Biomedical magnesium(Mg)alloys have garnered significant attention because of their unique biodegradability,favorable biocompatibility,and suitable mechanical properties.The incorporation of rare earth(RE)elements,wit...Biomedical magnesium(Mg)alloys have garnered significant attention because of their unique biodegradability,favorable biocompatibility,and suitable mechanical properties.The incorporation of rare earth(RE)elements,with their distinct physical and chemical properties,has greatly contributed to enhancing the mechanical performance,degradation behavior,and biological performance of biomedical Mg alloys.Currently,a series of RE-Mg alloys are being designed and investigated for orthopedic implants and cardiovascular stents,achieving substantial and encouraging research progress.In this work,a comprehensive summary of the state-of-the-art in biomedical RE-Mg alloys is provided.The physiological effects and design standards of RE elements in biomedical Mg alloys are discussed.Particularly,the degradation behavior and mechanical properties,including their underlying action are studied in-depth.Furthermore,the preparation techniques and current application status of RE-Mg alloys are reviewed.Finally,we address the ongoing challenges and propose future prospects to guide the development of high-performance biomedical Mg-RE alloys.展开更多
The small muddy areas developed in the southern Shandong Peninsula have attracted increasing attention from researchers because of complex changes in sediment sources driven by sea-level fluctuations and land-sea inte...The small muddy areas developed in the southern Shandong Peninsula have attracted increasing attention from researchers because of complex changes in sediment sources driven by sea-level fluctuations and land-sea interactions since the late Pleistocene.This study investigates the evolution of sediment sources and their responses to environmental changes since the late Pleistocene,using core WHZK01 collected from the nearshore muddy area in southern Weihai for rare earth element(REE)analysis.In doing so,this work highlights the changing patterns of material sources and the primary control factors.The results reveal that the sedimentary deposits in core WHZK01 exhibit distinct terrestrial characteristics.Discriminant function analysis(F_(D))and source discrimination dia-grams both suggest that the primary sources of these deposits are the Yellow River and adjacent small and medium-sized rivers,although the sources vary among different sedimentary units.Furthermore,the DU3 layer(17.82-25.10 m)displays typical riverine sedimentation,dominated by terrestrial detrital input,primarily from the local rivers,namely the Huanglei and Muzhu Rivers.The material in the DU2 layer(14.91-17.82 m)is mainly influenced by a mixture of the Qinglong and Yellow Rivers.The DU1 layer(0-14.91 m)is influenced by sea-level changes during the Holocene,with the Yellow River being the primary source,although there is also some input from local rivers.The changes in sea level during the Holocene and the input of Yellow River material carried by the coastal currents of the Yellow Sea are identified as the main controlling factors for the changes in material sources in the study area since the late Pleistocene,with small and mediumsized rivers also exerting some influence on the material sources.The above mentioned findings not only contribute to a better understanding of the source-sink systems of the Yellow River and adjacent small and mediumsized rivers but also deepen our understanding of the late Quaternary land-sea interactions in the Shandong Peninsula.展开更多
Co/NC catalysts modified with rare earth elements(La,Ce,Pr)were prepared by pyrolysis of rare earth elements doped ZIF-67.The experimental results show that the modification of rare earth elements significantly improv...Co/NC catalysts modified with rare earth elements(La,Ce,Pr)were prepared by pyrolysis of rare earth elements doped ZIF-67.The experimental results show that the modification of rare earth elements significantly improves the ammonia decomposition activity and stability of the Co/NC catalyst.The La-Co/NC catalyst can achieve an 82.3%ammonia decomposition and 18.4 mmol hydrogen production rate at 550℃with a GHSV of 20000 cm^(3)·h^(-1).Furthermore,no obvious performance degradation is observed after 72 hours of reaction for all rare earth elements modified catalysts.It is shown that the modification of rare earth elements significantly improves the surface alkalinity and surface chemical state of the catalyst,and thus improves the ammonia decomposition activity of the catalyst.A new type of high-performance ammonia decomposition Co-based catalyst is proposed,and the promoting effect of rare earth elements on the activity of ammonia decomposition is revealed.展开更多
The A_(2)B_(2)O_(7)-type rare earth zirconate compounds have been considered as promising candidates for thermal barrier coating(TBC) materials because of their low sintering rate,improved phase stability,and reduced ...The A_(2)B_(2)O_(7)-type rare earth zirconate compounds have been considered as promising candidates for thermal barrier coating(TBC) materials because of their low sintering rate,improved phase stability,and reduced thermal conductivity in contrast with the currently used yttria-partially stabilized zirconia (YSZ) in high operating temperature environments.This review summarizes the recent progress on rare earth zirconates for TBCs that insulate high-temperature gas from hot-section components in gas turbines.Based on the first principles,molecular dynamics,and new data-driven calculation approaches,doping and high-entropy strategies have now been adopted in advanced TBC materials design.In this paper,the solid-state heat transfer mechanism of TBCs is explained from two aspects,including heat conduction over the full operating temperature range and thermal radiation at medium and high temperature.This paper also provides new insights into design considerations of adaptive TBC materials,and the challenges and potential breakthroughs are further highlighted for extreme environmental applications.Strategies for improving thermophysical performance are proposed in two approaches:defect engineering and material compositing.展开更多
