The identification of anomalies within stream sediment geochemical data is one of the fastest developing areas in mineral exploration.The various means used to achieve this objective make use of either continuous or d...The identification of anomalies within stream sediment geochemical data is one of the fastest developing areas in mineral exploration.The various means used to achieve this objective make use of either continuous or discrete field models of stream sediment geochemical data.To map anomalies in a discrete field model of such data,two corrections are required:background correction and downstream dilution correction.Topography and geomorphology are important factors in variations of element content in stream sediments.However,few studies have considered,through the use of digital terrain analysis,the influence of geomorphic features in downstream dilution correction of stream sediment geochemical data.This study proposes and demonstrates an improvement to the traditional downstream dilution correction equation,based on the use of digital terrain analysis to map single-element anomalies in stream sediment geochemical landscapes.Moreover,this study compares the results of analyses using discrete and continuous field models of stream sediment geochemical data from the Xincang area,Tibet.The efficiency of the proposed methodology was validated against known mineral occurrences.The results indicate that catchment-based analysis outperforms interpolation-based analysis of stream sediment geochemical data for anomaly mapping.Meanwhile,the proposed modified downstream dilution correction equation proved more effective than the original equation.However,further testing of this modified downstream dilution correction is needed in other areas,in order to investigate its efficiency further.展开更多
Tanzania is located in eastern Africa with a predominantly agricultural ecomomy,the potential for developing and utilizing cultivated land are promising,but scientific guidance is required.B,Zn and Se are essential mi...Tanzania is located in eastern Africa with a predominantly agricultural ecomomy,the potential for developing and utilizing cultivated land are promising,but scientific guidance is required.B,Zn and Se are essential micronutrients for plants and human body with crucial biological functions,in particular,Se is significant for human health and considered as“the king of anti-cancer”.As these elements required by human or plants are mainly absorbed from soil directly or indirectly,therefore,it is important to understand the contents and distributions of them in the soil of cultivated land for guiding agricultural production.In this work,low-density geochemical survey at the scale of 1∶1000000 was carried out in Tanzania,and the results show that the concentrations of B,Zn and Se in stream sediments are low and their distributions are heterogeneous.According to the distributions of geological units,the existing cultivated land resources can be divided into five regions in Tanzania.Compared with the national background values,the concentrations of B,Zn and Se are insufficient overall but enriched locally in these regions.In general,element concentrations in stream sediments and soil have a positive correlation because of their similar sources,which is essential in agriculture application.Based on the information provided by low-density geochemical data and maps,the Se-sufficient and Se-rich regions were delineated in Tanzania,where can be used to develop Se-rich industries.Finally,this paper believes that geochemical survey is a powerful tool for cultivated land evaluation,agriculture management and land development.展开更多
Stream sediment sampling is a significant tool in geochemical exploration. The stream sediment composition reflects the bedrock geology, overburden cover, and metalliferous mineralization. This research article focuse...Stream sediment sampling is a significant tool in geochemical exploration. The stream sediment composition reflects the bedrock geology, overburden cover, and metalliferous mineralization. This research article focuses on assessing selected trace element concentrations in stream sediments and interpreting their inter-element relationships using multivariate statistical methods. Tagadur Ranganathaswamy Gudda and its surroundings in the Nuggihalli schist belt of southern India have been investigated in the present work. The geology of the study area is complex, with a diverse range of litho units and evidence of strong structural deformation. The area is known for its mineralization potential for chromite, vanadiferous titanomagnetite, and sulfides. The topography of the region is characterized by an undulating terrain with a radial drainage pattern. Most part of the schist belt is soil covered except the Tagadur Ranganathaswamy Gudda area. For this study, a discrete stream sediment sampling method was adopted to collect the samples. Stream sediment samples were collected using a discrete sampling method and analyzed for trace elements using an ICP-AES spectrophotometer: Fe, Cr, Ti, V, Cu, Ni, Zn, Pb, Mn, Cd, and As have been analyzed. The analytical data were statistically treated using the SPSS software, including descriptive statistics, normalization of data using natural log transformation, and factor analysis with varimax rotation. The transformed data showed a log-normal distribution, indicating the presence of geochemical anomalies. The results of the study provide valuable insights into the geochemical processes and mineralization potential of the study area. The statistical analysis helps in understanding the inter-element relationships and identifying element groups and their implications on bedrock potential mineralization. Additionally, spatial analysis using inverse distance weighting interpolation provides information about the distribution of geochemical parameters across the study area. Overall, this research contributes to the understanding of stream sediment geochemistry and its application in mineral exploration. The findings have implications for future exploration efforts and can aid in the identification of potential ore deposits in the Nuggihalli schist belt and similar geological settings.展开更多
In order to investigate the source,contamination,and risk of heavy metals such as Pb,Zn,Cu,Ni,Co,Fe,Mn,and Cr,twelve(12)stream sediments and ten(10)rock samples were collected from pegmatite mining sites at Olode and ...In order to investigate the source,contamination,and risk of heavy metals such as Pb,Zn,Cu,Ni,Co,Fe,Mn,and Cr,twelve(12)stream sediments and ten(10)rock samples were collected from pegmatite mining sites at Olode and its environs inside Ibadan,Southwestern Nigeria.The average values and order of abundance obtained followed the pattern:Mn(595.09)>Ba(80)>Cr(50.82)>V(45.09)>Zn(29.73)>Cu(13.82)>Co(13.82)>Sr(10.46)>Ni(9.73)>Pb(9.09)>Fe(1.59).These were greater than the background values,indicating that mining has a negative impact on the study area,as indicated by the high coefficient of variation and correlation values(>0.6)for Copper-Lead(0.929),Copper-Vanadium(0.970),Copper-Chromium(0.815),Lead-Vanadium(0.884),and others.On the basis of the enrichment factor(EF),the Olode sediments show extremely high enrichment for Mn and Ba in the research region.Cu and Ni are most likely to blame for the elevated contamination levels,according to CF values.The degree of contamination(CD),pollution load index(PLI),pollution index(PI),and modified pollution index(MPI)all revealed high levels of contamination in all stream sediment samples,whereas Igeo shows that the Olode stream sediments are“practically uncontaminated to extremely contaminated by Ni,Co,and Mn”.Ni and Cu are the major regulating factors that are most likely causing the possible Eri.As a result,these findings give important information for conducting appropriate ecological management research.展开更多
