and energy with outside. They are governed not only byfluid dynamics, but by thermodynamics, especially the second law of thermodynamics as well. Accordi...Fluidized beds are nonlinear dynamic systems that exchange mass and energy with outside. They are governed not only byfluid dynamics, but by thermodynamics, especially the second law of thermodynamics as well. According to Prigogine's dissipative structure theory, the following have been concluded: (l) a fixed bed is on thermodynamic blanch, and bubbling, turbulent and fast beds areon the dissipatve structure branches. (2) Entropy in fluidized beds is divided into tWo parts: entropy production and entropy flux. The latter increases with gas velocity and decreases with pressure of the systems. That means the entropy of a system may reduce and the systemwith higher gas velocity behaves as dissipative structure characteristics. (3) For a giVen velocity, a fluidized bed operates stably on thewhole, but it is unstable to local gas-solid phases. The unstable phases are described by fluid dynamic equations, While the minimum ofsystem energy function assures whole stability of the system. (4) A transition criterion of a bubbling bed is derived from Prigogine's stability theory.展开更多
Temperature distribution and control have been investigated in a liquefiedpetroleum gas (LPG) fluidized bed with hollow corundum spheres (A1_2O_3) of 0.867-1.212 mm indiameter at moderately high temperatures (800-1100...Temperature distribution and control have been investigated in a liquefiedpetroleum gas (LPG) fluidized bed with hollow corundum spheres (A1_2O_3) of 0.867-1.212 mm indiameter at moderately high temperatures (800-1100℃). Experiments were carried out for the airconsumption coefficient α in the range of 0.3 to 1.0 and the fluidization number N in the range of1.3 to 3.0. Particle properties, initial bed height, α and N all affect temperature distribution inthe bed. Bed temperature can be adjusted about 200℃ by combined the adjusting of α and N.展开更多
The gas-solid reaction process with wide particle size distribution is extensively used in the chemical engineering field,especially the particle reacts with the gas gradually,such as fluorination reactions in fluidiz...The gas-solid reaction process with wide particle size distribution is extensively used in the chemical engineering field,especially the particle reacts with the gas gradually,such as fluorination reactions in fluidized beds.When the computational fluid dynamics-discrete element method(CFD-DEM)is used for the coupling simulation of multiphase and polydisperse particle reaction system,the grid size directly affects the accuracy of flow field information and simulation of chemical reaction.Furthermore,particle calculation time step will directly affect the efficiency of coupling calculation.In this work,a local grid and time step refinement method is proposed to simulate multiphase and polydisperse particle fluid-ization reaction system.In this method,the refined DEM grids are automatically generated in the computational domain around the fine particles,and the detailed fluid phase information is obtained with the interpolation algorithm.In the two-phase coupling process,particles are divided into different groups based on physical properties,each group has its own independent time step.The multistage conical-cylindrical spouted bed is proposed for the fluorination reaction process;the operating gas ve-locity range of the polydisperse particle system is extended by the new design while the particle size distribution changes with the gas-solid reaction process.It is demonstrated that the local grid and time step refinement method can improve the accuracy and efficiency of the traditional CFD-DEM method in the reaction process simulation,which describes a polydisperse particle system with wide particle size distribution.Aimed at improving the simulation accuracy and efficiency,this paper will be helpful for simulating the particle reaction process in the gas-solid fluidized bed and beneficial for the development of the CFD-DEM method.展开更多
In the past few decades,multi-scale numerical methods have been developed to model dense gas-solidflow in fluidized beds with different resolutions,accuracies,and efficiencies.However,ambiguity needsto be clarified in...In the past few decades,multi-scale numerical methods have been developed to model dense gas-solidflow in fluidized beds with different resolutions,accuracies,and efficiencies.However,ambiguity needsto be clarified in the multi-scale numerical simulation of fluidized beds:(i)the selection of the submodels,parameters,and numerical resolution;(ii)the multivariate coupling of operating conditions,bed configurations,polydispersity,and additional forces.Accordingly,a state-of-the-art review is performed to assess the applicability of multi-scale numerical methods in predicting dense gas-solid flow influidized beds at specific fluidization regimes(e.g.,bubbling fluidization region,fast fluidization regime),with a focus on the inter-particle collision models,inter-phase interaction models,collision parameters,and polydispersity effect.A mutual restriction exists between resolution and efficiency.Higherresolution methods need more computational resources and thus are suitable for smaller-scale simulations to provide a database for closure development.Lower-resolution methods require fewercomputational resources and thus underpin large-scale simulations to explore macro-scale phenomena.Model validations need to be further conducted under multiple flow conditions and comprehensivemetrics(e.g.,velocity profiles at different heights,bubbles,or cluster characteristics)for furtherimprovement of the applicability of each numerical method.展开更多
In this study,a CFD model coupled with heterogeneous flow structure,mass transfer equations,and chemical reaction kinetics is established to forecast the pyrolusite reduction reaction behavior.Compared with the previo...In this study,a CFD model coupled with heterogeneous flow structure,mass transfer equations,and chemical reaction kinetics is established to forecast the pyrolusite reduction reaction behavior.Compared with the previous studies which ignore the volume change of solids phase,the influence of volume shrinkage on reaction and flow behavior is explored in this research.Volume shrinkage of pyrolusite is proved to be non-negligible in predicting the conversion rate.The negligence of volume shrinkage leads to the overestimation of conversion rate for its inaccurate estimation of surface area for reaction.Besides,the influence of volume shrinkage on the reaction is found smaller in the scaled-up reactor.展开更多
基金supported by the National Natural Science Foundation of China(52336003,52206096,52176076)the Special Expert Project of Shandong Province Taishan Scholars Program(ts20190937).
