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Comparison of Calibration Curve Method and Partial Least Square Method in the Laser Induced Breakdown Spectroscopy Quantitative Analysis 被引量:1
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作者 Zhi-bo Cong Lan-xiang Sun +2 位作者 Yong Xin Yang Li Li-feng Qi 《Journal of Computer and Communications》 2013年第7期14-18,共5页
The Laser Induced Breakdown Spectroscopy (LIBS) is a fast, non-contact, no sample preparation analytic technology;it is very suitable for on-line analysis of alloy composition. In the copper smelting industry, analysi... The Laser Induced Breakdown Spectroscopy (LIBS) is a fast, non-contact, no sample preparation analytic technology;it is very suitable for on-line analysis of alloy composition. In the copper smelting industry, analysis and control of the copper alloy concentration affect the quality of the products greatly, so LIBS is an efficient quantitative analysis tech- nology in the copper smelting industry. But for the lead brass, the components of Pb, Al and Ni elements are very low and the atomic emission lines are easily submerged under copper complex characteristic spectral lines because of the matrix effects. So it is difficult to get the online quantitative result of these important elements. In this paper, both the partial least squares (PLS) method and the calibration curve (CC) method are used to quantitatively analyze the laser induced breakdown spectroscopy data which is obtained from the standard lead brass alloy samples. Both the major and trace elements were quantitatively analyzed. By comparing the two results of the different calibration method, some useful results were obtained: both for major and trace elements, the PLS method was better than the CC method in quantitative analysis. And the regression coefficient of PLS method is compared with the original spectral data with background interference to explain the advantage of the PLS method in the LIBS quantitative analysis. Results proved that the PLS method used in laser induced breakdown spectroscopy was suitable for simultaneous quantitative analysis of different content elements in copper smelting industry. 展开更多
关键词 LASER-INDUCED BREAKDOWN Spectroscopy (LIBS) partial least square method (PLS) Matrix Effects Quantitative Analysis
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Estimating canopy closure density and above-ground tree biomass using partial least square methods in Chinese boreal forests 被引量:4
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作者 LEI Cheng-liang JU Cun-yong +3 位作者 CAI Ti-jiu J1NG Xia WEI Xiao-hua DI Xue-ying 《Journal of Forestry Research》 CAS CSCD 2012年第2期191-196,共6页
Boreal forests play an important role in global environment systems. Understanding boreal forest ecosystem structure and function requires accurate monitoring and estimating of forest canopy and biomass. We used parti... Boreal forests play an important role in global environment systems. Understanding boreal forest ecosystem structure and function requires accurate monitoring and estimating of forest canopy and biomass. We used partial least square regression (PLSR) models to relate forest parameters, i.e. canopy closure density and above ground tree biomass, to Landsat ETM+ data. The established models were optimized according to the variable importance for projection (VIP) criterion and the bootstrap method, and their performance was compared using several statistical indices. All variables selected by the VIP criterion passed the bootstrap test (p<0.05). The simplified models without insignificant variables (VIP <1) performed as well as the full model but with less computation time. The relative root mean square error (RMSE%) was 29% for canopy closure density, and 58% for above-ground tree biomass. We conclude that PLSR can be an effective method for estimating canopy closure density and above-ground biomass. 展开更多
关键词 地上生物量 温带森林 偏最小二乘方法 郁闭度 密度 中国北方 估计 偏最小二乘回归
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Least square method based on Haar wavelet to solve multi-dimensional stochastic Ito-Volterra integral equations
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作者 JIANG Guo KE Ting DENG Meng-ting 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2023年第4期591-603,共13页
This paper proposes a method combining blue the Haar wavelet and the least square to solve the multi-dimensional stochastic Ito-Volterra integral equation.This approach is to transform stochastic integral equations in... This paper proposes a method combining blue the Haar wavelet and the least square to solve the multi-dimensional stochastic Ito-Volterra integral equation.This approach is to transform stochastic integral equations into a system of algebraic equations.Meanwhile,the error analysis is proven.Finally,the effectiveness of the approach is verified by two numerical examples. 展开更多
关键词 least squares method Haar wavelet Ito-Volterra integral equations integration operational matrix.