Mineralogical and geochemical characteristics of stream sediments collected from 30 stations in the Dahab-Wadi Kid area(southeastern Sinai,Egypt)are presented.The studied sediments contain considerable amounts of heav...Mineralogical and geochemical characteristics of stream sediments collected from 30 stations in the Dahab-Wadi Kid area(southeastern Sinai,Egypt)are presented.The studied sediments contain considerable amounts of heavy minerals,including abundant Fe–Ti oxides,with up to 25.94%index figure that measures the relative abundance of heavy minerals to light minerals.Immaturity of the sediments and nature of Fe–Ti oxide intergrowths,in addition to some non-opaque heavy minerals,indicate multiple provenances with contributions from a variety of Neoproterozoic mafic to felsic intrusions.Appreciable amounts of heavy minerals are derived from schists that belong to the so-called Wadi Kid volcanosedimentary group.Owing to the considerable contribution of the felsic intrusions represented by within-plate granites,the sediments are enriched in REE-bearing minerals(e.g.,monazite,cerianite,La-cerianite and allanite),V-bearing thorite,zircon,and a ZrO_(2) phase.The majority of Fe–Ti oxides are derived from the mafic intrusions,and they show evidence of pre-,syn-and post-depositional phases of alteration and formation of intergrowths.As to the geochemical signature of the bulk silt fraction,there is remarkable enrichment of LREEs with distinct negative Eu anomaly,and this supports dominance of a provenance dominated by felsic intrusions(i.e.,the A-type within-plate granite and associated pegmatites).Also,the felsic provenance is responsible for slight abnormality of ∑PU+Th content(up to~37 ppm)and few anomalous samples bear uraniferous zircon and Ce-type monazite.The present paper sheds light on the fertility of the Dahab stream sediments in some economic minerals for possible future exploitation,not for gold only,but for potential REEbearing minerals that are needed for a wide spectrum of modern technological industries.展开更多
River Iyiudene is a vital distributary resource in Abakaliki, southeastern Nigeria and conveys an abundant amount of sediments to provincial and residual ecosystems. Although the importance of the river cannot be over...River Iyiudene is a vital distributary resource in Abakaliki, southeastern Nigeria and conveys an abundant amount of sediments to provincial and residual ecosystems. Although the importance of the river cannot be overemphasized, the geochemistry of its stream sediments is less investigated. Twenty (20) stream sediment samples were taken at the centre of the river channels to represent the entire drainage area well and avoid collapsed bank materials. The stream sediment samples were used to determine the dispersion, contamination status and sources of heavy metal concentrations. Total elemental digestion accompanied this with the use of aqua regia, an admixture of Hydrochloric acid (HCl) and Nitric acid (HNO<sub>3</sub>) in the ratio of 3:1 using the atomic absorption spectrometer (AAS). The heavy metal concentration levels in River Iyiudene were low compared with sediments from Imo River, Gulf of California, Upper continental crust, Average shale and surface horizons, excluding Cd, which showed high concentration levels than the other reference studies. The results delineated a wide contrast in the concentration levels of the heavy metals, with the mean contents in the order Zn > Cu > Pb > Cd > Ni > As. The pollution evaluation utilizing the Effect range low (ERL), Effect range median (ERM), single pollution index, and geo-accumulation index revealed Cd contamination. This study indicates that the heavy metals were sourced from the natural geological background of the river basin and possibly from agricultural runoff and atmospheric pollutants.展开更多
In order to study stream sediments in the terahertz range, we have measured six reference stream sediment samples by terahertz time-domain spectroscopy (THz-TDS). We obtained the absorption coefficients and refractive...In order to study stream sediments in the terahertz range, we have measured six reference stream sediment samples by terahertz time-domain spectroscopy (THz-TDS). We obtained the absorption coefficients and refractive indexes. By analyzing the spectra, we got different drops in amplitude and delays in time. The absorption and refractive properties of samples changed with its components and types. In addition, we also found there was a nearly linear relationship between the absorption coefficient and the frequency. We calculated the slope value (K) of each sample by linear fitting, and find the K was corresponding to the contents of the samples. The results showed THz-TDS was an effective method to the analysis of stream sediments.展开更多
Mining and smelting activities are the main causes for the in creasing pollution of heavy metals in soil, water body and stream sediment. An e nvironmental geochemical investigation was carried out in and around the P...Mining and smelting activities are the main causes for the in creasing pollution of heavy metals in soil, water body and stream sediment. An e nvironmental geochemical investigation was carried out in and around the Panzhih ua mining and smelting area to determine the extent of chemical contamination in soil and sediment. The main objective of this study was to investigate the envi ronmental geochemistry of Ti, V, Cr, Mn, Cu, Pb, Zn and As in soil and sediment and to assess the degree of pollution in the study area. The data of heavy metal concentrations reveal that soils and sediments in the area have been slightly c ontaminated. Geochemical maps of I\-\{geo\} of each heavy metal show that the co ntaminated sites are located in V-Ti-magnetite sloping and smelting, gangues d am. The pollution sources of the selected elements come mainly from dusts result ant from mining activities and other three-waste-effluents. The area needs to be monitored regularly for trace metal, especially heavy metal enrichment.展开更多
The present paper investigates the stream sediment geochemistry,behavior of gold and associated elements,delineates Au-anomalous sites and defines related sources in the Wadi Umm Rilan area.Fifty three major and trace...The present paper investigates the stream sediment geochemistry,behavior of gold and associated elements,delineates Au-anomalous sites and defines related sources in the Wadi Umm Rilan area.Fifty three major and trace elements were analyzed using ICP-MS and treated applying various statistical and mapping techniques.The results showed a significant difference of mean and median Au and most chemical elements in the three portions of the area,and higher values were recorded in the western portion.Furthermore,Au-anomalous sites appeared in upper and lower parts of the Wadi Umm Rilan,along the tributaries of metavolcanic unit and near granitoid contacts.This indicates the main source of Au mineralization is related to emplacement of granitoid plutons and accompanying hydrothermal solutions.There are significant indications for the presence of more than one mineralization event forming a probable single major episode of mineralization in the area,involving Au,Pb and U mineralizations.Geology,geomorphologic aspects and weathering processes could control stream sediment geochemistry,anomalies of Au and associated elements,elemental association and their dispersion patterns.Therefore,the area is fruitful and regarded as a promising target for Au exploration,using Ag,As,Sb,Cd,Cs,and Tl as pathfinder elements.展开更多