文摘As a high-performance material with great application potential,the application of carbon nanotubes has been limited by their production volume.A distributor-less conical fluidized bed is the main equipment used in the industrial production of carbon nanotubes.To improve the production volume and product quality of carbon nanotubes,the study of fluidized-bed-diameter scaling is important.Three different diameters of distributor-less conical fluidized beds were established,and then the particle behavior and bubble characteristics of carbon nanotube clusters at these bed diameters were investigated.Time-series and wavelet analysis methods were used to analyze the pressure-fluctuation signals inside the fluidized beds.Results showed that the distributor-less design caused the airflow to break through the middle of the bed,which did not change with the change in bed diameter.The powder-bridging phenomenon of carbon nanotube clusters in a 100-mm-diameter fluidized bed was related to the special microstructure of carbon nanotube clusters.The frequency of pressure fluctuations in the bed decreased nonlinearly with increasing bed diameter.This study can guide the design and scale-up of distributor-less conical fluidized beds,especially for the scale-up of carbon nanotube production equipment,which can contribute to the improvement of carbon nanotubes’capacity and quality in industrial production.
基金supported by the National Natural Science Foundation of China(No.51234001)the Major State Basic Research Development Program of China(No.2012CB720401)
文摘The fixed-gas drag force from a model calculation method that stabilizes the agitation capabilities of different gas ratios was used to explore the influence of temperature and hydrogen concentration on fluidizing duration, metallization ratio, utilization rate of reduction gas, and sticking behavior. Different hydrogen concentrations from 5vol%to 100vol%at 1073 and 1273 K were used while the drag force with the flow of N2 and H2 （N2：2 L·min^-1;H2：2 L·min^-1） at 1073 K was chosen as the standard drag force. The metallization ratio, mean reduc-tion rate, and utilization rate of reduction gas were observed to generally increase with increasing hydrogen concentration. Faster reduction rates and higher metallization ratios were obtained when the reduction temperature decreased from 1273 to 1073 K. A numerical relation among particle diameter, particle drag force, and fluidization state was plotted in a diagram by this model.
基金The National Science Foundation of China(No.51276036,51306035)the Fundamental Research Funds for the Central Universities(No.KYLX_0114)
文摘A Markov chain-based stochastic model （MCM） is developed to simulate the movement of particles in a 2D bubbling fluidized bed （BFB）. The state spaces are determined by the discretized physical cells of the bed, and the transition probability matrix is directly calculated by the results of a discrete element method （DEM） simulation. The Markov property of the BFB is discussed by the comparison results calculated from both static and dynamic transition probability matrices. The static matrix is calculated based on the Markov chain while the dynamic matrix is calculated based on the memory property of the particle movement. Results show that the difference in the trends of particle movement between the static and dynamic matrix calculation is very small. Besides, the particle mixing curves of the MCM and DEM have the same trend and similar numerical values, and the details show the time averaged characteristic of the MCM and also expose its shortcoming in describing the instantaneous particle dynamics in the BFB.
基金This work was financially supported by the Education Department of China (No.00020)
文摘A heat pump assisted fluidized bed grain drying experimental system wasdeveloped. Based on this system, a serial of experiments was performed under four kinds of air cycleconditions. According to the experimental analysis, an appropriate drying medium-air cycle for theheat pump assisted fluidized bed drying equipment was decided, which is different from the commonlyused heat pump assisted drying system. The experimental results concerning the drying operationperformance of the new system show that the averaged coefficient of performance (COP) can reach morethan 2.5. The economical evaluation was performed and the power consumption for removing a kilogramwater from grains was about 0.485 kW-h/kg (H_2O), which shows its reasonable commercial efficiencyand great application potentiality in future market.