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Penalized total least squares method for dealing with systematic errors in partial EIV model and its precision estimation 被引量:3
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作者 Leyang Wang Luyun Xiong Tao Chen 《Geodesy and Geodynamics》 CSCD 2021年第4期249-257,共9页
When the total least squares(TLS)solution is used to solve the parameters in the errors-in-variables(EIV)model,the obtained parameter estimations will be unreliable in the observations containing systematic errors.To ... When the total least squares(TLS)solution is used to solve the parameters in the errors-in-variables(EIV)model,the obtained parameter estimations will be unreliable in the observations containing systematic errors.To solve this problem,we propose to add the nonparametric part(systematic errors)to the partial EIV model,and build the partial EIV model to weaken the influence of systematic errors.Then,having rewritten the model as a nonlinear model,we derive the formula of parameter estimations based on the penalized total least squares criterion.Furthermore,based on the second-order approximation method of precision estimation,we derive the second-order bias and covariance of parameter estimations and calculate the mean square error(MSE).Aiming at the selection of the smoothing factor,we propose to use the U curve method.The experiments show that the proposed method can mitigate the influence of systematic errors to a certain extent compared with the traditional method and get more reliable parameter estimations and its precision information,which validates the feasibility and effectiveness of the proposed method. 展开更多
关键词 partial EIV model Systematic errors Nonlinear model Penalized total least squares criterion U curve method
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Application of neural network model coupling with the partial least-squares method for forecasting watre yield of mine 被引量:2
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作者 陈南祥 曹连海 黄强 《Journal of Coal Science & Engineering(China)》 2005年第1期40-43,共4页
Scientific forecasting water yield of mine is of great significance to the safety production of mine and the colligated using of water resources. The paper established the forecasting model for water yield of mine, co... Scientific forecasting water yield of mine is of great significance to the safety production of mine and the colligated using of water resources. The paper established the forecasting model for water yield of mine, combining neural network with the partial least square method. Dealt with independent variables by the partial least square method, it can not only solve the relationship between independent variables but also reduce the input dimensions in neural network model, and then use the neural network which can solve the non-linear problem better. The result of an example shows that the prediction has higher precision in forecasting and fitting. 展开更多
关键词 地下水 水量 矿山 人工神经网络 数学模型 动态预报模型
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DATA MODELING METHOD BASED ON PARTIAL LEAST SQUARE REGRESSION AND APPLICATIO N IN CORRELATION ANALYSIS OF THE STATOR BARS CONDITION PARAMETERS
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作者 李锐华 高乃奎 +1 位作者 谢恒堃 史维祥 《Journal of Pharmaceutical Analysis》 SCIE CAS 2004年第2期127-131,共5页
Objective To investigate v arious data message of the stator bars condition parameters under the condition that only a few samples are available, especially about correlation information between the nondestructive par... Objective To investigate v arious data message of the stator bars condition parameters under the condition that only a few samples are available, especially about correlation information between the nondestructive parameters and residual breakdown voltage of the stat or bars. Methods Artificial stator bars is designed to simulat e the generator bars. The partial didcharge( PD) and dielectric loss experiments are performed in order to obtain the nondestructive parameters, and the residua l breakdown voltage acquired by AC damage experiment. In order to eliminate the dimension effect on measurement data, raw data is preprocessed by centered-compr ess. Based on the idea of extracting principal components, a partial least squar e (PLS) method is applied to screen and synthesize correlation information betwe en the nondestructive parameters and residual breakdown voltage easily. Moreover , various data message about condition parameters are also discussed. Re sults Graphical analysis function of PLS is easily to understand vario us data message of the stator bars condition parameters. The analysis Results ar e consistent with result of aging testing. Conclusion The meth od can select and extract PLS components of condition parameters from sample dat a, and the problems of less samples and multicollinearity are solved effectively in regression analysis. 展开更多
关键词 partial least square PCA CONDITION PARAMETER s tator WINDING
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Development a Spectrophotometric of Fe(Ⅲ), Al(Ⅲ) and Cu(Ⅱ) Using Eriochrome Cyanine R Ligand and Assessment of the Obtained Data by Partial Least-Squares and Artificial Neural Network Method-Application to Natural Waters
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作者 A. Hakan AKTAS 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2018年第8期2638-2644,共7页
