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Proppant transport law in multi-branched fractures induced by volume fracturing
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作者 GUO Tiankui LYU Mingkun +6 位作者 CHEN Ming XU Yun WENG Dingwei QU Zhanqing DAI Caili HOU Jian LIU Xiaoqiang 《Petroleum Exploration and Development》 SCIE 2023年第4期955-970,共16页
To further clarify the proppant transport and placement law in multi-branched fractures induced by volume fracturing, proppant transport simulation experiments were performed with different fracture shapes, sand ratio... To further clarify the proppant transport and placement law in multi-branched fractures induced by volume fracturing, proppant transport simulation experiments were performed with different fracture shapes, sand ratios, branched fracture opening time and injection sequence of proppants in varied particle sizes. The results show that the settled proppant height increases and the placement length decreases in main fractures as the fracturing fluid diverts gradually to the branched fractures at different positions. The flow rate in branched fractures is the main factor affecting their filling. The diverion to branched fractures leads to low flow rate and poor filling of far-wellbore branched fractures. The inclined fracture wall exerts a frictional force on the proppant to slow its settlement, thus enhancing the vertical proppant distribution in the fracture. The increase of sand ratio can improve the filling of near-wellbore main fracture and far-wellbore branched fracture and also increase the settled proppant height in main fracture. Due to the limitation of fracture height, when the sand ratio increases to a certain level, the increment of fracture filling decreases. When branched fracture is always open(or extends continuously), the supporting effect on the branched fractures is the best, but the proppant placement length within the main fractures is shorter. The fractures support effect is better when it is first closed and then opened(or extends in late stage) than when it is first opened and then closed(or extends in early stage). Injecting proppants with different particle sizes in a specific sequence can improve the placement lengths of main fracture and branched fracture. Injection of proppants in an ascending order of particle size improves the near-wellbore fracture filling, to a better extent than that in a descending order of particle size. 展开更多
关键词 volume fracturing proppant transport complex fracture support multi-branched fracture fracture inclination opening time of branched fracture
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Lightweight Res-Connection Multi-Branch Network for Highly Accurate Crowd Counting and Localization
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作者 Mingze Li Diwen Zheng Shuhua Lu 《Computers, Materials & Continua》 SCIE EI 2024年第5期2105-2122,共18页
Crowd counting is a promising hotspot of computer vision involving crowd intelligence analysis,achieving tremendous success recently with the development of deep learning.However,there have been stillmany challenges i... Crowd counting is a promising hotspot of computer vision involving crowd intelligence analysis,achieving tremendous success recently with the development of deep learning.However,there have been stillmany challenges including crowd multi-scale variations and high network complexity,etc.To tackle these issues,a lightweight Resconnection multi-branch network(LRMBNet)for highly accurate crowd counting and localization is