Due to the presence of ice and unfrozen water in pores of frozen rock,the rock fracture behaviors are susceptible to temperature.In this study,the potential thawing-induced softening effects on the fracture behaviors ...Due to the presence of ice and unfrozen water in pores of frozen rock,the rock fracture behaviors are susceptible to temperature.In this study,the potential thawing-induced softening effects on the fracture behaviors of frozen rock is evaluated by testing the tension fracture toughness(KIC)of frozen rock at different temperatures(i.e.-20℃,-15℃,-12℃,-10℃,-8℃,-6℃,-4℃,-2℃,and 0℃).Acoustic emission(AE)and digital image correlation(DIC)methods are utilized to analyze the microcrack propagation during fracturing.The melting of pore ice is measured using nuclear magnetic resonance(NMR)method.The results indicate that:(1)The KIC of frozen rock decreases moderately between-20℃ and-4℃,and rapidly between-4℃ and 0℃.(2)At-20℃ to-4℃,the fracturing process,deduced from the DIC results at the notch tip,exhibits three stages:elastic deformation,microcrack propagation and microcrack coalescence.However,at-4℃e0℃,only the latter two stages are observed.(3)At-4℃e0℃,the AE activities during fracturing are less than that at-20℃ to-4℃,while more small events are reported.(4)The NMR results demonstrate a reverse variation trend in pore ice content with increasing temperature,that is,a moderate decrease is followed by a sharp decrease and-4℃ is exactly the critical temperature.Next,we interpret the thawing-induced softening effect by linking the evolution in microscopic structure of frozen rock with its macroscopic fracture behaviors as follow:from-20℃ to-4℃,the thickening of the unfrozen water film diminishes the cementation strength between ice and rock skeleton,leading to the decrease in fracture parameters.From-4℃ to 0℃,the cementation effect of ice almost vanishes,and the filling effect of pore ice is reduced significantly,which facilitates microcrack propagation and thus the easier fracture of frozen rocks.展开更多
Biodegradable polylactic acid(PLA)melt-blown nonwovens are attractive candidates to replace nondegradable polypropylene melt-blown nonwovens.However,it is still an extremely challenging task to prepare PLA melt-blown ...Biodegradable polylactic acid(PLA)melt-blown nonwovens are attractive candidates to replace nondegradable polypropylene melt-blown nonwovens.However,it is still an extremely challenging task to prepare PLA melt-blown nonwovens with sufficient mechanical properties for practical application.Herein,we report a simple strategy for the large-scale preparation of biodegradable PLA/poly(3-hydroxybutyrate-co-3-hydroxyvalerate)(PHBV)melt-blown nonwovens with high strength and excellent toughness.In this process,a small amount of PHBV is added to PLA to improve the latter’s crystallization rate and crystallinity.In addition,when the PHBV content increases from 0 to 7.5 wt%,the diameters of the PLA/PHBV melt-blown fibers decrease significantly(with the proportion of nanofibers increasing from 7.7%to 42.9%).The resultant PLA/PHBV(5 wt%PHBV)melt-blown nonwovens exhibit the highest mechanical properties.The tensile stress,elongation,and toughness of PLA/PHBV(5 wt%PHBV)melt-blown nonwovens reach 2.5 MPa,45%,and 1.0 MJm3,respectively.More importantly,PLA/PHBV melt-blown nonwovens can be completely degraded into carbon dioxide and water after four months in the soil,making them environmentally friendly.A general tensile-failure model of melt-blown nonwovens is proposed in this study,which may shed light on mechanical performance enhancement for nonwovens.展开更多
A toughener that can effectively improve the interlaminar toughness in carbon fiber composites is crucial for various applications.We investigated,the toughening effects of phenolphthalein-based cardo poly(ether sulfo...A toughener that can effectively improve the interlaminar toughness in carbon fiber composites is crucial for various applications.We investigated,the toughening effects of phenolphthalein-based cardo poly(ether sulfone)(PES-C)on E51/DETDA epoxy and its carbon fiber composites(CFCs).Scanning electron microscopy showed that the phase structures of PES-C/epoxy blends change from island(of dispersed phase)structures to bi-continuous structures(of the matrix)as the PES-C content increased,which is associated with reaction-induced phase separation.After adding 15 phr PES-C,the glass transition temperature(T_(g))of the blends increased by 51.5℃,and the flexural strength,impact strength and fracture toughness of the blends were improved by 41.1%,186.2%and 42.7%,respectively.These improvements could be attributed to the phase separation structure of the PES-C/epoxy sys-tem.A PES-C film was used to improve the mode-II fracture toughness(G_(IIC))of CFCs.The G_(IIC) value of the 7μm PES-C film toughened laminate was improved by 80.3%compared to that of the control laminate.The increase in G_(IIC) was attributed to cohesive failure and plastic deformation in the interleaving region.展开更多
Bioimplant grade hot-rolled magnesium with equiaxed microstructure and basal texture was examined for fracture toughness(FT)anisotropy using fatigue pre-cracked single-edge notch bending specimens with the notch,an||,...Bioimplant grade hot-rolled magnesium with equiaxed microstructure and basal texture was examined for fracture toughness(FT)anisotropy using fatigue pre-cracked single-edge notch bending specimens with the notch,an||,⊥and 45°to rolling direction(RD).Due to adequate crack-tip plasticity,the size-independent elastic-plastic fracture toughness(JIC)were determined.Anisotropic JIC was ob-served due to different twin lamellae formation w.r.t.notch owing to the initial basal texture with{10¯10}and{11¯20}poles mostlyand⊥to RD.The out-of-plane tensile stresses activated the{10¯12}||10¯11||extension twins(ET)as usual with matrix-ET∑15b coincident site lattice boundary(CSLB)interfaces.While the in-plane tensile stress⊥to the crack-tip activated{10¯11}||10¯12||contraction twins(CT)that transform into{10¯11}-{10¯12}double twins(DT)with matrix-DT∑23b and∑15a CSLBs.For an||RD,large DT lamellae fraction formed at∼30°and few ETs at∼30°and∼90°to the notch with crack growth mainly via the∑23b/∑15a CSLB interfaces during FT.While,significant DT and ET lamellae developed at∼0°and∼60°with cracking via the matrix-DT∑23b/∑15a and matrix-ET||15b CSLBs for an⊥RD.The DT and ET lamellae activated at∼15°,and the crack propagated through∑15b for an∼45°to RD.The JIC and the crack-tip plastic zone decreases,while the elastic component of the J-integral(Jel)and the ET formation increases from an||,⊥,to∼45°to RD.The strain incompatibility of matrices was higher with the geometrically hard ETs than DTs.Thus,brittle interlamellar cracking occurred through the∑15b interfaces.In contrast,almost similar and higher crack-tip plasticity occurred in matrix and DT domains during crack propagation via||23b/||15a CSLBs.Crack growth through∑23b/||15a led to high JIC,both∑15b and||23b/||15a led to moderate JIC,and∑15b least JIC for an||,⊥and 45°to RD,respectively.展开更多
