We demonstrate a home-built electrochemical scanning tunneling microscope (ECSTM). The ECSTM exhibits highly stable performance. The drifting rates in XY and Z directions of the ECSTM are about 67 and 55.6 pm/min, r...We demonstrate a home-built electrochemical scanning tunneling microscope (ECSTM). The ECSTM exhibits highly stable performance. The drifting rates in XY and Z directions of the ECSTM are about 67 and 55.6 pm/min, respectively. Moreover, a specially designed scanner unit successfully solves the well-known problem of large leakage current in high humidity atmosphere. The mechanical structure of the ECSTM is described in detail. The excellent performances of the system are demonstrated by the measured STM images (in copper sulfate solution), including clean and well-ordered large area morphology of Au(111) and the atomically resolved image of highly oriented pyrolytic graphite.展开更多
Coordination engineering can enhance the activity and stability of the catalyst in heterogeneous catalysis.However,the axial coordination engineering between different groups on the carbon carrier and molecular cataly...Coordination engineering can enhance the activity and stability of the catalyst in heterogeneous catalysis.However,the axial coordination engineering between different groups on the carbon carrier and molecular catalysts in the electrocatalytic carbon dioxide reduction reaction(CO_(2)RR)has been studied rarely.Through coordination engineering strategy,a series of amino(NH_(2)),hydroxyl(OH),and carboxyl(COOH)groups functionalized carbon nanotubes(CNT)immobilized cobalt phthalocyanine(CoPc)catalysts are designed.Compared with no groups,OH groups and COOH groups,NH_(2)groups can effectively change the coordination environment of the central metal Co,thereby significantly increasing the turnover frequency(TOF)(31.4 s^(-1)at-0.6 V vs.RHE,CoPc/NH_(2)-CNT>CoPc/OH-CNT>CoPc/COOH-CN>CoPc/CNT).In the flow cell,the CoPc/NH_(2)-CNT catalyst has high carbon monoxide(CO)selectivity at high current density(~100%at-225 mA·cm^(-2),~96%at-351 mA·cm^(-2)).Importantly,the CoPc/NH_(2)-CNT catalyst can operate stably for 100 h at 225 mA·cm^(-2).Theoretical calculations reveal that CoPc/NH_(2)-CNT catalyst is beneficial to the formation of^(*)COOH and desorption of^(*)CO,thus promoting CO_(2)RR.This work provides an excellent platform for understanding the effect of coordination engineering on electrocatalytic performance and promotes a way to explore efficient and stable catalysts in other applications.展开更多
We modify the pulse-reference-based compensation technique and propose a low-noise and highly stable optical fiber temperature sensor based on a zinc telluride film-coated fiber tip. The system noise is measured to be...We modify the pulse-reference-based compensation technique and propose a low-noise and highly stable optical fiber temperature sensor based on a zinc telluride film-coated fiber tip. The system noise is measured to be 0.0005 dB, which makes it possible for the detection of the minor reflectivity change of the film at different temperatures. The temperature sensitivity is 0.0034 d B/℃, so the resolution can achieve 0.2℃. The maximum difference of the temperature output values of the sensor at 20℃ at different points in time is 0.39℃. The low cost, ultra-small size, high stability, and good repeatability of the sensor make it a promising temperature sensing device for practical application.展开更多
Highly efficient and stable hybrid white organic light-emitting diodes (HWOLEDs) with a mixed bipolar interlayer between fluorescent blue and phosphorescent yellow emitting layers are demonstrated. The bipolar inter...Highly efficient and stable hybrid white organic light-emitting diodes (HWOLEDs) with a mixed bipolar interlayer between fluorescent blue and phosphorescent yellow emitting layers are demonstrated. The bipolar interlayer is a mixture of p-type diphenyl (l0-phenyl-lOH-spiro [acridine-9,9'-fluoren]-3Lyl) phosphine oxide and n-type 2',2- (1,3,5-benzinetriyl)-tris(1-phenyl-l-H-benzimidazole). The electroluminance and Commission Internationale de l'Eclairage (CIE1931) coordinates' characteristics can be modulated easily by adjusting the ratio of the hole- predominated material to the electron-predominated material in the interlayer. The hybrid WOLED with a p-type:n-type ratio of 1:3 shows a maximum current efficiency and power efficiency of 61.1 ed/A and 55.8 lm/W, respectively, with warm white CIE coordinates of (0.34, 0.43). The excellent efficiency and adaptive CIE coordi- nates are attributed to the mixed interlayer with improved charge carrier balance, optimized exciton distribution, and enhanced harvesting of singlet and triplet excitons.展开更多