文摘In most industrial fluidization units, two- or three-stage cyclone systems are used to clean the product gases. To return the solids to the bed, these cyclones are fitted with diplegs. By pass of gas from the bed through the dipleg is partially overcome by the back pressure build-up in the dipleg and by adding a trickle valve at the bottom of the dipleg. Diplegs of primary cyclones, operating at a high solid loading behave differently from diplegs of secondary and tertiary cyclones which operate at low solid loading. Both types have been investigated by pressure drop measurements, visual observation and by measurements of the air flow rate flowing up the riser. The primary dipleg was also studied using electrical capacitance tomography. The results are reported hereafter and will give a first indication towards the right design of the dipleg and the selection of the trickle valve. The influence of gas flow in the dipleg on the conversion in a catalytic fluidized bed reactor is found to be negligible.
文摘The HCl emission characteristics of typical municipal solid waste(MSW) components and their mixtures have been investigated in a Φ150 mm fluidized bed. Some influencing factors of HCl emission in MSW fluidized bed incinerator was found in this study. The HCl emission is increasing with the growth of bed temperature, while it is decreasing with the increment of oxygen concentration at furnace exit. When the weight percentage of auxiliary coal is increased, the conversion rate of Cl to HCl is increasing. The HCl emission is decreased, if the sorbent(CaO) is added during the incineration process. Based on these experimental results, a 14×6×1 three-layer BP neural networks prediction model of HCl emission in MSW/coal co-fired fluidized bed incinerator was built. The numbers of input nodes and hidden nodes were fixed on by canonical correlation analysis technique and dynamic construction method respectively. The prediction results of this model gave good agreement with the experimental results, which indicates that the model has relatively high accuracy and good generalization ability. It was found that BP neural network is an effectual method used to predict the HCl emission of MSW/coal co-fired fluidized bed incinerator.
基金Supported by the National Excellent Youth Foundation of China (No. 29425006).
文摘This study is devoted to gas-solid mass transfer behavior inheterogeneous two-phase flow. Experiments were carried out in a coldcirculating fluidized bed of 3.0 m in height and 72 mm in diameterwith naphthalene particles. Axial and radial distributions ofsublimated naphthalene concentration in air were measured with an on-line concentration monitoring system HP GC-MS. Mass transfercoefficients were obtained under various operating conditions,showing that heterogeneous flow structure strongly influences theaxial and radial profiles of mass transfer coefficients.
基金Projects (504740309021003550025411) supported by National Natural Science Foundation of China
文摘The settling behavior of coarse particles in a gas-solid fluidized bed was experimentally studied by using magnetic tracer. It is well known that the calculation of terminal velocity is of interest in dense medium separation. However, this problem has not been completely solved up to now. In this work, the terminal velocity of an object mov-ing in a gas-solid fluidized bed was experimentally measured and theoretically calculated. The experimental results in-dicated that the plastic viscosity and yield stress of the bed increase as the size of fluidized particles increases, but it varies little when some coarser particles are mixed with the fluidized particles. The resistance to a rising object was an order magnitude greater than that to a settling object. The efficient buoyancy on a flaky object, which lies flatly on the gas distributor, was much less than that calculated by the Archimedes principle. The object does not always rise or set-tle with minimal projective area owing to radial motion of the fluidized particles. But in the lower part of the bed, the bar-shaped objects were likely with minimal projective area rising or settling.
文摘An experimental verification is reported on the early predicting index of agglomeration in bubbling fluidized bed. Coarse quartz sand, which has the same density but larger diameter than the bed material, was used to simulate the initial agglomerated particle. Wigner distribution was used to analyze the pressure fuctuation of the tested bed, and the average amplitude of local domain frequency （LDF） and local peak weighted average frequency （LPWA） under different operating conditions were measured and compared. The results showed that the LDF is sensitive to the agglomeration phenomena and had quick response to the incipient agglomeration in fluidized beds. It can be concluded from the results that these two parameters could be taken as the characteristic indexes to the agglomeration in fuidized beds.
文摘A CFD code has been developed based on the conservation principles describing gas and solid flow in fluidized beds. This code is employed to simulate not only the spatiotemporal gas and solid phase velocities and voidage profiles in a two dimensional bed but also fluid dynamics in the jet region. The computational results show that gas flow direction is upward in the entire bed accompanied with random local circulations, whilst solid flow direction is upward at the center and downward near the wall. The radical reason of strong back mixing of solid particles and good transfer behavior between two phases is that the jet entrains solid particles. Numerical calculation indicates that gas velocity, solid velocity and pressure profile have a significant change when the voidage is 0 8. The simulated time averaged voidage profiles agree with the experimental results and simulated data reported by Gidaspow and Ettehadieh(1983). Therefore, CFD model can be regarded as a useful tool to study the jet characteristics in dense gas solid fluidized beds.
