SiO2 in calcium aluminate slag exists in the form of γ-2CaO·SiO2 which is more stable than β-2CaO·SiO2. However, it is decomposed by sodium carbonate solution during leaching process, leading to the second...SiO2 in calcium aluminate slag exists in the form of γ-2CaO·SiO2 which is more stable than β-2CaO·SiO2. However, it is decomposed by sodium carbonate solution during leaching process, leading to the secondary reaction. The extent of secondary reaction and reaction mechanism of calcium aluminate slag were studied using XRD. The results show that the decomposition rate of γ-2CaO·SiO2 increases with the increase in leaching time and sodium carbonate concentration. The main products of secondary reaction are the mixture of hydrogarnet and sodium hydrate alumina-silicate. SiO2 concentration rises firstly and then drops with the increase of leaching temperature. XRD results indicate that the stable product of secondary reaction at low temperature is hydrogarnet. But hydrogarnet is transformed into sodium hydrate alumina-silicate at high temperature.展开更多
Mono-substituted heterocyclic ketene aminals are formed by the reaction of 1-methyl-2-methylthio-imidazoline with active methylene compounds containinq an acetyl or benzoyl group by the elimination of both a methylthi...Mono-substituted heterocyclic ketene aminals are formed by the reaction of 1-methyl-2-methylthio-imidazoline with active methylene compounds containinq an acetyl or benzoyl group by the elimination of both a methylthio and an acyl group.This is resulted by the secondary reactio of the produced methanethiol to attack the more active carbonyl group.展开更多
The revolution in information and communication technology has brought huge technical benefits and wealth, but has created a major global problem： the generation of vast amounts of electronic waste, or e-waste throug...The revolution in information and communication technology has brought huge technical benefits and wealth, but has created a major global problem： the generation of vast amounts of electronic waste, or e-waste through product obsolesce. The challenge in managing e-waste will be in developing sustainable recycling tech- nologies that are able to address the volume and complexity of this waste using cost effective and ecologically sen-sitive methods. In this study, the capability or microorganism metabolic acids in dissolving the metallic tractions from waste printed circuit boards was examined. Several factors were considered in the examination of the activityof the acids-including secondary reactions, solution pH, temperature and the nature of ligands in solutions （or bioacid constituents）. The leaching tests were cgnducted ex-situ, using synthetic organic acids. Leaching was performed for periods of up to 6 hat 70-90 ℃ and 1000 r-min-1.展开更多
We report a fresh and simpler approach to the modelling of the kinetics of the polymerization of Hb SS in sickle cell patients that couples the kinetics and the hydrodynamics of blood flow in mechanistic understanding...We report a fresh and simpler approach to the modelling of the kinetics of the polymerization of Hb SS in sickle cell patients that couples the kinetics and the hydrodynamics of blood flow in mechanistic understanding of the process. The well-known two-step autocatalytic reaction scheme was used for the polymerization reaction with the assumption of simpler first-order reaction scheme for each stage. In addition, the forces acting on a particle in motion were also introduced to account for compelling settling of the red cells that lead to vessel occlusion (vaso-occlusion). A first attempt on the prediction of vessel blockage was made using this novel model. The time for the onset of the polymerization reaction was derived from hydrodynamic considerations and kinetics while the kinetic rate constants were obtained from the autocatalytic nature of the reaction. Experimental data for model validation were obtained from recruited SS patients and in vitro data of Hofrichter. Over 100 volunteers were recruited for participation in this work but less than 40% met the inclusion criteria. Participants were of age range 13 - 43 (with a mean of 26 ± 8 years) for SCD patients and 18 - 43 (with a mean of 28 ± 7 years) for control participants. Blood indices and Transcranial Doppler (TCD) test parameters of all participants were the principal parameters used for model validation. Constant k2/k1 ratios was obtained for individual in vivo/in vitro system. This ratio is unique for any individual, independent on protein sequence and also suggests the degree of expression of the symptoms of Sickle Cell Disease (SCD) with higher values reflecting greater propensity to pain crisis. Delay time, tD, was found to have an inverse relationship with the kinetic constant for the residual reaction, k1. Therefore, long delay times calculated, offer insight on why SCD patients are not in perpetual crises because enough time is provided the cells to escape microcirculation while keeping the residual reaction at the minimum. Sensitivity analysis was carried out to obviate the limitations encountered in the course of the work. Results showed the onset of occlusion to be most sensitive to the diameter of the blood vessel. 展开更多