The ternary-element storage and flow concept for shale oil reservoirs in Jiyang Depression of Bohai Bay Basin,East China,was proposed based on the data of more than 10000 m cores and the production of more than 60 hor...The ternary-element storage and flow concept for shale oil reservoirs in Jiyang Depression of Bohai Bay Basin,East China,was proposed based on the data of more than 10000 m cores and the production of more than 60 horizontal wells.The synergy of three elements(storage,fracture and pressure)contributes to the enrichment and high production of shale oil in Jiyang Depression.The storage element controls the enrichment of shale oil;specifically,the presence of inorganic pores and fractures,as well as laminae of lime-mud rocks,in the saline lake basin,is conducive to the storage of shale oil,and the high hydrocarbon generating capacity and free hydrocarbon content are the material basis for high production.The fracture element controls the shale oil flow;specifically,natural fractures act as flow channels for shale oil to migrate and accumulate,and induced fractures communicate natural fractures to form complex fracture network,which is fundamental to high production.The pressure element controls the high and stable production of shale oil;specifically,the high formation pressure provides the drive force for the migration and accumulation of hydrocarbons,and fracturing stimulation significantly increases the elastic energy of rock and fluid,improves the imbibition replacement of oil in the pores/fractures,and reduces the stress sensitivity,guaranteeing the stable production of shale oil for a long time.Based on the ternary-element storage and flow concept,a 3D development technology was formed,with the core techniques of 3D well pattern optimization,3D balanced fracturing,and full-cycle optimization of adjustment and control.This technology effectively guides the production and provides a support to the large-scale beneficial development of shale oil in Jiyang Depression.展开更多
High efficiency, stable organic light-emitting diodes (OLEDs) based on 2-pheyl-4'-carbazole-9-H-Thioxanthen-9- one-10, 10-dioxide (TXO-PhCz) with different doping concentration are constructed. The stability of t...High efficiency, stable organic light-emitting diodes (OLEDs) based on 2-pheyl-4'-carbazole-9-H-Thioxanthen-9- one-10, 10-dioxide (TXO-PhCz) with different doping concentration are constructed. The stability of the encap- sulated devices are investigated in detail. The devices with the 10 wt% doped TXO-PhCz emitter layer (EML) show the best performance with a current efficiency of 52.1 cd/A, a power efficiency of 32.71re^W, and an external quantum efficiency (EQE) of 17.7%. The devices based on the lOwt%-doped TXO-PhCz EML show the best operational stability with a half-life time (LTSO) of 8Oh, which is 8 h longer than that of the reference devices based on fac-tris(2-phenylpyridinato)iridium( Ⅲ) (Ir(ppy)a). These indicate excellent stability of TXO-PhCz for redox and oxidation processes under electrical excitation and TXO-PhCz can be potentially used as the emitters for OLEDs with high efficiency and excellent stability. The high-performance device based on TXO-PhCz with high stability can be further improved by the optimization of the encapsulation technology and the development of a new host for TXO-PhCz.展开更多
This paper mainly introduces an output control method with high stable precision of a large power IGBT arc welding inverter. Experiments indicate that this kind of control mode can effectively improve the static and d...This paper mainly introduces an output control method with high stable precision of a large power IGBT arc welding inverter. Experiments indicate that this kind of control mode can effectively improve the static and dynamic characteristics and stability of power supply system. And it can decrease the spatters in the welding process apparently. This power supply is especially suitable to automatic robot welding assembly line. It will be the developing direction of robot welding supply in the future.展开更多
