It is urgent to develop low-reflection electromagnetic interference shielding material to shield electromagnetic waves(EMW)and reduce their secondary radiation pollution.Herein,an electromagnetic interference shieldin...It is urgent to develop low-reflection electromagnetic interference shielding material to shield electromagnetic waves(EMW)and reduce their secondary radiation pollution.Herein,an electromagnetic interference shielding nanofiber film is composed of ZnO and carbon nanofiber(CNF)via electrospinning and carbonization approachs,and subsequently coating perfuorooctyltriethoxysilane as a protective layer.On the one hand,ZnO coated by porous carbon,which is derived from ZIF-8,endows the nanofiber film low reflection property through optimizing impedance matching between free space and the nanofiber film.On the other hand,the nanofiber film possesses high electromagnetic interference shielding efficiency,which is beneficial by excellent electrical conductivity of CNF derived from waste leather scraps.Furthermore,the nanofiber film involves abundant interface,which contributes to high interfacial polarization loss.Thus,the nanofiber film with a thickness of 250 pm has electrical conductivity of 53 S/m and shielding efficiency of 50 dB.The reflection coefficient of the nanofiber film is inferior to 0.4 indicates that most of EMW are absorbed inside the materials and the nanofiber film is effective in reducing secondary radiation contamination of electromagnetic waves.Fortunately,the nanofiber film exhibits outstanding solar harvesting performance(106℃at 1 sun density)and good self-cleaning performance,which ensure that the nanofiber film can work in harsh environments.This work supplies a credible reference for fabricating low-reflection electromagnetic shielding nanofiber film to reduce secondary radiation pollution and facilitates the upcycling of waste leather scraps.展开更多
A zwitterionic nanofiber film was constructed through combining zwitterionic polymer with anodic aluminum oxide template for anti-adhering typical marine corrosive microorganisms,i.e.Pseudomonas aeruginosa,Desulfovibr...A zwitterionic nanofiber film was constructed through combining zwitterionic polymer with anodic aluminum oxide template for anti-adhering typical marine corrosive microorganisms,i.e.Pseudomonas aeruginosa,Desulfovibrio vulgaris and Chaetoceros muelleri.Results showed that the fabricated zwitterionic polymers film has fibrous nanostructure with uniform distribution and super hydrophilia.This film has wide anti-adhering properties,and it can effectively reduce the attachment of these three microorganisms by more than 99%.Moreover,the adhesion of extracellular polymeric substances secreted from these three microorganisms are also inhibited,which is one reason for the fabricated nanofiber film with antiadhesion characteristic of microorganisms.This research provides valuable information for solving the problem of microbial adhesion on metal surfaces in the marine environment.展开更多
Na superionic conductor(NASICON)-type La_(0.33)Ti_(2)(PO_(4))_(3)(LaTP) is firstly proposed as sodium/potassium storage materials.The density functional theory(DFT) calculations show that LaTP has good electronic char...Na superionic conductor(NASICON)-type La_(0.33)Ti_(2)(PO_(4))_(3)(LaTP) is firstly proposed as sodium/potassium storage materials.The density functional theory(DFT) calculations show that LaTP has good electronic character and low Na^(+)/K^(+)migration barriers.The flexible La_(0.33)Ti_(2)(PO_(4))_(3)/C nanofiber film is synthesized via electrostatic spinning and investigated as free-standing electrode applied to sodium-ion batteries(SIBs) and potassiumion batteries(PIBs) in this work.The low band gap and Na^(+)/K^(+) migration barriers of LaTP,unique morphology,and complete conductive carbon net allow the La_(0.33)Ti_(2)(PO_(4))_(3)/C nanofibers film to deliver high capacity(296.3 mAh·g^(-1) for SIBs and 235.8 mAh·g^(-1) for PIBs),excellent rate performance(142.5 mAh·g^(-1) for SIBs and50.5 mAh·g^(-1) for PIBs at 1.00 A·g^(-1)),and superior cyclability above 1000 cycles.The full-cell tests show that the material has a good application prospect,indicating a promising flexible anode material for SIBs and PIBs.展开更多
A facile synthesis of the hierarchically porous cathode with Mo2C nanoparticles through the electrospinning technique and heat treatment is proposed. The carbonization temperature of the precursors is the key factor f...A facile synthesis of the hierarchically porous cathode with Mo2C nanoparticles through the electrospinning technique and heat treatment is proposed. The carbonization temperature of the precursors is the key factor for the formation of M02C nanoparticles on the carbon nanofibers （MCNFs）. Compared with the Mo2N nanoparticles embedded into N-doped carbon nanofibers film （MNNFs） and N-doped carbon nanofibers film （NFs）, the battery with MCNFs cathode is capable of operation with a high-capacity （10,509 mAhg-1 at 100 mAg-l）, a much reduced discharge-charge voltage gap, and a long-term life （124 cycles at 200 mA g-1 with a specific capacity limit of 500 mAh g -1）. These excellent performances are derived from the synergy of the following advantageous factors： （1） the hierarchically self-standing and binder-free structure of MCNFs could ensure the high diffusion flux of Li＋ and O2 as well as avoid clogging of the discharge product, bulk Li202; （2） the well dispersed M02C nanoparticles not only afford rich active sites, but also facilitate the electronic transfer for catalysis.展开更多
基金funded by the Shaanxi Provincial“Special Support Plan for High-level Talents”the Key Project of Natural Science Basic Research Program of Shaanxi Province(Special Support)(Program No.2023JC-XJ-12)the Innovation Capability Support Program of Shaanxi(Program No.2021TD-16).