Fracture propagation in shale under in situ conditions is a critical but poorly understood mechanical process in hydraulic fracturing for deep shale gas reservoirs. To address this, hydraulic fracturing experiments we...Fracture propagation in shale under in situ conditions is a critical but poorly understood mechanical process in hydraulic fracturing for deep shale gas reservoirs. To address this, hydraulic fracturing experiments were conducted on hollow double-wing crack specimens of the Longmaxi shale under conditions simulating the ground surface(confining pressure σ_(cp)=0, room temperature(Tr)) and at depths of 1600 m(σ_(cp)=40 MPa, Ti=70 ℃) and 3300 m(σ_(cp)=80 MPa, high temperature Ti=110 ℃) in the study area.High in situ stress was found to significantly increase fracture toughness through constrained microcracking and particle frictional bridging mechanisms. Increasing the temperature enhances rather than weakens the fracture resistance because it increases the grain debonding length, which dissipates more plastic energy and enlarges grains to close microdefects and generate compressive stress to inhibit microcracking. Interestingly, the fracture toughness anisotropy in the shale was found to be nearly constant across burial depths, despite reported variations with increasing confining pressure. Heated water was not found to be as important as the in situ environment in influencing shale fracture. These findings emphasize the need to test the fracture toughness of deep shales under coupled in situ stress and temperature conditions rather than focusing on either in situ stress or temperature alone.展开更多
The instrumented scratch test,which has the advantages of simple sample preparation,high test efficiency,and low cost,has become an effective technique to investigate contact mechanisms(e.g.,contact-induced surface de...The instrumented scratch test,which has the advantages of simple sample preparation,high test efficiency,and low cost,has become an effective technique to investigate contact mechanisms(e.g.,contact-induced surface deformation,single-asperity contact,sliding contact,reciprocating sliding,elastic recovery,stick-slip behaviors,damage/cracking,buckling failure of films,mechanical glass frosting,abrasive machining mechanism,cutting,wear,grinding and polishing)and a large quantity of mechanical properties(e.g.,scratch resistance,tribological behavior,friction coefficient,structural integrity,hardness,strength,and fracture toughness)of various solids(e.g.,multilayer coatings,single crystals,bones,gels,polymers,ceramics,glasses,semiconductors,metals,concreates,shales,rocks,and composites)based on the measured scratch variables such as penetration depth and lateral force.展开更多
The instrumented scratch test,which has the advantages of simple sample preparation,high test efficiency,and low cost,has become an effective technique to investigate contact mechanisms(e.g.,contact-induced surface de...The instrumented scratch test,which has the advantages of simple sample preparation,high test efficiency,and low cost,has become an effective technique to investigate contact mechanisms(e.g.,contact-induced surface deformation,single-asperity contact,sliding contact,reciprocating sliding,elastic recovery,stick-slip behaviors,damage/cracking,buckling failure of films,mechanical glass frosting,abrasive machining mechanism,cutting,wear,grinding and polishing)and a large quantity of mechanical properties(e.g.,scratch resistance,tribological behavior,friction coefficient,structural integrity,hardness,strength,and fracture toughness)of various solids(e.g.,multilayer coatings,single crystals,bones,gels,polymers,ceramics,glasses,semiconductors,metals,concreates,shales,rocks,and composites)based on the measured scratch variables such as penetration depth and lateral force.The application of instrumented scratch to characterization of mechanical properties of materials based on the quantitative relationships linking macroscopic mechanical properties of materials with characteristic values of measured variables during scratching under different conditions(e.g.,different geometries of indenters)has great potential in the fields of materials science and engineering.展开更多
By both the Charpy V-notched impact and the projectile tests, we here investigated the dynamic fracture behavior of a recently developed ultrastrong lightweight steel comprising a hierarchical martensitic matrix, disp...By both the Charpy V-notched impact and the projectile tests, we here investigated the dynamic fracture behavior of a recently developed ultrastrong lightweight steel comprising a hierarchical martensitic matrix, dispersed ultra-fine-retained austenite grains and oriented δ-ferrite lamellas, the latter being due to high Al and Si contents employed for low-density design. This steel shows a superior combination of specific ultimate tensile strength and impact toughness to other ultrastrong steels and has successfully arrested a real steel-cored bullet shot. These are attributed to the densely textured δ-ferrite lamellas that can deflect the propagating cracks until they are trapped and enclosed besides austenite-to-martensite transformation crack closure, leading to more energy consumed before failure. These results suggest a new pathway for toughening ultrastrong lightweight steels.展开更多
Silicon-based materials have demonstrated remarkable potential in high-energy-density batteries owing to their high theoretical capacity.However,the significant volume expansion of silicon seriously hinders its utiliz...Silicon-based materials have demonstrated remarkable potential in high-energy-density batteries owing to their high theoretical capacity.However,the significant volume expansion of silicon seriously hinders its utilization as a lithium-ion anode.Herein,a functionalized high-toughness polyimide(PDMI) is synthesized by copolymerizing the 4,4'-Oxydiphthalic anhydride(ODPA) with 4,4'-oxydianiline(ODA),2,3-diaminobenzoic acid(DABA),and 1,3-bis(3-aminopropyl)-tetramethyl disiloxane(DMS).The combination of rigid benzene rings and flexible oxygen groups(-O-) in the PDMI molecular chain via a rigidness/softness coupling mechanism contributes to high toughness.The plentiful polar carboxyl(-COOH) groups establish robust bonding strength.Rapid ionic transport is achieved by incorporating the flexible siloxane segment(Si-O-Si),which imparts high molecular chain motility and augments free volume holes to facilitate lithium-ion transport(9.8 × 10^(-10) cm^(2) s^(-1) vs.16 × 10^(-10) cm^(2) s~(-1)).As expected,the SiO_x@PDMI-1.5 electrode delivers brilliant long-term cycle performance with a remarkable capacity retention of 85% over 500 cycles at 1.3 A g^(-1).The well-designed functionalized polyimide also significantly enhances the electrochemical properties of Si nanoparticles electrode.Meanwhile,the assembled SiO_x@PDMI-1.5/NCM811 full cell delivers a high retention of 80% after 100 cycles.The perspective of the binder design strategy based on polyimide modification delivers a novel path toward high-capacity electrodes for high-energy-density batteries.展开更多