<span style="font-family:;" "=""><span style="font-family:Verdana;">In this paper, it was introduced that </span><i><span style="font-family:Verdana;&...<span style="font-family:;" "=""><span style="font-family:Verdana;">In this paper, it was introduced that </span><i><span style="font-family:Verdana;">Coix lacryma-jobi</span></i><span style="font-family:Verdana;"> is a traditional dual-</span></span><span style="font-family:;" "=""><span style="font-family:Verdana;">use edible and medicine crops in China, and the nutritional components and medicinal value of </span><i><span style="font-family:Verdana;">Coix lacryma-jobi</span></i><span style="font-family:Verdana;"> were described. Based on the published literature at home and abroad, a variety of chemical components found in </span><i><span style="font-family:Verdana;">Coix lacryma jobi</span></i><span style="font-family:Verdana;"> and their medicinal effects were reviewed. At the same time,</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">the problems existing in the production of </span><i><span style="font-family:Verdana;">Coix lacryma jobi</span></i><span style="font-family:Verdana;"> were put forward. With the improvement of people’s living standards, the nutritional and health care value of </span><i><span style="font-family:Verdana;">Coix lacryma-jobi</span></i><span style="font-family:Verdana;"> has been paid more and more attention.</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">The problems of </span><i><span style="font-family:Verdana;">Coix lacryma-jobi</span></i><span style="font-family:Verdana;"> in production were analyzed.</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">Some biological characteristics of </span><i><span style="font-family:Verdana;">Coix lacryma-jobi</span></i><span style="font-family:Verdana;">, especially its hygrophyte characteristics, were re-recognized, which is very important to increase the yield of </span><i><span style="font-family:Verdana;">Coix lacryma jobi</span></i><span style="font-family:Verdana;">. In the paper, the key cultivation techniques for high and stable yield of </span><i><span style="font-family:Verdana;">Coix lacryma-jobi</span></i><span style="font-family:Verdana;"> were also summarized. In order to obtain high quality, high and stable yield, we should adopt the new technical methods of “two wet, two dry and two water” in water management. At </span></span><span style="font-family:Verdana;">the </span><span style="font-family:Verdana;">same time, if artificial pollination is applied in the peak of flowering period, the seed setting rate and the yield will be increased.</span>展开更多
We investigate strong stability preserving(SSP)implicit-explicit(IMEX)methods for partitioned systems of differential equations with stiff and nonstiff subsystems.Conditions for order p and stage order q=p are derived...We investigate strong stability preserving(SSP)implicit-explicit(IMEX)methods for partitioned systems of differential equations with stiff and nonstiff subsystems.Conditions for order p and stage order q=p are derived,and characterization of SSP IMEX methods is provided following the recent work by Spijker.Stability properties of these methods with respect to the decoupled linear system with a complex parameter,and a coupled linear system with real parameters are also investigated.Examples of methods up to the order p=4 and stage order q—p are provided.Numerical examples on six partitioned test systems confirm that the derived methods achieve the expected order of convergence for large range of stepsizes of integration,and they are also suitable for preserving the accuracy in the stiff limit or preserving the positivity of the numerical solution for large stepsizes.展开更多
The vertical sections of the La−Fe−B system were investigated using electron probe microanalysis and differential thermal analysis.Based on the microstructures and phase compositions of the as-cast and equilibrium all...The vertical sections of the La−Fe−B system were investigated using electron probe microanalysis and differential thermal analysis.Based on the microstructures and phase compositions of the as-cast and equilibrium alloys,together with their heat flow−temperature curves,phase diagrams for three vertical sections were drawn:La_(x)Fe_(82)B_(y)(x+y=18),La_(x)Fe_(70)B_(y)(x+y=30)and La_(x)Fe_(53)B_(y)(x+y=47),where x and y represent mass fraction of La and B,respectively,%.Additionally,according to the phase diagrams,the compound La2Fe14B was identified as a stable phase at high temperatures.It was found to be stable between 926.2 and 792.6℃;at low temperatures,however,it decomposed into α-La,α-Fe and LaFe_(4)B_(4),according to the reaction La_(2)Fe_(14)B→α-Fe+α-La+LaFe_(4)B_(4).展开更多