基金the Multiphase Reactors Engineering and Applications Laboratory(mReal) for funding and support
文摘The chaotic scale-up approach by matching the Kolmogorov entropy(E_K) proposed by Schouten et al.(1996) was assessed in two geometrically similar gas–solid fluidized bed columns of 0.14 and 0.44 m diameter.We used four conditions of our validated new mechanistic scale-up method based on matching the radial profiles of gas holdup where the local dimensionless hydrodynamic parameters were similar as measured by advanced measurement techniques.These experimental conditions were used to evaluate the validity of the chaotic scale-up method,which were selected based on our new mechanistic scale-up methodology.Pressure gauge transducer measurements at the wall and inside the bed at various local radial locations and at three axial heights were used to estimate KE.It was found that the experimental conditions with similar or close radial profiles of the Kolmogorov entropy and with similar or close radial profiles of the gas holdup achieve the similarity in local dimensionless hydrodynamic parameters,and vice versa.
基金Supported by the National Natural Science Foundation of China(No.29576251)
文摘It is found analytically that the parabolic radial profile of liquid velocity in cylindrical liquid-solid fluidized bed (LSFB) causes particles to circulate around some radial position. This is the main reason for liquid-phase axial dispersions. The liquid-phase axial dispersion is depressed as the liquid velocity presents a flatter Bessel radial profile in a converging taper LSFB. The void fraction increases with axial distance in converging taper LSFB. The behavior produces less liquid-phase axial dispersion. Experimental results show good coincidence.
基金Supported by the National Natural Science Foundation of China(No.59776036)
文摘Experiments of biomass pyrolysis were carried out in a fluidized bed, and dynamic signals of pressure and temperature were recorded. Correlation dimension was employed to characterize the chaotic behavior of pressure and temperature signals. Both pressure and temperature signals exhibit chaotic behavior, and the chaotic behavior of temperature signals is always weaker than that of pressure signals. Chaos transfer theory was advanced to explain the above phenomena. The discussion on the algorithm of the correlation dimension shows that the distance definition based on rhombic neighborhood is a better choice than the traditional one based on spherical neighborhood. The former provides a satisfactory result in a much shorter time.
文摘A model is proposed to predict boiling heat transfer coefficient in a three-phase circulating fluidized bed (CFB), which is a new type of evaporation boiling means for enhancing heat transfer and preventing fouling. To verify the model, experiments are conducted in a stainless steel column with 39mm ID and 2.0m height, in which the heat transfer coefficient is measured for different superficial velocities, steam pressures, particle concentrations and materials of particle. As the steam pressure and particle concentrations increase, the heat transfer coefficient in the bed increases. The heat transfer coefficient increases with the liquid velocity but it exhibits a local minimum.The heat transfer coefficient is correlated with cluster renewed model and two-mechanism method. The prediction of the model is in good agreement with experimental data.
基金Supported by the Fujian Provincial Education Council (No. JB9940).
文摘The axial concentration distribution of both particles with betterwetting (forming non-attached system) and poorer wetting (formingattached system) was investigated in a vertical gas-liquid-solidfluidized bed of 4.2 cm in diameters and 130 cm in height with thesolids holdup less than 0.05. The one-dimensionalsedimentation-dispersion model could be used satisfactorily todescribe the axial distribution of solids holdup by modifying only amodel parameter, i.e. by means of the terminal settling velocityminus a certain value, which is a functions of gas velocity andconsiders the effect of an additional drag force resulted fromattached rising bubbles.
文摘Fluidized beds are nonlinear dynamic systems that exchange mass and energy with outside. They are governed not only byfluid dynamics, but by thermodynamics, especially the second law of thermodynamics as well. According to Prigogine's dissipative structure theory, the following have been concluded: (l) a fixed bed is on thermodynamic blanch, and bubbling, turbulent and fast beds areon the dissipatve structure branches. (2) Entropy in fluidized beds is divided into tWo parts: entropy production and entropy flux. The latter increases with gas velocity and decreases with pressure of the systems. That means the entropy of a system may reduce and the systemwith higher gas velocity behaves as dissipative structure characteristics. (3) For a giVen velocity, a fluidized bed operates stably on thewhole, but it is unstable to local gas-solid phases. The unstable phases are described by fluid dynamic equations, While the minimum ofsystem energy function assures whole stability of the system. (4) A transition criterion of a bubbling bed is derived from Prigogine's stability theory.