文摘It is urgent to develop low-reflection electromagnetic interference shielding material to shield electromagnetic waves(EMW)and reduce their secondary radiation pollution.Herein,an electromagnetic interference shielding nanofiber film is composed of ZnO and carbon nanofiber(CNF)via electrospinning and carbonization approachs,and subsequently coating perfuorooctyltriethoxysilane as a protective layer.On the one hand,ZnO coated by porous carbon,which is derived from ZIF-8,endows the nanofiber film low reflection property through optimizing impedance matching between free space and the nanofiber film.On the other hand,the nanofiber film possesses high electromagnetic interference shielding efficiency,which is beneficial by excellent electrical conductivity of CNF derived from waste leather scraps.Furthermore,the nanofiber film involves abundant interface,which contributes to high interfacial polarization loss.Thus,the nanofiber film with a thickness of 250 pm has electrical conductivity of 53 S/m and shielding efficiency of 50 dB.The reflection coefficient of the nanofiber film is inferior to 0.4 indicates that most of EMW are absorbed inside the materials and the nanofiber film is effective in reducing secondary radiation contamination of electromagnetic waves.Fortunately,the nanofiber film exhibits outstanding solar harvesting performance(106℃at 1 sun density)and good self-cleaning performance,which ensure that the nanofiber film can work in harsh environments.This work supplies a credible reference for fabricating low-reflection electromagnetic shielding nanofiber film to reduce secondary radiation pollution and facilitates the upcycling of waste leather scraps.
基金financially supported by the National Natural Science Foundation of China(No.41906039)the Key Research and Development Program of Shandong Province(No.2019JZZY010333)the Shandong University Future Plan for Young Scholars and Fundamental Research Funds of Shandong University。
文摘A zwitterionic nanofiber film was constructed through combining zwitterionic polymer with anodic aluminum oxide template for anti-adhering typical marine corrosive microorganisms,i.e.Pseudomonas aeruginosa,Desulfovibrio vulgaris and Chaetoceros muelleri.Results showed that the fabricated zwitterionic polymers film has fibrous nanostructure with uniform distribution and super hydrophilia.This film has wide anti-adhering properties,and it can effectively reduce the attachment of these three microorganisms by more than 99%.Moreover,the adhesion of extracellular polymeric substances secreted from these three microorganisms are also inhibited,which is one reason for the fabricated nanofiber film with antiadhesion characteristic of microorganisms.This research provides valuable information for solving the problem of microbial adhesion on metal surfaces in the marine environment.
基金financially supported by the National Natural Science Foundation of China (No. 52072325)the Key Research Foundation of Education Bureau of Hunan Province, China (No. 20A486)+2 种基金Hunan 2011 Collaborative Innovation Center of Chemical Engineering and Technology with Environmental Benignity and Effective Resource Utilization, Program for Innovative Research Cultivation Team in University of Ministry of Education of China (No. 1337304)the 111 Project (No. B12015)the Natural Science Foundation of Shandong Province (No. ZR2020MB045)。
文摘Na superionic conductor(NASICON)-type La_(0.33)Ti_(2)(PO_(4))_(3)(LaTP) is firstly proposed as sodium/potassium storage materials.The density functional theory(DFT) calculations show that LaTP has good electronic character and low Na^(+)/K^(+)migration barriers.The flexible La_(0.33)Ti_(2)(PO_(4))_(3)/C nanofiber film is synthesized via electrostatic spinning and investigated as free-standing electrode applied to sodium-ion batteries(SIBs) and potassiumion batteries(PIBs) in this work.The low band gap and Na^(+)/K^(+) migration barriers of LaTP,unique morphology,and complete conductive carbon net allow the La_(0.33)Ti_(2)(PO_(4))_(3)/C nanofibers film to deliver high capacity(296.3 mAh·g^(-1) for SIBs and 235.8 mAh·g^(-1) for PIBs),excellent rate performance(142.5 mAh·g^(-1) for SIBs and50.5 mAh·g^(-1) for PIBs at 1.00 A·g^(-1)),and superior cyclability above 1000 cycles.The full-cell tests show that the material has a good application prospect,indicating a promising flexible anode material for SIBs and PIBs.
基金supported by the National Key Research and Development Program of China(2017YFA0206704 and 2016YFB0100103)the National Basic Research Program of China(2014CB932300)+3 种基金Strategic Priority Research Program of the Chinese Academy of Sciences(XDA09010404)Technology and Industry for National Defence of China(JCKY2016130B010)the National Natural Science Foundation of China(51771177,21422108,51472209,and 51472232)Jilin Province Science and Technology Development Program(20160101289JC)
文摘A facile synthesis of the hierarchically porous cathode with Mo2C nanoparticles through the electrospinning technique and heat treatment is proposed. The carbonization temperature of the precursors is the key factor for the formation of M02C nanoparticles on the carbon nanofibers （MCNFs）. Compared with the Mo2N nanoparticles embedded into N-doped carbon nanofibers film （MNNFs） and N-doped carbon nanofibers film （NFs）, the battery with MCNFs cathode is capable of operation with a high-capacity （10,509 mAhg-1 at 100 mAg-l）, a much reduced discharge-charge voltage gap, and a long-term life （124 cycles at 200 mA g-1 with a specific capacity limit of 500 mAh g -1）. These excellent performances are derived from the synergy of the following advantageous factors： （1） the hierarchically self-standing and binder-free structure of MCNFs could ensure the high diffusion flux of Li＋ and O2 as well as avoid clogging of the discharge product, bulk Li202; （2） the well dispersed M02C nanoparticles not only afford rich active sites, but also facilitate the electronic transfer for catalysis.