A hydrotalcite(layered double hydroxide, LDH) inhibitor which is suitable for the whole process of coal spontaneous combustion and a LDH inhibitor containing rare earth lanthanum elements were prepared. The inhibition...A hydrotalcite(layered double hydroxide, LDH) inhibitor which is suitable for the whole process of coal spontaneous combustion and a LDH inhibitor containing rare earth lanthanum elements were prepared. The inhibition effect and mechanism were analyzed by scanning electron microscopy(SEM),X-ray diffraction(XRD), thermal performance analysis, in-situ diffuse reflectance infrared spectroscopy and temperature-programmed experiment. The results have shown that the inhibitor containing lanthanum can play a good inhibitory role in every stage of coal oxidation. During the slow oxidation of coal samples, the inhibitor containing lanthanum ions can slow down the oxidation process of coal and increase the initial temperature of coal spontaneous combustion. At the same time, because the hydroxyl groups in LDHs are connected with-COO-groups on the coal surface through hydrogen bonds, the stability of coal is improved. With the increase of temperature, LDHs can remove interlayer water molecules and reduce the surface temperature of coal. CO release rate of coal samples decreases significantly after adding inhibitor containing lanthanum element, and the maximum inhibition rate of the inhibitor is 58.1%.展开更多
We took Co_(0.2)Ni_(0.8)-MOF-74 with bimetallic synergistic effect as the basic material,and selected rare earth ions Ho,Gd,and Er with ion radii close to Co and Ni as the research objects for doping.The influence of ...We took Co_(0.2)Ni_(0.8)-MOF-74 with bimetallic synergistic effect as the basic material,and selected rare earth ions Ho,Gd,and Er with ion radii close to Co and Ni as the research objects for doping.The influence of rare earth ion doping amount and doping type on the eNRR performance of the catalyst was explored.The experimental results show that the ammonia yield rate and Faraday efficiency doped with Co_(0.2)Ni_(0.8)-MOF-0.5Ho are the highest,reaching 1.28×10^(-10)mol·s^(-1)·cm^(-2)/39.8%,which is higher than the1.12×10^(-10)mol·s^(-1)·cm^(-2)/32.2%of Co_(0.2)Ni_(0.8)-MOF-74,and is about 14.3%/23.7%higher than that without doping,respectively.And the stability of Co_(0.2)Ni_(0.8)-MOF-0.5 Ho is good(after 80 hours of continuous testing,the current density did not significantly decrease).This is mainly due to doping,which gives Co_(0.2)Ni_(0.8)-MOF-74 a larger specific surface area and catalytic active sites.The catalyst doped at the same time has more metal cation centers,which increases the electron density of the metal centers and enhances the corresponding eNRR performance.展开更多
Objective The study aimed to investigate the impact of rare earth elements(REEs)exposure on pregnancy outcomes of in vitro fertilization-embryo transfer(IVF-ET)by analyzing samples from spouses.Methods A total of 141 ...Objective The study aimed to investigate the impact of rare earth elements(REEs)exposure on pregnancy outcomes of in vitro fertilization-embryo transfer(IVF-ET)by analyzing samples from spouses.Methods A total of 141 couples were included.Blood and follicular fluid from the wives and semen plasma from the husbands,were analyzed for REEs using inductively coupled plasma mass spectrometry(ICP-MS).Spearman's correlation coefficients and the Mann–Whitney U test were used to assess correlations and compare REE concentrations among three types of samples,respectively.Logistic models were utilized to estimate the individual REE effect on IVF-ET outcomes,while BKMR and WQS models explored the mixture of REE interaction effects on IVF-ET outcomes.Results Higher La concentration in semen(median 0.089 ng/mL,P=0.03)was associated with a lower fertilization rate.However,this effect was not observed after artificial selection intervention through intracytoplasmic sperm injection(ICSI)(P=0.27).In semen,the REEs mixture did not exhibit any significant association with clinical pregnancy.Conclusion Our study revealed a potential association between high La exposure in semen and a decline in fertilization rate,but not clinical pregnancy rate.This is the first to report REEs concentrations in follicular fluid with La,Ce,Pr,and Nd found at significantly lower concentrations than in serum,suggesting that these four REEs may not accumulate in the female reproductive system.However,at the current exposure levels,mixed REEs exposure did not exhibit reproductive toxicity.展开更多
In the process of ion-adsorption rare earth ore leaching,the migration characteristics of the wetting front in multi-hole injection holes and the influence of wetting front intersection effect on the migration distanc...In the process of ion-adsorption rare earth ore leaching,the migration characteristics of the wetting front in multi-hole injection holes and the influence of wetting front intersection effect on the migration distance of wetting fronts are still unclear.Besides,wetting front migration distance and leaching time are usually required to optimize the leaching process.In this study,wetting front migration tests of ionadsorption rare earth ores during the multi-hole fluid injection(the spacing between injection holes was 10 cm,12 cm and 14 cm)and single-hole fluid injection were completed under the constant water head height.At the pre-intersection stage,the wetting front migration laws of ion-adsorption rare earth ores during the multi-hole fluid injection and single-hole fluid injection were identical.At the postintersection stage,the intersection accelerated the wetting front migration.By using the Darcy’s law,the intersection effect of wetting fronts during the multi-hole liquid injection was transformed into the water head height directly above the intersection.Finally,based on the Green-Ampt model,a wetting front migration model of ion-adsorption rare earth ores during the multi-hole unsaturated liquid injection was established.Error analysis results showed that the proposed model can accurately simulate the infiltration process under experimental conditions.The research results enrich the infiltration law and theory of ion-adsorption rare earth ores during the multi-hole liquid injection,and this study provides a scientific basis for optimizing the liquid injection well pattern parameters of ion-adsorption rare earth in situ leaching in the future.展开更多
