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Synergism of Zinc Oxide/Organoclay-Loaded Poly(lactic acid) Hybrid Nanocomposite Plasticized by Triacetin for Sustainable Active Food Packaging
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作者 Ponusa Songtipya Thummanoon Prodpran +1 位作者 Ladawan Songtipya Theerarat Sengsuk 《Journal of Renewable Materials》 EI CAS 2024年第5期951-967,共17页
The synergistic effect of organoclay(OC)and zinc oxide(ZnO)nanoparticles on the crucial properties of poly(lactic acid)(PLA)nanocompositefilms was systematically investigated herein.After their incorporation into PLA v... The synergistic effect of organoclay(OC)and zinc oxide(ZnO)nanoparticles on the crucial properties of poly(lactic acid)(PLA)nanocompositefilms was systematically investigated herein.After their incorporation into PLA via the solvent casting technique,the water vapor barrier property of the PLA/OC/ZnOfilm improved by a maximum of 86%compared to the neat PLAfilm without the deterioration of Young’s modulus or the tensile strength.Moreover,thefilm’s self-antibacterial activity against foodborne pathogens,including gram-negative(Escherichia coli,E.coli)and gram-positive(Staphylococcus aureus,S.aureus)bacteria,was enhanced by a max-imum of approximately 98–99%compared to the neat PLAfilm.Furthermore,SEM images revealed the homo-geneous dispersion of both nano-fillers in the PLA matrix.However,the thermal stability of thefilm decreased slightly after the addition of the OC and ZnO.Thefilm exhibited notable light barrier properties in the UV-Vis range.Moreover,the incorporation of a suitable biodegradable plasticizer significantly decreased the Tg and notably enhanced theflexibility of the nanocompositefilm by increasing the elongation at break approxi-mately 1.5-fold compared to that of the neat PLAfilm.This contributes to its feasibility as an active food packa-ging material. 展开更多
关键词 Poly(lactic acid)nanocomposite organoclay zinc oxide barrier property antibacterial activity active food packaging
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有机层状硅酸盐改善油基钻井液沉降稳定性室内评价
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作者 赵景原 窦旭斌 +1 位作者 冯福平 蔡明会 《当代化工》 CAS 2024年第2期396-400,共5页
基于油基钻井液有机土有机改性剂阳离子受高温易分解脱附,引起钻井液性能变差、加重材料沉降等问题,利用六水合氯化镁和十六烷基三甲氧基硅烷等为原料,合成了一种适用于柴油基钻井液体系的有机土(有机层状硅酸盐),用于改善油基钻井液的... 基于油基钻井液有机土有机改性剂阳离子受高温易分解脱附,引起钻井液性能变差、加重材料沉降等问题,利用六水合氯化镁和十六烷基三甲氧基硅烷等为原料,合成了一种适用于柴油基钻井液体系的有机土(有机层状硅酸盐),用于改善油基钻井液的沉降稳定性;通过傅里叶红外光谱、X-射线衍射以及室内钻井液沉降实验进行结构表征和沉降稳定性评价。结果表明:该有机硅酸盐材料具备2∶1层状硅酸盐结构和以Si—C共价键连接的不对称链状有机官能团结构,且300℃无明显热分解;相比于大庆油田常用油基钻井液,该有机层状硅酸盐提高了油基钻井液的动切力、动塑比和储能模量,明显改善了1.4~2.0 g·cm^(-3)密度范围、150℃以下老化温度油基钻井液的悬浮性能和沉降稳定性能。 展开更多
关键词 有机层状硅酸盐 沉降稳定性 有机土 油基钻井液
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“Cutting effect” of organoclay platelets in compatibilizing immiscible polypropylene/polystyrene blends 被引量:3
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作者 Yan ZHU Hai-yun MA +1 位作者 Li-fang TONG Zheng-ping FANG 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2008年第11期1614-1620,共7页