β-2CaO＇SiO2 was obtained with analytical grade reagents. Polyethylene glycol （PEG）, sodium polyacrylate （PAAS） and their mixture were used to inhibit the decomposition of β-2CaO·SiO2 in sodium aluminate so...β-2CaO＇SiO2 was obtained with analytical grade reagents. Polyethylene glycol （PEG）, sodium polyacrylate （PAAS） and their mixture were used to inhibit the decomposition of β-2CaO·SiO2 in sodium aluminate solution. The potential of solid-liquid interface and the adsorption mechanism were studied by the methods of Zeta potential measurement and XPS. The results indicate that PEG and PAAS have synergistic effect on the inhibition of secondary reaction. The inhibitory effect is the best when the volume ratio of PAAS to PEG is 1：1 and the total concentration is 12.5 mg/L. PAAS adsorbs on the surface of β-2CaO-SiO2 by the formation of --COOCa coordinate bond, and the negative charge enters into Stem layer, which results in the decrease of particle potential and the obvious change of binding energy of Ca 2p, Si 2p and O Is. PEG only physically adsorbs on the surface ofβ-2CaO·SiO2, and had little effect on particle potential and binding energy of Ca 2p, Si 2p and O Is.展开更多
It is essential for alumina production by alkaline process to know the behavior of minerals containing Al and Si in basic solution,and the behavior of SiO2 in the process of clinker leaching is an important portion. T...It is essential for alumina production by alkaline process to know the behavior of minerals containing Al and Si in basic solution,and the behavior of SiO2 in the process of clinker leaching is an important portion. To study the behavior of SiO2 in the process of high concentration clinker leaching,experiments were carried out in home-made reactors. The results indicate that factors,such as temperature,time,Al2O3 concentration,as well as SiO2 concentration,have profound impact on the SiO2 and Al2O3 concen-tration of pregnant liquor during the high concentration leaching. However,sodium carbonate and free caustic soda concentrations have no remarkable effect on it,thus they are the secondary factors compared with Al2O3 concentration. The concentration of SiO2 in the pregnant liquor could be reduced to a lower level when the major effect parameters of this process are controlled properly.展开更多
Objective: Whether early massive bronchoalveolar lavage can remove the harmful substances from the lungs injured with smoke inhalation remains uncertain. This study was designed to observe the effects of early massive...Objective: Whether early massive bronchoalveolar lavage can remove the harmful substances from the lungs injured with smoke inhalation remains uncertain. This study was designed to observe the effects of early massive bronchoalveolar lavage fluid (BALF) on the healthy lungs in rats. Methods: Mongrel dogs were inflicted with severe smoke inhalation injury. The injured lungs were lavaged with large amount of normal saline in the first hour after injury and the BALF was collected. The BALF was injected into the healthy lungs of 30 rats (group C) in the dosage of 5 ml/kg. The functions and pathological changes of the lungs were observed 24 h after perfusion with the BALF. The data were compared with those of 23 rats (group B) whose lungs were perfused with the BALF collected from normal dogs and those of 21 rats (group A) whose lungs were perfused with normal saline. Results: The mortality rate 24 h after lung perfusion was higher in group C than in groups A and B. The survivors of group C exhibited fluctuation of respiratory rate (RR), remarkable decrease of PaO 2, significantly higher content of lung water, decrease of total static pulmonary compliance and pulmonary expansion index, and increasse of inflammatory cytokines in the tissues of lungs. Only slight mechanic obstructive effect on the airway was observed in rats of group A and B. The pathological changes of the lungs of the rats in group C were similar to those of the dogs with actual smoke inhalation injury. Conclusion: Our findings indicate that the BALF collected from dogs with acute severe smoke inhalation injury in the early stage after injury injured the normal lungs of rats with the bioactive substances in the BALF. These findings show us that it is a valuable therapeutic procedure to apply massive bronchoalveolar fluid lavage in the early stage after inhalation injury.展开更多