Simultaneous determination of heavy metal cations and accurate quantitative prediction of them are of great interest in analytical chemistry.This work has focused on a comprehensive comparison of partial least squares... Simultaneous determination of heavy metal cations and accurate quantitative prediction of them are of great interest in analytical chemistry.This work has focused on a comprehensive comparison of partial least squares(PLS-1)and artificial neural networks(ANN)as two types of chemometric methods.For this purpose,aluminum,iron and copper were studied as three analytes whose UV-Vis absorption spectra highly overlap each other.Accordance with determined parameters(ligand concentration,pH,waiting times,the relationship between absorbance and concentration of metal ion effect and foreign ions)are provided and the optimum conditions.After establishing the optimum conditions for Fe^(3+),Al^(3+) and Cu^(2+) containing mixtures spectrophotometric determinations and the data calibration method of least squares(PLS-1)regression,and artificial neural network(ANN)methods were used.Chemometric methods are applied in a fast,simple,and the results are applicable. 展开更多
关键词 UV-Vis spectrophotometry partial least squares Artificial neural network ALUMINUM IRON COPPER
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Partial Least Squares(PLS)Methods for Abnormal Detection of Breast Cells
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作者 Yuchen Zhu Shanxiong Chen +1 位作者 Chunrong Chen Lin Chen 《国际计算机前沿大会会议论文集》 2017年第1期22-24,共3页
Breast cancer is one of the malignant tumors having high incidence in women,the incidence of breast cancer has increased in all parts of the world since twentieth century,but its etiology is not yet completely clear,s... Breast cancer is one of the malignant tumors having high incidence in women,the incidence of breast cancer has increased in all parts of the world since twentieth century,but its etiology is not yet completely clear,so it is very important to detect breast cells.In this paper,we built a regression model to detect breast cells,and generated a method for predicting the formation of benign and malignant breast cells by training the model,then we used the 10 features of breast cells to predict it,the results reaching upto 93.67%accuracy,it was very effective to predict and analyse whether the breast cells getting cancer,It had an important role in the diagnosis and prevention of breast cancer. 展开更多
关键词 partial least squareS MULTIVARIATE analysis BREAST CANCER Prediction
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偏最小二乘(PartialLeast Square)方法的拟合指标及其在满意度研究中的应用 被引量:21
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作者 金勇进 梁燕 《数理统计与管理》 CSSCI 北大核心 2005年第2期40-44,共5页
本文在对顾客满意度模型及PLS方法进行简单介绍的基础上,对PLS的拟合指标,包括共同因子、多元相关平方和冗余,进行了讨论。
关键词 顾客满意度 偏最小二乘 共同因子 多元相关平方 冗余
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Adaptive multi-step piecewise interpolation reproducing kernel method for solving the nonlinear time-fractional partial differential equation arising from financial economics 被引量:1
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作者 杜明婧 孙宝军 凯歌 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第3期53-57,共5页
This paper is aimed at solving the nonlinear time-fractional partial differential equation with two small parameters arising from option pricing model in financial economics.The traditional reproducing kernel(RK)metho... This paper is aimed at solving the nonlinear time-fractional partial differential equation with two small parameters arising from option pricing model in financial economics.The traditional reproducing kernel(RK)method which deals with this problem is very troublesome.This paper proposes a new method by adaptive multi-step piecewise interpolation reproducing kernel(AMPIRK)method for the first time.This method has three obvious advantages which are as follows.Firstly,the piecewise number is reduced.Secondly,the calculation accuracy is improved.Finally,the waste time caused by too many fragments is avoided.Then four numerical examples show that this new method has a higher precision and it is a more timesaving numerical method than the others.The research in this paper provides a powerful mathematical tool for solving time-fractional option pricing model which will play an important role in financial economics. 展开更多
关键词 time-fractional partial differential equation adaptive multi-step reproducing kernel method method numerical solution
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A multivariate partial least squares approach to joint association analysis for multiple correlated traits 被引量:3
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作者 Yang Xu Wenming Hu +1 位作者 Zefeng Yang Chenwu Xu 《The Crop Journal》 SCIE CAS CSCD 2016年第1期21-29,共9页
Many complex traits are highly correlated rather than independent. By taking the correlation structure of multiple traits into account, joint association analyses can achieve both higher statistical power and more acc... Many complex traits are highly correlated rather than independent. By taking the correlation structure of multiple traits into account, joint association analyses can achieve both higher statistical power and more accurate estimation. To develop a statistical approach to joint association analysis that includes allele detection and genetic effect estimation, we combined multivariate partial least squares regression with variable selection strategies and selected the optimal model using the Bayesian Information Criterion(BIC). We then performed extensive simulations under varying heritabilities and sample sizes to compare the performance achieved using our method with those obtained by single-trait multilocus methods. Joint association analysis has measurable advantages over single-trait methods, as it exhibits superior gene detection power, especially for pleiotropic genes. Sample size, heritability,polymorphic information content(PIC), and magnitude of gene effects influence the statistical power, accuracy and precision of effect estimation by the joint association analysis. 展开更多