The fracture toughness of extruded Mg-1Zn-2Y(at.%)alloys,featuring a multimodal microstructure containing fine dynamically recrystallized(DRXed)grains with random crystallographic orientation and coarse-worked grains ...The fracture toughness of extruded Mg-1Zn-2Y(at.%)alloys,featuring a multimodal microstructure containing fine dynamically recrystallized(DRXed)grains with random crystallographic orientation and coarse-worked grains with a strong fiber texture,was investigated.The DRXed grains comprised randomly oriented equiaxedα-Mg grains.In contrast,the worked grains includedα-Mg and long-period stacking ordered(LPSO)phases that extended in the extrusion direction(ED).Both types displayed a strong texture,aligning the(10.10)direction parallel to the ED.The volume fractions of the DRXed and worked grains were controlled by adjusting the extrusion temperature.In the longitudinal-transverse(L-T)orientation,where the loading direction was aligned parallel to the ED,there was a tendency for the conditional fracture toughness,KQ,tended to increase as the volume fraction of the worked grains increased.However,the KQ values in the T-L orientation,where the loading direction was perpendicular to the ED,decreased with an increase in the volume fraction of the worked grains.This suggests strong anisotropy in the fracture toughness of the specimen with a high volume fraction of the worked grains,relative to the test direction.The worked grains,which included the LPSO phase and were elongated perpendicular to the initial crack plane,suppressed the straight crack extension,causing crack deflection,and generating secondary cracks.Thus,these worked grains significantly contributed to the fracture toughness of the extruded Mg-1Zn-2Y alloys in the L-T orientation.展开更多
The current research of Charpy impact mainly focuses on obtaining the ductile brittle transition temperature of materials by experiments.Compared with experiments,numerical simulation can study many problems with hars...The current research of Charpy impact mainly focuses on obtaining the ductile brittle transition temperature of materials by experiments.Compared with experiments,numerical simulation can study many problems with harsh conditions.However,there are still few studies on the influence of geometric factors such as side grooves.In this paper,the geometry of standard Charpy impact test is designed.Specimens with different widths and side grooves are tested.The finite element model of Charpy impact was established by ABAQUS software.Use test results and simulation results to verify each other.The effects of sample width,side groove depth and side groove bottom fillet on the impact fracture resistance of the sample were studied.The results show that the specimen width is positively correlated with the impact toughness of the specimen.The side groove greatly reduces the impact toughness of the material;the toughness of side groove decreases with the increase of depth;the fracture toughness of side groove decreases with the increase of fillet at the bottom of side groove.The proportion of toughness energy to impact energy of samples was analyzed.The results show that the toughness energy accounts for about 70%of the impact energy of the sample,which has little to do with the geometric characteristics of the sample.This study presents a reliable method for studying Charpy impact tests.The influence of geometric parameters is obtained,which provides a reference method for the study of impact toughness of high toughness materials.展开更多
The peridynamics(PD),as a promising nonlocal continuum mechanics theory,shines in solving discontinuous problems.Up to now,various numerical methods,such as the peridynamic mesh-free particlemethod(PD-MPM),peridynamic...The peridynamics(PD),as a promising nonlocal continuum mechanics theory,shines in solving discontinuous problems.Up to now,various numerical methods,such as the peridynamic mesh-free particlemethod(PD-MPM),peridynamic finite element method(PD-FEM),and peridynamic boundary element method(PD-BEM),have been proposed.PD-BEM,in particular,outperforms other methods by eliminating spurious boundary softening,efficiently handling infinite problems,and ensuring high computational accuracy.However,the existing PD-BEM is constructed exclusively for bond-based peridynamics(BBPD)with fixed Poisson’s ratio,limiting its applicability to crack propagation problems and scenarios involving infinite or semi-infinite problems.In this paper,we address these limitations by introducing the boundary element method(BEM)for ordinary state-based peridynamics(OSPD-BEM).Additionally,we present a crack propagationmodel embeddedwithin the framework ofOSPD-BEM to simulate crack propagations.To validate the effectiveness of OSPD-BEM,we conduct four numerical examples:deformation under uniaxial loading,crack initiation in a double-notched specimen,wedge-splitting test,and threepoint bending test.The results demonstrate the accuracy and efficiency of OSPD-BEM,highlighting its capability to successfully eliminate spurious boundary softening phenomena under varying Poisson’s ratios.Moreover,OSPDBEMsignificantly reduces computational time and exhibits greater consistencywith experimental results compared to PD-MPM.展开更多
Compared with the conventional Charpy impact test method,the oscillographic impact test can help in the behavioral analysis of materials during the fracture process.In this study,the trade-off relationship between the...Compared with the conventional Charpy impact test method,the oscillographic impact test can help in the behavioral analysis of materials during the fracture process.In this study,the trade-off relationship between the strength and toughness of a DZ2 axle steel at various tempering temperatures and the cause of the improvement in impact toughness was evaluated.The tempering process dramatically influenced carbide precipitation behavior,which resulted in different aspect ratios of carbides.Impact toughness improved along with the rise in tempering temperature mainly due to the increase in energy required in impact crack propagation.The characteristics of the impact crack propagation process were studied through a comprehensive analysis of stress distribution,oscilloscopic impact statistics,fracture morphology,and carbide morphology.The poor impact toughness of low-tempering-temperature specimens was attributed to the increased number of stress concentration points caused by carbide morphology in the small plastic zone during the propagation process,which resulted in a mixed distribution of brittle and ductile fractures on the fracture surface.展开更多