In this work, polypropylene (PP)/polystyrene (PS) blends with different organoclay concentrations were prepared via melt compounding. Differing from the results of previous reports, the organoclay platelets are mostly... In this work, polypropylene (PP)/polystyrene (PS) blends with different organoclay concentrations were prepared via melt compounding. Differing from the results of previous reports, the organoclay platelets are mostly located in the dispersed PS phase instead of the interface. The dimensions of the dispersed PS droplets are greatly reduced and apparent compatibilization effect still exists, which cannot be explained by the traditional compatibilization mechanism. A novel compatibilization mecha- nism, "cutting" to apparently compatibilize the immiscible PP/PS blends was proposed. The organoclay platelets tend to form a special "knife-like structure" in the PS domain under the shear stress of the continuous PP phase during compounding. The "clay knife" can split the dispersed PS domain apart and lead to the dramatic reduction of the dispersed domain size. 展开更多
关键词 COMPATIBILIZATION organoclay Polymer blends Polypropylene (PP) Polystyrene (PS)
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Adsorption of phenthoate and acetochlor from water by clays and organoclays
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作者 LIAOMin XIEXiao-mei 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2004年第5期738-741,共4页
Adsorption of phenthoate and acetochlor onto kaolin, montmorillonite, bentonite clays and respective organoclays prepared by the exchange of quaternary ammonium as tetradecyltrimethyl ammonium bromide(TTAB), dodecyltr... Adsorption of phenthoate and acetochlor onto kaolin, montmorillonite, bentonite clays and respective organoclays prepared by the exchange of quaternary ammonium as tetradecyltrimethyl ammonium bromide(TTAB), dodecyltrimethylammonium bromide(DTAB), and cetylpyridinium chloride(CPC) were studied. The adsorption equilibrium data points were fitted to Freundlich isotherm equations. The adsorption of phenthoate and acetochlor were significantly enhanced by surfactant treatment of the clays. The amount of both pesticides adsorbed per unit mass of organoclay followed the order of TTA-kaolin < TTA-montmorillonite < TTA-bentonite, which is inconsistent with the organic carbon content of the clays. The removal efficiency of organomontmorillonite to treat acetochlor is in the order of CP(C 16 )-montmorillonite > TTA(C 14 )-montmorillonite > DTA(C 12 )-montmorillonite. Phenthoate is adsorbed to greater extent than acetochlor by each adsorbent, which may be due to the higher hydrophobicity of phenthoate, indicating considerable hydrophobic interaction between adsorbent/adsorbate systems. 展开更多
关键词 ADSORPTION clays organoclayS PHENTHOATE ACETOCHLOR
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Facile Method for the Synthesis of Copper Nanoparticles Supported on the Organoclay Material