The design and synthesis of stable metal–organic frameworks(MOFs)have been a core obstacle in the widespread application of these functional crystalline porous materials,because of the stability limitations of MOFs u...The design and synthesis of stable metal–organic frameworks(MOFs)have been a core obstacle in the widespread application of these functional crystalline porous materials,because of the stability limitations of MOFs under harsh operating conditions.Herein,a highly stable microporous MOF based on the Fe_(3)O cluster(PCN-678)has been synthesized using a tetracarboxylate ligand.Utilizing symmetry reduced tetratopic carboxylate ligand,a mesoporous MOF(PCN-668)could be obtained in which nanoscale cage-like building units and one-dimensional(1D)channels coexist.The neighboring cages were mutual diastereomers in PCN-668 due to the further reduction of the Cs symmetry of the free ligand to C1 symmetry after self-assembly.Furthermore,the acid stability of this mesoporous MOF was improved via postsynthetic metal exchange to chromium(PCN-668-Cr).The PCN-668-Cr exhibited very high stability in both acidic and basic aqueous solutions(pH=1–11).Additionally,the mesoporous MOF showed a high total gravimetric methane uptake(∼500 cm^(3) g^(−1) at 100 bar),while the microporous MOF showed a high volumetric methane storage capacity of 147 cm3 cm−3 at room temperature.展开更多
A DC active power filter is an indispensable part in a high power and high stability power supply system, especially in the power supply system of the Steady High Magnetic Field Facility, which requires that the curre...A DC active power filter is an indispensable part in a high power and high stability power supply system, especially in the power supply system of the Steady High Magnetic Field Facility, which requires that the current ripple should be limited to 50 parts per million. In view of the disadvantages of the series DC active power filter and shunt Pulse Width Modulation DC active filter, this paper puts forward a novel DC active filter by combining the advantages of the transistor regulator and the shunt type. The structure and principle of the new shunt linear active filter are introduced. Meanwhile, the design of several key components that construct the new shunt linear active filter is also analyzed. The simulation model and an experimental prototype of the shunt linear active filter are developed, and the results verify that the parameter design is reasonable and the shunt active filter has a good filter effect.展开更多
文摘We demonstrate a home-built electrochemical scanning tunneling microscope (ECSTM). The ECSTM exhibits highly stable performance. The drifting rates in XY and Z directions of the ECSTM are about 67 and 55.6 pm/min, respectively. Moreover, a specially designed scanner unit successfully solves the well-known problem of large leakage current in high humidity atmosphere. The mechanical structure of the ECSTM is described in detail. The excellent performances of the system are demonstrated by the measured STM images (in copper sulfate solution), including clean and well-ordered large area morphology of Au(111) and the atomically resolved image of highly oriented pyrolytic graphite.
基金This work was supported by the National Natural Science Foundation of China(Nos.51772162,22001143,and 52072197)Youth Innovation and Technology Foundation of Shandong Higher Education Institutions,China(No.2019KJC004)+4 种基金Outstanding Youth Foundation of Shandong Province,China(No.ZR2019JQ14)Taishan Scholar Young Talent Program,China(Nos.tsqn201909114 and tsqn201909123)Natural Science Foundation of Shandong Province,China(No.ZR2020YQ34)Major Scientific and Technological Innovation Project,China(No.2019JZZY020405)Major Basic Research Program of Natural Science Foundation of Shandong Province,China(No.ZR2020ZD09).
文摘Coordination engineering can enhance the activity and stability of the catalyst in heterogeneous catalysis.However,the axial coordination engineering between different groups on the carbon carrier and molecular catalysts in the electrocatalytic carbon dioxide reduction reaction(CO_(2)RR)has been studied rarely.Through coordination engineering strategy,a series of amino(NH_(2)),hydroxyl(OH),and carboxyl(COOH)groups functionalized carbon nanotubes(CNT)immobilized cobalt phthalocyanine(CoPc)catalysts are designed.Compared with no groups,OH groups and COOH groups,NH_(2)groups can effectively change the coordination environment of the central metal Co,thereby significantly increasing the turnover frequency(TOF)(31.4 s^(-1)at-0.6 V vs.RHE,CoPc/NH_(2)-CNT>CoPc/OH-CNT>CoPc/COOH-CN>CoPc/CNT).In the flow cell,the CoPc/NH_(2)-CNT catalyst has high carbon monoxide(CO)selectivity at high current density(~100%at-225 mA·cm^(-2),~96%at-351 mA·cm^(-2)).Importantly,the CoPc/NH_(2)-CNT catalyst can operate stably for 100 h at 225 mA·cm^(-2).Theoretical calculations reveal that CoPc/NH_(2)-CNT catalyst is beneficial to the formation of^(*)COOH and desorption of^(*)CO,thus promoting CO_(2)RR.This work provides an excellent platform for understanding the effect of coordination engineering on electrocatalytic performance and promotes a way to explore efficient and stable catalysts in other applications.