This study was to explore the functional mechanism of rare earth regulating soybean leaves and the characteristics and functions of differentially expressed proteins under the regulation of rare earth. In this study, ...This study was to explore the functional mechanism of rare earth regulating soybean leaves and the characteristics and functions of differentially expressed proteins under the regulation of rare earth. In this study, Dongnong 42 was used as material, and 30 mg·L^(-1) CeCl_(3) solution was sprayed on soybean leaves at the seedling stage. Tandem mass tag(TMT) quantitative proteomics technique and bioinformatics analysis were used to identify soybean leaf proteins. A total of 8 510 proteins were identified, and 127 differentially expressed proteins(DEPs) in response to rare earth cerium regulation were identified, among which 64 were upregulated and 63 were down-regulated. The gene ontology(GO) annotation indicated that DEPs were mainly involved in metabolic process, cellular process, response to stimulus, biological regulation, and response to a stimulus;DEPs in cell module categories were mainly involved in cells, cell part, organelle, membrane, membrane part, organelle par, and protein-containing complex;DEPs in molecular functional categories were mainly involved in catalytic activity, binding and antioxidant activity. Kyoto encyclopedia of genes and genomes(KEGG) pathway significantly enriched starch and sucrose metabolism, glycolysis/gluconeogenesis, galactose metabolism, pentose phosphate pathway, and MAPK signaling pathway-plant. These DEPs were mainly involved in photosynthesis, glucose metabolism and stress response. Forty-six differential protein interaction networks were identified by protein interaction network analysis. This experiment provided a reference for studies of the mechanism of rare earth cerium regulating soybean leaf function from the proteomic perspective.展开更多
Recently,high temperature(T_(c)≈80 K)superconductivity(SC)has been discovered in La_(3)Ni_(2)O_(7)(LNO)under pressure.This raises the question of whether the superconducting transition temperature T_(c) could be furt...Recently,high temperature(T_(c)≈80 K)superconductivity(SC)has been discovered in La_(3)Ni_(2)O_(7)(LNO)under pressure.This raises the question of whether the superconducting transition temperature T_(c) could be further enhanced under suitable conditions.One possible route for achieving higher T_(c) is element substitution.Similar SC could appear in the Fmmm phase of rare-earth(RE)R_(3)Ni_(2)O_(7)(RNO,R=RE element)material series under suitable pressure.The electronic properties in the RNO materials are dominated by the Ni 3d orbitals in the bilayer NiO_(2) plane.In the strong coupling limit,the SC could be fully characterized by a bilayer single 3d_(x^(2)−y^(2))-orbital t–J‖–J⊥ model.With RE element substitution from La to other RE element,the lattice constant of the Fmmm RNO material decreases,and the resultant electronic hopping integral increases,leading to stronger superexchanges between the 3d_(x^(2)−y^(2)) orbitals.Based on the slave-boson mean-field theory,we explore the pairing nature and the evolution of T_(c) in RNO materials under pressure.Consequently,it is found that the element substitution does not alter the pairing nature,i.e.,the inter-layer s-wave pairing is always favored in the superconducting RNO under pressure.However,the T_(c) increases from La to Sm,and a nearly doubled T_(c) could be realized in SmNO under pressure.This work provides evidence for possible higher T_(c) R_(3)Ni_(2)O_(7) materials,which may be realized in further experiments.展开更多
(Updated 2024)Rare earth metal production was on the rise again in 2023,jumping to 350,000 metric tons(MT)worldwide—that's up significantly from 190,000 MT in 2018,just five years prior.Demand for rare earth meta...(Updated 2024)Rare earth metal production was on the rise again in 2023,jumping to 350,000 metric tons(MT)worldwide—that's up significantly from 190,000 MT in 2018,just five years prior.Demand for rare earth metals is increasing as renewable energy becomes more important across the globe.Rare earths such as neodymium and praseodymium,which are important in clean energy applications and high-tech industries,are in the spotlight,particularly as electric vehicles and hybrid cars gain further popularity.With that in mind,it's worth being aware of rare earth metal production by country figures.Here's a look at the 11 countries that mined the most rare earths in 2023,as per the latest data from US Geological Survey(USGS).展开更多
A new paper in Nature Physics shows that by cramming lots of rare earth ions into a crystal,some will form pairs that act as highly coherent qubits,thus debunking the idea that solid-state qubits need to be super dilu...A new paper in Nature Physics shows that by cramming lots of rare earth ions into a crystal,some will form pairs that act as highly coherent qubits,thus debunking the idea that solid-state qubits need to be super dilute in an ultra-clean material to achieve long lifetimes.According to the study's authors,one of the major barriers to practical quantum computing has been how to make qubits that retain their quantum information long enough to be useful.展开更多
State Key Laboratory of Baiyun Obo Rare Earth Resource Researches and Comprehensive Utilization was approved by the Ministry of Science and Technology to be one of the national key laboratories in November 2022.The la...State Key Laboratory of Baiyun Obo Rare Earth Resource Researches and Comprehensive Utilization was approved by the Ministry of Science and Technology to be one of the national key laboratories in November 2022.The laboratory was reconstructed based on former State Key Laboratory of Baiyun Obo Rare Earth Resources Researches and Comprehensive Utilization.The key laboratory takes Baotou Research Institute of Rare Earths as the main research body,cooperating with scientific and technological strength from Lanzhou University and Changsha Research Institute of Mining and Metallurgy.It optimizes the research direction to the research on the complex coexisting resources in the Baiyun Obo mine and specializes in efficient enrichment techniques,green metallurgical technology,and high-value utilization of rare earth,fluorite,and niobium resources in Baiyun Obo.展开更多
The overall rare earth market was relatively stagnant in the first half of 2024,with mainstream rare earth prices downward..On the supply side:The production quotas for mining and separation allocated for light rare e...The overall rare earth market was relatively stagnant in the first half of 2024,with mainstream rare earth prices downward..On the supply side:The production quotas for mining and separation allocated for light rare earths in the first half of 2024 was increased compared with that in the same period of 2023;Supply of raw materials was sufficient for separation enterprises;Recycling enterprises were operated under their capacity.展开更多
State Key Laboratory of Baiyun Obo Rare Earth Resource Researches and Comprehensive Utilization was approved by the Ministry of Science and Technology to be one of the national key laboratories in November 2022.The la...State Key Laboratory of Baiyun Obo Rare Earth Resource Researches and Comprehensive Utilization was approved by the Ministry of Science and Technology to be one of the national key laboratories in November 2022.The laboratory was reconstructed based on former State Key Laboratory of Baiyun Obo Rare Earth Resources Researchesand Comprehensive Utilization.展开更多