Stream sediment geochemistry remains a versatile tool in exploration especially in regions where knowledge of the primary mineralization is lacking and the exploration activities are still at reconnaissance stage. In ...Stream sediment geochemistry remains a versatile tool in exploration especially in regions where knowledge of the primary mineralization is lacking and the exploration activities are still at reconnaissance stage. In this study, we investigate the concentrations of gold and associated elements in stream sediment samples from the Vaimba-Lidi drainage system in northern Cameroon;a relatively remote area where alluvial gold is worked locally, and exploration activities are at early stage. The main river and its principal first and second order tributaries were sampled, panned for gold grain recovery and the 100 μm size fraction analyzed for Au by fire assay with Ni finish. A suite of other elements were analyzed for by inductively coupled plasma mass spectrometry (ICP-MS). Gold grades estimated by the panning and weighing technique rarely exceed1 g/t while the Au concentrations from chemical analysis range from 3.0 to 354.0 ppm. The spatial distribution of gold and all the other elements are presented as point symbol maps and the data analyzed using multivariate statistics. From the principal component analysis (PCA), the As-Mo-W-Ag as well as the Au-Zn factors point to the presence of primary hydrothermal gold-sulphide mineralization in the area and this can be further investigated. These results highlight the importance of multielement analysis and multivariate statistical interpretation of sediment geochemical data in inferring the nature of the underlying primary mineralization in any region.展开更多
This study is aimed at determining the level of environmental degradation as well as the concentration of trace elements in soil and stream sediments in order to evaluate the environmental impact of the mining operati...This study is aimed at determining the level of environmental degradation as well as the concentration of trace elements in soil and stream sediments in order to evaluate the environmental impact of the mining operation.Twenty-five(25) soils and ten(10) stream sediment samples were collected from the study area. The physicochemical parameters were determined using appropriate instrumentation with the aid of a digital p H meter(Milwaukee meter) to measure the p H and electrical conductivity, total dissolved solids, moisture content and loss on ignition of the soil and stream sediment samples. The p H of the soil sample ranged from(6.10 to 7.19); Electrical conductivity ranged from(21.3 to 279.4 μS/cm), moisture content varied from(0.60% to 7.20%), and the LOI ranged from(2.03% to 18.62%). The results of the analysis showed that the concentrations of the trace elements in the soils and stream sediment samples were slightly higher than the background values. Plots of the trace elements in stream sediment samples show moderate, consistent decrease downstream except at points where there was mine water discharge into the main river. The pollution levels of heavy metals were examined in stream sediment and soil samples using different assessable indices, such as the enrichment factor, which showed significant-moderate enrichment for Cr, Th, Nb, Zn, Pb, Y and Zr and the geoaccumulation index, which showed practically moderate contamination with Cr, Ni and Sr based on regional background reference values. Geo-accumulation index and contamination index for soils and stream sediment revealed uncontaminated to moderate contamination. Likewise,elements with moderate contamination were Cr, Ni and Sr.The Pearson correlation showed that there were significant positive associations among selected metals in soil and stream sediment samples.展开更多
Stream sediments are widely employed in reconnaissance exploration for gold especially in areas where outcrops are scarce and the overburden thick such as in the eastern Cameroon goldfields. In this study, 337 stream ...Stream sediments are widely employed in reconnaissance exploration for gold especially in areas where outcrops are scarce and the overburden thick such as in the eastern Cameroon goldfields. In this study, 337 stream sediment samples were collected from the Lom river drainage basin. The study aims at identifying the main geological processes affecting the geochemical data from the sediments by considering the multi-elements relationships and spatial features of single elements. The samples were collected in duplicate. One set was panned, gold grains picked and weighed while the second set was wet sieved and the ≤100 microns size fraction retained. This fraction was eventually analyzed for gold by fire assay and a suite of elements by inductively coupled plasma mass spectrometry (ICP-MS). Single element maps were constructed using ArcGIS and the relationship between elements measured using Pearson correlation and principal component analysis (PCA). Gold concentrations in the samples are erratic, most below the detection limit and attain a high of 450 ppm. Five factors are derived from the PCA including single element factors for As and Au reflecting bedrock-hosted mineralization. The Cu-Zn-Y-Nb-Pb factor suggests sulphide mineralization perhaps related to felsic intrusions while the Sr-Ba-La-Ce-Zr factor is linked to lithologic control. These results demonstrate the usefulness of multi-element analysis and data interpretation using GIS tools in the exploration efforts for gold worldwide.展开更多
Geochemical data of altered wall rocks are important for the metallogenic prognosis of hydrothermal gold deposits. Indicator elements of altered wall rocks such as K, Al, As, Sb, and Hg have been successfully used to ...Geochemical data of altered wall rocks are important for the metallogenic prognosis of hydrothermal gold deposits. Indicator elements of altered wall rocks such as K, Al, As, Sb, and Hg have been successfully used to assess gold anomalies in lithogeochemical survey. However, such researches have rarely been done in stream sediment survey for the exploration of gold from various landscapes. On the basis of the geochemical analysis of altered wall rocks of gold deposits in the cold desert areas of Gansu (甘肃) Province in Northwest China, it is found that the combination of Al, K, and Sn could serve as an important indicator of hydrothermal gold deposits and can be used to evaluate the metallogenic prospective of gold anomalies in stream sediments. More studies performed in the cold grassland areas and the moderate-low relief mountainous areas showed that, both weak and strong geochemical anomalies can be extracted, if strictly abiding by the ways of calculation and addition of the binary values of the indicator elements with equal weight, and this provides the sound delineation of metallogenic perspective areas.展开更多
An R-mode quartimax rotated factor matrix was applied to a statistical study of stream sediment geochemical data from Onyami drainage system within Igarra area in southwestern Nigeria. The area is underlain by the gne...An R-mode quartimax rotated factor matrix was applied to a statistical study of stream sediment geochemical data from Onyami drainage system within Igarra area in southwestern Nigeria. The area is underlain by the gneiss-migmatite complex, the low grade supracrustal schist belts and the Pan-African granitoids which intruded both the gneiss-migmatite complex and the supracrustal units. A four-factor model which accounts for 76.49% of the total variance of the stream sediment geochemical data was established. Factor 1 (Sc-Ga-V-La-Ni-Co-Ag-Bi-Sr-Pb-Hf-Nb-Cu-Cr) probably defines an underlying complex granitic lithology with contributions from mafic and ultramafic rocks. Factor 2 (Th-U) is attributable to a granitic lithology which reflects the parent rock as the influencing factor. Factor 3 (Mo-Nb-Zn) appears to define a minor sulphide mineralization associated with granitic rocks that intruded the schists and granite gneiss in the area. Factor 4 indicates the occurrence of gold and its pathfinder element, As, in the study area. This inference is consistent with the reported occurrence and mining of gold during the colonial era in Dagbala, which lies within the Onyami river catchment area.展开更多