The fracture toughness of rocks is a critical fracturing parameter in geo-energy exploitation playing a significant role in fracture mechanics and hydraulic fracturing.The edge-notched disk bending(ENDB)specimens are ...The fracture toughness of rocks is a critical fracturing parameter in geo-energy exploitation playing a significant role in fracture mechanics and hydraulic fracturing.The edge-notched disk bending(ENDB)specimens are employed to measure the entire range of mixed-modeⅠ/Ⅲfracture toughness of Longmaxi shale.To theoretically interpret the fracture mechanisms,this research first introduces the detailed derivations of three established fracture criteria.By distinguishing the volumetric and distortional strain energy densities,an improved three-dimensional mean strain energy density(MSED)criterion is proposed.As the critical volumetric to distortional MSED ratio decreases,the transition from tensiondominated fracture to shear-dominated fracture is observed.Our results indicate that both peak load and applied energy increase significantly with the transition from pure mode I(i.e.,tension)to pure modeⅢ(i.e.,torsion or tearing)since mode-Ⅲcracking happens in a twisted manner and mode-Ⅰcracking occurs in a coplanar manner.The macroscopic fracture signatures are consistent with those of triaxial hydraulic fracturing.The average ratio of pure mode-Ⅲfracture toughness to pure mode-Ⅰfracture toughness is 0.68,indicating that the obtained mode-Ⅲfracture resistance for a tensionbased loading system is apparent rather than true.Compared to the three mainstream fracture criteria,the present fracture criterion exhibits greater competitiveness and can successfully evaluate and predict mixed-modeⅠ/Ⅲfracture toughness of distinct materials and loading methods.展开更多
The mechanical properties of two main precipitating phases(LPSO and MgRE)and matrix in Mg-Gd-Y-Nd-Zn bioalloy were examined using nanoindentation method.A new is suggested for characterizing the elastic-plastic behavi...The mechanical properties of two main precipitating phases(LPSO and MgRE)and matrix in Mg-Gd-Y-Nd-Zn bioalloy were examined using nanoindentation method.A new is suggested for characterizing the elastic-plastic behavior,fracture toughness and strain rate sensitivity(SRS)of materials within micro/nanoscale.Firstly,a nanomechanical model was developed for extracting hardness(H),young’s modulus(E)and yield stress(σY)from the characteristic load points which were subsequently analyzed by atomic force microscope(AFM)images.The elasticity data and AFM data were then utilized for determination of plastic deformation in constituent phases.The displacement of the indentation gets the highest value for Mg matrix and between precipitates,depth is more in LPSO rather than that of MgRE.The serrated flow or the behavior of shear bands may originate from the side effect of the interface region in Mg alloys with precipitates.It can be deduced that the KIC produced by both L method and energy-based calculation are both reliable for KIC approximation.The maximum load in simulation withμ=0.2 friction is marginally lesser than that of the frictionless(μ=0)one while elastic recovery of indentation withμ=0.2 is higher to some extent.展开更多
The present work attributes the role of boron on the high strength steel submerged arc weld using an undermatching filler wire.Mild steel filler wire was used for welding in constant machine parameters setting to eval...The present work attributes the role of boron on the high strength steel submerged arc weld using an undermatching filler wire.Mild steel filler wire was used for welding in constant machine parameters setting to evaluate the joint strength due to the enrichment of boron.To change the chemical composition of the weld metal,boron trioxide powder was blended with virgin flux in various proportions(2.5%−12.5%),which led to an increase in boron weight percentage in the range of 0−0.0065.The results show that weld metals(WM)optical micrographs depict the various types of ferrites,pearlites and secondary phases like martensite-austenite(M-A).Acicular ferrite content was influenced by the boron trioxide addition.Heat affected zone(HAZ)micrographs were not showing appreciable changes with oxide enrichment.Hardness and toughness of weld metals showed the mixed trend with B_(2)O_(3) enrichment whereas,small reduction in ultimate tensile strength(UTS)and yield strength(YS)was observed.展开更多
World Cinema Issue 3(Bimonthly),2024 Film as Painting:Nollywood's Philosophical Understanding of the Photographic Medium This issue focuses on national films,with three articles analyzing one or more representativ...World Cinema Issue 3(Bimonthly),2024 Film as Painting:Nollywood's Philosophical Understanding of the Photographic Medium This issue focuses on national films,with three articles analyzing one or more representative flms from three countries.Film as Painting:Nollywood's Philosophical Understanding of the Photographic Medium explores thephilosophical roots of photography in Nigerian film;Stalkers in Istanbul:Silence,Urban Space,and Damaged Masculinity in Nuri Bilge Ceylan's UZAK shows the decaying male image on Turkish film screens as opposed to the tough guy;The Broken Frame:The Non-Creative WaysofAbbasKiarostami in 24 FRAME Sprovides a frame-by-frame analysis of the lranian director's use of off-screen space to activate the imagination of the audience.展开更多
主题语境:人与自然篇幅:379词关键词:structural color1 Scientists at the University of Central Florida(UCF)have created a new kind of paint thats super light and super tough.The colors in the new paint arent at all like ...主题语境:人与自然篇幅:379词关键词:structural color1 Scientists at the University of Central Florida(UCF)have created a new kind of paint thats super light and super tough.The colors in the new paint arent at all like those in most paints.Instead,theyre more like the colors on a butterflys wings.展开更多
In 2023,unfavorable macro-economic conditions such as high inflation and interest rates currently combine with unfavorable industry specific aspects such as high inventories at brand and retail level,creating pressure...In 2023,unfavorable macro-economic conditions such as high inflation and interest rates currently combine with unfavorable industry specific aspects such as high inventories at brand and retail level,creating pressure on textile manufacturers from both supply and demand sides.When the textile industry is going through a tough phase,ITMF helps the industry to change its growth pattern with an innovative and responsible attitude,actively promotes international trade and investment,plays its full role in promoting the economic growth of the industry and strives to build an open global textile economy.At the same time,ITMF advocates diversity and inclusion,implements the United Nations"The 2030 Agenda for Sustainable Development"and promotes the realisation of the industry’s development outcomes.展开更多
On March 12,the official account of the International Business Daily of the Ministry of Commerce published an article titled“Foreign trade enterprises:full of confidence,clear direction,strong motivation”.The conten...On March 12,the official account of the International Business Daily of the Ministry of Commerce published an article titled“Foreign trade enterprises:full of confidence,clear direction,strong motivation”.The content is as follows:This year,China is still facing a tough foreign trade situation.On the one hand,many international organizations predict that global economic growth in 2024 will still be lower than the historical average and the pressure on external demand will increase;on the other hand,trade protectionism and unilateralism are on the rise,geopolitical conflicts,the global“super election year”and other spillover factors have created many uncertainties.展开更多
基金We acknowledge the funding support from the National Natural Science Foundation of China(Grant No.42271148).