The eme reactions of α-ionones with singlet oxygen were examined to ascertain the effect of secondary Me interaction between the reactants on the reaction regiospecificity. Exclusive formation of 3-hydroxy-γ-ionones...The eme reactions of α-ionones with singlet oxygen were examined to ascertain the effect of secondary Me interaction between the reactants on the reaction regiospecificity. Exclusive formation of 3-hydroxy-γ-ionones found in the reactions reveals favorable interaction of singlet oxygen with the acyclic α-hydrogen atom,On the other hand,no formation of 3-hy- droxy-β-ionones implies that the steric requirement was not met for the bond formation between zwitterionic perepoxide with C_1-hydrogen in the process.The MMP21 and MNDO calculations indicate minus value of the secondary interaction energy for the aeyelie α-hydrogen abstrac- tion and a repulsion between the oxygen with C_1-hydrogen atom.Twisting tilting of the double bond may account for favorable attack of singlet oxygen on C_3.An explanation of the excellent regiospecificity was addressed and placed in proper mechanic prospective.展开更多
The negative secondary ion mass spectrometry,in combination with the stereoselective derivatizations with substituted boronic acid RB(OH)_2,was used in the analysis of fourteen oligosac- charides.The mass spectra of t...The negative secondary ion mass spectrometry,in combination with the stereoselective derivatizations with substituted boronic acid RB(OH)_2,was used in the analysis of fourteen oligosac- charides.The mass spectra of the derivatives provide information on their linkage Positions and iso- merism of the individual monoscaccharide units.The results indicated that among the derivatives of the oligosaccharides analyzed,those with 1—4 and 1—6 linkages all presented the ion peaks at m/z 287,sometimes one more peak at m/z 449.Furthermore,a relationship was found between the linkage positions and the intensity orders of the derivative ions.Finally,the derivatives of the disaccharides with a galactose presented an intense ion peak at m/z 347,and those of oligosaccharides with 1—6 linkage to a galactose at terminal presented the ion at m/z 317.In the case of oligosaccharides with a fructose residue,characteristic ion of m/z 155 was produced.The conditions of stereoselective derivatizations and mass spectrometry were studied,in order to obtain a better reproducibility of the mass spectra.展开更多
This study investigated the characteristics of pyrolysis for waste tire particles in the newly developed fixed-bed reactor with internals that are a central gas collection channel mounted inside reactor.And a few meta...This study investigated the characteristics of pyrolysis for waste tire particles in the newly developed fixed-bed reactor with internals that are a central gas collection channel mounted inside reactor.And a few metallic plates vertically welded on the internal wall of the reactors and extending to the region closing their central gas collection pipe walls.Experiments were conducted in two laboratory fixed bed reactors with or without the internals.The results shown that employing internals produced more light oil at externally heating temperatures above 700℃due to the inhibited secondary reactions in the reactor.The oil from the reactor with internals contained more aliphatic hydrocarbons and fewer aromatic hydrocarbons,leading to its higher H/C atomic ratios as for crude petroleum oil.The char yield was relatively stable for two beds and showed the higher heating values(HHVs)of about 23 MJ/kg.The gaseous product of pyrolysis mainly consisted of H2 and CH4,but the use of internals led to less pyrolysis gas through its promotion of oil production.展开更多
基金Project(51104053)supported by the National Natural Science Foundation of ChinaProject(E2012208047)supported by the Natural Science Foundation of Hebei Province,China
文摘SiO2 in calcium aluminate slag exists in the form of γ-2CaO·SiO2 which is more stable than β-2CaO·SiO2. However, it is decomposed by sodium carbonate solution during leaching process, leading to the secondary reaction. The extent of secondary reaction and reaction mechanism of calcium aluminate slag were studied using XRD. The results show that the decomposition rate of γ-2CaO·SiO2 increases with the increase in leaching time and sodium carbonate concentration. The main products of secondary reaction are the mixture of hydrogarnet and sodium hydrate alumina-silicate. SiO2 concentration rises firstly and then drops with the increase of leaching temperature. XRD results indicate that the stable product of secondary reaction at low temperature is hydrogarnet. But hydrogarnet is transformed into sodium hydrate alumina-silicate at high temperature.
文摘Mono-substituted heterocyclic ketene aminals are formed by the reaction of 1-methyl-2-methylthio-imidazoline with active methylene compounds containinq an acetyl or benzoyl group by the elimination of both a methylthio and an acyl group.This is resulted by the secondary reactio of the produced methanethiol to attack the more active carbonyl group.