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作者 Mokae Fanuel Bambo Rui Werner Marcedo Krause Richard Motlhaletsi Moutloali 《Journal of Biomaterials and Nanobiotechnology》 2017年第2期144-158,共15页
In this study, synthesis of copper nanoparticles was performed using organoclay as a support to stabilize the nanoparticles. Organoclay amount was gradually increased, which had an effect on the morphology of the resu... In this study, synthesis of copper nanoparticles was performed using organoclay as a support to stabilize the nanoparticles. Organoclay amount was gradually increased, which had an effect on the morphology of the resultant nanoparticles. Low amount of organoclay added resulted in larger and agglomerated copper nanoparticles whereas increased amount of organoclay gave smaller sized nanoparticles. The hybrid materials were characterized using the SEM and TEM for morphology, XRD and FT-IR spectroscopy for structural elucidation, thermal analysis using TGA and also studying their antibacterial effect on the two well-known gram negative bacteria of E. coli and P. Aeruginosa. The synthesized nanoparticles were found to be crystalline Cu nanoparticles with a mix of CuO. Larger sized copper nanoparticles and agglomerates showed the higher thermal behaviour as compared with smaller nanoparticles with higher organoclay loading. The hybrid showed an improved antibacterial activity as compared with organoclay alone. The hybrid showed the higher antibacterial effect against the P. aeruginosa microorganism as compared with the E. coli microorganism. 展开更多
关键词 organoclay COPPER NANOPARTICLES Hybrid MICROORGANISMS
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Synthesis and Characterization of Trithiocarbonate-Organoclays Nanohybrids and Their Interaction with MCF-7 Cancer Cells
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作者 Ulviye Bunyatova Zakir Rzayev +1 位作者 Mustath Turk Abdullah Emur Soylemez 《Journal of Chemistry and Chemical Engineering》 2014年第11期1068-1081,共14页
This work presents a new approach for the fabrication of organic/inorganic nanohybrids as anticancer drugs by an intercalation method using S,S-bis(α,α′-dimethyl-α″-acetic acid) (trithiocarbonate) as a modifi... This work presents a new approach for the fabrication of organic/inorganic nanohybrids as anticancer drugs by an intercalation method using S,S-bis(α,α′-dimethyl-α″-acetic acid) (trithiocarbonate) as a modifier and two organoclays, such as reactive octadecylamine/MMT (montmorillonite) and non-reactive dimethyldidodecyl ammonium/MMT. The chemical and physical structures and the surface morphology of these covalently and non-covalently linked nanohybrids were investigated by FT-IR (Fourier translbrm infrared) spectroscopy, ^13C and ^29Si solid state NMR (nuclear magnetic resonance) spectroscopy, XRD (X-ray powder diffraction) and SEM (scanning electron microscopy) analyses, respectively. To evaluate the anticancer activities of the novel BATC/organoclay hybrids against MCF-7 breast cancer cells, a combination of different biochemical and biophysical testing techniques