Baoxinggou area is located in northern Daxing'anling. In this area,comprehensive use of geophysical and geochemical exploration methods plays an important role in the prospecting,and has yielded some application r...Baoxinggou area is located in northern Daxing'anling. In this area,comprehensive use of geophysical and geochemical exploration methods plays an important role in the prospecting,and has yielded some application results so far. Based on the 1 /100 000 stream sediment anomaly survey,the methods of 1 /20 000 soil geochemical measurement,trenching engineering on the earth's surface and 1 /10 000 IP intermediate gradient survey were all used to verify and decompose drainage anomalies,as well as to find and locate ore bodies. In this way,an effective,economical and quick prospecting method was concluded,which focuses on the middle and lower mountain forest swamp landscape in the northern part of Daxing'anling,and provides reference for the prospecting in the area.展开更多
Aljustrel mines were classified as having high environmental hazard due to their large tailings volume and high metal concentrations in waters and sediments.To assess acid mine drainage impacted systems whose environm...Aljustrel mines were classified as having high environmental hazard due to their large tailings volume and high metal concentrations in waters and sediments.To assess acid mine drainage impacted systems whose environmental conditions change quickly,the use of biological indicators with short generation time such as diatoms is advantageous.This study combined geochemical and diatom data,whose results were highlighted in 3 groups:Group 1,with low p H(1.9–5.1)and high metal/metalloid(Al,As,Cd,Co,Cu,Fe,Mn,Ni,Pb,Zn;0.65–1032 mg/L)and SO_4(405–39124 mg/L)concentrations.An acidophilic species,Pinnularia aljustrelica,was perfectly adapted to the adverse conditions;in contrast,teratological forms of Eunotia exigua were found,showing that metal toxicity affected this species.The low availability of metals/metalloids in sediments of this group indicates that metals/metalloids of the exchangeable fractions had been solubilized,which in fact enables metal/metalloid diatom uptake and consequently the occurrence of teratologies;Group 2,with sites of near neutral p H(5.0–6.8)and intermediate metal/metalloid(0.002–6 mg/L)and SO_4(302–2179 mg/L)concentrations;this enabled the existence of typical species of uncontaminated streams(Brachysira neglectissima,Achnanthidium minutissimum);Group 3,with samples from unimpacted sites,showing low metal/metalloid(0–0.8 mg/L)and SO_4(10–315 mg/L)concentrations,high pH(7.0–8.4)and Cl contents(10–2119 mg/L)and the presence of brackish to marine species(Entomoneis paludosa).For similar conditions of acidity,differences in diversity,abundance and teratologies of diatoms can be explained by the levels of metals/metalloids.展开更多
The aim of this study is to quantify the geochemical elements distribution patterns analyzed from stream sediment data and then to delineate favorable areas for mineral exploration. A total of 7 270 stream sediment sa...The aim of this study is to quantify the geochemical elements distribution patterns analyzed from stream sediment data and then to delineate favorable areas for mineral exploration. A total of 7 270 stream sediment samples were collected from four subareas and 37 rock(ore) chip samples from five different locations in the Bange region, northern Tibet(China). The multifractal spectra of 12 elements including Au, Ag, As, Cu, Mo, Pb, Zn, W, Sn, Bi, Sb and Hg are represented by the method of moments, and characterized by five quantitative multifractal parameters. The results show that the multifractality for Cu and Bi in the Gongma area is much stronger than those in other subareas. Both the asymmetry index of multifractal spectra and the variance coefficients of Cu and Bi in this area are the highest, which imply that the distribution pattern of Cu and Bi in the Gongma area is the most heterogeneous. These multifractal parameters indicate that the Gongma area is the most favorable for prospecting Cu and Bi. The results obtained by the method of moments are in agreement with petrochemical analysis and field observation. It is suggested that multifractal analysis can be used as an effective tool to evaluate the ore-forming potential in the study area and to provide new approaches for geochemical exploration.展开更多
Based on a detailed environmental investigation of the whole Qingshui Stream catchments,samples of water and surface sediments were collected at 15 different places from the upper to the lower reaches of Qingshui Stre...Based on a detailed environmental investigation of the whole Qingshui Stream catchments,samples of water and surface sediments were collected at 15 different places from the upper to the lower reaches of Qingshui Stream,and samples of suspended matter were obtained by filtrating the water samples. The concentrations of heavy metals (Cd,Cu and Zn) were measured in filtered water,suspended matter,and surface sediment by ICP-AES. The results show that the concentrations of the three heavy metals in filtered water are 0.18,6.6 and 17.67 μg/L,lower than that of the Fresh Water Quality Criteria (US EPA) and those of the plain urban rivers,but the contents of Cd,Cu and Zn are much higher than the mean values of rivers in the world and the background value in Jialing River basin. The heavy metals concentrations in the suspended matter from Qingshui Stream are 2.08,438.14 and 1 348.05 mg/kg,much higher than the corresponding background values of soils in Chongqing city. The heavy metals concentrations in the surface sediment from Qingshui Stream are 0.84,189.75 and 838.23 mg/kg,and the values of index of geoaccumulation Igeo of Cd,Cu and Zn show that their pollution degrees are moderate. The heavy metals exist in three transferable forms such as water,suspended matter and surface sediment in Qingshui Stream. The heavy metals concentrations in water are the lowest,and those in the suspended matter are the highest,so the ecological risk in suspended matter is the highest. The distribution tendencies of three metals in water,suspended matter and surface sediment in main riverbed are different.展开更多
Eutrophication of surface waters is a critical concern in regions around the world facing nutrient surpluses as a result of confined animal feeding operations (CAFOs) and subsequent land application of manures. While ...Eutrophication of surface waters is a critical concern in regions around the world facing nutrient surpluses as a result of confined animal feeding operations (CAFOs) and subsequent land application of manures. While large amounts of research exist on the transport of nutrient enriched runoff from fields to surface waters less information is available on in-stream processes controlling the transport of P in-stream. Thus, information is needed on the role of stream sediments in regulating transient phosphorus (P) to better understand the relationship between nutrient inputs and water quality. Fine-sized sediments ( 2-mm) consume and store P. From fine-sized sediment a modified P saturation ratio (PSRmod), related to the sediment’s ability to bind P and determined from Mehlich-3 extracted nutrients, has been correlated to in-stream dissolved reactive P (DRP) concentrations. The objectives of this study were to determine the relative size distribution of total- and fine-sized sediment (sand, silt clay) fractions among streams, determine the optimum sample number needed to characterize Mehlich-3 P (M3P) and PSRmod, and finally determine the applicability of PSRmod, as an indicator of stream water column DRP concentrations. Stream sediments were sampled from the 0- to 3-cm depth from stream reaches ranging from (25 – 75 m) in August, 2008 for characterization along with water samples collected from the thalweg for DRP concentration determination. Additional water column samples were collected along with fine-sized sedi- ment chemical properties in February, May, and June 2009. The distribution of sediment size classes was statistically similar, with 2- to 20- and 20- to 75-mm sized sediment dominating. Fine-sized sediment (mod, were determined to typically be sufficiently characterized by a sample scheme utilizing three samples points. Modified P saturation ratio of mod, has the potential to be used as an indicator of the ability of stream sediments to enrich stream water with P. Thus, fine-sized sediment nutrient concentrations appear to be key regulators of water column P concentrations.展开更多