基金Supported by Australian Research Council's Discovery Projects fundings scheme(DP1096342)
文摘The revolution in information and communication technology has brought huge technical benefits and wealth, but has created a major global problem： the generation of vast amounts of electronic waste, or e-waste through product obsolesce. The challenge in managing e-waste will be in developing sustainable recycling tech- nologies that are able to address the volume and complexity of this waste using cost effective and ecologically sen-sitive methods. In this study, the capability or microorganism metabolic acids in dissolving the metallic tractions from waste printed circuit boards was examined. Several factors were considered in the examination of the activityof the acids-including secondary reactions, solution pH, temperature and the nature of ligands in solutions （or bioacid constituents）. The leaching tests were cgnducted ex-situ, using synthetic organic acids. Leaching was performed for periods of up to 6 hat 70-90 ℃ and 1000 r-min-1.
文摘We report a fresh and simpler approach to the modelling of the kinetics of the polymerization of Hb SS in sickle cell patients that couples the kinetics and the hydrodynamics of blood flow in mechanistic understanding of the process. The well-known two-step autocatalytic reaction scheme was used for the polymerization reaction with the assumption of simpler first-order reaction scheme for each stage. In addition, the forces acting on a particle in motion were also introduced to account for compelling settling of the red cells that lead to vessel occlusion (vaso-occlusion). A first attempt on the prediction of vessel blockage was made using this novel model. The time for the onset of the polymerization reaction was derived from hydrodynamic considerations and kinetics while the kinetic rate constants were obtained from the autocatalytic nature of the reaction. Experimental data for model validation were obtained from recruited SS patients and in vitro data of Hofrichter. Over 100 volunteers were recruited for participation in this work but less than 40% met the inclusion criteria. Participants were of age range 13 - 43 (with a mean of 26 ± 8 years) for SCD patients and 18 - 43 (with a mean of 28 ± 7 years) for control participants. Blood indices and Transcranial Doppler (TCD) test parameters of all participants were the principal parameters used for model validation. Constant k2/k1 ratios was obtained for individual in vivo/in vitro system. This ratio is unique for any individual, independent on protein sequence and also suggests the degree of expression of the symptoms of Sickle Cell Disease (SCD) with higher values reflecting greater propensity to pain crisis. Delay time, tD, was found to have an inverse relationship with the kinetic constant for the residual reaction, k1. Therefore, long delay times calculated, offer insight on why SCD patients are not in perpetual crises because enough time is provided the cells to escape microcirculation while keeping the residual reaction at the minimum. Sensitivity analysis was carried out to obviate the limitations encountered in the course of the work. Results showed the onset of occlusion to be most sensitive to the diameter of the blood vessel.
文摘β-2CaO＇SiO2 was obtained with analytical grade reagents. Polyethylene glycol （PEG）, sodium polyacrylate （PAAS） and their mixture were used to inhibit the decomposition of β-2CaO·SiO2 in sodium aluminate solution. The potential of solid-liquid interface and the adsorption mechanism were studied by the methods of Zeta potential measurement and XPS. The results indicate that PEG and PAAS have synergistic effect on the inhibition of secondary reaction. The inhibitory effect is the best when the volume ratio of PAAS to PEG is 1：1 and the total concentration is 12.5 mg/L. PAAS adsorbs on the surface of β-2CaO-SiO2 by the formation of --COOCa coordinate bond, and the negative charge enters into Stem layer, which results in the decrease of particle potential and the obvious change of binding energy of Ca 2p, Si 2p and O Is. PEG only physically adsorbs on the surface ofβ-2CaO·SiO2, and had little effect on particle potential and binding energy of Ca 2p, Si 2p and O Is.
文摘It is essential for alumina production by alkaline process to know the behavior of minerals containing Al and Si in basic solution,and the behavior of SiO2 in the process of clinker leaching is an important portion. To study the behavior of SiO2 in the process of high concentration clinker leaching,experiments were carried out in home-made reactors. The results indicate that factors,such as temperature,time,Al2O3 concentration,as well as SiO2 concentration,have profound impact on the SiO2 and Al2O3 concen-tration of pregnant liquor during the high concentration leaching. However,sodium carbonate and free caustic soda concentrations have no remarkable effect on it,thus they are the secondary factors compared with Al2O3 concentration. The concentration of SiO2 in the pregnant liquor could be reduced to a lower level when the major effect parameters of this process are controlled properly.