proposed.Specifically,using improved ShuffleNet V2 as the backbone,a lightweight shallow extractor has been designed by employing the channel compression mechanism to reduce enormously the number of network parameters.A light multi-branch structure with different expansion rate convolutions is demonstrated to extract multi-scale features and enlarged receptive fields,where the information transmission and fusion of diverse scale features is enhanced via residual concatenation.In addition,a compound loss function is introduced for training themethod to improve global context information correlation.The proposed method is evaluated on the SHHA,SHHB,UCF-QNRF and UCF_CC_50 public datasets.The accuracy is better than those of many advanced approaches,while the number of parameters is smaller.The experimental results show that the proposed method achieves a good tradeoff between the complexity and accuracy of crowd counting,indicating a lightweight and high-precision method for crowd counting. 展开更多
关键词 Crowd counting Res-connection multi-branch compound loss function
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Multi-Branch Fault Line Location Method Based on Time Difference Matrix Fitting
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作者 Hua Leng Silin He +3 位作者 Jian Qiu Feng Liu Xinfei Huang Jiran Zhu 《Energy Engineering》 EI 2024年第1期77-94,共18页
The distribution network exhibits complex structural characteristics,which makes fault localization a challenging task.Especially when a branch of the multi-branch distribution network fails,the traditional multi-bran... The distribution network exhibits complex structural characteristics,which makes fault localization a challenging task.Especially when a branch of the multi-branch distribution network fails,the traditional multi-branch fault location algorithm makes it difficult to meet the demands of high-precision fault localization in the multi-branch distribution network system.In this paper,the multi-branch mainline is decomposed into single branch lines,transforming the complex multi-branch fault location problem into a double-ended fault location problem.Based on the different transmission characteristics of the fault-traveling wave in fault lines and non-fault lines,the endpoint reference time difference matrix S and the fault time difference matrix G were established.The time variation rule of the fault-traveling wave arriving at each endpoint before and after a fault was comprehensively utilized.To realize the fault segment location,the least square method was introduced.It was used to find the first-order fitting relation that satisfies the matching relationship between the corresponding row vector and the first-order function in the two matrices,to realize the fault segment location.Then,the time difference matrix is used to determine the traveling wave velocity,which,combined with the double-ended traveling wave location,enables accurate fault location. 展开更多
关键词 multi-branch lines distribution network fault location double-ended traveling wave positioning least square method
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Multi-branched carbazole derivatives for two-photon absorption and two-photon excited fluorescence 被引量:1
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作者 钱鹰 黄维 +3 位作者 路志锋 孟康 吕昌贵 崔一平 《Journal of Southeast University(English Edition)》 EI CAS 2008年第2期234-237,共4页