文摘Due to the presence of ice and unfrozen water in pores of frozen rock,the rock fracture behaviors are susceptible to temperature.In this study,the potential thawing-induced softening effects on the fracture behaviors of frozen rock is evaluated by testing the tension fracture toughness(KIC)of frozen rock at different temperatures(i.e.-20℃,-15℃,-12℃,-10℃,-8℃,-6℃,-4℃,-2℃,and 0℃).Acoustic emission(AE)and digital image correlation(DIC)methods are utilized to analyze the microcrack propagation during fracturing.The melting of pore ice is measured using nuclear magnetic resonance(NMR)method.The results indicate that:(1)The KIC of frozen rock decreases moderately between-20℃ and-4℃,and rapidly between-4℃ and 0℃.(2)At-20℃ to-4℃,the fracturing process,deduced from the DIC results at the notch tip,exhibits three stages:elastic deformation,microcrack propagation and microcrack coalescence.However,at-4℃e0℃,only the latter two stages are observed.(3)At-4℃e0℃,the AE activities during fracturing are less than that at-20℃ to-4℃,while more small events are reported.(4)The NMR results demonstrate a reverse variation trend in pore ice content with increasing temperature,that is,a moderate decrease is followed by a sharp decrease and-4℃ is exactly the critical temperature.Next,we interpret the thawing-induced softening effect by linking the evolution in microscopic structure of frozen rock with its macroscopic fracture behaviors as follow:from-20℃ to-4℃,the thickening of the unfrozen water film diminishes the cementation strength between ice and rock skeleton,leading to the decrease in fracture parameters.From-4℃ to 0℃,the cementation effect of ice almost vanishes,and the filling effect of pore ice is reduced significantly,which facilitates microcrack propagation and thus the easier fracture of frozen rocks.
基金supported by the National Key Research and Development Program of China(2022YFB3804903 and 2022YFB3804900)the National Natural Science Foundation of China(52273052)+1 种基金the Program of Shanghai Academic/Technology Research Leader(21XD1420100)the International Cooperation Fund of Science and Technology Commission of Shanghai Municipality(21130750100).
文摘Biodegradable polylactic acid(PLA)melt-blown nonwovens are attractive candidates to replace nondegradable polypropylene melt-blown nonwovens.However,it is still an extremely challenging task to prepare PLA melt-blown nonwovens with sufficient mechanical properties for practical application.Herein,we report a simple strategy for the large-scale preparation of biodegradable PLA/poly(3-hydroxybutyrate-co-3-hydroxyvalerate)(PHBV)melt-blown nonwovens with high strength and excellent toughness.In this process,a small amount of PHBV is added to PLA to improve the latter’s crystallization rate and crystallinity.In addition,when the PHBV content increases from 0 to 7.5 wt%,the diameters of the PLA/PHBV melt-blown fibers decrease significantly(with the proportion of nanofibers increasing from 7.7%to 42.9%).The resultant PLA/PHBV(5 wt%PHBV)melt-blown nonwovens exhibit the highest mechanical properties.The tensile stress,elongation,and toughness of PLA/PHBV(5 wt%PHBV)melt-blown nonwovens reach 2.5 MPa,45%,and 1.0 MJm3,respectively.More importantly,PLA/PHBV melt-blown nonwovens can be completely degraded into carbon dioxide and water after four months in the soil,making them environmentally friendly.A general tensile-failure model of melt-blown nonwovens is proposed in this study,which may shed light on mechanical performance enhancement for nonwovens.
文摘A toughener that can effectively improve the interlaminar toughness in carbon fiber composites is crucial for various applications.We investigated,the toughening effects of phenolphthalein-based cardo poly(ether sulfone)(PES-C)on E51/DETDA epoxy and its carbon fiber composites(CFCs).Scanning electron microscopy showed that the phase structures of PES-C/epoxy blends change from island(of dispersed phase)structures to bi-continuous structures(of the matrix)as the PES-C content increased,which is associated with reaction-induced phase separation.After adding 15 phr PES-C,the glass transition temperature(T_(g))of the blends increased by 51.5℃,and the flexural strength,impact strength and fracture toughness of the blends were improved by 41.1%,186.2%and 42.7%,respectively.These improvements could be attributed to the phase separation structure of the PES-C/epoxy sys-tem.A PES-C film was used to improve the mode-II fracture toughness(G_(IIC))of CFCs.The G_(IIC) value of the 7μm PES-C film toughened laminate was improved by 80.3%compared to that of the control laminate.The increase in G_(IIC) was attributed to cohesive failure and plastic deformation in the interleaving region.