基金financially supported by the National Natural Science Foundation of China(NNSFC,Project No.42002298)the Chinese Geological Survey(Project Nos.DD20201181,DD20211403)+1 种基金the National Key Research and Development Program of China(NKRDPC,Project No.2017YFC0601501)funded by The Project of"Big Data Analysis and Major Project Evaluation of Strategic Mineral Resources"from the Chinese Geological Survey。
文摘The identification of anomalies within stream sediment geochemical data is one of the fastest developing areas in mineral exploration.The various means used to achieve this objective make use of either continuous or discrete field models of stream sediment geochemical data.To map anomalies in a discrete field model of such data,two corrections are required:background correction and downstream dilution correction.Topography and geomorphology are important factors in variations of element content in stream sediments.However,few studies have considered,through the use of digital terrain analysis,the influence of geomorphic features in downstream dilution correction of stream sediment geochemical data.This study proposes and demonstrates an improvement to the traditional downstream dilution correction equation,based on the use of digital terrain analysis to map single-element anomalies in stream sediment geochemical landscapes.Moreover,this study compares the results of analyses using discrete and continuous field models of stream sediment geochemical data from the Xincang area,Tibet.The efficiency of the proposed methodology was validated against known mineral occurrences.The results indicate that catchment-based analysis outperforms interpolation-based analysis of stream sediment geochemical data for anomaly mapping.Meanwhile,the proposed modified downstream dilution correction equation proved more effective than the original equation.However,further testing of this modified downstream dilution correction is needed in other areas,in order to investigate its efficiency further.
基金the cooperation projects between China Geological Survey and geological survey institutions of Africa(DD20190439,DD20160108,DD20221801)。
文摘Tanzania is located in eastern Africa with a predominantly agricultural ecomomy,the potential for developing and utilizing cultivated land are promising,but scientific guidance is required.B,Zn and Se are essential micronutrients for plants and human body with crucial biological functions,in particular,Se is significant for human health and considered as“the king of anti-cancer”.As these elements required by human or plants are mainly absorbed from soil directly or indirectly,therefore,it is important to understand the contents and distributions of them in the soil of cultivated land for guiding agricultural production.In this work,low-density geochemical survey at the scale of 1∶1000000 was carried out in Tanzania,and the results show that the concentrations of B,Zn and Se in stream sediments are low and their distributions are heterogeneous.According to the distributions of geological units,the existing cultivated land resources can be divided into five regions in Tanzania.Compared with the national background values,the concentrations of B,Zn and Se are insufficient overall but enriched locally in these regions.In general,element concentrations in stream sediments and soil have a positive correlation because of their similar sources,which is essential in agriculture application.Based on the information provided by low-density geochemical data and maps,the Se-sufficient and Se-rich regions were delineated in Tanzania,where can be used to develop Se-rich industries.Finally,this paper believes that geochemical survey is a powerful tool for cultivated land evaluation,agriculture management and land development.
文摘Stream sediment sampling is a significant tool in geochemical exploration. The stream sediment composition reflects the bedrock geology, overburden cover, and metalliferous mineralization. This research article focuses on assessing selected trace element concentrations in stream sediments and interpreting their inter-element relationships using multivariate statistical methods. Tagadur Ranganathaswamy Gudda and its surroundings in the Nuggihalli schist belt of southern India have been investigated in the present work. The geology of the study area is complex, with a diverse range of litho units and evidence of strong structural deformation. The area is known for its mineralization potential for chromite, vanadiferous titanomagnetite, and sulfides. The topography of the region is characterized by an undulating terrain with a radial drainage pattern. Most part of the schist belt is soil covered except the Tagadur Ranganathaswamy Gudda area. For this study, a discrete stream sediment sampling method was adopted to collect the samples. Stream sediment samples were collected using a discrete sampling method and analyzed for trace elements using an ICP-AES spectrophotometer: Fe, Cr, Ti, V, Cu, Ni, Zn, Pb, Mn, Cd, and As have been analyzed. The analytical data were statistically treated using the SPSS software, including descriptive statistics, normalization of data using natural log transformation, and factor analysis with varimax rotation. The transformed data showed a log-normal distribution, indicating the presence of geochemical anomalies. The results of the study provide valuable insights into the geochemical processes and mineralization potential of the study area. The statistical analysis helps in understanding the inter-element relationships and identifying element groups and their implications on bedrock potential mineralization. Additionally, spatial analysis using inverse distance weighting interpolation provides information about the distribution of geochemical parameters across the study area. Overall, this research contributes to the understanding of stream sediment geochemistry and its application in mineral exploration. The findings have implications for future exploration efforts and can aid in the identification of potential ore deposits in the Nuggihalli schist belt and similar geological settings.
文摘In order to investigate the source,contamination,and risk of heavy metals such as Pb,Zn,Cu,Ni,Co,Fe,Mn,and Cr,twelve(12)stream sediments and ten(10)rock samples were collected from pegmatite mining sites at Olode and its environs inside Ibadan,Southwestern Nigeria.The average values and order of abundance obtained followed the pattern:Mn(595.09)>Ba(80)>Cr(50.82)>V(45.09)>Zn(29.73)>Cu(13.82)>Co(13.82)>Sr(10.46)>Ni(9.73)>Pb(9.09)>Fe(1.59).These were greater than the background values,indicating that mining has a negative impact on the study area,as indicated by the high coefficient of variation and correlation values(>0.6)for Copper-Lead(0.929),Copper-Vanadium(0.970),Copper-Chromium(0.815),Lead-Vanadium(0.884),and others.On the basis of the enrichment factor(EF),the Olode sediments show extremely high enrichment for Mn and Ba in the research region.Cu and Ni are most likely to blame for the elevated contamination levels,according to CF values.The degree of contamination(CD),pollution load index(PLI),pollution index(PI),and modified pollution index(MPI)all revealed high levels of contamination in all stream sediment samples,whereas Igeo shows that the Olode stream sediments are“practically uncontaminated to extremely contaminated by Ni,Co,and Mn”.Ni and Cu are the major regulating factors that are most likely causing the possible Eri.As a result,these findings give important information for conducting appropriate ecological management research.
