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Surface form inspection with contact coordinate measurement:a review 被引量:4
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作者 Yijun Shen Jieji Ren +3 位作者 Nuodi Huang Yang Zhang Xinquan Zhang Limin Zhu 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2023年第2期119-147,共29页
Parts with high-quality freeform surfaces have been widely used in industries,which require strict quality control during the manufacturing process.Among all the industrial inspection methods,contact measurement with ... Parts with high-quality freeform surfaces have been widely used in industries,which require strict quality control during the manufacturing process.Among all the industrial inspection methods,contact measurement with coordinate measuring machines or computer numerical control machine tool is a fundamental technique due to its high accuracy,robustness,and universality.In this paper,the existing research in the contact measurement field is systematically reviewed.First,different configurations of the measuring machines are introduced in detail,which may have influence on the corresponding sampling and inspection path generation criteria.Then,the entire inspection pipeline is divided into two stages,namely the pre-inspection and post-inspection stages.The typical methods of each sub-stage are systematically overviewed and classified,including sampling,accessibility analysis,inspection path generation,probe tip radius compensation,surface reconstruction,and uncertainty analysis.Apart from those classical research,the applications of the emerging deep learning technique in some specific tasks of measurement are introduced.Furthermore,some potential and promising trends are provided for future investigation. 展开更多
关键词 freeform surface form inspection contact measurement coordinate measurement on-machine inspection
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Vertical 2D Modeling of Free Surface Flow with Hydrodynamic Pressure Using SIMPLE Arithmetic in σ Coordinates 被引量:3
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作者 吴修广 沈永明 郑永红 《海洋工程:英文版》 2004年第1期79-92,共14页
A numerical model for shallow water flow has been developed based on the unsteady Reynolds-averaged Navier-Stokes equations with the hydrodynamic pressure instead of hydrostatic pressure assumption. The equations are ... A numerical model for shallow water flow has been developed based on the unsteady Reynolds-averaged Navier-Stokes equations with the hydrodynamic pressure instead of hydrostatic pressure assumption. The equations are transformed into the σ-coordinate system and the eddy viscosity is calculated with the standard k-ε turbulence model. The control volume method is used to discrete the equations, and the boundary conditions at the bed for shallow water models only include vertical diffusion terms expressed with wall functions. And the semi-implicit method for pressure linked equation arithmetic is adopted to solve the equations. The model is applied to the 2D vertical plane flow of a current over two steep-sided trenches for which experiment data are available for comparison and good agreement is obtained. And the model is used to predicting the flow in a channel with a steep-sided submerged breakwater at the bottom, and the streamline is drawn. 展开更多
关键词 free surface flow hydrodynamic pressure kinematic boundary condition Σ-coordinate SIMPLE arithmetic
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Impact of global sea surface temperature on the recent early winter Arctic tropospheric warming in coordinated large ensemble simulations
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作者 Lutao Wang Yongqi Gao +3 位作者 Dong Guo Tao Wang Ying Zhang Wei Hua 《Atmospheric and Oceanic Science Letters》 CSCD 2021年第1期57-62,共6页
Coordinated numerical ensemble experiments with six different state-of-the-art atmosphere models were used to evaluate and quantify the impact of global SST(from reanalysis data)on the early winter Arctic warming duri... Coordinated numerical ensemble experiments with six different state-of-the-art atmosphere models were used to evaluate and quantify the impact of global SST(from reanalysis data)on the early winter Arctic warming during 1982-2014.Two sets of experiments were designed:in the first set(EXP1),OISSTv2 daily sea-ice concentration and SST variations were used as the lower boundary forcing,while in the second set(EXP2)the SST data were replaced by the daily SST climatology.In the results,the multi-model ensemble mean of EXP1 showed a nearsurface(~850 hPa)warming trend of 0.4℃/10 yr,which was 80%of the warming trend in the reanalysis.The simulated warming trend was robust across the six models,with a magnitude of 0.36-0.50℃/10 yr.The global SST could explain most of the simulated warming trend in EXP1 in the mid and low troposphere over the Arctic,and accounted for 58%of the simulated near-surface warming.The results also suggest that the uppertropospheric warming(~200 hPa)over the Arctic in the reanalysis is likely not a forced signal;rather,it is caused by natural climate variability.The source regions that can potentially impact the early winter Arctic warming are explored and the limitations of the study are discussed. 展开更多