基金This work was financially suppoded by the Key Project Foundation for Science and Technology Research by the Education Ministry of China (No.00020).
文摘Temperature distribution and control have been investigated in a liquefiedpetroleum gas (LPG) fluidized bed with hollow corundum spheres (A1_2O_3) of 0.867-1.212 mm indiameter at moderately high temperatures (800-1100℃). Experiments were carried out for the airconsumption coefficient α in the range of 0.3 to 1.0 and the fluidization number N in the range of1.3 to 3.0. Particle properties, initial bed height, α and N all affect temperature distribution inthe bed. Bed temperature can be adjusted about 200℃ by combined the adjusting of α and N.
基金supported by the National Youth Talent Support Program(grant No.20224723061)the National S&T Major Project of China(grant No.ZX06901).
文摘The gas-solid reaction process with wide particle size distribution is extensively used in the chemical engineering field,especially the particle reacts with the gas gradually,such as fluorination reactions in fluidized beds.When the computational fluid dynamics-discrete element method(CFD-DEM)is used for the coupling simulation of multiphase and polydisperse particle reaction system,the grid size directly affects the accuracy of flow field information and simulation of chemical reaction.Furthermore,particle calculation time step will directly affect the efficiency of coupling calculation.In this work,a local grid and time step refinement method is proposed to simulate multiphase and polydisperse particle fluid-ization reaction system.In this method,the refined DEM grids are automatically generated in the computational domain around the fine particles,and the detailed fluid phase information is obtained with the interpolation algorithm.In the two-phase coupling process,particles are divided into different groups based on physical properties,each group has its own independent time step.The multistage conical-cylindrical spouted bed is proposed for the fluorination reaction process;the operating gas ve-locity range of the polydisperse particle system is extended by the new design while the particle size distribution changes with the gas-solid reaction process.It is demonstrated that the local grid and time step refinement method can improve the accuracy and efficiency of the traditional CFD-DEM method in the reaction process simulation,which describes a polydisperse particle system with wide particle size distribution.Aimed at improving the simulation accuracy and efficiency,this paper will be helpful for simulating the particle reaction process in the gas-solid fluidized bed and beneficial for the development of the CFD-DEM method.
基金This work was supported by the National Natural ScienceFoundation of China(No.51925603)the Fundamental ResearchFunds for the Central Universities(No.2022ZFJH004).
文摘In the past few decades,multi-scale numerical methods have been developed to model dense gas-solidflow in fluidized beds with different resolutions,accuracies,and efficiencies.However,ambiguity needsto be clarified in the multi-scale numerical simulation of fluidized beds:(i)the selection of the submodels,parameters,and numerical resolution;(ii)the multivariate coupling of operating conditions,bed configurations,polydispersity,and additional forces.Accordingly,a state-of-the-art review is performed to assess the applicability of multi-scale numerical methods in predicting dense gas-solid flow influidized beds at specific fluidization regimes(e.g.,bubbling fluidization region,fast fluidization regime),with a focus on the inter-particle collision models,inter-phase interaction models,collision parameters,and polydispersity effect.A mutual restriction exists between resolution and efficiency.Higherresolution methods need more computational resources and thus are suitable for smaller-scale simulations to provide a database for closure development.Lower-resolution methods require fewercomputational resources and thus underpin large-scale simulations to explore macro-scale phenomena.Model validations need to be further conducted under multiple flow conditions and comprehensivemetrics(e.g.,velocity profiles at different heights,bubbles,or cluster characteristics)for furtherimprovement of the applicability of each numerical method.
基金grateful to the National Natural Science Foundation of China(grant No.21878304 and 21736010)the Strategic Priority Research Program of the Chinese Academy of Sciences(grant No.XDA29040200)the Science Fund for Creative Research Groups of the National Natural Science Foundation of China(grant No.21921005).
文摘In this study,a CFD model coupled with heterogeneous flow structure,mass transfer equations,and chemical reaction kinetics is established to forecast the pyrolusite reduction reaction behavior.Compared with the previous studies which ignore the volume change of solids phase,the influence of volume shrinkage on reaction and flow behavior is explored in this research.Volume shrinkage of pyrolusite is proved to be non-negligible in predicting the conversion rate.The negligence of volume shrinkage leads to the overestimation of conversion rate for its inaccurate estimation of surface area for reaction.Besides,the influence of volume shrinkage on the reaction is found smaller in the scaled-up reactor.