关键词 Association analysis MULTIPLE CORRELATED TRAITS Supersaturated model MULTILOCUS MULTIVARIATE partial least squareS
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Online Detection of Broken Rotor Bar Fault in Induction Motors by Combining Estimation of Signal Parameters via Min-norm Algorithm and Least Square Method 被引量:4
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作者 Pan-Pan Wang Qiang Yu +1 位作者 Yong-Jun Hu Chang-Xin Miao 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2017年第6期1285-1295,共11页
Current research in broken rotor bar(BRB) fault detection in induction motors is primarily focused on a high-frequency resolution analysis of the stator current.Compared with a discrete Fourier transformation, the par... Current research in broken rotor bar(BRB) fault detection in induction motors is primarily focused on a high-frequency resolution analysis of the stator current.Compared with a discrete Fourier transformation, the parametric spectrum estimation technique has a higher frequency accuracy and resolution. However, the existing detection methods based on parametric spectrum estimation cannot realize online detection, owing to the large computational cost. To improve the efficiency of BRB fault detection,a new detection method based on the min-norm algorithm and least square estimation is proposed in this paper. First, the stator current is filtered using a band-pass filter and divided into short overlapped data windows. The min-norm algorithm is then applied to determine the frequencies of the fundamental and fault characteristic components with each overlapped data window. Next, based on the frequency values obtained, a model of the fault current signal is constructed. Subsequently, a linear least squares problem solved through singular value decomposition is designed to estimate the amplitudes and phases of the related components. Finally,the proposed method is applied to a simulated current and an actual motor,the results of which indicate that, not only parametric spectrum estimation technique. 展开更多
关键词 Fault detection Broken rotor bars Min-norm least squares method Induction motors
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On-Line Batch Process Monitoring Using Multiway Kernel Partial Least Squares 被引量:4
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作者 胡益 马贺贺 侍洪波 《Journal of Donghua University(English Edition)》 EI CAS 2011年第6期585-590,共6页
An approach for batch processes monitoring and fault detection based on multiway kernel partial least squares(MKPLS) was presented.It is known that conventional batch process monitoring methods,such as multiway partia... An approach for batch processes monitoring and fault detection based on multiway kernel partial least squares(MKPLS) was presented.It is known that conventional batch process monitoring methods,such as multiway partial least squares(MPLS),are not suitable due to their intrinsic linearity when the variations are nonlinear.To address this issue,kernel partial least squares(KPLS) was used to capture the nonlinear relationship between the latent structures and predictive variables.In addition,KPLS requires only linear algebra and does not involve any nonlinear optimization.In this paper,the application of KPLS was extended to on-line monitoring of batch processes.The proposed batch monitoring method was applied to a simulation benchmark of fed-batch penicillin fermentation process.And the results demonstrate the superior monitoring performance of MKPLS in comparison to MPLS monitoring. 展开更多
关键词 process monitoring fault detection kernel partial least squares(KPLS) nonlinear process multiway kernel partial least squares(MKPLS)
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Mechanical properties of wood materials using near-infrared spectroscopy based on correlation local embedding and partial least-squares 被引量:2
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作者 Lei Yu Yuliang Liang +1 位作者 Yizhuo Zhang Jun Cao 《Journal of Forestry Research》 SCIE CAS CSCD 2020年第3期1053-1060,共8页
This study used near-infrared(NIR)spectroscopy to predict mechanical properties of wood.NIR spectra were collected in wavelengths 900–1700 nm,and spectra averaged by radial and tangential surface spectra were used to... This study used near-infrared(NIR)spectroscopy to predict mechanical properties of wood.NIR spectra were collected in wavelengths 900–1700 nm,and spectra averaged by radial and tangential surface spectra were used to establish a partial least square(PLS)model based on correlation local embedding(CLE).Mongolian oak(Quercus mongolica Fisch.ex Ledeb.)was used to test the eff ectiveness of the model.The cross-validation method was used to verify the robustness of the CLE–PLS model.Ninety samples were tested as the calibration set and forty-fi ve as the validation set.The results show that the prediction coeffi cient of determination(R2 p)is 0.80 for MOR,and 0.78 for MOE.The ratio of performance to deviation is 2.23 for MOR and 2.15 for MOE. 展开更多
