The potential—pH diagrams of the Cr-H2O system at temperatures of 298, 323, 373 and 423 K were established through thermodynamic calculation with coupling of experimental results. The potential—pH diagram at 298 K a...The potential—pH diagrams of the Cr-H2O system at temperatures of 298, 323, 373 and 423 K were established through thermodynamic calculation with coupling of experimental results. The potential—pH diagram at 298 K agrees well with the previously reported results. Based on the potential—pH diagrams of the Cr-H2O and Fe-H2O systems, IR spectra and XRD pattern, the existence forms of iron in the potassium chromate were analyzed, and the methods of iron removal were investigated. The results show that the existence forms of iron in the potassium chromate are potassium ferrate. These results are instructive and helpful to the hydrometallurgical processing of chromite ore.展开更多
For aqueous interfacial reactions involving H+and OH-, the interfacial pH varies dynamically during the reaction process, which is a key factor determining the reaction performance. Herein, the kinetic relevance betwe...For aqueous interfacial reactions involving H+and OH-, the interfacial pH varies dynamically during the reaction process, which is a key factor determining the reaction performance. Herein, the kinetic relevance between the interfacial pH and reaction rate is deciphered owing to the success in establishing the transport equations of H+/OH- in unbuffered solutions, and is charted as a current(j)–pH diagram in the form of an electrochemical response. The as-described j–pH interplay is experimentally verified by the oxygen reduction and hydrogen evolution reactions. This diagram serves to form a panoramic graphic view of pH function working on the interfacial reactions in conjunction with the Pourbaix’s potential–pH diagram, and particularly enables a kinetic understanding of the transport effect of H+and OH-on the reaction rate and valuable instruction toward associated pH control and buffering manipulation.展开更多
For a highly efficient recycling of a wastewater containing a high concentration of MgCl_(2),Al(Ⅲ)and P507 were scheduled to be removed in advance.In this study,the in-situ removal of Al(Ⅲ)and P507 from a high conce...For a highly efficient recycling of a wastewater containing a high concentration of MgCl_(2),Al(Ⅲ)and P507 were scheduled to be removed in advance.In this study,the in-situ removal of Al(Ⅲ)and P507 from a high concentration MgCl_(2)solution at different pH values and Al/P molar ratios was investigated.The results showed that P507 formed organic complexes of Al_(x)(OH)_y^(Z+)-P507 at pH of 2.0-4.0.At pH of 4.0-5.0,Al(Ⅲ)precipitated and transferred into Al(OH)_(3)with a flocculent amorphous morphology.Active sites on the Al(OH)_(3)surface enhanced the removal efficiency of P507.At pH of 6.0-6.5,Al(Ⅲ)and Mg(Ⅱ)formed layered crystalline Al(OH)_(3)and MgAl_(2)(OH)_(8with)small pore channels and fewer active sites,resulting in a reduced removal efficiency of P507.When the Al/P molar ratio exceeded 13 and the pH was between 4.0 and 5.0,the removal rates of both Al(Ⅲ)and P507 were higher than98%,while the concentration loss of Mg(Ⅱ)was only 0.2%-0.9%.展开更多
Aqueous E pH Diagram is an essential tool for analyzing hydrometallurgical and corrosion processes. Due to the requirements for environmental protection and energy saving in recent years, waste water processing a...Aqueous E pH Diagram is an essential tool for analyzing hydrometallurgical and corrosion processes. Due to the requirements for environmental protection and energy saving in recent years, waste water processing and hydrometallurgical process of concentrate have been greatly developed. The construction of E pH diagrams has turned to multi component systems. However, there are some limits in plotting such diagrams. There is only one diagram for one multi component system, which can not reflect the truth of the aqueous reaction. In the paper, a new computation method is proposed to construct E pH diagrams. Component activity term is used to determine the boundary of stable areas. For the multi component systems, different atom ratios of elements have been taken into account. M S H 2O system is chosen to study since it is of importance in metallurgical solution. Compared with conventional methods, the algorithm is simple and conforms to real conditions.展开更多