基金financial support provided by the Science and Engineering Research Board (Ref. no.: ECR/2016/000125), Department of Science and Technology, Government of India
文摘Bioimplant grade hot-rolled magnesium with equiaxed microstructure and basal texture was examined for fracture toughness(FT)anisotropy using fatigue pre-cracked single-edge notch bending specimens with the notch,an||,⊥and 45°to rolling direction(RD).Due to adequate crack-tip plasticity,the size-independent elastic-plastic fracture toughness(JIC)were determined.Anisotropic JIC was ob-served due to different twin lamellae formation w.r.t.notch owing to the initial basal texture with{10¯10}and{11¯20}poles mostlyand⊥to RD.The out-of-plane tensile stresses activated the{10¯12}||10¯11||extension twins(ET)as usual with matrix-ET∑15b coincident site lattice boundary(CSLB)interfaces.While the in-plane tensile stress⊥to the crack-tip activated{10¯11}||10¯12||contraction twins(CT)that transform into{10¯11}-{10¯12}double twins(DT)with matrix-DT∑23b and∑15a CSLBs.For an||RD,large DT lamellae fraction formed at∼30°and few ETs at∼30°and∼90°to the notch with crack growth mainly via the∑23b/∑15a CSLB interfaces during FT.While,significant DT and ET lamellae developed at∼0°and∼60°with cracking via the matrix-DT∑23b/∑15a and matrix-ET||15b CSLBs for an⊥RD.The DT and ET lamellae activated at∼15°,and the crack propagated through∑15b for an∼45°to RD.The JIC and the crack-tip plastic zone decreases,while the elastic component of the J-integral(Jel)and the ET formation increases from an||,⊥,to∼45°to RD.The strain incompatibility of matrices was higher with the geometrically hard ETs than DTs.Thus,brittle interlamellar cracking occurred through the∑15b interfaces.In contrast,almost similar and higher crack-tip plasticity occurred in matrix and DT domains during crack propagation via||23b/||15a CSLBs.Crack growth through∑23b/||15a led to high JIC,both∑15b and||23b/||15a led to moderate JIC,and∑15b least JIC for an||,⊥and 45°to RD,respectively.
基金supported by the National Natural Science Foundation of China(No.12172240).
文摘Fracture propagation in shale under in situ conditions is a critical but poorly understood mechanical process in hydraulic fracturing for deep shale gas reservoirs. To address this, hydraulic fracturing experiments were conducted on hollow double-wing crack specimens of the Longmaxi shale under conditions simulating the ground surface(confining pressure σ_(cp)=0, room temperature(Tr)) and at depths of 1600 m(σ_(cp)=40 MPa, Ti=70 ℃) and 3300 m(σ_(cp)=80 MPa, high temperature Ti=110 ℃) in the study area.High in situ stress was found to significantly increase fracture toughness through constrained microcracking and particle frictional bridging mechanisms. Increasing the temperature enhances rather than weakens the fracture resistance because it increases the grain debonding length, which dissipates more plastic energy and enlarges grains to close microdefects and generate compressive stress to inhibit microcracking. Interestingly, the fracture toughness anisotropy in the shale was found to be nearly constant across burial depths, despite reported variations with increasing confining pressure. Heated water was not found to be as important as the in situ environment in influencing shale fracture. These findings emphasize the need to test the fracture toughness of deep shales under coupled in situ stress and temperature conditions rather than focusing on either in situ stress or temperature alone.
文摘The instrumented scratch test,which has the advantages of simple sample preparation,high test efficiency,and low cost,has become an effective technique to investigate contact mechanisms(e.g.,contact-induced surface deformation,single-asperity contact,sliding contact,reciprocating sliding,elastic recovery,stick-slip behaviors,damage/cracking,buckling failure of films,mechanical glass frosting,abrasive machining mechanism,cutting,wear,grinding and polishing)and a large quantity of mechanical properties(e.g.,scratch resistance,tribological behavior,friction coefficient,structural integrity,hardness,strength,and fracture toughness)of various solids(e.g.,multilayer coatings,single crystals,bones,gels,polymers,ceramics,glasses,semiconductors,metals,concreates,shales,rocks,and composites)based on the measured scratch variables such as penetration depth and lateral force.
文摘The instrumented scratch test,which has the advantages of simple sample preparation,high test efficiency,and low cost,has become an effective technique to investigate contact mechanisms(e.g.,contact-induced surface deformation,single-asperity contact,sliding contact,reciprocating sliding,elastic recovery,stick-slip behaviors,damage/cracking,buckling failure of films,mechanical glass frosting,abrasive machining mechanism,cutting,wear,grinding and polishing)and a large quantity of mechanical properties(e.g.,scratch resistance,tribological behavior,friction coefficient,structural integrity,hardness,strength,and fracture toughness)of various solids(e.g.,multilayer coatings,single crystals,bones,gels,polymers,ceramics,glasses,semiconductors,metals,concreates,shales,rocks,and composites)based on the measured scratch variables such as penetration depth and lateral force.The application of instrumented scratch to characterization of mechanical properties of materials based on the quantitative relationships linking macroscopic mechanical properties of materials with characteristic values of measured variables during scratching under different conditions(e.g.,different geometries of indenters)has great potential in the fields of materials science and engineering.
基金financial support from National Natural Science Foundation of China(Grant Nos.51831002,51904028 and 52233018),ChinaFundamental Research Funds for the Central Universities(Grant No.06500151),China.
文摘By both the Charpy V-notched impact and the projectile tests, we here investigated the dynamic fracture behavior of a recently developed ultrastrong lightweight steel comprising a hierarchical martensitic matrix, dispersed ultra-fine-retained austenite grains and oriented δ-ferrite lamellas, the latter being due to high Al and Si contents employed for low-density design. This steel shows a superior combination of specific ultimate tensile strength and impact toughness to other ultrastrong steels and has successfully arrested a real steel-cored bullet shot. These are attributed to the densely textured δ-ferrite lamellas that can deflect the propagating cracks until they are trapped and enclosed besides austenite-to-martensite transformation crack closure, leading to more energy consumed before failure. These results suggest a new pathway for toughening ultrastrong lightweight steels.