关键词 MODULUS of RUPTURE MODULUS of ELASTICITY Near-infrared CORRELATION LOCAL EMBEDDING partial least square
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Near-Infrared Spectroscopy Combined with Partial Least Squares Discriminant Analysis Applied to Identification of Liquor Brands 被引量:3
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作者 Bin Yang Lijun Yao Tao Pan 《Engineering(科研)》 2017年第2期181-189,共9页
The identification of liquor brands is very important for food safety. Most of the fake liquors are usually made into the products with the same flavor and alcohol content as regular brand, so the identification for t... The identification of liquor brands is very important for food safety. Most of the fake liquors are usually made into the products with the same flavor and alcohol content as regular brand, so the identification for the liquor brands with the same flavor and the same alcohol content is essential. However, it is also difficult because the components of such liquor samples are very similar. Near-infrared (NIR) spectroscopy combined with partial least squares discriminant analysis (PLS-DA) was applied to identification of liquor brands with the same flavor and alcohol content. A total of 160 samples of Luzhou Laojiao liquor and 200 samples of non-Luzhou Laojiao liquor with the same flavor and alcohol content were used for identification. Samples of each type were randomly divided into the modeling and validation sets. The modeling samples were further divided into calibration and prediction sets using the Kennard-Stone algorithm to achieve uniformity and representativeness. In the modeling and validation processes based on PLS-DA method, the recognition rates of samples achieved 99.1% and 98.7%, respectively. The results show high prediction performance for the identification of liquor brands, and were obviously better than those obtained from the principal component linear discriminant analysis method. NIR spectroscopy combined with the PLS-DA method provides a quick and effective means of the discriminant analysis of liquor brands, and is also a promising tool for large-scale inspection of liquor food safety. 展开更多
关键词 IDENTIFICATION of LIQUOR Brands NEAR-INFRARED Spectroscopy partial least squareS DISCRIMINANT ANALYSIS Principal Component Linear DISCRIMINANT ANALYSIS
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Factors influencing the internet banking adoption decision in North Cyprus: an evidence from the partial least square approach of the structural equation modeling 被引量:2
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作者 Hiba Alhassany Faisal Faisal 《Financial Innovation》 2018年第1期422-442,共21页
Purpose:This paper aims to examine how the adoption decision of the internet banking in North Cyprus would be affected based on the following dimensions;the technology features,the personal characteristics,the social ... Purpose:This paper aims to examine how the adoption decision of the internet banking in North Cyprus would be affected based on the following dimensions;the technology features,the personal characteristics,the social environment and the expected risk.Design/methodology/approach:A self-administered survey was conducted with 291 participants responded to it.The partial least square approach of the structural equation modeling(PLS-SEM)is employed to investigate the direct effects of the proposed factors on the adoption decision.Additionally,the mediation test is used to examine indirect effects.Findings:Results showed that even though the participants appreciated the benefits of the online banking as the perceived usefulness factor exerts the greatest direct effect,they would rather use clear and easy-to-use websites,adding to that their assessments of the usefulness of these services are significantly influenced by the surrounding people’s views and prior experience.This is demonstrated by the total effects of the perceived ease of use and the subjective norm factors,which are greater than the direct effect of the perceived usefulness factor since both of these factors have significant direct and indirect effects mediated by the perceived usefulness factor.The negative impact of the perceived risk factor is weak compared to the previous factors.While the personal innovativeness factor showed the weakest effect among the proposed factors. 展开更多
关键词 Behavioral theories Technology adoption TAM Subjective norm Personal innovativeness Perceived risk partial least square Structural equation modeling
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Least Squares Method from the View Point of Deep Learning 被引量:1
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作者 Kazuyuki Fujii 《Advances in Pure Mathematics》 2018年第5期485-493,共9页
The least squares method is one of the most fundamental methods in Statistics to estimate correlations among various data. On the other hand, Deep Learning is the heart of Artificial Intelligence and it is a learning ... The least squares method is one of the most fundamental methods in Statistics to estimate correlations among various data. On the other hand, Deep Learning is the heart of Artificial Intelligence and it is a learning method based on the least squares. In this paper we reconsider the least squares method from the view point of Deep Learning and we carry out the computation thoroughly for the gradient descent sequence in a very simple setting. Depending on the values of the learning rate, an essential parameter of Deep Learning, the least squares methods of Statistics and Deep Learning reveal an interesting difference. 展开更多