Carbazole-core multi-branched chromophores 9-ethyl- 3, 6-bis ( 2- { 4- [ 5- (4-tert-butyl-phenyl) - [ 1, 3, 4 ] oxadiazol-2-yl ] - phenyl }-vinyl) -carbazole(3) and 9-ethyl-3-( 2- {4-[ 5-(4-tert-butyl- phenyl... Carbazole-core multi-branched chromophores 9-ethyl- 3, 6-bis ( 2- { 4- [ 5- (4-tert-butyl-phenyl) - [ 1, 3, 4 ] oxadiazol-2-yl ] - phenyl }-vinyl) -carbazole(3) and 9-ethyl-3-( 2- {4-[ 5-(4-tert-butyl- phenyl) -[ 1, 3, 4 ] oxadiazol-2-yl ] -phenyl }-vinyl ) -carbazole ( 2 ) are synthesized through Wittig reaction and characterized by nuclear magnetic resonance(NMR)and infrared(IR). The two- photon absorption properties of chromophores are investigated. These chromophores exhibit large two-photon absorption crosssections and strong blue two-photon excited fluorescence. The cooperative enhancement of two-photon absorption(TPA) in the multi-branched structures is observed. This enhancement is partly attributed to the electronic coupling between the branches. The electronic push-pull structures in the arm and their cooperative effects help the extended charge transfer for TPA. 展开更多
关键词 two-photon absorption two-photon excited fluorescence multi-branched chromophores carbazole derivatives
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Wireless Interference Classification with Low Complexity Multi-Branch Networks 被引量:1
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作者 Song Ma Yufan Cheng +3 位作者 Ying Mou Pengyu Wang Qihang Peng Jun Wang 《China Communications》 SCIE CSCD 2023年第4期382-394,共13页
In non-cooperative communication systems,wireless interference classification(WIC)is one of the most essential technologies.Recently,deep learning(DL)based WIC methods have been proposed.However,conventional DL-based ... In non-cooperative communication systems,wireless interference classification(WIC)is one of the most essential technologies.Recently,deep learning(DL)based WIC methods have been proposed.However,conventional DL-based WIC methods have high computational complexity and unsatisfactory accuracy,especially when the interference-tonoise ratio(INR)is low.To this end,we propose three effective approaches.Firstly,we introduce multibranch convolutional neural networks(CNNs)for interference recognition.The multi-branch CNN is constructed by repeating a layer that aggregates several transformations with the same topology,and it notably improves the recognition ability for WIC.Our design avoids the carefully crafted selection of each transformation.Unfortunately,multi-branch CNNs are computationally expensive and memory-inefficient.To this end,we further propose Low complexity multibranch networks(LCMN),which are mathematically equivalent to multi-branch CNNs but maintain low computing costs and efficient inference.Thirdly,we present novel loss function,which encourages networks to have consistent prediction probabilities for samples with high visual similarities,resulting in increasing recognition accuracy of LCMN.Experimental results demonstrate the proposed methods consistently boost the classification performance of WIC without substantially increasing computational overhead compared to traditional DL-based methods. 展开更多
关键词 electromagnetic interference wireless interference identification deep learning multi-branch architectures
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Linear and Nonlinear Optical Properties of Novel Multi-branched Oligomers
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作者 Li-jing Gong Ying-hui Wang +3 位作者 Zhi-hui Kang Tian-hao Huang Ran Lu Han-zhuang Zhang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2012年第6期636-641,I0003,共7页