were used. Cell proliferation and cytotoxicity were detected in vitro using a real-time analysis. Cell death was confirmed by using apoptotic and necrotic analyses, the effects of which were detennined by the double staining and Annexin-V-FLUOS testing method. The results demonstrate that intercalated hybrid complexes containing a combination of various anticancer sites, such as free and complexed carboxyl, trithiocarbonate, amine and ammonium cations significantly induced cell death in breast cancer via their interactions with the DNA macromolecules of cancer cells by destroying the self-assemb|ed structure of growing cells. Fabricated hybrid complexes may represent a new generation of effective and selective anticancer drug systems with a synthetic/natural origin for cancer chemotherapy. 展开更多
关键词 Synthesis. intercalating TRITHIOCARBONATE organoclayS NANOHYBRIDS MCF-7 breast cancer cells real-time cytotoxicity apoptosis necrosis.
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Effect of Cosolvent in a Nucleophilic Substitution Reaction Using Organoclay in Triphase Catalytic System
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作者 Nahid Shabestary Cynthia M. Chapple +4 位作者 Derek T. Rensing Thao T. Doan Sadegh Khazaeli Michael J. Sabo Andrew D. Beach 《Modern Research in Catalysis》 2015年第3期78-85,共8页
A remarkable rate enhancement technique has been devised for a typical nucleophilic displacement reaction by using triphase catalytic materials based on tetraoctylammonium exchange forms of hectorite clay. Pseudo-firs... A remarkable rate enhancement technique has been devised for a typical nucleophilic displacement reaction by using triphase catalytic materials based on tetraoctylammonium exchange forms of hectorite clay. Pseudo-first order rate constants (kobs) for the conversion of 1-bromobutane to the corresponding chloride under triphase conditions using the clay catalyst in the presence of various polar cosolvents have been observed. The results here have shown that the addition of a cosolvent increases the catalytic activity of the triphase system by several fold. In addition, the results have demonstrated that each cosolvent has a unique concentration for achieving an optimum reaction rate. 展开更多
关键词 Triphase CATALYSIS COSOLVENT organoclay NUCLEOPHILIC DISPLACEMENT Reaction
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Development of key additives for organoclay-free oil-based drilling mud and system performance evaluation 被引量:1
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作者 SUN Jinsheng HUANG Xianbin +3 位作者 JIANG Guancheng LYU Kaihe LIU Jingping DAI Zhiwen 《Petroleum Exploration and Development》 2018年第4期764-769,共6页