National Key Laboratory of Baiyun Obo Rare Earth Resource Researches and Comprehensive Utilization was approved by the Ministry of Science and Technology to be one of the national key laboratories in November 2022.The...National Key Laboratory of Baiyun Obo Rare Earth Resource Researches and Comprehensive Utilization was approved by the Ministry of Science and Technology to be one of the national key laboratories in November 2022.The laboratory was reconstructed based on former State Key Laboratory of Baiyun Obo Rare Earth Resources Researches and Comprehensive Utilization.The key laboratory takes Baotou Research Institute of Rare Earths as the main research body,cooperating with scientific and technological strength from Lanzhou University and Changsha Research Institute of Mining and Metallurgy.展开更多
The chemical formula for rare earth-ferro nitrides is R_(x)Fe_(y)N_(z),where R represents a rare earth element.Anisotropic rare earth-ferro nitrides include two types of materials with different chemical compositions ...The chemical formula for rare earth-ferro nitrides is R_(x)Fe_(y)N_(z),where R represents a rare earth element.Anisotropic rare earth-ferro nitrides include two types of materials with different chemical compositions and crystal structures:(1) Nd(Fe,M)_(12)N_(x) or Pr(Fe,M)_(12)N_(x),where M=Ti,V,Mo,etc.,having a ThMn_(12)-type tetragonal crystal structure,commonly referred to as Neodymium-Ferro-Nitrogen (NdFeN);(2) Sm_(2)Fe_(17)N_(x), having a Th_(2)Zn_(17)-type rhombohedral crystal structure,abbreviated as Samarium-Ferro-Nitrogen (SmFeN).The academic community refers to these two types of materials collectively as rare earth-ferro nitrides.展开更多
The hot deformation behavior of Mn18Cr18N and Mn18Cr18N+Ce high nitrogen austenitic stainless steels at 1173-1473 K and 0.01-1 s^(-1) were investigated by thermal compression tests.The influence mechanism of Ce on the...The hot deformation behavior of Mn18Cr18N and Mn18Cr18N+Ce high nitrogen austenitic stainless steels at 1173-1473 K and 0.01-1 s^(-1) were investigated by thermal compression tests.The influence mechanism of Ce on the hot deformation behavior was analyzed by Ce-containing inclusions and segregation of Ce.The results show that after the addition of Ce,large,angular,hard,and brittle inclusions(TiN-Al_(2)O_(3),TiN,and Al_(2)O_(3)) can be modified to fine and dispersed Ce-containing inclusions(Ce-Al-O-S and TiN-Ce-Al-O-S).During the solidification,Ce-containing inclusions can be used as heterogeneous nucleation particles to refine as-cast grains.During the hot deformation,Ce-containing inclusions can pin dislocation movement and grain boundary migration,induce dynamic recrystallization(DRX)nucleation,and avoid the formation and propagation of micro cracks and gaps.In addition,during the solidification,Ce atoms enrich at the front of solid-li-quid interface,resulting in composition supercooling and refining the secondary dendrites.Similarly,during the hot deformation,Ce atoms tend to segregate at the boundaries of DRX grains,inhibiting the growth of grains.Under the synergistic effect of Ce-containing inclusions and Ce segregation,although the hot deformation resistance and hot deformation activation energy are improved,DRX is more likely to occur and the size of DRX grains is significantly refined,and the problem of hot deformation cracking can be alleviated.Finally,the microhardness of the samples was measured.The results show that compared with as-cast samples,the microhardness of hot-deformed samples increases signific-antly,and with the increase of DRX degree,the microhardness decreases continuously.In addition,Ce can affect the microhardness of Mn18Cr18N steel by affecting as-cast and hot deformation microstructures.展开更多
In this study,we successfully developed a low RE containing Mg-3Y-2Gd-1Nd-0.5Zr(wt%)alloy with high strength-ductility synergy by combined processes of hot extrusion,hot rolling and ageing.This alloy exhibits an excel...In this study,we successfully developed a low RE containing Mg-3Y-2Gd-1Nd-0.5Zr(wt%)alloy with high strength-ductility synergy by combined processes of hot extrusion,hot rolling and ageing.This alloy exhibits an excellent strength-ductility balance(UTS of 345±2.0 MPa,TYS of 301±5.0 MPa and EL of 9.2±1.9%),which is better than that of many Mg-RE wrought alloys with higher RE concentration and even comparable to that of 6061 Al wrought alloy.A long-range chain-like structure consisting ofβphase,βH phase,βM phase and zig-zag atomic columns is observed for the first time in the studied alloy.The combined process of hot extrusion and hot rolling boosts the formation of deformed grains and low angle grain boundaries,and makes the deformed grains dominate in the alloy strengthening.Under this circumstance,the following ageing generates a novel heterogeneous structure comprising the long-range chain-like structure with broad interparticle spacing and the spacious precipitate-free zones in the deformed grains,which plays a key role in the concurrent strengthening and toughening of the alloy.The present study demonstrates that the deformed grains with long-range chain-like structures and precipitate-free zones is desirable microstructure for the low RE containing Mg alloys to achieve high strength-ductility synergy.展开更多
To investigate the effect of rare earth on size and distribution of TiB2 phase in aluminum alloy refiner,Al-5Ti-1B-RE master alloy was fabricated,and its microstructure and phase constitutions were investigated by the...To investigate the effect of rare earth on size and distribution of TiB2 phase in aluminum alloy refiner,Al-5Ti-1B-RE master alloy was fabricated,and its microstructure and phase constitutions were investigated by the combination of first principles calculations and experimental investigation.The calculated results reveal that Ce has the most effective modification ability due to the most positive adsorption energy and the largest charge transfer value compared with other rare earth elements.Results of experimental investigation indicate that the addition of rare earth in the Al-5Ti-1B alloys can greatly refine the particle size of TiB2,improve the distribution of particles and lead to better refinement effect than that of the Al-5Ti-1B alloys without rare earth.Moreover,Ce has the best optimization effect,which agrees well with the calculated results.展开更多
基金supported by National Key Research and Development Program of China[2023YFB4605800]National Natural Science Foundation of China[51935014,52165043]+3 种基金JiangXi Provincial Natural Science Foundation of China[20224ACB204013,20224ACB214008]Jiangxi Provincial Cultivation Program for Academic and Technical Leaders of Major Subjects[20225BCJ23008]Anhui Provincial Natural Science Foundation[2308085ME171]The University Synergy Innovation Program of Anhui Province[GXXT-2023-025,GXXT-2023-026].