We investigate the fluorene-vinylene unit dependent photo-physical properties of multi- branched truxene based oligomers (Tr-OFVn, n=1-4) employing steady-state absorption and emission spectroscopy, transient absorp... We investigate the fluorene-vinylene unit dependent photo-physical properties of multi- branched truxene based oligomers (Tr-OFVn, n=1-4) employing steady-state absorption and emission spectroscopy, transient absorption spectroscopy, two-photon fluorescence, and z-scan technique. The results show that the increasing of fluorene-vinylene unit leads to a red-shift in the spectra of absorption and fluorescence, and shortens the excited state lifetime. Meanwhile, two-photon fluorescence efficiency and two-photon absorption cross section of truxene based oligolners gradually enhance in company with the extension of π- conjugated length. In addition, the values of two-photon absorption cross section modeled on the sum-over-state approach agree well with the experimental ones. The results indicate multi-branched truxene based oligomers bearing organic materials for two-photon applications. 展开更多
关键词 multi-branch oligomer Two-photo absorption Z-SCAN
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Optical Properties and Response Mechanism Analysis of Multi-branched Fluorescent Probes Based on Intramolecular Charge Transfer
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作者 Yong Zhou Xiao-fei Wang +1 位作者 Chao-hua Tan Chuan-kui Wang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2019年第4期467-473,I0003,共8页
In this work, the optical properties of fluorescent probes used for detection of biothiol were studied by employing time-dependent density functional theory. By calculating the single photon absorption and emission pr... In this work, the optical properties of fluorescent probes used for detection of biothiol were studied by employing time-dependent density functional theory. By calculating the single photon absorption and emission properties of probe Mol.1, Mol.2 and Mol.3 before and after reaction with cysteine and homocysteine, we have investigated the effect of carboncarbon triple bond and benzene ring on the properties of fluorescent probes. It is found that the oscillator strength of probe molecules increases gradually with the improvement of the structure of the electron donor triphenylamine and the addition of carbon-carbon triple bonds, and better properties of fluorescence probes have also been demonstrated. At the same time, the effect of different number of side branches on the molecular properties of the probe was also studied. The results showed that compared with single-branched molecule Z1 and tribranched probe Mol.3, two side probe molecules Z2 had higher oscillator strength and better detection effect. In addition, the new single-branched probe Mol.4 with the addition of carbon-carbon triple bonds and benzene rings has better probe properties and simpler structure than the tribranched probe Mol.3. 展开更多
关键词 Fluorescent probe multi-branched molecule Intramolecular charge transfer
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Multi-Branch Deepfake Detection Algorithm Based on Fine-Grained Features
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作者 Wenkai Qin Tianliang Lu +2 位作者 Lu Zhang Shufan Peng Da Wan 《Computers, Materials & Continua》 SCIE EI 2023年第10期467-490,共24页