文摘Mineralogical and geochemical characteristics of stream sediments collected from 30 stations in the Dahab-Wadi Kid area(southeastern Sinai,Egypt)are presented.The studied sediments contain considerable amounts of heavy minerals,including abundant Fe–Ti oxides,with up to 25.94%index figure that measures the relative abundance of heavy minerals to light minerals.Immaturity of the sediments and nature of Fe–Ti oxide intergrowths,in addition to some non-opaque heavy minerals,indicate multiple provenances with contributions from a variety of Neoproterozoic mafic to felsic intrusions.Appreciable amounts of heavy minerals are derived from schists that belong to the so-called Wadi Kid volcanosedimentary group.Owing to the considerable contribution of the felsic intrusions represented by within-plate granites,the sediments are enriched in REE-bearing minerals(e.g.,monazite,cerianite,La-cerianite and allanite),V-bearing thorite,zircon,and a ZrO_(2) phase.The majority of Fe–Ti oxides are derived from the mafic intrusions,and they show evidence of pre-,syn-and post-depositional phases of alteration and formation of intergrowths.As to the geochemical signature of the bulk silt fraction,there is remarkable enrichment of LREEs with distinct negative Eu anomaly,and this supports dominance of a provenance dominated by felsic intrusions(i.e.,the A-type within-plate granite and associated pegmatites).Also,the felsic provenance is responsible for slight abnormality of ∑PU+Th content(up to~37 ppm)and few anomalous samples bear uraniferous zircon and Ce-type monazite.The present paper sheds light on the fertility of the Dahab stream sediments in some economic minerals for possible future exploitation,not for gold only,but for potential REEbearing minerals that are needed for a wide spectrum of modern technological industries.
文摘River Iyiudene is a vital distributary resource in Abakaliki, southeastern Nigeria and conveys an abundant amount of sediments to provincial and residual ecosystems. Although the importance of the river cannot be overemphasized, the geochemistry of its stream sediments is less investigated. Twenty (20) stream sediment samples were taken at the centre of the river channels to represent the entire drainage area well and avoid collapsed bank materials. The stream sediment samples were used to determine the dispersion, contamination status and sources of heavy metal concentrations. Total elemental digestion accompanied this with the use of aqua regia, an admixture of Hydrochloric acid (HCl) and Nitric acid (HNO<sub>3</sub>) in the ratio of 3:1 using the atomic absorption spectrometer (AAS). The heavy metal concentration levels in River Iyiudene were low compared with sediments from Imo River, Gulf of California, Upper continental crust, Average shale and surface horizons, excluding Cd, which showed high concentration levels than the other reference studies. The results delineated a wide contrast in the concentration levels of the heavy metals, with the mean contents in the order Zn > Cu > Pb > Cd > Ni > As. The pollution evaluation utilizing the Effect range low (ERL), Effect range median (ERM), single pollution index, and geo-accumulation index revealed Cd contamination. This study indicates that the heavy metals were sourced from the natural geological background of the river basin and possibly from agricultural runoff and atmospheric pollutants.
文摘In order to study stream sediments in the terahertz range, we have measured six reference stream sediment samples by terahertz time-domain spectroscopy (THz-TDS). We obtained the absorption coefficients and refractive indexes. By analyzing the spectra, we got different drops in amplitude and delays in time. The absorption and refractive properties of samples changed with its components and types. In addition, we also found there was a nearly linear relationship between the absorption coefficient and the frequency. We calculated the slope value (K) of each sample by linear fitting, and find the K was corresponding to the contents of the samples. The results showed THz-TDS was an effective method to the analysis of stream sediments.
文摘Mining and smelting activities are the main causes for the in creasing pollution of heavy metals in soil, water body and stream sediment. An e nvironmental geochemical investigation was carried out in and around the Panzhih ua mining and smelting area to determine the extent of chemical contamination in soil and sediment. The main objective of this study was to investigate the envi ronmental geochemistry of Ti, V, Cr, Mn, Cu, Pb, Zn and As in soil and sediment and to assess the degree of pollution in the study area. The data of heavy metal concentrations reveal that soils and sediments in the area have been slightly c ontaminated. Geochemical maps of I\-\{geo\} of each heavy metal show that the co ntaminated sites are located in V-Ti-magnetite sloping and smelting, gangues d am. The pollution sources of the selected elements come mainly from dusts result ant from mining activities and other three-waste-effluents. The area needs to be monitored regularly for trace metal, especially heavy metal enrichment.
文摘The present paper investigates the stream sediment geochemistry,behavior of gold and associated elements,delineates Au-anomalous sites and defines related sources in the Wadi Umm Rilan area.Fifty three major and trace elements were analyzed using ICP-MS and treated applying various statistical and mapping techniques.The results showed a significant difference of mean and median Au and most chemical elements in the three portions of the area,and higher values were recorded in the western portion.Furthermore,Au-anomalous sites appeared in upper and lower parts of the Wadi Umm Rilan,along the tributaries of metavolcanic unit and near granitoid contacts.This indicates the main source of Au mineralization is related to emplacement of granitoid plutons and accompanying hydrothermal solutions.There are significant indications for the presence of more than one mineralization event forming a probable single major episode of mineralization in the area,involving Au,Pb and U mineralizations.Geology,geomorphologic aspects and weathering processes could control stream sediment geochemistry,anomalies of Au and associated elements,elemental association and their dispersion patterns.Therefore,the area is fruitful and regarded as a promising target for Au exploration,using Ag,As,Sb,Cd,Cs,and Tl as pathfinder elements.