文摘Biomedical magnesium(Mg)alloys have garnered significant attention because of their unique biodegradability,favorable biocompatibility,and suitable mechanical properties.The incorporation of rare earth(RE)elements,with their distinct physical and chemical properties,has greatly contributed to enhancing the mechanical performance,degradation behavior,and biological performance of biomedical Mg alloys.Currently,a series of RE-Mg alloys are being designed and investigated for orthopedic implants and cardiovascular stents,achieving substantial and encouraging research progress.In this work,a comprehensive summary of the state-of-the-art in biomedical RE-Mg alloys is provided.The physiological effects and design standards of RE elements in biomedical Mg alloys are discussed.Particularly,the degradation behavior and mechanical properties,including their underlying action are studied in-depth.Furthermore,the preparation techniques and current application status of RE-Mg alloys are reviewed.Finally,we address the ongoing challenges and propose future prospects to guide the development of high-performance biomedical Mg-RE alloys.
基金supported by the Natural Science Foundation of Shandong Province(No.ZR2022MD114)the Project of Global Earth Observation on Asian Delta and Estuary Corresponding to Anthropogenic Impacts and Climate Changes(No.2019YFE0127200).
文摘The small muddy areas developed in the southern Shandong Peninsula have attracted increasing attention from researchers because of complex changes in sediment sources driven by sea-level fluctuations and land-sea interactions since the late Pleistocene.This study investigates the evolution of sediment sources and their responses to environmental changes since the late Pleistocene,using core WHZK01 collected from the nearshore muddy area in southern Weihai for rare earth element(REE)analysis.In doing so,this work highlights the changing patterns of material sources and the primary control factors.The results reveal that the sedimentary deposits in core WHZK01 exhibit distinct terrestrial characteristics.Discriminant function analysis(F_(D))and source discrimination dia-grams both suggest that the primary sources of these deposits are the Yellow River and adjacent small and medium-sized rivers,although the sources vary among different sedimentary units.Furthermore,the DU3 layer(17.82-25.10 m)displays typical riverine sedimentation,dominated by terrestrial detrital input,primarily from the local rivers,namely the Huanglei and Muzhu Rivers.The material in the DU2 layer(14.91-17.82 m)is mainly influenced by a mixture of the Qinglong and Yellow Rivers.The DU1 layer(0-14.91 m)is influenced by sea-level changes during the Holocene,with the Yellow River being the primary source,although there is also some input from local rivers.The changes in sea level during the Holocene and the input of Yellow River material carried by the coastal currents of the Yellow Sea are identified as the main controlling factors for the changes in material sources in the study area since the late Pleistocene,with small and mediumsized rivers also exerting some influence on the material sources.The above mentioned findings not only contribute to a better understanding of the source-sink systems of the Yellow River and adjacent small and mediumsized rivers but also deepen our understanding of the late Quaternary land-sea interactions in the Shandong Peninsula.
基金Funded in part by the Natural Science Foundation of China(No.22279096)the Guangdong Basic and Applied Basic Research Foundation(No.2021B1515120072)。
文摘Co/NC catalysts modified with rare earth elements(La,Ce,Pr)were prepared by pyrolysis of rare earth elements doped ZIF-67.The experimental results show that the modification of rare earth elements significantly improves the ammonia decomposition activity and stability of the Co/NC catalyst.The La-Co/NC catalyst can achieve an 82.3%ammonia decomposition and 18.4 mmol hydrogen production rate at 550℃with a GHSV of 20000 cm^(3)·h^(-1).Furthermore,no obvious performance degradation is observed after 72 hours of reaction for all rare earth elements modified catalysts.It is shown that the modification of rare earth elements significantly improves the surface alkalinity and surface chemical state of the catalyst,and thus improves the ammonia decomposition activity of the catalyst.A new type of high-performance ammonia decomposition Co-based catalyst is proposed,and the promoting effect of rare earth elements on the activity of ammonia decomposition is revealed.
基金the financial support from the National Natural Science Foundation of China(Nos.51572061,51621091,and 51321061)the Heilongjiang Touyan Team Program。
文摘The A_(2)B_(2)O_(7)-type rare earth zirconate compounds have been considered as promising candidates for thermal barrier coating(TBC) materials because of their low sintering rate,improved phase stability,and reduced thermal conductivity in contrast with the currently used yttria-partially stabilized zirconia (YSZ) in high operating temperature environments.This review summarizes the recent progress on rare earth zirconates for TBCs that insulate high-temperature gas from hot-section components in gas turbines.Based on the first principles,molecular dynamics,and new data-driven calculation approaches,doping and high-entropy strategies have now been adopted in advanced TBC materials design.In this paper,the solid-state heat transfer mechanism of TBCs is explained from two aspects,including heat conduction over the full operating temperature range and thermal radiation at medium and high temperature.This paper also provides new insights into design considerations of adaptive TBC materials,and the challenges and potential breakthroughs are further highlighted for extreme environmental applications.Strategies for improving thermophysical performance are proposed in two approaches:defect engineering and material compositing.