Traditional oil-based drilling muds(OBMs) have a relatively high solid content, which is detrimental to penetration rate increase and reservoir protection. Aimed at solving this problem, an organoclay-free OBM system ... Traditional oil-based drilling muds(OBMs) have a relatively high solid content, which is detrimental to penetration rate increase and reservoir protection. Aimed at solving this problem, an organoclay-free OBM system was studied, the synthesis methods and functioning mechanism of key additives were introduced, and performance evaluation of the system was performed. The rheology modifier was prepared by reacting a dimer fatty acid with diethanolamine, the primary emulsifier was made by oxidation and addition reaction of fatty acids, the secondary emulsifier was made by amidation of a fatty acid, and finally the fluid loss additive of water-soluble acrylic resin was synthesized by introducing acrylic acid into styrene/butyl acrylate polymerization. The rheology modifier could enhance the attraction between droplets, particles in the emulsion via intermolecular hydrogen bonding and improve the shear stress by forming a three-dimensional network structure in the emulsion. Lab experimental results show that the organoclay-free OBM could tolerate temperatures up to 220 ?C and HTHP filtration is less than 5 m L. Compared with the traditional OBMs, the organoclay-free OBM has low plastic viscosity, high shear stress, high ratio of dynamic shear force to plastic viscosity and high permeability recovery, which are beneficial to penetration rate increase, hole cleaning and reservoir protection. 展开更多
关键词 organoclay-free OIL-BASED drilling MUD rheology MODIFIER EMULSIFIER fluid loss REDUCER weak gel reservoir protection
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The Effect of Stearic Acid on Expanded Organoclay and Rheometric Properties of Natural Rubber/Expanded Organoclay Nanocomposites
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作者 Mohamad Irfan Fathurrohman Bambang Soegijono Emil Budianto 《材料科学与工程(中英文B版)》 2013年第9期575-581,共7页
关键词 纳米复合材料 有机粘土 流变性能 天然橡胶 硬脂酸 膨胀 场发射扫描电子显微镜 NR胶料
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Characterization of the Natural and Organomodified Clay Soil of Moukosso (Republic of Congo) by Dimethylsulfoxide: Application to the Adsorption of Lead (II) in Aqueous Solution
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作者 Ottard Arnaud M. R. Ossiby Mwa Ngo Ferland Ngoro-Elenga +3 位作者 Erman E. Nzaba Madila Zita F. Diamouangana Mpissi Exaucé R. Kinzonzi Ngongot Joseph Marie Moutou 《Materials Sciences and Applications》 CAS 2023年第2期63-77,共15页
In this study, the authors characterized the raw clayey soil of Moukosso and modified by dimethylsulfoxide (DMSO) by several analytical methods, namely: X-ray diffraction (XRD), Fourier transform infrared (FTIR) and g... In this study, the authors characterized the raw clayey soil of Moukosso and modified by dimethylsulfoxide (DMSO) by several analytical methods, namely: X-ray diffraction (XRD), Fourier transform infrared (FTIR) and gravimetric thermal analysis (TGA). The cation exchange capacity (CEC) was also determined. Mineralogical analysis by XRD revealed the presence of muscovite (29.7%), kaolinite (8.9%), anatase (2.4%) and quartz (58.9%). The characterization of the organo-clay by infrared and by thermogravimetric