Based on field observations carried out in August, 2008, we obtained a set of data on velocity, hydrography, and hydroehemistry in the Luzon Strait, with which the velocity structure of the area, especially in deep ch...Based on field observations carried out in August, 2008, we obtained a set of data on velocity, hydrography, and hydroehemistry in the Luzon Strait, with which the velocity structure of the area, especially in deep channels, was analyzed, and the material fluxes, including water, dissolved oxygen, and nutrients were calculated. The results indicate that a net eastward water flux of 7.0 Sv occurred through the Luzon Strait. The deep layer flux in the southern part, through the deep channel, was westward with a value of 1.9 Sv, which confirms that deep Pacific water flows into the South China Sea via the deep passage in the Luzon Strait. Accordingly, the net flux of dissolved oxygen was 13.2× 10 5 mol/s, and the values for dissolved inorganic nitrogen, phosphate and silicate were 4.6× 10 4 mol/s, 2.4× 10 3 mol/s, and 8.9×10 4 mol/s, respectively. Detailed descriptions of these material fluxes in the upper layer, the upper-intermediate layer, the lower-intermediate layer, and the deep layer through the Luzon Strait are discussed. These results and interpretations highlight the importance of material exchanges between the South China Sea and the Pacific Ocean.展开更多
A modified inverse method is ed to compute the volume transport (VT), the heat transport (HT) andthe horizontal meterial fluxes in the East China Sea with data of CTD, T2, DOC, PCO, etc. Obtained in April1994. In Apri...A modified inverse method is ed to compute the volume transport (VT), the heat transport (HT) andthe horizontal meterial fluxes in the East China Sea with data of CTD, T2, DOC, PCO, etc. Obtained in April1994. In April 1994 VT and HT through Section PN in the East China As are 30.6×106 m3/s and 2.42× 1015 Wrespectively, and the horizontal fluxes of T2, DOC and POC through Section PN are 65× 106,2. 2×106 and 0. 17×106 mol/s respectively. This means that the Percentages of fluxes of T2 , DOC and POC in total C flux are about96.5%, 3.3% and 0.2% respectively. VT and HT through betion Ss(near the Tokara Strait) are 26. 7×106m3/sand 2. 14× 1015 W respectively, which are about 87% and 88% of VT and HT through Section PN respectively. Thehorizontal flux of T2 through sation % is 61×106 mol/s, which is about 93. 8 % of the flux of T2 through SectionPN, i. e., its percentage is close to that of VT and HT of betions S5 and PN. The horizontal fluxes of DOC and POCthrough Section S5 are 2. 5× 106 and 0.08×106 mol/s respectively. The sum of the horizontal influx and outflux ofTop through the boundaries of Box-2 is about-2×106 mol/s (outflux), which is about 3% of the flux of T2 through Section PN. This value is the same order of magnitude of the vertical flux caused by the downwelling or theupwelling. Tins means that the horizontal flux of T2 must be considered, when the vertical flux of T2 is computed,and so are the other material vertical fluxes (DOC, etc. ). Finally, the vertical velocity component is computed with adiagnostic model.展开更多
This study prepares a group of single crystalline β-Zn_4Sb_3 with Ge and Sn codoped by the Sn-flux method according to the nominal stoichiometric ratios of Zn_（4.4）Sb_3 Ge_xSn_3（x = 0–0.15）. The prepared samples...This study prepares a group of single crystalline β-Zn_4Sb_3 with Ge and Sn codoped by the Sn-flux method according to the nominal stoichiometric ratios of Zn_（4.4）Sb_3 Ge_xSn_3（x = 0–0.15）. The prepared samples possess a metallic luster surface with perfect appearance and large crystal sizes. The microscopic cracks or defects are invisible in the samples from the back-scattered electron image. Except for the heavily Ge-doped sample of x = 0.15, all the samples are single phase with space group R3c. The thermal analysis results show that the samples doped with Ge exhibit an excellent thermal stability.Compared with the polycrystalline Ge-substituted β-Zn_4Sb_3, the present single crystals have higher carrier mobility, and hence the electrical conductivity is improved, which reaches 7.48×10~4S·m^（-1） at room temperature for the x = 0.1 sample.The change of Ge and Sn contents does not improve the Seebeck coefficient significantly. Benefiting from the increased electrical conductivity, the sample with x = 0.075 gets the highest power factor of 1.45×10^（-3）W·m^（-1）·K^（-2） at 543 K.展开更多
Cerium-doped yttrium aluminum garnet（YAG：Ce） as a yellow phosphor for white light-emitting diodes（LEDs） was synthesized via a facile combustion method using Y2 O3, CeO2, Al2 O3, Al,and NaClO4 as raw materials. Th...Cerium-doped yttrium aluminum garnet（YAG：Ce） as a yellow phosphor for white light-emitting diodes（LEDs） was synthesized via a facile combustion method using Y2 O3, CeO2, Al2 O3, Al,and NaClO4 as raw materials. The combustion synthesis approach utilizes the strong exothermic oxidation of aluminum to realize a self-sustaining reaction. In this study, we investigated the effects of the ratios of Al2 O3 to AI,fluxes, and coprecipitated materials as raw materials on the luminescence properties of the synthesized YAG：Ce phosphors. When the amount of Al2 O3 x is varied, the combustion reaction proceeds at x ≤ 1.8,with x = 1.725 being the optimum condition for producing a high-performance product. When 5 wt%BaF2 is added, the luminescence intensity is significantly improved owing to a decrease of YAP（YAlO3）formation with improved uniformity. However, the addition of CaF2 and NaF does not improve the luminescence properties. To suppress the segregation of CeO2, we used the coprecipitated material Y2 O3-CeO2 as a raw material. Unlike with separate addition of Y2 O3 and CeO2, Ce ions are uniformly distributed in the coprecipitated material, resulting in improved luminescence properties. The combination of BaF2 and coprecipitated material significantly improves the internal quantum efficiency to83.0%, which is close to that of commercial phosphors.展开更多
基金Supported by National Natural Science Foundation of China (Nos.40906004,40776005 and 40890153)National High Technology Research and Development Program of China (863 Program) (2008AA09A402)Polar Science Foundation of China (20080206)
文摘Based on field observations carried out in August, 2008, we obtained a set of data on velocity, hydrography, and hydroehemistry in the Luzon Strait, with which the velocity structure of the area, especially in deep channels, was analyzed, and the material fluxes, including water, dissolved oxygen, and nutrients were calculated. The results indicate that a net eastward water flux of 7.0 Sv occurred through the Luzon Strait. The deep layer flux in the southern part, through the deep channel, was westward with a value of 1.9 Sv, which confirms that deep Pacific water flows into the South China Sea via the deep passage in the Luzon Strait. Accordingly, the net flux of dissolved oxygen was 13.2× 10 5 mol/s, and the values for dissolved inorganic nitrogen, phosphate and silicate were 4.6× 10 4 mol/s, 2.4× 10 3 mol/s, and 8.9×10 4 mol/s, respectively. Detailed descriptions of these material fluxes in the upper layer, the upper-intermediate layer, the lower-intermediate layer, and the deep layer through the Luzon Strait are discussed. These results and interpretations highlight the importance of material exchanges between the South China Sea and the Pacific Ocean.