基金Funded by National Natural Science Foundation of China (No.52074218)。
文摘A hydrotalcite(layered double hydroxide, LDH) inhibitor which is suitable for the whole process of coal spontaneous combustion and a LDH inhibitor containing rare earth lanthanum elements were prepared. The inhibition effect and mechanism were analyzed by scanning electron microscopy(SEM),X-ray diffraction(XRD), thermal performance analysis, in-situ diffuse reflectance infrared spectroscopy and temperature-programmed experiment. The results have shown that the inhibitor containing lanthanum can play a good inhibitory role in every stage of coal oxidation. During the slow oxidation of coal samples, the inhibitor containing lanthanum ions can slow down the oxidation process of coal and increase the initial temperature of coal spontaneous combustion. At the same time, because the hydroxyl groups in LDHs are connected with-COO-groups on the coal surface through hydrogen bonds, the stability of coal is improved. With the increase of temperature, LDHs can remove interlayer water molecules and reduce the surface temperature of coal. CO release rate of coal samples decreases significantly after adding inhibitor containing lanthanum element, and the maximum inhibition rate of the inhibitor is 58.1%.
基金Funded by the Central Government Guides Local Funds for Scientific and Technological Development(No.2023ZYQ004)the Hunan Provincial Natural Science Foundation of China(No.2021JJ50036)the Hunan Provincial Key Research and Development Plan(No.2023GK2083)。
文摘We took Co_(0.2)Ni_(0.8)-MOF-74 with bimetallic synergistic effect as the basic material,and selected rare earth ions Ho,Gd,and Er with ion radii close to Co and Ni as the research objects for doping.The influence of rare earth ion doping amount and doping type on the eNRR performance of the catalyst was explored.The experimental results show that the ammonia yield rate and Faraday efficiency doped with Co_(0.2)Ni_(0.8)-MOF-0.5Ho are the highest,reaching 1.28×10^(-10)mol·s^(-1)·cm^(-2)/39.8%,which is higher than the1.12×10^(-10)mol·s^(-1)·cm^(-2)/32.2%of Co_(0.2)Ni_(0.8)-MOF-74,and is about 14.3%/23.7%higher than that without doping,respectively.And the stability of Co_(0.2)Ni_(0.8)-MOF-0.5 Ho is good(after 80 hours of continuous testing,the current density did not significantly decrease).This is mainly due to doping,which gives Co_(0.2)Ni_(0.8)-MOF-74 a larger specific surface area and catalytic active sites.The catalyst doped at the same time has more metal cation centers,which increases the electron density of the metal centers and enhances the corresponding eNRR performance.
基金supported by the National Key Research and Development Program of China(2022YFC2702900 and 2021YFC2701103)National Natural Science Foundation of China(82171654)。
文摘Objective The study aimed to investigate the impact of rare earth elements(REEs)exposure on pregnancy outcomes of in vitro fertilization-embryo transfer(IVF-ET)by analyzing samples from spouses.Methods A total of 141 couples were included.Blood and follicular fluid from the wives and semen plasma from the husbands,were analyzed for REEs using inductively coupled plasma mass spectrometry(ICP-MS).Spearman's correlation coefficients and the Mann–Whitney U test were used to assess correlations and compare REE concentrations among three types of samples,respectively.Logistic models were utilized to estimate the individual REE effect on IVF-ET outcomes,while BKMR and WQS models explored the mixture of REE interaction effects on IVF-ET outcomes.Results Higher La concentration in semen(median 0.089 ng/mL,P=0.03)was associated with a lower fertilization rate.However,this effect was not observed after artificial selection intervention through intracytoplasmic sperm injection(ICSI)(P=0.27).In semen,the REEs mixture did not exhibit any significant association with clinical pregnancy.Conclusion Our study revealed a potential association between high La exposure in semen and a decline in fertilization rate,but not clinical pregnancy rate.This is the first to report REEs concentrations in follicular fluid with La,Ce,Pr,and Nd found at significantly lower concentrations than in serum,suggesting that these four REEs may not accumulate in the female reproductive system.However,at the current exposure levels,mixed REEs exposure did not exhibit reproductive toxicity.
基金This research was funded by the National Natural Science Foundation of China(Grant No.52174113)the Young Jinggang Scholars Award Program in Jiangxi Province,China(Grant No.QNJG2018051)the“Thousand Talents”of Jiangxi Province,China(Grant No.jxsq2019201043).
文摘In the process of ion-adsorption rare earth ore leaching,the migration characteristics of the wetting front in multi-hole injection holes and the influence of wetting front intersection effect on the migration distance of wetting fronts are still unclear.Besides,wetting front migration distance and leaching time are usually required to optimize the leaching process.In this study,wetting front migration tests of ionadsorption rare earth ores during the multi-hole fluid injection(the spacing between injection holes was 10 cm,12 cm and 14 cm)and single-hole fluid injection were completed under the constant water head height.At the pre-intersection stage,the wetting front migration laws of ion-adsorption rare earth ores during the multi-hole fluid injection and single-hole fluid injection were identical.At the postintersection stage,the intersection accelerated the wetting front migration.By using the Darcy’s law,the intersection effect of wetting fronts during the multi-hole liquid injection was transformed into the water head height directly above the intersection.Finally,based on the Green-Ampt model,a wetting front migration model of ion-adsorption rare earth ores during the multi-hole unsaturated liquid injection was established.Error analysis results showed that the proposed model can accurately simulate the infiltration process under experimental conditions.The research results enrich the infiltration law and theory of ion-adsorption rare earth ores during the multi-hole liquid injection,and this study provides a scientific basis for optimizing the liquid injection well pattern parameters of ion-adsorption rare earth in situ leaching in the future.