基金supported by the National Natural Science Foundation of China (51673017)the National Natural Science Foundation of China (21404005)+1 种基金the Fundamental Research Funds for the Central Universities (XK1802-2)the Natural Science Foundation of Jiangsu Province (BK20150273)。
文摘Silicon-based materials have demonstrated remarkable potential in high-energy-density batteries owing to their high theoretical capacity.However,the significant volume expansion of silicon seriously hinders its utilization as a lithium-ion anode.Herein,a functionalized high-toughness polyimide(PDMI) is synthesized by copolymerizing the 4,4'-Oxydiphthalic anhydride(ODPA) with 4,4'-oxydianiline(ODA),2,3-diaminobenzoic acid(DABA),and 1,3-bis(3-aminopropyl)-tetramethyl disiloxane(DMS).The combination of rigid benzene rings and flexible oxygen groups(-O-) in the PDMI molecular chain via a rigidness/softness coupling mechanism contributes to high toughness.The plentiful polar carboxyl(-COOH) groups establish robust bonding strength.Rapid ionic transport is achieved by incorporating the flexible siloxane segment(Si-O-Si),which imparts high molecular chain motility and augments free volume holes to facilitate lithium-ion transport(9.8 × 10^(-10) cm^(2) s^(-1) vs.16 × 10^(-10) cm^(2) s~(-1)).As expected,the SiO_x@PDMI-1.5 electrode delivers brilliant long-term cycle performance with a remarkable capacity retention of 85% over 500 cycles at 1.3 A g^(-1).The well-designed functionalized polyimide also significantly enhances the electrochemical properties of Si nanoparticles electrode.Meanwhile,the assembled SiO_x@PDMI-1.5/NCM811 full cell delivers a high retention of 80% after 100 cycles.The perspective of the binder design strategy based on polyimide modification delivers a novel path toward high-capacity electrodes for high-energy-density batteries.
基金supported by the JST CREST for Research Area“Nanomechanics”[JPMJCR2094]the JSPS KAKENHI for Scientific Research B[JP21H01673]the AMADA Foundation[AF-2023044-C2].
文摘The fracture toughness of extruded Mg-1Zn-2Y(at.%)alloys,featuring a multimodal microstructure containing fine dynamically recrystallized(DRXed)grains with random crystallographic orientation and coarse-worked grains with a strong fiber texture,was investigated.The DRXed grains comprised randomly oriented equiaxedα-Mg grains.In contrast,the worked grains includedα-Mg and long-period stacking ordered(LPSO)phases that extended in the extrusion direction(ED).Both types displayed a strong texture,aligning the(10.10)direction parallel to the ED.The volume fractions of the DRXed and worked grains were controlled by adjusting the extrusion temperature.In the longitudinal-transverse(L-T)orientation,where the loading direction was aligned parallel to the ED,there was a tendency for the conditional fracture toughness,KQ,tended to increase as the volume fraction of the worked grains increased.However,the KQ values in the T-L orientation,where the loading direction was perpendicular to the ED,decreased with an increase in the volume fraction of the worked grains.This suggests strong anisotropy in the fracture toughness of the specimen with a high volume fraction of the worked grains,relative to the test direction.The worked grains,which included the LPSO phase and were elongated perpendicular to the initial crack plane,suppressed the straight crack extension,causing crack deflection,and generating secondary cracks.Thus,these worked grains significantly contributed to the fracture toughness of the extruded Mg-1Zn-2Y alloys in the L-T orientation.
基金Supported by National Natural Science Foundation of China(Grant Nos.51975526,51505425)National Key R&D Program of China(Grant No.2018YFC0808800)+1 种基金Open Project of Key Laboratory of MEM of China(Grant No.2020XFZB10)Technical Service Projects(Grant Nos.HZFS-XZ-2022-07-02,XJBY-20211221).
文摘The current research of Charpy impact mainly focuses on obtaining the ductile brittle transition temperature of materials by experiments.Compared with experiments,numerical simulation can study many problems with harsh conditions.However,there are still few studies on the influence of geometric factors such as side grooves.In this paper,the geometry of standard Charpy impact test is designed.Specimens with different widths and side grooves are tested.The finite element model of Charpy impact was established by ABAQUS software.Use test results and simulation results to verify each other.The effects of sample width,side groove depth and side groove bottom fillet on the impact fracture resistance of the sample were studied.The results show that the specimen width is positively correlated with the impact toughness of the specimen.The side groove greatly reduces the impact toughness of the material;the toughness of side groove decreases with the increase of depth;the fracture toughness of side groove decreases with the increase of fillet at the bottom of side groove.The proportion of toughness energy to impact energy of samples was analyzed.The results show that the toughness energy accounts for about 70%of the impact energy of the sample,which has little to do with the geometric characteristics of the sample.This study presents a reliable method for studying Charpy impact tests.The influence of geometric parameters is obtained,which provides a reference method for the study of impact toughness of high toughness materials.
基金supported by the National Key R&D Program of China(2020YFA0710500).
文摘The peridynamics(PD),as a promising nonlocal continuum mechanics theory,shines in solving discontinuous problems.Up to now,various numerical methods,such as the peridynamic mesh-free particlemethod(PD-MPM),peridynamic finite element method(PD-FEM),and peridynamic boundary element method(PD-BEM),have been proposed.PD-BEM,in particular,outperforms other methods by eliminating spurious boundary softening,efficiently handling infinite problems,and ensuring high computational accuracy.However,the existing PD-BEM is constructed exclusively for bond-based peridynamics(BBPD)with fixed Poisson’s ratio,limiting its applicability to crack propagation problems and scenarios involving infinite or semi-infinite problems.In this paper,we address these limitations by introducing the boundary element method(BEM)for ordinary state-based peridynamics(OSPD-BEM).Additionally,we present a crack propagationmodel embeddedwithin the framework ofOSPD-BEM to simulate crack propagations.To validate the effectiveness of OSPD-BEM,we conduct four numerical examples:deformation under uniaxial loading,crack initiation in a double-notched specimen,wedge-splitting test,and threepoint bending test.The results demonstrate the accuracy and efficiency of OSPD-BEM,highlighting its capability to successfully eliminate spurious boundary softening phenomena under varying Poisson’s ratios.Moreover,OSPDBEMsignificantly reduces computational time and exhibits greater consistencywith experimental results compared to PD-MPM.