文摘Stream sediment geochemistry remains a versatile tool in exploration especially in regions where knowledge of the primary mineralization is lacking and the exploration activities are still at reconnaissance stage. In this study, we investigate the concentrations of gold and associated elements in stream sediment samples from the Vaimba-Lidi drainage system in northern Cameroon;a relatively remote area where alluvial gold is worked locally, and exploration activities are at early stage. The main river and its principal first and second order tributaries were sampled, panned for gold grain recovery and the 100 μm size fraction analyzed for Au by fire assay with Ni finish. A suite of other elements were analyzed for by inductively coupled plasma mass spectrometry (ICP-MS). Gold grades estimated by the panning and weighing technique rarely exceed1 g/t while the Au concentrations from chemical analysis range from 3.0 to 354.0 ppm. The spatial distribution of gold and all the other elements are presented as point symbol maps and the data analyzed using multivariate statistics. From the principal component analysis (PCA), the As-Mo-W-Ag as well as the Au-Zn factors point to the presence of primary hydrothermal gold-sulphide mineralization in the area and this can be further investigated. These results highlight the importance of multielement analysis and multivariate statistical interpretation of sediment geochemical data in inferring the nature of the underlying primary mineralization in any region.
基金the Chinese Academy of Sciences and The World Academy of Sciences for sponsoring this research through the CAS-TWAS President’s Fellowship program
文摘This study is aimed at determining the level of environmental degradation as well as the concentration of trace elements in soil and stream sediments in order to evaluate the environmental impact of the mining operation.Twenty-five(25) soils and ten(10) stream sediment samples were collected from the study area. The physicochemical parameters were determined using appropriate instrumentation with the aid of a digital p H meter(Milwaukee meter) to measure the p H and electrical conductivity, total dissolved solids, moisture content and loss on ignition of the soil and stream sediment samples. The p H of the soil sample ranged from(6.10 to 7.19); Electrical conductivity ranged from(21.3 to 279.4 μS/cm), moisture content varied from(0.60% to 7.20%), and the LOI ranged from(2.03% to 18.62%). The results of the analysis showed that the concentrations of the trace elements in the soils and stream sediment samples were slightly higher than the background values. Plots of the trace elements in stream sediment samples show moderate, consistent decrease downstream except at points where there was mine water discharge into the main river. The pollution levels of heavy metals were examined in stream sediment and soil samples using different assessable indices, such as the enrichment factor, which showed significant-moderate enrichment for Cr, Th, Nb, Zn, Pb, Y and Zr and the geoaccumulation index, which showed practically moderate contamination with Cr, Ni and Sr based on regional background reference values. Geo-accumulation index and contamination index for soils and stream sediment revealed uncontaminated to moderate contamination. Likewise,elements with moderate contamination were Cr, Ni and Sr.The Pearson correlation showed that there were significant positive associations among selected metals in soil and stream sediment samples.
文摘Stream sediments are widely employed in reconnaissance exploration for gold especially in areas where outcrops are scarce and the overburden thick such as in the eastern Cameroon goldfields. In this study, 337 stream sediment samples were collected from the Lom river drainage basin. The study aims at identifying the main geological processes affecting the geochemical data from the sediments by considering the multi-elements relationships and spatial features of single elements. The samples were collected in duplicate. One set was panned, gold grains picked and weighed while the second set was wet sieved and the ≤100 microns size fraction retained. This fraction was eventually analyzed for gold by fire assay and a suite of elements by inductively coupled plasma mass spectrometry (ICP-MS). Single element maps were constructed using ArcGIS and the relationship between elements measured using Pearson correlation and principal component analysis (PCA). Gold concentrations in the samples are erratic, most below the detection limit and attain a high of 450 ppm. Five factors are derived from the PCA including single element factors for As and Au reflecting bedrock-hosted mineralization. The Cu-Zn-Y-Nb-Pb factor suggests sulphide mineralization perhaps related to felsic intrusions while the Sr-Ba-La-Ce-Zr factor is linked to lithologic control. These results demonstrate the usefulness of multi-element analysis and data interpretation using GIS tools in the exploration efforts for gold worldwide.
基金This paper is supported by China Geological Survey (No. 200310200040).
文摘Geochemical data of altered wall rocks are important for the metallogenic prognosis of hydrothermal gold deposits. Indicator elements of altered wall rocks such as K, Al, As, Sb, and Hg have been successfully used to assess gold anomalies in lithogeochemical survey. However, such researches have rarely been done in stream sediment survey for the exploration of gold from various landscapes. On the basis of the geochemical analysis of altered wall rocks of gold deposits in the cold desert areas of Gansu (甘肃) Province in Northwest China, it is found that the combination of Al, K, and Sn could serve as an important indicator of hydrothermal gold deposits and can be used to evaluate the metallogenic prospective of gold anomalies in stream sediments. More studies performed in the cold grassland areas and the moderate-low relief mountainous areas showed that, both weak and strong geochemical anomalies can be extracted, if strictly abiding by the ways of calculation and addition of the binary values of the indicator elements with equal weight, and this provides the sound delineation of metallogenic perspective areas.
文摘An R-mode quartimax rotated factor matrix was applied to a statistical study of stream sediment geochemical data from Onyami drainage system within Igarra area in southwestern Nigeria. The area is underlain by the gneiss-migmatite complex, the low grade supracrustal schist belts and the Pan-African granitoids which intruded both the gneiss-migmatite complex and the supracrustal units. A four-factor model which accounts for 76.49% of the total variance of the stream sediment geochemical data was established. Factor 1 (Sc-Ga-V-La-Ni-Co-Ag-Bi-Sr-Pb-Hf-Nb-Cu-Cr) probably defines an underlying complex granitic lithology with contributions from mafic and ultramafic rocks. Factor 2 (Th-U) is attributable to a granitic lithology which reflects the parent rock as the influencing factor. Factor 3 (Mo-Nb-Zn) appears to define a minor sulphide mineralization associated with granitic rocks that intruded the schists and granite gneiss in the area. Factor 4 indicates the occurrence of gold and its pathfinder element, As, in the study area. This inference is consistent with the reported occurrence and mining of gold during the colonial era in Dagbala, which lies within the Onyami river catchment area.
基金Supported by project of Special Service Funds for Gold Geology of Gold Headquarters(2008,No.20130301)
文摘Baoxinggou area is located in northern Daxing'anling. In this area,comprehensive use of geophysical and geochemical exploration methods plays an important role in the prospecting,and has yielded some application results so far. Based on the 1 /100 000 stream sediment anomaly survey,the methods of 1 /20 000 soil geochemical measurement,trenching engineering on the earth's surface and 1 /10 000 IP intermediate gradient survey were all used to verify and decompose drainage anomalies,as well as to find and locate ore bodies. In this way,an effective,economical and quick prospecting method was concluded,which focuses on the middle and lower mountain forest swamp landscape in the northern part of Daxing'anling,and provides reference for the prospecting in the area.