Phosphorus is an important element for larch (\%Larix gmelinii\% Rupr.)root development.P-availability in rhizosphere is close with root exudates or excretions,e.g.,organic acid exudation,proton excretion.These materi...Phosphorus is an important element for larch (\%Larix gmelinii\% Rupr.)root development.P-availability in rhizosphere is close with root exudates or excretions,e.g.,organic acid exudation,proton excretion.These materials from roots will affect pH value of rhizosphere.The aim of this paper were to study on pH changes at different P-stress conditions,and to test on the relation between available P and pH in rhizosphere.This work was carried out under pot experiment and field soil smaple analysis.Larch seedlings,1 and 2-year-old,were planted into sand pots.Nutrient solution with different P contents (0,0.035,0.071 and 0.142g·L -1 respectively) were supplied everyday.There were 2 replicates for 1-year-old seedlings,5 replicates for 2-year-old seedlings at ecch P-level treatment.After 1-year-old seedlings growing for 40 days and 2-year-old seedlings growing for 90 days,seedlings were taken out and used to visualize acidification by means of an agar plate technique.The result showed that pH of rhizosphere decreased from 6.40 to 4.73～4.84 in 1-year-old seedlings and to 5.30～5.50 in 2-year-old after 36h incubation.Average pH decreased were 1.56～1.67 for 1-year-old seedlings,and 0.90～1.10 for 2-year-old seedlings.There was not significant,for pH variations in rhizosphere,among four kind treatments.The pH change was not affected by P-level.The result of soil sample analysis,from 12-year-old,21-year-old,and 40-year-old pure larch stands respectively,indicated that the pH changes in rhizosphere is 0.11,0.04,and 0.09,respectively,lower than that in the non-rhizosphere,acidification is not significant,While the available P in the rhizosphere is 18.1%,86.5% and 23.4%,higher than that in the non-rhizosphere in three stands.The correlation between pH variations and available P was not remarkable at this analysis.This means that there was no relationship between the available P and pH change of rhizosphere in larch root system.展开更多
基金Project(2007CB613501) supported by the National Basic Research Program of ChinaProject(2006BAC02A05) supported by the National Science and Technology Pillar Program of ChinaProject(50904058) supported by the National Natural Science Foundation of China
文摘The potential—pH diagrams of the Cr-H2O system at temperatures of 298, 323, 373 and 423 K were established through thermodynamic calculation with coupling of experimental results. The potential—pH diagram at 298 K agrees well with the previously reported results. Based on the potential—pH diagrams of the Cr-H2O and Fe-H2O systems, IR spectra and XRD pattern, the existence forms of iron in the potassium chromate were analyzed, and the methods of iron removal were investigated. The results show that the existence forms of iron in the potassium chromate are potassium ferrate. These results are instructive and helpful to the hydrometallurgical processing of chromite ore.
基金the National Natural Science Foundation of China(51525805,51727812,51808526)。
文摘For aqueous interfacial reactions involving H+and OH-, the interfacial pH varies dynamically during the reaction process, which is a key factor determining the reaction performance. Herein, the kinetic relevance between the interfacial pH and reaction rate is deciphered owing to the success in establishing the transport equations of H+/OH- in unbuffered solutions, and is charted as a current(j)–pH diagram in the form of an electrochemical response. The as-described j–pH interplay is experimentally verified by the oxygen reduction and hydrogen evolution reactions. This diagram serves to form a panoramic graphic view of pH function working on the interfacial reactions in conjunction with the Pourbaix’s potential–pH diagram, and particularly enables a kinetic understanding of the transport effect of H+and OH-on the reaction rate and valuable instruction toward associated pH control and buffering manipulation.