基金supported by the National Natural Science Foundation of China(Nos.11574397,61775238,61705262,and 61705263)the Scientific Research Project of National University of Defense Technology(No.JC15-11-02)
文摘We modify the pulse-reference-based compensation technique and propose a low-noise and highly stable optical fiber temperature sensor based on a zinc telluride film-coated fiber tip. The system noise is measured to be 0.0005 dB, which makes it possible for the detection of the minor reflectivity change of the film at different temperatures. The temperature sensitivity is 0.0034 d B/℃, so the resolution can achieve 0.2℃. The maximum difference of the temperature output values of the sensor at 20℃ at different points in time is 0.39℃. The low cost, ultra-small size, high stability, and good repeatability of the sensor make it a promising temperature sensing device for practical application.
基金Supported by the National Natural Science Foundation of China under Grant No 91441201
文摘Highly efficient and stable hybrid white organic light-emitting diodes (HWOLEDs) with a mixed bipolar interlayer between fluorescent blue and phosphorescent yellow emitting layers are demonstrated. The bipolar interlayer is a mixture of p-type diphenyl (l0-phenyl-lOH-spiro [acridine-9,9'-fluoren]-3Lyl) phosphine oxide and n-type 2',2- (1,3,5-benzinetriyl)-tris(1-phenyl-l-H-benzimidazole). The electroluminance and Commission Internationale de l'Eclairage (CIE1931) coordinates' characteristics can be modulated easily by adjusting the ratio of the hole- predominated material to the electron-predominated material in the interlayer. The hybrid WOLED with a p-type:n-type ratio of 1:3 shows a maximum current efficiency and power efficiency of 61.1 ed/A and 55.8 lm/W, respectively, with warm white CIE coordinates of (0.34, 0.43). The excellent efficiency and adaptive CIE coordi- nates are attributed to the mixed interlayer with improved charge carrier balance, optimized exciton distribution, and enhanced harvesting of singlet and triplet excitons.
基金Supported by Sinopec Key Science and Technology Research Project(P21060)。
文摘The ternary-element storage and flow concept for shale oil reservoirs in Jiyang Depression of Bohai Bay Basin,East China,was proposed based on the data of more than 10000 m cores and the production of more than 60 horizontal wells.The synergy of three elements(storage,fracture and pressure)contributes to the enrichment and high production of shale oil in Jiyang Depression.The storage element controls the enrichment of shale oil;specifically,the presence of inorganic pores and fractures,as well as laminae of lime-mud rocks,in the saline lake basin,is conducive to the storage of shale oil,and the high hydrocarbon generating capacity and free hydrocarbon content are the material basis for high production.The fracture element controls the shale oil flow;specifically,natural fractures act as flow channels for shale oil to migrate and accumulate,and induced fractures communicate natural fractures to form complex fracture network,which is fundamental to high production.The pressure element controls the high and stable production of shale oil;specifically,the high formation pressure provides the drive force for the migration and accumulation of hydrocarbons,and fracturing stimulation significantly increases the elastic energy of rock and fluid,improves the imbibition replacement of oil in the pores/fractures,and reduces the stress sensitivity,guaranteeing the stable production of shale oil for a long time.Based on the ternary-element storage and flow concept,a 3D development technology was formed,with the core techniques of 3D well pattern optimization,3D balanced fracturing,and full-cycle optimization of adjustment and control.This technology effectively guides the production and provides a support to the large-scale beneficial development of shale oil in Jiyang Depression.