With the rapid development of deepfake technology,the authenticity of various types of fake synthetic content is increasing rapidly,which brings potential security threats to people’s daily life and social stability.... With the rapid development of deepfake technology,the authenticity of various types of fake synthetic content is increasing rapidly,which brings potential security threats to people’s daily life and social stability.Currently,most algorithms define deepfake detection as a binary classification problem,i.e.,global features are first extracted using a backbone network and then fed into a binary classifier to discriminate true or false.However,the differences between real and fake samples are often subtle and local,and such global feature-based detection algorithms are not optimal in efficiency and accuracy.To this end,to enhance the extraction of forgery details in deep forgery samples,we propose a multi-branch deepfake detection algorithm based on fine-grained features from the perspective of fine-grained classification.First,to address the critical problem in locating discriminative feature regions in fine-grained classification tasks,we investigate a method for locating multiple different discriminative regions and design a lightweight feature localization module to obtain crucial feature representations by augmenting the most significant parts of the feature map.Second,using information complementation,we introduce a correlation-guided fusion module to enhance the discriminative feature information of different branches.Finally,we use the global attention module in the multi-branch model to improve the cross-dimensional interaction of spatial domain and channel domain information and increase the weights of crucial feature regions and feature channels.We conduct sufficient ablation experiments and comparative experiments.The experimental results show that the algorithm outperforms the detection accuracy and effectiveness on the FaceForensics++and Celeb-DF-v2 datasets compared with the representative detection algorithms in recent years,which can achieve better detection results. 展开更多
关键词 Deepfake detection fine-grained classification multi-branch global attention
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Parameters Optimization of Multi-Branch Horizontal Well Basing on Streamline Simulation 被引量:1
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作者 Hong-Jun Yin Xiao-Qi Chen +1 位作者 Ming Cai Jun-Ting Zhang 《Engineering(科研)》 2010年第12期953-957,共5页
As a highly efficient production method, the technique of multi-branch horizontal well is widely used in low permeability reservoirs, heavy oil reservoirs, shallow layer reservoirs and multi-layer reservoirs, because ... As a highly efficient production method, the technique of multi-branch horizontal well is widely used in low permeability reservoirs, heavy oil reservoirs, shallow layer reservoirs and multi-layer reservoirs, because it can significantly improve the productivity of a single well, inhibit coning and enhance oil recovery. Study on sweep efficiency and parameters optimization of multi-branch horizontal well is at the leading edge of research. Therefore, the study is important for enhancing oil recovery and integral exploitation benefit of oil fields. In many applications, streamline simulation shows particular advantages over finite-difference simulation. With the advantages of streamline simulation such as its ability to display paths of fluid flow and acceleration factor in simulation, the flooding process is more visual. The communication between wells and flooding area has been represented appropriately. This method has been applied to the XS9 reservoir in Daqing Oilfield. The production history of this reservoir is about 10 years. The reservoir is maintained above bubble point so that the simulation meets the slight compressibility assumption. New horizontal wells are drilled following this rule. 展开更多