基金Supported by the National Natural Science Foundation of China(31471440)。
文摘This study was to explore the functional mechanism of rare earth regulating soybean leaves and the characteristics and functions of differentially expressed proteins under the regulation of rare earth. In this study, Dongnong 42 was used as material, and 30 mg·L^(-1) CeCl_(3) solution was sprayed on soybean leaves at the seedling stage. Tandem mass tag(TMT) quantitative proteomics technique and bioinformatics analysis were used to identify soybean leaf proteins. A total of 8 510 proteins were identified, and 127 differentially expressed proteins(DEPs) in response to rare earth cerium regulation were identified, among which 64 were upregulated and 63 were down-regulated. The gene ontology(GO) annotation indicated that DEPs were mainly involved in metabolic process, cellular process, response to stimulus, biological regulation, and response to a stimulus;DEPs in cell module categories were mainly involved in cells, cell part, organelle, membrane, membrane part, organelle par, and protein-containing complex;DEPs in molecular functional categories were mainly involved in catalytic activity, binding and antioxidant activity. Kyoto encyclopedia of genes and genomes(KEGG) pathway significantly enriched starch and sucrose metabolism, glycolysis/gluconeogenesis, galactose metabolism, pentose phosphate pathway, and MAPK signaling pathway-plant. These DEPs were mainly involved in photosynthesis, glucose metabolism and stress response. Forty-six differential protein interaction networks were identified by protein interaction network analysis. This experiment provided a reference for studies of the mechanism of rare earth cerium regulating soybean leaf function from the proteomic perspective.
基金supported by the National Natural Science Foundation of China(Grant Nos.12234016,12174317,and 12074031)the New Cornerstone Science Foundation.
文摘Recently,high temperature(T_(c)≈80 K)superconductivity(SC)has been discovered in La_(3)Ni_(2)O_(7)(LNO)under pressure.This raises the question of whether the superconducting transition temperature T_(c) could be further enhanced under suitable conditions.One possible route for achieving higher T_(c) is element substitution.Similar SC could appear in the Fmmm phase of rare-earth(RE)R_(3)Ni_(2)O_(7)(RNO,R=RE element)material series under suitable pressure.The electronic properties in the RNO materials are dominated by the Ni 3d orbitals in the bilayer NiO_(2) plane.In the strong coupling limit,the SC could be fully characterized by a bilayer single 3d_(x^(2)−y^(2))-orbital t–J‖–J⊥ model.With RE element substitution from La to other RE element,the lattice constant of the Fmmm RNO material decreases,and the resultant electronic hopping integral increases,leading to stronger superexchanges between the 3d_(x^(2)−y^(2)) orbitals.Based on the slave-boson mean-field theory,we explore the pairing nature and the evolution of T_(c) in RNO materials under pressure.Consequently,it is found that the element substitution does not alter the pairing nature,i.e.,the inter-layer s-wave pairing is always favored in the superconducting RNO under pressure.However,the T_(c) increases from La to Sm,and a nearly doubled T_(c) could be realized in SmNO under pressure.This work provides evidence for possible higher T_(c) R_(3)Ni_(2)O_(7) materials,which may be realized in further experiments.
文摘(Updated 2024)Rare earth metal production was on the rise again in 2023,jumping to 350,000 metric tons(MT)worldwide—that's up significantly from 190,000 MT in 2018,just five years prior.Demand for rare earth metals is increasing as renewable energy becomes more important across the globe.Rare earths such as neodymium and praseodymium,which are important in clean energy applications and high-tech industries,are in the spotlight,particularly as electric vehicles and hybrid cars gain further popularity.With that in mind,it's worth being aware of rare earth metal production by country figures.Here's a look at the 11 countries that mined the most rare earths in 2023,as per the latest data from US Geological Survey(USGS).
文摘A new paper in Nature Physics shows that by cramming lots of rare earth ions into a crystal,some will form pairs that act as highly coherent qubits,thus debunking the idea that solid-state qubits need to be super dilute in an ultra-clean material to achieve long lifetimes.According to the study's authors,one of the major barriers to practical quantum computing has been how to make qubits that retain their quantum information long enough to be useful.
文摘State Key Laboratory of Baiyun Obo Rare Earth Resource Researches and Comprehensive Utilization was approved by the Ministry of Science and Technology to be one of the national key laboratories in November 2022.The laboratory was reconstructed based on former State Key Laboratory of Baiyun Obo Rare Earth Resources Researches and Comprehensive Utilization.The key laboratory takes Baotou Research Institute of Rare Earths as the main research body,cooperating with scientific and technological strength from Lanzhou University and Changsha Research Institute of Mining and Metallurgy.It optimizes the research direction to the research on the complex coexisting resources in the Baiyun Obo mine and specializes in efficient enrichment techniques,green metallurgical technology,and high-value utilization of rare earth,fluorite,and niobium resources in Baiyun Obo.
文摘The overall rare earth market was relatively stagnant in the first half of 2024,with mainstream rare earth prices downward..On the supply side:The production quotas for mining and separation allocated for light rare earths in the first half of 2024 was increased compared with that in the same period of 2023;Supply of raw materials was sufficient for separation enterprises;Recycling enterprises were operated under their capacity.