基金Supported by the National Natural Science Foundation of China under Grant Nos 61420106002,51373189,61178061,and 61227008the Hundred Talents Program of the Chinese Academy of Sciences,the National Basic Research Program of China under Grant No 2014CB932600the Start-Up Fund of the Technical Institute of Physics and Chemistry of the Chinese Academy of Sciences
文摘High efficiency, stable organic light-emitting diodes (OLEDs) based on 2-pheyl-4'-carbazole-9-H-Thioxanthen-9- one-10, 10-dioxide (TXO-PhCz) with different doping concentration are constructed. The stability of the encap- sulated devices are investigated in detail. The devices with the 10 wt% doped TXO-PhCz emitter layer (EML) show the best performance with a current efficiency of 52.1 cd/A, a power efficiency of 32.71re^W, and an external quantum efficiency (EQE) of 17.7%. The devices based on the lOwt%-doped TXO-PhCz EML show the best operational stability with a half-life time (LTSO) of 8Oh, which is 8 h longer than that of the reference devices based on fac-tris(2-phenylpyridinato)iridium( Ⅲ) (Ir(ppy)a). These indicate excellent stability of TXO-PhCz for redox and oxidation processes under electrical excitation and TXO-PhCz can be potentially used as the emitters for OLEDs with high efficiency and excellent stability. The high-performance device based on TXO-PhCz with high stability can be further improved by the optimization of the encapsulation technology and the development of a new host for TXO-PhCz.
文摘This paper mainly introduces an output control method with high stable precision of a large power IGBT arc welding inverter. Experiments indicate that this kind of control mode can effectively improve the static and dynamic characteristics and stability of power supply system. And it can decrease the spatters in the welding process apparently. This power supply is especially suitable to automatic robot welding assembly line. It will be the developing direction of robot welding supply in the future.
文摘<span style="font-family:;" "=""><span style="font-family:Verdana;">In this paper, it was introduced that </span><i><span style="font-family:Verdana;">Coix lacryma-jobi</span></i><span style="font-family:Verdana;"> is a traditional dual-</span></span><span style="font-family:;" "=""><span style="font-family:Verdana;">use edible and medicine crops in China, and the nutritional components and medicinal value of </span><i><span style="font-family:Verdana;">Coix lacryma-jobi</span></i><span style="font-family:Verdana;"> were described. Based on the published literature at home and abroad, a variety of chemical components found in </span><i><span style="font-family:Verdana;">Coix lacryma jobi</span></i><span style="font-family:Verdana;"> and their medicinal effects were reviewed. At the same time,</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">the problems existing in the production of </span><i><span style="font-family:Verdana;">Coix lacryma jobi</span></i><span style="font-family:Verdana;"> were put forward. With the improvement of people’s living standards, the nutritional and health care value of </span><i><span style="font-family:Verdana;">Coix lacryma-jobi</span></i><span style="font-family:Verdana;"> has been paid more and more attention.</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">The problems of </span><i><span style="font-family:Verdana;">Coix lacryma-jobi</span></i><span style="font-family:Verdana;"> in production were analyzed.</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">Some biological characteristics of </span><i><span style="font-family:Verdana;">Coix lacryma-jobi</span></i><span style="font-family:Verdana;">, especially its hygrophyte characteristics, were re-recognized, which is very important to increase the yield of </span><i><span style="font-family:Verdana;">Coix lacryma jobi</span></i><span style="font-family:Verdana;">. In the paper, the key cultivation techniques for high and stable yield of </span><i><span style="font-family:Verdana;">Coix lacryma-jobi</span></i><span style="font-family:Verdana;"> were also summarized. In order to obtain high quality, high and stable yield, we should adopt the new technical methods of “two wet, two dry and two water” in water management. At </span></span><span style="font-family:Verdana;">the </span><span style="font-family:Verdana;">same time, if artificial pollination is applied in the peak of flowering period, the seed setting rate and the yield will be increased.</span>
文摘We investigate strong stability preserving(SSP)implicit-explicit(IMEX)methods for partitioned systems of differential equations with stiff and nonstiff subsystems.Conditions for order p and stage order q=p are derived,and characterization of SSP IMEX methods is provided following the recent work by Spijker.Stability properties of these methods with respect to the decoupled linear system with a complex parameter,and a coupled linear system with real parameters are also investigated.Examples of methods up to the order p=4 and stage order q—p are provided.Numerical examples on six partitioned test systems confirm that the derived methods achieve the expected order of convergence for large range of stepsizes of integration,and they are also suitable for preserving the accuracy in the stiff limit or preserving the positivity of the numerical solution for large stepsizes.