基金the National Natural Science Foundation of China(Nos.52001310 and 52130002)the National Science and Technology Major Project(No.J2019-VI-0019-0134)+1 种基金KC Wong Education Foundation(No.GJTD-2020-09)Institute of Metal Res earch Innovation Fund(No.2023-ZD01)。
文摘Compared with the conventional Charpy impact test method,the oscillographic impact test can help in the behavioral analysis of materials during the fracture process.In this study,the trade-off relationship between the strength and toughness of a DZ2 axle steel at various tempering temperatures and the cause of the improvement in impact toughness was evaluated.The tempering process dramatically influenced carbide precipitation behavior,which resulted in different aspect ratios of carbides.Impact toughness improved along with the rise in tempering temperature mainly due to the increase in energy required in impact crack propagation.The characteristics of the impact crack propagation process were studied through a comprehensive analysis of stress distribution,oscilloscopic impact statistics,fracture morphology,and carbide morphology.The poor impact toughness of low-tempering-temperature specimens was attributed to the increased number of stress concentration points caused by carbide morphology in the small plastic zone during the propagation process,which resulted in a mixed distribution of brittle and ductile fractures on the fracture surface.
基金supported by National Natural Science Foundation of China(Grant Nos.52364004,52264006,and 52164001).
文摘The fracture toughness of rocks is a critical fracturing parameter in geo-energy exploitation playing a significant role in fracture mechanics and hydraulic fracturing.The edge-notched disk bending(ENDB)specimens are employed to measure the entire range of mixed-modeⅠ/Ⅲfracture toughness of Longmaxi shale.To theoretically interpret the fracture mechanisms,this research first introduces the detailed derivations of three established fracture criteria.By distinguishing the volumetric and distortional strain energy densities,an improved three-dimensional mean strain energy density(MSED)criterion is proposed.As the critical volumetric to distortional MSED ratio decreases,the transition from tensiondominated fracture to shear-dominated fracture is observed.Our results indicate that both peak load and applied energy increase significantly with the transition from pure mode I(i.e.,tension)to pure modeⅢ(i.e.,torsion or tearing)since mode-Ⅲcracking happens in a twisted manner and mode-Ⅰcracking occurs in a coplanar manner.The macroscopic fracture signatures are consistent with those of triaxial hydraulic fracturing.The average ratio of pure mode-Ⅲfracture toughness to pure mode-Ⅰfracture toughness is 0.68,indicating that the obtained mode-Ⅲfracture resistance for a tensionbased loading system is apparent rather than true.Compared to the three mainstream fracture criteria,the present fracture criterion exhibits greater competitiveness and can successfully evaluate and predict mixed-modeⅠ/Ⅲfracture toughness of distinct materials and loading methods.
文摘The mechanical properties of two main precipitating phases(LPSO and MgRE)and matrix in Mg-Gd-Y-Nd-Zn bioalloy were examined using nanoindentation method.A new is suggested for characterizing the elastic-plastic behavior,fracture toughness and strain rate sensitivity(SRS)of materials within micro/nanoscale.Firstly,a nanomechanical model was developed for extracting hardness(H),young’s modulus(E)and yield stress(σY)from the characteristic load points which were subsequently analyzed by atomic force microscope(AFM)images.The elasticity data and AFM data were then utilized for determination of plastic deformation in constituent phases.The displacement of the indentation gets the highest value for Mg matrix and between precipitates,depth is more in LPSO rather than that of MgRE.The serrated flow or the behavior of shear bands may originate from the side effect of the interface region in Mg alloys with precipitates.It can be deduced that the KIC produced by both L method and energy-based calculation are both reliable for KIC approximation.The maximum load in simulation withμ=0.2 friction is marginally lesser than that of the frictionless(μ=0)one while elastic recovery of indentation withμ=0.2 is higher to some extent.
文摘The present work attributes the role of boron on the high strength steel submerged arc weld using an undermatching filler wire.Mild steel filler wire was used for welding in constant machine parameters setting to evaluate the joint strength due to the enrichment of boron.To change the chemical composition of the weld metal,boron trioxide powder was blended with virgin flux in various proportions(2.5%−12.5%),which led to an increase in boron weight percentage in the range of 0−0.0065.The results show that weld metals(WM)optical micrographs depict the various types of ferrites,pearlites and secondary phases like martensite-austenite(M-A).Acicular ferrite content was influenced by the boron trioxide addition.Heat affected zone(HAZ)micrographs were not showing appreciable changes with oxide enrichment.Hardness and toughness of weld metals showed the mixed trend with B_(2)O_(3) enrichment whereas,small reduction in ultimate tensile strength(UTS)and yield strength(YS)was observed.
文摘World Cinema Issue 3(Bimonthly),2024 Film as Painting:Nollywood's Philosophical Understanding of the Photographic Medium This issue focuses on national films,with three articles analyzing one or more representative flms from three countries.Film as Painting:Nollywood's Philosophical Understanding of the Photographic Medium explores thephilosophical roots of photography in Nigerian film;Stalkers in Istanbul:Silence,Urban Space,and Damaged Masculinity in Nuri Bilge Ceylan's UZAK shows the decaying male image on Turkish film screens as opposed to the tough guy;The Broken Frame:The Non-Creative WaysofAbbasKiarostami in 24 FRAME Sprovides a frame-by-frame analysis of the lranian director's use of off-screen space to activate the imagination of the audience.
文摘主题语境:人与自然篇幅:379词关键词:structural color1 Scientists at the University of Central Florida(UCF)have created a new kind of paint thats super light and super tough.The colors in the new paint arent at all like those in most paints.Instead,theyre more like the colors on a butterflys wings.
文摘In 2023,unfavorable macro-economic conditions such as high inflation and interest rates currently combine with unfavorable industry specific aspects such as high inventories at brand and retail level,creating pressure on textile manufacturers from both supply and demand sides.When the textile industry is going through a tough phase,ITMF helps the industry to change its growth pattern with an innovative and responsible attitude,actively promotes international trade and investment,plays its full role in promoting the economic growth of the industry and strives to build an open global textile economy.At the same time,ITMF advocates diversity and inclusion,implements the United Nations"The 2030 Agenda for Sustainable Development"and promotes the realisation of the industry’s development outcomes.
文摘On March 12,the official account of the International Business Daily of the Ministry of Commerce published an article titled“Foreign trade enterprises:full of confidence,clear direction,strong motivation”.The content is as follows:This year,China is still facing a tough foreign trade situation.On the one hand,many international organizations predict that global economic growth in 2024 will still be lower than the historical average and the pressure on external demand will increase;on the other hand,trade protectionism and unilateralism are on the rise,geopolitical conflicts,the global“super election year”and other spillover factors have created many uncertainties.