基金the Biology and Geosciences Departments of the University of Aveiro,Portugal and to the Fundacao para a Ciência e a Tecnologia,Portugal(grant number SFRH/BD/36137/2007)
文摘Aljustrel mines were classified as having high environmental hazard due to their large tailings volume and high metal concentrations in waters and sediments.To assess acid mine drainage impacted systems whose environmental conditions change quickly,the use of biological indicators with short generation time such as diatoms is advantageous.This study combined geochemical and diatom data,whose results were highlighted in 3 groups:Group 1,with low p H(1.9–5.1)and high metal/metalloid(Al,As,Cd,Co,Cu,Fe,Mn,Ni,Pb,Zn;0.65–1032 mg/L)and SO_4(405–39124 mg/L)concentrations.An acidophilic species,Pinnularia aljustrelica,was perfectly adapted to the adverse conditions;in contrast,teratological forms of Eunotia exigua were found,showing that metal toxicity affected this species.The low availability of metals/metalloids in sediments of this group indicates that metals/metalloids of the exchangeable fractions had been solubilized,which in fact enables metal/metalloid diatom uptake and consequently the occurrence of teratologies;Group 2,with sites of near neutral p H(5.0–6.8)and intermediate metal/metalloid(0.002–6 mg/L)and SO_4(302–2179 mg/L)concentrations;this enabled the existence of typical species of uncontaminated streams(Brachysira neglectissima,Achnanthidium minutissimum);Group 3,with samples from unimpacted sites,showing low metal/metalloid(0–0.8 mg/L)and SO_4(10–315 mg/L)concentrations,high pH(7.0–8.4)and Cl contents(10–2119 mg/L)and the presence of brackish to marine species(Entomoneis paludosa).For similar conditions of acidity,differences in diversity,abundance and teratologies of diatoms can be explained by the levels of metals/metalloids.
基金financially supported by the Special Project on Mineral Exploration and Assessment in Tibetan Plateau (No. 1212010818038)the Program for Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China (No. IRT1083)the National Natural Science Foundation of China (No. 41272362)
文摘The aim of this study is to quantify the geochemical elements distribution patterns analyzed from stream sediment data and then to delineate favorable areas for mineral exploration. A total of 7 270 stream sediment samples were collected from four subareas and 37 rock(ore) chip samples from five different locations in the Bange region, northern Tibet(China). The multifractal spectra of 12 elements including Au, Ag, As, Cu, Mo, Pb, Zn, W, Sn, Bi, Sb and Hg are represented by the method of moments, and characterized by five quantitative multifractal parameters. The results show that the multifractality for Cu and Bi in the Gongma area is much stronger than those in other subareas. Both the asymmetry index of multifractal spectra and the variance coefficients of Cu and Bi in this area are the highest, which imply that the distribution pattern of Cu and Bi in the Gongma area is the most heterogeneous. These multifractal parameters indicate that the Gongma area is the most favorable for prospecting Cu and Bi. The results obtained by the method of moments are in agreement with petrochemical analysis and field observation. It is suggested that multifractal analysis can be used as an effective tool to evaluate the ore-forming potential in the study area and to provide new approaches for geochemical exploration.
基金Project(KLVF-2007-4) supported by Key Laboratory of the Three Gorges Reservoir Region’s Eco-Environment,Ministry of Education,Chongqing University,ChinaProject(CSTC2008CE9095) supported by Chongqing Science and Technology Commission,ChinaProject(KJ080803) supported by Chongqing Municipal Education Commission,China
文摘Based on a detailed environmental investigation of the whole Qingshui Stream catchments,samples of water and surface sediments were collected at 15 different places from the upper to the lower reaches of Qingshui Stream,and samples of suspended matter were obtained by filtrating the water samples. The concentrations of heavy metals (Cd,Cu and Zn) were measured in filtered water,suspended matter,and surface sediment by ICP-AES. The results show that the concentrations of the three heavy metals in filtered water are 0.18,6.6 and 17.67 μg/L,lower than that of the Fresh Water Quality Criteria (US EPA) and those of the plain urban rivers,but the contents of Cd,Cu and Zn are much higher than the mean values of rivers in the world and the background value in Jialing River basin. The heavy metals concentrations in the suspended matter from Qingshui Stream are 2.08,438.14 and 1 348.05 mg/kg,much higher than the corresponding background values of soils in Chongqing city. The heavy metals concentrations in the surface sediment from Qingshui Stream are 0.84,189.75 and 838.23 mg/kg,and the values of index of geoaccumulation Igeo of Cd,Cu and Zn show that their pollution degrees are moderate. The heavy metals exist in three transferable forms such as water,suspended matter and surface sediment in Qingshui Stream. The heavy metals concentrations in water are the lowest,and those in the suspended matter are the highest,so the ecological risk in suspended matter is the highest. The distribution tendencies of three metals in water,suspended matter and surface sediment in main riverbed are different.
文摘Eutrophication of surface waters is a critical concern in regions around the world facing nutrient surpluses as a result of confined animal feeding operations (CAFOs) and subsequent land application of manures. While large amounts of research exist on the transport of nutrient enriched runoff from fields to surface waters less information is available on in-stream processes controlling the transport of P in-stream. Thus, information is needed on the role of stream sediments in regulating transient phosphorus (P) to better understand the relationship between nutrient inputs and water quality. Fine-sized sediments ( 2-mm) consume and store P. From fine-sized sediment a modified P saturation ratio (PSRmod), related to the sediment’s ability to bind P and determined from Mehlich-3 extracted nutrients, has been correlated to in-stream dissolved reactive P (DRP) concentrations. The objectives of this study were to determine the relative size distribution of total- and fine-sized sediment (sand, silt clay) fractions among streams, determine the optimum sample number needed to characterize Mehlich-3 P (M3P) and PSRmod, and finally determine the applicability of PSRmod, as an indicator of stream water column DRP concentrations. Stream sediments were sampled from the 0- to 3-cm depth from stream reaches ranging from (25 – 75 m) in August, 2008 for characterization along with water samples collected from the thalweg for DRP concentration determination. Additional water column samples were collected along with fine-sized sedi- ment chemical properties in February, May, and June 2009. The distribution of sediment size classes was statistically similar, with 2- to 20- and 20- to 75-mm sized sediment dominating. Fine-sized sediment (mod, were determined to typically be sufficiently characterized by a sample scheme utilizing three samples points. Modified P saturation ratio of mod, has the potential to be used as an indicator of the ability of stream sediments to enrich stream water with P. Thus, fine-sized sediment nutrient concentrations appear to be key regulators of water column P concentrations.