基金SupportedbytheFoundationforthe"NinthFive yearPlan"ofPLA (No .96L0 4 3)
文摘Objective: Whether early massive bronchoalveolar lavage can remove the harmful substances from the lungs injured with smoke inhalation remains uncertain. This study was designed to observe the effects of early massive bronchoalveolar lavage fluid (BALF) on the healthy lungs in rats. Methods: Mongrel dogs were inflicted with severe smoke inhalation injury. The injured lungs were lavaged with large amount of normal saline in the first hour after injury and the BALF was collected. The BALF was injected into the healthy lungs of 30 rats (group C) in the dosage of 5 ml/kg. The functions and pathological changes of the lungs were observed 24 h after perfusion with the BALF. The data were compared with those of 23 rats (group B) whose lungs were perfused with the BALF collected from normal dogs and those of 21 rats (group A) whose lungs were perfused with normal saline. Results: The mortality rate 24 h after lung perfusion was higher in group C than in groups A and B. The survivors of group C exhibited fluctuation of respiratory rate (RR), remarkable decrease of PaO 2, significantly higher content of lung water, decrease of total static pulmonary compliance and pulmonary expansion index, and increasse of inflammatory cytokines in the tissues of lungs. Only slight mechanic obstructive effect on the airway was observed in rats of group A and B. The pathological changes of the lungs of the rats in group C were similar to those of the dogs with actual smoke inhalation injury. Conclusion: Our findings indicate that the BALF collected from dogs with acute severe smoke inhalation injury in the early stage after injury injured the normal lungs of rats with the bioactive substances in the BALF. These findings show us that it is a valuable therapeutic procedure to apply massive bronchoalveolar fluid lavage in the early stage after inhalation injury.
基金project supported by the National Natural Science Foundation of China.
文摘The eme reactions of α-ionones with singlet oxygen were examined to ascertain the effect of secondary Me interaction between the reactants on the reaction regiospecificity. Exclusive formation of 3-hydroxy-γ-ionones found in the reactions reveals favorable interaction of singlet oxygen with the acyclic α-hydrogen atom,On the other hand,no formation of 3-hy- droxy-β-ionones implies that the steric requirement was not met for the bond formation between zwitterionic perepoxide with C_1-hydrogen in the process.The MMP21 and MNDO calculations indicate minus value of the secondary interaction energy for the aeyelie α-hydrogen abstrac- tion and a repulsion between the oxygen with C_1-hydrogen atom.Twisting tilting of the double bond may account for favorable attack of singlet oxygen on C_3.An explanation of the excellent regiospecificity was addressed and placed in proper mechanic prospective.
基金Project supported by the National Natural Science Foundation of China
文摘The negative secondary ion mass spectrometry,in combination with the stereoselective derivatizations with substituted boronic acid RB(OH)_2,was used in the analysis of fourteen oligosac- charides.The mass spectra of the derivatives provide information on their linkage Positions and iso- merism of the individual monoscaccharide units.The results indicated that among the derivatives of the oligosaccharides analyzed,those with 1—4 and 1—6 linkages all presented the ion peaks at m/z 287,sometimes one more peak at m/z 449.Furthermore,a relationship was found between the linkage positions and the intensity orders of the derivative ions.Finally,the derivatives of the disaccharides with a galactose presented an intense ion peak at m/z 347,and those of oligosaccharides with 1—6 linkage to a galactose at terminal presented the ion at m/z 317.In the case of oligosaccharides with a fructose residue,characteristic ion of m/z 155 was produced.The conditions of stereoselective derivatizations and mass spectrometry were studied,in order to obtain a better reproducibility of the mass spectra.
基金the National Basic Research Program of China(2014CB744303).
文摘This study investigated the characteristics of pyrolysis for waste tire particles in the newly developed fixed-bed reactor with internals that are a central gas collection channel mounted inside reactor.And a few metallic plates vertically welded on the internal wall of the reactors and extending to the region closing their central gas collection pipe walls.Experiments were conducted in two laboratory fixed bed reactors with or without the internals.The results shown that employing internals produced more light oil at externally heating temperatures above 700℃due to the inhibited secondary reactions in the reactor.The oil from the reactor with internals contained more aliphatic hydrocarbons and fewer aromatic hydrocarbons,leading to its higher H/C atomic ratios as for crude petroleum oil.The char yield was relatively stable for two beds and showed the higher heating values(HHVs)of about 23 MJ/kg.The gaseous product of pyrolysis mainly consisted of H2 and CH4,but the use of internals led to less pyrolysis gas through its promotion of oil production.