关键词 least squareS method STATISTICS Deep LEARNING LEARNING Rate Linear ALGEBRA
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Least Squares Method from the View Point of Deep Learning II: Generalization 被引量:1
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作者 Kazuyuki Fujii 《Advances in Pure Mathematics》 2018年第9期782-791,共10页
The least squares method is one of the most fundamental methods in Statistics to estimate correlations among various data. On the other hand, Deep Learning is the heart of Artificial Intelligence and it is a learning ... The least squares method is one of the most fundamental methods in Statistics to estimate correlations among various data. On the other hand, Deep Learning is the heart of Artificial Intelligence and it is a learning method based on the least squares method, in which a parameter called learning rate plays an important role. It is in general very hard to determine its value. In this paper we generalize the preceding paper [K. Fujii: Least squares method from the view point of Deep Learning: Advances in Pure Mathematics, 8, 485-493, 2018] and give an admissible value of the learning rate, which is easily obtained. 展开更多
关键词 least squareS method STATISTICS Deep LEARNING LEARNING Rate Gerschgorin’s THEOREM
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Novel Real-Time Seam Tracking Algorithm Based on Vector Angle and Least Square Method 被引量:1
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作者 Guanhao Liang Qingsheng Luo +1 位作者 Zhuo Ge Xiaoqing Guan 《Journal of Beijing Institute of Technology》 EI CAS 2017年第2期150-157,共8页
Real-time seam tracking can improve welding quality and enhance welding efficiency during the welding process in automobile manufacturing.However,the teaching-playing welding process,an off-line seam tracking method,i... Real-time seam tracking can improve welding quality and enhance welding efficiency during the welding process in automobile manufacturing.However,the teaching-playing welding process,an off-line seam tracking method,is still dominant in automobile industry,which is less flexible when welding objects or situation change.A novel real-time algorithm consisting of seam detection and generation is proposed to track seam.Using captured 3D points,space vectors were created between two adjacent points along each laser line and then a vector angle based algorithm was developed to detect target points on the seam.Least square method was used to fit target points to a welding trajectory for seam tracking.Furthermore,the real-time seam tracking process was simulated in MATLAB/Simulink.The trend of joint angles vs.time was logged and a comparison between the off-line and the proposed seam tracking algorithm was conducted.Results show that the proposed real-time seam tracking algorithm can work in a real-time scenario and have high accuracy in welding point positioning. 展开更多
关键词 real-time seam tracking real-time seam detection laser scanner vector angle least square method algorithm research
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Near-Infrared Spectroscopy Combined with Absorbance Upper Optimization Partial Least Squares Applied to Rapid Analysis of Polysaccharide for Proprietary Chinese Medicine Oral Solution 被引量:2
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作者 Jiexiong Su Xinkai Gao +5 位作者 Lirong Tan Xianzhao Liu Yueqing Ye Yifang Chen Kaisheng Ma Tao Pan 《American Journal of Analytical Chemistry》 2016年第3期275-281,共7页
Near-infrared (NIR) spectroscopy was applied to reagent-free quantitative analysis of polysaccharide of a brand product of proprietary Chinese medicine (PCM) oral solution samples. A novel method, called absorbance up... Near-infrared (NIR) spectroscopy was applied to reagent-free quantitative analysis of polysaccharide of a brand product of proprietary Chinese medicine (PCM) oral solution samples. A novel method, called absorbance upper optimization partial least squares (AUO-PLS), was proposed and successfully applied to the wavelength selection. Based on varied partitioning of the calibration and prediction sample sets, the parameter optimization was performed to achieve stability. On the basis of the AUO-PLS method, the selected upper bound of appropriate absorbance was 1.53 and the corresponding wavebands combination was 400 - 1880 & 2088 - 2346 nm. With the use of random validation samples excluded from the modeling process, the root-mean-square error and correlation coefficient of prediction for polysaccharide were 27.09 mg·L<sup>-</sup><sup>1</sup> and 0.888, respectively. The results indicate that the NIR prediction values are close to those of the measured values. NIR spectroscopy combined with AUO-PLS method provided a promising tool for quantification of the polysaccharide for PCM oral solution and this technique is rapid and simple when compared with conventional methods. 展开更多
关键词 Near-Infrared Spectroscopic Analysis Proprietary Chinese Medicine Oral Solution POLYSACCHARIDE Absorbance Upper Optimization partial least squares
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