关键词 STREAMLINE Simulation multi-branch HORIZONTAL WELL Optimization Waterflood SWEEP EFFICIENCY
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Optimization for Hydroforming Loading Paths of Parallel Multi-branch Tubes Based on Grey System Theory
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作者 Kai Zhang Xiao-Ting Xiao +2 位作者 Zhen Chen Hua-Dian Wen Ying Chen 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2013年第4期116-120,共5页
According to characteristic of hydroforming of parallel multi-branch tubes,multi-objective problems were transformed to single objective problem of relational grade comparison by grey system theory.Two different objec... According to characteristic of hydroforming of parallel multi-branch tubes,multi-objective problems were transformed to single objective problem of relational grade comparison by grey system theory.Two different objectives were selected,according to the principle that process parameters were optimal which of grey relational grade were maximum,the optimal loading parameters under different objective condition were obtained,and loading paths were optimized.The results indicated that parallel multi-branch tubes hydroformed under loading paths optimized by grey system theory could meet with the requirement that objective was optimal.And the optimal loading paths under different objectives were different,and the appropriate objective should be selected according to forming characteristic. 展开更多
关键词 relational grade parallel multi-branch tubes HYDROFORMING OPTIMIZATION
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聚硫醇固化剂生产工艺及应用分析 被引量:1
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作者 钱旦 刘时禾 范宏 《中国胶粘剂》 CAS 2023年第3期53-57,69,共6页
聚硫醇常用作环氧树脂低温或室温固化剂以及不饱和树脂紫外光交联剂。本文综述了国内外聚硫醇固化剂主要生产企业的产品结构、性能、应用领域及生产工艺。从市场需求角度分析了这些产品的特性及其在胶粘剂、涂料和油墨等领域中的应用。
关键词 聚硫醇 多硫醇 固化剂 合成工艺
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基于改进YOLOX算法的交通标志检测研究
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作者 王惠吾 洪智勇 +2 位作者 王宪伟 余文华 李泽亮 《五邑大学学报(自然科学版)》 CAS 2023年第3期73-78,共6页
为进一步提升交通标志图像视觉检测算法的性能,本文提出了一种改进的YOLOX_M算法.首先为YOLOX_M构建了新的特征融合网络Multi-branch FPN,该网络通过多分支结构提取模型底层的特征信息,并通过FPN进行特征融合,可进一步提高模型利用特征... 为进一步提升交通标志图像视觉检测算法的性能,本文提出了一种改进的YOLOX_M算法.首先为YOLOX_M构建了新的特征融合网络Multi-branch FPN,该网络通过多分支结构提取模型底层的特征信息,并通过FPN进行特征融合,可进一步提高模型利用特征的能力.其次,在YOLOX_M检测头引入的Alpha-GIoU损失函数,可以更好地应用于带噪声的边界框,提高边界框的回归精度.实验表明,改进后的YOLOX_M模型在数据集TT100K上的mAP提高了1.8%,具备较好的检测性能.本文研究结果对交通标志检测具有一定的参考价值. 展开更多
关键词 交通标志检测 特征融合 YOLOX multi-branch FPN Alpha-GIoU
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环氧树脂/三乙硫醇胺固化反应行为的研究 被引量:27
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作者 崔占臣 吕长利 +3 位作者 杨柏 苏小平 杨海 霍承松 《高分子学报》 SCIE CAS CSCD 北大核心 2002年第2期149-152,共4页
用差热式扫描量热仪 (DSC)对双酚 A环氧 (DGEBA) 三乙硫醇胺自催化固化体系的固化反应过程进行分析 ,并根据Kissinger和Ozawa方法分别求得体系固化反应的表观活化能ΔE为 4 1.35和 4 6 .6kJ mol;根据Crane等理论计算得到该体系的固化... 用差热式扫描量热仪 (DSC)对双酚 A环氧 (DGEBA) 三乙硫醇胺自催化固化体系的固化反应过程进行分析 ,并根据Kissinger和Ozawa方法分别求得体系固化反应的表观活化能ΔE为 4 1.35和 4 6 .6kJ mol;根据Crane等理论计算得到该体系的固化反应级数n =0 .84及指前因子A =7.4 3× 10 3(s- 1 ) ;同时利用FTIR在位跟踪固化反应过程特征官能团吸收峰的变化 ,确定了最佳固化反应工艺条件 :T凝胶 =80℃ ,T固化 =12 0℃ ,T后处理 =16 展开更多
关键词 环氧树脂 含氮多硫醇 自催化 固化动力学 三乙硫醇胺
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多支化聚硫醇与环氧树脂的固化研究 被引量:14
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作者 胡张燕 吴通宇 +1 位作者 李朝龙 王跃川 《塑料》 CAS CSCD 北大核心 2009年第2期48-50,共3页