基金financially supported by the Natural Science Foundation of China(No.51761007)the Guangxi Natural Science Foundation,China(Nos.2019GXNSFAA245003,2018GXNSFAA294069,2020GXNSFFA297004,2021GXNSFDA075009)+5 种基金the Guangxi Project of Science and Technology,China(Nos.AD19110078,AA18242023-1)the Scientific Research Foundation of Guilin University of Electronic Technology,China(No.UF18016)the Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials(No.2019GXYSOF08),Chinathe Guangxi Key Laboratory of Information Materials,China(No.191012-Z)the National Key R&D Program of China(No.2016YFB0700901)financial support from the foundation for Guangxi Bagui scholars,China。
文摘The vertical sections of the La−Fe−B system were investigated using electron probe microanalysis and differential thermal analysis.Based on the microstructures and phase compositions of the as-cast and equilibrium alloys,together with their heat flow−temperature curves,phase diagrams for three vertical sections were drawn:La_(x)Fe_(82)B_(y)(x+y=18),La_(x)Fe_(70)B_(y)(x+y=30)and La_(x)Fe_(53)B_(y)(x+y=47),where x and y represent mass fraction of La and B,respectively,%.Additionally,according to the phase diagrams,the compound La2Fe14B was identified as a stable phase at high temperatures.It was found to be stable between 926.2 and 792.6℃;at low temperatures,however,it decomposed into α-La,α-Fe and LaFe_(4)B_(4),according to the reaction La_(2)Fe_(14)B→α-Fe+α-La+LaFe_(4)B_(4).
基金supported by the Center for Gas Separations,an Energy Frontier Research Center funded by the U.S.Department of Energy,Office of Science,Office of Basic Energy Sciences(no.DESC0001015)Structural analyses were supported by the Robert A.Welch Foundation through a Welch Endowed Chair to H.-C.Z.(A-0030)+3 种基金The National Science Foundation Graduate Research Fellowship(DGE:1252521)is gratefully acknowledged.The authors also acknowledge the financial support of the U.S.Department of Energy Office of Fossil Energy,National Energy Technology Laboratory(no.DE-FE0026472)and National Science Foundation Small Business Innovation Research(NSFSBIR)under grant no.(1632486)the financial support of the Strategic Priority Research Program of the Chinese Academy of Sciences(no.XDB20000000)National Nature Science Foundation of China(no.21871266),CAS(no.QYZDY-SSWSLH025),and Youth Innovation Promotion Association CAS.
文摘The design and synthesis of stable metal–organic frameworks(MOFs)have been a core obstacle in the widespread application of these functional crystalline porous materials,because of the stability limitations of MOFs under harsh operating conditions.Herein,a highly stable microporous MOF based on the Fe_(3)O cluster(PCN-678)has been synthesized using a tetracarboxylate ligand.Utilizing symmetry reduced tetratopic carboxylate ligand,a mesoporous MOF(PCN-668)could be obtained in which nanoscale cage-like building units and one-dimensional(1D)channels coexist.The neighboring cages were mutual diastereomers in PCN-668 due to the further reduction of the Cs symmetry of the free ligand to C1 symmetry after self-assembly.Furthermore,the acid stability of this mesoporous MOF was improved via postsynthetic metal exchange to chromium(PCN-668-Cr).The PCN-668-Cr exhibited very high stability in both acidic and basic aqueous solutions(pH=1–11).Additionally,the mesoporous MOF showed a high total gravimetric methane uptake(∼500 cm^(3) g^(−1) at 100 bar),while the microporous MOF showed a high volumetric methane storage capacity of 147 cm3 cm−3 at room temperature.
基金Supported by National Important Project on Science of SHMFFNational Natural Science Foundation of China (50977086)
文摘A DC active power filter is an indispensable part in a high power and high stability power supply system, especially in the power supply system of the Steady High Magnetic Field Facility, which requires that the current ripple should be limited to 50 parts per million. In view of the disadvantages of the series DC active power filter and shunt Pulse Width Modulation DC active filter, this paper puts forward a novel DC active filter by combining the advantages of the transistor regulator and the shunt type. The structure and principle of the new shunt linear active filter are introduced. Meanwhile, the design of several key components that construct the new shunt linear active filter is also analyzed. The simulation model and an experimental prototype of the shunt linear active filter are developed, and the results verify that the parameter design is reasonable and the shunt active filter has a good filter effect.