analysis confirmed the intercalation of DMSO by the presence of vibration bands at 1008 cm<sup>-1</sup> and 1070 cm<sup>-1</sup> and a strong increase in the loss of mass. The cation exchange capacity of the raw material is 7.4 meq/100g. Rapid adsorption of Pb<sup>2+</sup> ions was observed between 5 and 15 minutes of stirring time in both cases (raw clay and organomodified clay). The modeling of the isotherms by the models of Langmuir and Freudlich showed that these are of type S with a maximum amount of adsorption of 22.471 mg/g for the fine fraction and 41.493 mg/g for the clay intercalated with DMSO. Langmuir’s model best reproduces the experimental data of this study. 展开更多
关键词 Clay DIMETHYLSULFOXIDE organoclay CHARACTERIZATION ADSORPTION ISOTHERM Moukosso
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有机粘土矿物对污染环境修复的研究进展 被引量:177
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作者 王晓蓉 吴顺年 +1 位作者 李万山 盛光遥 《环境化学》 CAS CSCD 北大核心 1997年第1期1-14,共14页
本文综述了国外在有机粘土矿物对污染环境修复研究方面的最新进展.具体介绍了利用表面活性剂制备有机粘土矿物的方法,不同类型有机粘土矿物的特征,有机粘土矿物对各种有机污染物的吸附行为及机理,在地下水污染的现场修复、土地填埋防渗... 本文综述了国外在有机粘土矿物对污染环境修复研究方面的最新进展.具体介绍了利用表面活性剂制备有机粘土矿物的方法,不同类型有机粘土矿物的特征,有机粘土矿物对各种有机污染物的吸附行为及机理,在地下水污染的现场修复、土地填埋防渗添加材料和去除工业废水有机污染物等方面的应用. 展开更多
关键词 有机粘土矿物 吸附 修复 环境污染 有机污染物
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环氧/粘土纳米复合材料的形成机理与性能 被引量:72
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作者 吕建坤 柯毓才 +1 位作者 漆宗能 益小苏 《高分子通报》 CAS CSCD 2000年第2期18-26,共9页
粘土 /聚合物纳米复合材料由于具有优良的物理力学性能和特殊功能而倍受关注。实验证明 ,粘土也很容易被环氧树脂插层 ,并在固化过程中剥离 ,得到纳米复合材料。本文重点综述了粘土 /环氧纳米复合材料的形成机理 ,结构形态和力学性能 ,... 粘土 /聚合物纳米复合材料由于具有优良的物理力学性能和特殊功能而倍受关注。实验证明 ,粘土也很容易被环氧树脂插层 ,并在固化过程中剥离 ,得到纳米复合材料。本文重点综述了粘土 /环氧纳米复合材料的形成机理 ,结构形态和力学性能 ,并对该类材料的应用前景进行了展望。 展开更多
关键词 环氧树脂 纳米复合材料 粘土 性能 结构
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有机蒙脱土/天然橡胶纳米复合材料的阻燃性能研究 被引量:26
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作者 李博 刘岚 +2 位作者 罗鸿鑫 罗远芳 贾德民 《高分子学报》 SCIE CAS CSCD 北大核心 2007年第5期456-461,共6页
采用机械混炼插层法制备有机蒙脱土/天然橡胶(TMT/NR)纳米复合材料.使用X-射线衍射(XRD)和红外表征了有机蒙脱土的结构特性,并用锥形量热仪测试了纳米复合材料的燃烧性能.结果表明,有机蒙脱土/NR纳米复合材料的热释放速率(HRR)、生烟速... 采用机械混炼插层法制备有机蒙脱土/天然橡胶(TMT/NR)纳米复合材料.使用X-射线衍射(XRD)和红外表征了有机蒙脱土的结构特性,并用锥形量热仪测试了纳米复合材料的燃烧性能.结果表明,有机蒙脱土/NR纳米复合材料的热释放速率(HRR)、生烟速率(SPR)等较纯天然橡胶、未改性蒙脱土/NR复合材料均所有降低,表现出较好的阻燃性能.通过对纳米复合材料的燃烧性能和燃烧残余物分析,探讨了该体系的阻燃机理. 展开更多
关键词 天然橡胶 有机蒙脱土 插层 纳米复合材料 阻燃性能
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一种促进粘土在环氧树脂中剥离的方法研究 被引量:8
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作者 吕建坤 柯毓才 +1 位作者 漆宗能 益小苏 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2002年第5期193-195,共3页
使用对环氧树脂的固化反应有促进作用的有机阳离子对粘土进行有机化处理 ,得到的有机土与环氧树脂混合后 ,尽管其层间距较小 ,层间容纳的环氧树脂较少 ,但由于催化作用使层间环氧树脂固化较快 ,结果在环氧的固化过程中粘土更易剥离 ,从... 使用对环氧树脂的固化反应有促进作用的有机阳离子对粘土进行有机化处理 ,得到的有机土与环氧树脂混合后 ,尽管其层间距较小 ,层间容纳的环氧树脂较少 ,但由于催化作用使层间环氧树脂固化较快 ,结果在环氧的固化过程中粘土更易剥离 ,从而得到粘土剥离程度较高的环氧树脂 /粘土纳米复合材料。这一研究为制备粘土剥离程度更高、性能更好的环氧 /粘土纳米复合材料提供了有效的方法。 展开更多
关键词 粘土 环氧树脂 剥离 方法 研究 插层聚合 纳米复合 有机化
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有机粘土在工业废水处理中的应用 被引量:15
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作者 高斌 徐仲艳 +1 位作者 王晓蓉 杨柳燕 《工业水处理》 CAS CSCD 2002年第4期29-31,34,共4页
