Correlation between the absolute configuration and the CD spectra of organic peroxides was studied by ab initio method with a mo- d el moleeule CH_3-O-O-CH_3.For P form when 0°≤θ(twist angle of C-O-O-C) <90&...Correlation between the absolute configuration and the CD spectra of organic peroxides was studied by ab initio method with a mo- d el moleeule CH_3-O-O-CH_3.For P form when 0°≤θ(twist angle of C-O-O-C) <90°, there is positive Cotton effect;when 90°<θ≤180°, there is nega- tive Cotton effect;the curve is bisignate at θ=90°.展开更多
文摘Correlation between the absolute configuration and the CD spectra of organic peroxides was studied by ab initio method with a mo- d el moleeule CH_3-O-O-CH_3.For P form when 0°≤θ(twist angle of C-O-O-C) <90°, there is positive Cotton effect;when 90°<θ≤180°, there is nega- tive Cotton effect;the curve is bisignate at θ=90°.