文摘State Key Laboratory of Baiyun Obo Rare Earth Resource Researches and Comprehensive Utilization was approved by the Ministry of Science and Technology to be one of the national key laboratories in November 2022.The laboratory was reconstructed based on former State Key Laboratory of Baiyun Obo Rare Earth Resources Researchesand Comprehensive Utilization.
文摘National Key Laboratory of Baiyun Obo Rare Earth Resource Researches and Comprehensive Utilization was approved by the Ministry of Science and Technology to be one of the national key laboratories in November 2022.The laboratory was reconstructed based on former State Key Laboratory of Baiyun Obo Rare Earth Resources Researches and Comprehensive Utilization.The key laboratory takes Baotou Research Institute of Rare Earths as the main research body,cooperating with scientific and technological strength from Lanzhou University and Changsha Research Institute of Mining and Metallurgy.
文摘The chemical formula for rare earth-ferro nitrides is R_(x)Fe_(y)N_(z),where R represents a rare earth element.Anisotropic rare earth-ferro nitrides include two types of materials with different chemical compositions and crystal structures:(1) Nd(Fe,M)_(12)N_(x) or Pr(Fe,M)_(12)N_(x),where M=Ti,V,Mo,etc.,having a ThMn_(12)-type tetragonal crystal structure,commonly referred to as Neodymium-Ferro-Nitrogen (NdFeN);(2) Sm_(2)Fe_(17)N_(x), having a Th_(2)Zn_(17)-type rhombohedral crystal structure,abbreviated as Samarium-Ferro-Nitrogen (SmFeN).The academic community refers to these two types of materials collectively as rare earth-ferro nitrides.
基金supported by the National Natural Science Foundation of China(No.51874084)the Fundamental Research Funds for the Central Universities(No.2125026)。
文摘The hot deformation behavior of Mn18Cr18N and Mn18Cr18N+Ce high nitrogen austenitic stainless steels at 1173-1473 K and 0.01-1 s^(-1) were investigated by thermal compression tests.The influence mechanism of Ce on the hot deformation behavior was analyzed by Ce-containing inclusions and segregation of Ce.The results show that after the addition of Ce,large,angular,hard,and brittle inclusions(TiN-Al_(2)O_(3),TiN,and Al_(2)O_(3)) can be modified to fine and dispersed Ce-containing inclusions(Ce-Al-O-S and TiN-Ce-Al-O-S).During the solidification,Ce-containing inclusions can be used as heterogeneous nucleation particles to refine as-cast grains.During the hot deformation,Ce-containing inclusions can pin dislocation movement and grain boundary migration,induce dynamic recrystallization(DRX)nucleation,and avoid the formation and propagation of micro cracks and gaps.In addition,during the solidification,Ce atoms enrich at the front of solid-li-quid interface,resulting in composition supercooling and refining the secondary dendrites.Similarly,during the hot deformation,Ce atoms tend to segregate at the boundaries of DRX grains,inhibiting the growth of grains.Under the synergistic effect of Ce-containing inclusions and Ce segregation,although the hot deformation resistance and hot deformation activation energy are improved,DRX is more likely to occur and the size of DRX grains is significantly refined,and the problem of hot deformation cracking can be alleviated.Finally,the microhardness of the samples was measured.The results show that compared with as-cast samples,the microhardness of hot-deformed samples increases signific-antly,and with the increase of DRX degree,the microhardness decreases continuously.In addition,Ce can affect the microhardness of Mn18Cr18N steel by affecting as-cast and hot deformation microstructures.
基金This work is supported by Beijing Municipal Natural Science Foundation(2202004)National Natural Science Foundation of China(51801048)Basic Research Fund for Newly Enrolled Teachers.
文摘In this study,we successfully developed a low RE containing Mg-3Y-2Gd-1Nd-0.5Zr(wt%)alloy with high strength-ductility synergy by combined processes of hot extrusion,hot rolling and ageing.This alloy exhibits an excellent strength-ductility balance(UTS of 345±2.0 MPa,TYS of 301±5.0 MPa and EL of 9.2±1.9%),which is better than that of many Mg-RE wrought alloys with higher RE concentration and even comparable to that of 6061 Al wrought alloy.A long-range chain-like structure consisting ofβphase,βH phase,βM phase and zig-zag atomic columns is observed for the first time in the studied alloy.The combined process of hot extrusion and hot rolling boosts the formation of deformed grains and low angle grain boundaries,and makes the deformed grains dominate in the alloy strengthening.Under this circumstance,the following ageing generates a novel heterogeneous structure comprising the long-range chain-like structure with broad interparticle spacing and the spacious precipitate-free zones in the deformed grains,which plays a key role in the concurrent strengthening and toughening of the alloy.The present study demonstrates that the deformed grains with long-range chain-like structures and precipitate-free zones is desirable microstructure for the low RE containing Mg alloys to achieve high strength-ductility synergy.
基金supported by the Natural Science Foundation of Inner Mongolia Autonomous Region(Grant No.2021MS05049)the Youth Fund Project of State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization(Grant No.2021Z2348)the Project of China North Rare Earth(Group)High-tech Co.,Ltd.(Grant No.2020H2177).
文摘To investigate the effect of rare earth on size and distribution of TiB2 phase in aluminum alloy refiner,Al-5Ti-1B-RE master alloy was fabricated,and its microstructure and phase constitutions were investigated by the combination of first principles calculations and experimental investigation.The calculated results reveal that Ce has the most effective modification ability due to the most positive adsorption energy and the largest charge transfer value compared with other rare earth elements.Results of experimental investigation indicate that the addition of rare earth in the Al-5Ti-1B alloys can greatly refine the particle size of TiB2,improve the distribution of particles and lead to better refinement effect than that of the Al-5Ti-1B alloys without rare earth.Moreover,Ce has the best optimization effect,which agrees well with the calculated results.