研究了季铵盐阳离子表面活性剂十六烷基铵离子 (HDTMA)改性的蒙脱土在处理工业废水中的应用。结果表明 :有机粘土对废水中有机污染物具有很强的吸附能力 ,且微生物的存在为有机粘土的再生提供了可能。因此在处理有机工业废水方面 。
关键词 表面活性剂 有机粘土 吸附 工业废水 废水处理
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一种新型抗高温有机土的研制及性能评价 被引量:12
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作者 李春霞 黄进军 +1 位作者 高海洋 侯勤立 《西南石油学院学报》 CSCD 2001年第4期54-56,共3页
有机土是油基钻井液中一种重要处理剂 ,主要功用是增粘提切。目前采用传统方法制备的有机土在高温下容易分解失去功效 ,解析出来的表面活性剂会降低油包水乳化钻井液的电稳定性 ,通过优选季铵盐和采用螯合技术合成一种高温稳定的有机土X... 有机土是油基钻井液中一种重要处理剂 ,主要功用是增粘提切。目前采用传统方法制备的有机土在高温下容易分解失去功效 ,解析出来的表面活性剂会降低油包水乳化钻井液的电稳定性 ,通过优选季铵盐和采用螯合技术合成一种高温稳定的有机土XNORB。评价结果表明 ,有机土XNORB不但在柴油和白油中具有良好的分散性能和增粘效果 ,而且能在 2 2 0℃的高温基本保持稳定 ,对乳状液的稳定性无不良影响 ,其性能明显优于现有国产有机土 ,与美国产品VG— 6 9性能相当。 展开更多
关键词 油基钻井液 抗高温有机土 高温 分解 螯合 评价
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机械共混法制备剥离型天然橡胶蒙脱土纳米复合材料及其微观结构与力学性能 被引量:6
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作者 宋国君 亓峰 +2 位作者 李培耀 殷兰兰 王立 《现代化工》 EI CAS CSCD 北大核心 2006年第10期46-48,共3页
采用常规的双辊混炼法制备出了剥离型的天然橡胶/蒙脱土纳米复合材料。利用透射电子显微镜观察复合材料的亚微观形态,测试了材料的物理性能,研究了材料的应力-应变变化曲线,表征了材料的加工流动性变化,测试结果表明制备出了剥离型纳米... 采用常规的双辊混炼法制备出了剥离型的天然橡胶/蒙脱土纳米复合材料。利用透射电子显微镜观察复合材料的亚微观形态,测试了材料的物理性能,研究了材料的应力-应变变化曲线,表征了材料的加工流动性变化,测试结果表明制备出了剥离型纳米复合材料,低填充量(小于3份)时力学性能大大提高,应力-应变明显变化,加工流动性略有不同。 展开更多
关键词 天然橡胶 有机蒙脱土 机械共混
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有机黏土生物流化床处理对苯二甲酸废水 被引量:3
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作者 吴剑 杨柳燕 +1 位作者 火慧琴 肖琳 《中国环境科学》 EI CAS CSSCI CSCD 北大核心 2003年第3期251-254,共4页
采用有机黏土为载体的两段三相生物流化床处理对苯二甲酸(TA),研究其处理有机污染物的能力.结果表明,在TA负荷低于3.5kg/(m3穌)时,有机黏土生物流化床能稳定运行,前段出水中TA和总有机碳(TOC)的去除率分别大于97%和96%.在高负荷时,有机... 采用有机黏土为载体的两段三相生物流化床处理对苯二甲酸(TA),研究其处理有机污染物的能力.结果表明,在TA负荷低于3.5kg/(m3穌)时,有机黏土生物流化床能稳定运行,前段出水中TA和总有机碳(TOC)的去除率分别大于97%和96%.在高负荷时,有机黏土生物流化床平均去除率比不加黏土的活性污泥对照床高15%,出水水质也相对稳定.因此,有机黏土生物流化床是一种高效的生物反应器. 展开更多
关键词 有机黏土生物反应器 有机黏土 对苯二甲酸废水 生物处理
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蒙脱土多孔异构材料合成条件初探 被引量:5
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作者 李庆伟 周春晖 +3 位作者 葛忠华 王敏华 林春绵 王旭 《浙江工业大学学报》 CAS 2002年第2期95-99,共5页
采用天然膨润土为原料 ,提纯后用季铵盐 (如十六烷基三甲基溴化铵 )有机改性成有机土 ,然后与中性胺 (如十二胺和八烷胺 )及正硅酸乙酯以一定的比例混合反应 4h ,经分离 ,干燥 ,焙烧后合成出蒙脱土多孔粘土异构材料。通过XRD、TGA等表... 采用天然膨润土为原料 ,提纯后用季铵盐 (如十六烷基三甲基溴化铵 )有机改性成有机土 ,然后与中性胺 (如十二胺和八烷胺 )及正硅酸乙酯以一定的比例混合反应 4h ,经分离 ,干燥 ,焙烧后合成出蒙脱土多孔粘土异构材料。通过XRD、TGA等表征手段对这些中间产品和成品进行了分析测试 ,考察了不同链长的中性胺、不同的有机土等对材料合成的影响。结果表明用商品有机土和八烷胺合成的样品具有 2 6 .4 的孔道高度 ,达到中孔 ,且其热稳定性可达 80 0℃以上。 展开更多
关键词 异构材料 有机改性 蒙脱土 多孔材料 有机土 催化剂
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有机粘土矿物对水中菲蒽混合物的吸附 被引量:6
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作者 刘娜 陈畅曙 付云娜 《环境科学与技术》 CAS CSCD 北大核心 2006年第5期81-83,共3页
选用长碳链季铵盐阳离子型表面活性剂十六烷三甲基溴化铵(HDTMA-Br)作为改性剂对天然粘土矿物进行改性。利用改性后的粘土矿物对混合污染物进行吸附/解吸实验,结果显示:HDTMA改性粘土矿物对混合溶液中菲、蒽及混合物的吸附等温线均呈线... 选用长碳链季铵盐阳离子型表面活性剂十六烷三甲基溴化铵(HDTMA-Br)作为改性剂对天然粘土矿物进行改性。利用改性后的粘土矿物对混合污染物进行吸附/解吸实验,结果显示:HDTMA改性粘土矿物对混合溶液中菲、蒽及混合物的吸附等温线均呈线性,是分配作用结果;随着改性土用量的增加,其吸附量逐渐减小,对污染物的去除率逐渐增大,最后趋于平衡;有机粘土矿物吸附混合污染物后解吸率均在5%以下;将改性土对混合污染物的吸附与对单体污染物的吸附进行对照,改性土总的吸附量大大增加,基本是对单体污染物的吸附量之和。 展开更多
关键词 有机粘土矿物 吸附作用 混合物
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