文摘A modified inverse method is ed to compute the volume transport (VT), the heat transport (HT) andthe horizontal meterial fluxes in the East China Sea with data of CTD, T2, DOC, PCO, etc. Obtained in April1994. In April 1994 VT and HT through Section PN in the East China As are 30.6×106 m3/s and 2.42× 1015 Wrespectively, and the horizontal fluxes of T2, DOC and POC through Section PN are 65× 106,2. 2×106 and 0. 17×106 mol/s respectively. This means that the Percentages of fluxes of T2 , DOC and POC in total C flux are about96.5%, 3.3% and 0.2% respectively. VT and HT through betion Ss(near the Tokara Strait) are 26. 7×106m3/sand 2. 14× 1015 W respectively, which are about 87% and 88% of VT and HT through Section PN respectively. Thehorizontal flux of T2 through sation % is 61×106 mol/s, which is about 93. 8 % of the flux of T2 through SectionPN, i. e., its percentage is close to that of VT and HT of betions S5 and PN. The horizontal fluxes of DOC and POCthrough Section S5 are 2. 5× 106 and 0.08×106 mol/s respectively. The sum of the horizontal influx and outflux ofTop through the boundaries of Box-2 is about-2×106 mol/s (outflux), which is about 3% of the flux of T2 through Section PN. This value is the same order of magnitude of the vertical flux caused by the downwelling or theupwelling. Tins means that the horizontal flux of T2 must be considered, when the vertical flux of T2 is computed,and so are the other material vertical fluxes (DOC, etc. ). Finally, the vertical velocity component is computed with adiagnostic model.
基金Project supported by the National Natural Science Foundation of China(Grant No.51262032)
文摘This study prepares a group of single crystalline β-Zn_4Sb_3 with Ge and Sn codoped by the Sn-flux method according to the nominal stoichiometric ratios of Zn_（4.4）Sb_3 Ge_xSn_3（x = 0–0.15）. The prepared samples possess a metallic luster surface with perfect appearance and large crystal sizes. The microscopic cracks or defects are invisible in the samples from the back-scattered electron image. Except for the heavily Ge-doped sample of x = 0.15, all the samples are single phase with space group R3c. The thermal analysis results show that the samples doped with Ge exhibit an excellent thermal stability.Compared with the polycrystalline Ge-substituted β-Zn_4Sb_3, the present single crystals have higher carrier mobility, and hence the electrical conductivity is improved, which reaches 7.48×10~4S·m^（-1） at room temperature for the x = 0.1 sample.The change of Ge and Sn contents does not improve the Seebeck coefficient significantly. Benefiting from the increased electrical conductivity, the sample with x = 0.075 gets the highest power factor of 1.45×10^（-3）W·m^（-1）·K^（-2） at 543 K.
基金supported by the"Nanotechnology Platform"Program of the Ministry of Education,Culture,Sports,Science and Technology of Japan(MEXT)
文摘Cerium-doped yttrium aluminum garnet（YAG：Ce） as a yellow phosphor for white light-emitting diodes（LEDs） was synthesized via a facile combustion method using Y2 O3, CeO2, Al2 O3, Al,and NaClO4 as raw materials. The combustion synthesis approach utilizes the strong exothermic oxidation of aluminum to realize a self-sustaining reaction. In this study, we investigated the effects of the ratios of Al2 O3 to AI,fluxes, and coprecipitated materials as raw materials on the luminescence properties of the synthesized YAG：Ce phosphors. When the amount of Al2 O3 x is varied, the combustion reaction proceeds at x ≤ 1.8,with x = 1.725 being the optimum condition for producing a high-performance product. When 5 wt%BaF2 is added, the luminescence intensity is significantly improved owing to a decrease of YAP（YAlO3）formation with improved uniformity. However, the addition of CaF2 and NaF does not improve the luminescence properties. To suppress the segregation of CeO2, we used the coprecipitated material Y2 O3-CeO2 as a raw material. Unlike with separate addition of Y2 O3 and CeO2, Ce ions are uniformly distributed in the coprecipitated material, resulting in improved luminescence properties. The combination of BaF2 and coprecipitated material significantly improves the internal quantum efficiency to83.0%, which is close to that of commercial phosphors.