环氧树脂的应用开发和性能提高依赖于新型固化剂的开发。以2,2’-二巯基乙硫醚(MES)与三羟甲基丙烷三丙烯酸酯(TMPTA)为原料,通过逐步聚合反应制备了具有多支化结构的聚硫醇,并研究了其与环氧树脂的室温固化过程。用核磁共振谱(1H NMR)... 环氧树脂的应用开发和性能提高依赖于新型固化剂的开发。以2,2’-二巯基乙硫醚(MES)与三羟甲基丙烷三丙烯酸酯(TMPTA)为原料,通过逐步聚合反应制备了具有多支化结构的聚硫醇,并研究了其与环氧树脂的室温固化过程。用核磁共振谱(1H NMR)和凝胶渗透色谱(GPC)测定了聚硫醇的巯基值、支化度和分子量;采用实时红外(RT-IR)跟踪研究了聚硫醇/环氧树脂的固化过程,热失重分析(TGA)表征了固化产物的热稳定性。结果表明:该固化体系与传统胺类室温固化体系相比,前固化速度明显提高,80min时巯基和环氧基的转化率可分别达到48%和36%,且热稳定性略有提高,起始分解温度为322℃。 展开更多
关键词 环氧树脂 多支化聚硫醇 室温固化 实时红外 合成
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环氧/多巯基型无色透明胶粘剂的研制 被引量:8
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作者 虞鑫海 王珂 +1 位作者 陈吉伟 刘万章 《粘接》 CAS 2014年第1期36-39,共4页
采用自制多巯基固化剂与E-51环氧树脂制备了一种环氧/多巯基型无色透明胶粘剂,对其拉伸剪切强度、黏度、紫外-可见光透过率等性能进行了研究,并在相同条件下与使用进口固化剂的胶粘剂性能进行了对比。结果表明,随着固化温度升高,2种胶... 采用自制多巯基固化剂与E-51环氧树脂制备了一种环氧/多巯基型无色透明胶粘剂,对其拉伸剪切强度、黏度、紫外-可见光透过率等性能进行了研究,并在相同条件下与使用进口固化剂的胶粘剂性能进行了对比。结果表明,随着固化温度升高,2种胶粘剂拉伸剪切强度均不断提高,在固化温度达到110℃时拉伸剪切强度均达到最大,随后开始下降。随温度升高,2种胶粘剂黏度均不断下降。紫外-可见光透过率的测试表明,固化温度对进口胶粘剂的透明度影响很大,80℃透过率就明显下降。固化温度在80℃内,自制胶粘剂的紫外-可见光透过率变化不大。在此环氧体系中,使用自制固化剂的胶粘剂在耐温性方面具有一定优势。 展开更多
关键词 多巯基环氧胶粘剂 拉伸剪切强度 紫外一可见光透过率
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基于2,3-双〔(2-巯乙基)硫基〕-1-丙硫醇和1,3-双(异氰酸根合甲基)环己烷的聚硫氨酯光学树脂的制备 被引量:3
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作者 张幼维 +3 位作者 陈瑜爽 蒋鑫 石荣喜 任嘉玮 《玻璃搪瓷与眼镜》 CAS 2021年第1期1-5,12,共6页
以2,3-双〔(2-巯乙基)硫基〕-1-丙硫醇(BMETP)和1,3-双(异氰酸根合甲基)环己烷(BIMC)为原料,制备了聚硫氨酯光学树脂。联合采用差示扫描量热法和红外光谱法,对制备BMETP-BIMC树脂的催化剂配方和固化条件进行了优化。研究结果表明BMETP-B... 以2,3-双〔(2-巯乙基)硫基〕-1-丙硫醇(BMETP)和1,3-双(异氰酸根合甲基)环己烷(BIMC)为原料,制备了聚硫氨酯光学树脂。联合采用差示扫描量热法和红外光谱法,对制备BMETP-BIMC树脂的催化剂配方和固化条件进行了优化。研究结果表明BMETP-BIMC树脂具有很好的热稳定性(T 5%=279℃),较好的透光性(T=87%),较高的折光指数(1.617)和阿贝数(38),满足树脂镜片的要求。 展开更多
关键词 多元硫醇 异氰酸酯 光学树脂 高折光指数
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不饱和环缩醛/多硫醇体系的光交联
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作者 李妙贞 聂俊 +1 位作者 李力 王尔鉴 《感光科学与光化学》 CSCD 1991年第2期112-119,共8页
本文研究了3,9-二丙烯基-2,4,8,10-四氧螺[5,5]十三烷(DPTST)和四巯基醋酸季戊四醇酯(PTMA)以苯乙酮衍生物、安息香醚和芳酮作光引发剂时的光交联。通过测定双键在1680cm^(-1)和巯基在2570cm^(-1)处的红外吸收随光照时间的变化以及凝胶... 本文研究了3,9-二丙烯基-2,4,8,10-四氧螺[5,5]十三烷(DPTST)和四巯基醋酸季戊四醇酯(PTMA)以苯乙酮衍生物、安息香醚和芳酮作光引发剂时的光交联。通过测定双键在1680cm^(-1)和巯基在2570cm^(-1)处的红外吸收随光照时间的变化以及凝胶转化率和硬度随光照时间的变化来表征光交联动力学。 光交联速度与组分配比、光引发剂性质及含量有明显关系。以苯乙酮衍生物和α,α-二甲氧基-α-苯基苯乙酮为光引发剂、DPTST/PTMA的摩尔比为2:1到3:1时,得到较好的实验结果。 展开更多
关键词 光化学交联 多烯 多硫醇系
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高折射率透明聚氨酯弹性体的制备及性能研究 被引量:4
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作者 叶耘峰 李乐 +1 位作者 唐果东 李康 《聚氨酯工业》 北大核心 2018年第6期9-11,共3页
以聚氧化丙烯二醇、异佛尔酮二异氰酸酯、自制2,3-双(2-巯基乙硫基)-1-丙硫醇(硫代三硫醇,简称M)、1,4-丁二醇等为原料,制备了透明聚氨酯弹性体。考察了硫代三硫醇M用量对透明聚氨酯弹性体的透光率、折射率、热稳定性及外观等性能的影... 以聚氧化丙烯二醇、异佛尔酮二异氰酸酯、自制2,3-双(2-巯基乙硫基)-1-丙硫醇(硫代三硫醇,简称M)、1,4-丁二醇等为原料,制备了透明聚氨酯弹性体。考察了硫代三硫醇M用量对透明聚氨酯弹性体的透光率、折射率、热稳定性及外观等性能的影响。结果表明,添加M后聚氨酯的透光率和折射率有了大幅提高,当M的添加质量分数为1. 90%时,透光率最高可达98. 58%,M的质量分数为4. 76%时,折射率达到1. 660。制备的聚氨酯样品热稳定性较好,具有良好的硬度和抗冲击性。 展开更多
关键词 透明聚氨酯材料 聚氨酯弹性体 高折射率 多元硫醇
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聚硫醇固化剂的制备与研究进展 被引量:2
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作者 刘明哲 冯望成 +4 位作者 敬波 李超 邹翠 邹晓轩 戴文利 《粘接》 CAS 2017年第11期57-59,共3页
介绍了几种聚硫醇的制备方法;综述了国内聚硫醇固化剂的制备研究进展,并对其发展前景进行了分析和展望。
关键词 聚硫醇 环氧树脂 快速 固化剂 制备
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硫醇固化剂的合成和应用 被引量:14
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作者 康富春 张宏伟 《热固性树脂》 CAS CSCD 2006年第3期15-16,19,共3页
硫醇固化剂与环氧树脂的配合物可低温快速固化,广泛应用于胶粘剂领域,目前尚依赖进口。为促进硫醇固化剂的国产化,对硫醇固化剂的制备方法和应用进行了研究。实验表明,选用β-巯基丙酸与季戊四醇在酸性催化剂存在下酯化,然后再与环氧树... 硫醇固化剂与环氧树脂的配合物可低温快速固化,广泛应用于胶粘剂领域,目前尚依赖进口。为促进硫醇固化剂的国产化,对硫醇固化剂的制备方法和应用进行了研究。实验表明,选用β-巯基丙酸与季戊四醇在酸性催化剂存在下酯化,然后再与环氧树脂进行扩链反应,可以制得黏度和使用配比均适用的硫醇固化剂,总产率为95%以上。用此固化剂与环氧树脂及叔胺混合后,能在5℃以下数分钟内固化。该合成方法工艺简单,易于控制,制得的硫醇固化剂黏度适中,与环氧树脂相溶性好,低温固化快,固化物无色透明等超过了进口产品。 展开更多
关键词 硫醇固化剂 合成 扩链 环氧树脂
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