基金Project(JKY2019-10) supported by the State Key Laboratory of Nickel and Cobalt Resources Comprehensive Utilization,ChinaProject(51804029) supported by the National Natural Science Foundation of China。
基金financial supports from the National Key Research and Development Program of China(No.2022YFB3504501)the National Natural Science Foundation of China(Nos.52274355,91962211)the Gansu Province Science and Technology Major Special Project,China(No.22ZD6GD061)。
文摘For a highly efficient recycling of a wastewater containing a high concentration of MgCl_(2),Al(Ⅲ)and P507 were scheduled to be removed in advance.In this study,the in-situ removal of Al(Ⅲ)and P507 from a high concentration MgCl_(2)solution at different pH values and Al/P molar ratios was investigated.The results showed that P507 formed organic complexes of Al_(x)(OH)_y^(Z+)-P507 at pH of 2.0-4.0.At pH of 4.0-5.0,Al(Ⅲ)precipitated and transferred into Al(OH)_(3)with a flocculent amorphous morphology.Active sites on the Al(OH)_(3)surface enhanced the removal efficiency of P507.At pH of 6.0-6.5,Al(Ⅲ)and Mg(Ⅱ)formed layered crystalline Al(OH)_(3)and MgAl_(2)(OH)_(8with)small pore channels and fewer active sites,resulting in a reduced removal efficiency of P507.When the Al/P molar ratio exceeded 13 and the pH was between 4.0 and 5.0,the removal rates of both Al(Ⅲ)and P507 were higher than98%,while the concentration loss of Mg(Ⅱ)was only 0.2%-0.9%.
文摘Aqueous E pH Diagram is an essential tool for analyzing hydrometallurgical and corrosion processes. Due to the requirements for environmental protection and energy saving in recent years, waste water processing and hydrometallurgical process of concentrate have been greatly developed. The construction of E pH diagrams has turned to multi component systems. However, there are some limits in plotting such diagrams. There is only one diagram for one multi component system, which can not reflect the truth of the aqueous reaction. In the paper, a new computation method is proposed to construct E pH diagrams. Component activity term is used to determine the boundary of stable areas. For the multi component systems, different atom ratios of elements have been taken into account. M S H 2O system is chosen to study since it is of importance in metallurgical solution. Compared with conventional methods, the algorithm is simple and conforms to real conditions.
文摘Phosphorus is an important element for larch (\%Larix gmelinii\% Rupr.)root development.P-availability in rhizosphere is close with root exudates or excretions,e.g.,organic acid exudation,proton excretion.These materials from roots will affect pH value of rhizosphere.The aim of this paper were to study on pH changes at different P-stress conditions,and to test on the relation between available P and pH in rhizosphere.This work was carried out under pot experiment and field soil smaple analysis.Larch seedlings,1 and 2-year-old,were planted into sand pots.Nutrient solution with different P contents (0,0.035,0.071 and 0.142g·L -1 respectively) were supplied everyday.There were 2 replicates for 1-year-old seedlings,5 replicates for 2-year-old seedlings at ecch P-level treatment.After 1-year-old seedlings growing for 40 days and 2-year-old seedlings growing for 90 days,seedlings were taken out and used to visualize acidification by means of an agar plate technique.The result showed that pH of rhizosphere decreased from 6.40 to 4.73～4.84 in 1-year-old seedlings and to 5.30～5.50 in 2-year-old after 36h incubation.Average pH decreased were 1.56～1.67 for 1-year-old seedlings,and 0.90～1.10 for 2-year-old seedlings.There was not significant,for pH variations in rhizosphere,among four kind treatments.The pH change was not affected by P-level.The result of soil sample analysis,from 12-year-old,21-year-old,and 40-year-old pure larch stands respectively,indicated that the pH changes in rhizosphere is 0.11,0.04,and 0.09,respectively,lower than that in the non-rhizosphere,acidification is not significant,While the available P in the rhizosphere is 18.1%,86.5% and 23.4%,higher than that in the non-rhizosphere in three stands.The correlation between pH variations and available P was not remarkable at this analysis.This means that there was no relationship between the available P and pH change of rhizosphere in larch root system.