关键词 Arctic warming Sea surface temperature Multi-model coordinated experiment Eliassen-Palm flux Planetary wave
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Event-triggered model-free adaptive control for a class of surface vessels with time-delay and external disturbance via state observer
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作者 CHEN Hua SHEN Chao +1 位作者 HUANG Jiahui CAO Yuhan 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2023年第3期783-797,共15页
This paper provides an improved model-free adaptive control(IMFAC)strategy for solving the surface vessel trajectory tracking issue with time delay and restricted disturbance.Firstly,the original nonlinear time-delay ... This paper provides an improved model-free adaptive control(IMFAC)strategy for solving the surface vessel trajectory tracking issue with time delay and restricted disturbance.Firstly,the original nonlinear time-delay system is transformed into a structure consisting of an unknown residual term and a parameter term with control inputs using a local compact form dynamic linearization(local-CFDL).To take advantage of the resulting structure,use a discrete-time extended state observer(DESO)to estimate the unknown residual factor.Then,according to the study,the inclusion of a time delay has no effect on the linearization structure,and an improved control approach is provided,in which DESO is used to adjust for uncertainties.Furthermore,a DESO-based event-triggered model-free adaptive control(ET-DESO-MFAC)is established by designing event-triggered conditions to assure Lyapunov stability.Only when the system’s indicator fulfills the provided event-triggered condition will the control input signal be updated;otherwise,the control input will stay the same as it is at the last trigger moment.A coordinate compensation approach is developed to reduce the steady-state inaccuracy of trajectory tracking.Finally,simulation experiments are used to assess the effectiveness of the proposed technique for trajectory tracking. 展开更多
关键词 surface vessels event-triggered condition(ETC) discrete-time extended state observer(DESO) model-free adaptive control(MFAC) coordinate compensation
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COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER
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作者 薛奇 戴庆平 +1 位作者 丁建夫 武培怡 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1989年第3期239-244,共6页
The coordination polymerization of benzotriazole with metallic copper has been investigated by infrared and X-ray photoelectron spectroscopies. We found that benzotriazole could react with copper (0) under mild condit... The coordination polymerization of benzotriazole with metallic copper has been investigated by infrared and X-ray photoelectron spectroscopies. We found that benzotriazole could react with copper (0) under mild conditions to form bis (benzotriazolato) copper (Ⅱ) and benzotriazolato copper (Ⅰ)which covered the surface of copper metal in the shape of polymeric materials. Since benzotriazole is of great interest as a ligand in that its presence in many biological system with metal ions, and is considered as a corrosion inhibitor, this work will be in favour of the study of protective corrosion. 展开更多
关键词 BENZOTRIAZOLE Metallic copper coordination polymerization on surface INFRARED X-ray photoelectron spectroscopy.
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Quasi-plane-hypothesis of strain coordination for RC beams seismically strengthened with externally-bonded or near-surface mounted fiber reinforced plastic 被引量:3
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作者 Ren Zhenhua Zeng Xiantao +1 位作者 Liu Hanlong Zhou Fengjun 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2013年第1期67-76,共10页
The application of fiber reinforced plastic(FRP),including carbon FRP and glass FRP,for structural repair and strengthening has grown due to their numerous advantages over conventional materials such as externally b... The application of fiber reinforced plastic(FRP),including carbon FRP and glass FRP,for structural repair and strengthening has grown due to their numerous advantages over conventional materials such as externally bonded reinforcement(EBR) and near-surface mounted(NSM) strengthening techniques.This paper summarizes the results from 21 reinforced concrete beams strengthened with different methods,including externally-bonded and near-surface mounted FRP,to study the strain coordination of the FRP and steel rebar of the RC beam.Since there is relative slipping between the RC beam and the FRP,the strain of the FRP and steel rebar of the RC beam satisfy the quasi-plane-hypothesis;that is,the strain of the longitudinal fiber that parallels the neutral axis of the plated beam within the scope of the effective height(h 0) of the cross section is in direct proportion to the distance from the fiber to the neutral axis.The strain of the FRP and steel rebar satisfies the equation:ε FRP =βε steel,and the value of β is equal to 1.1-1.3 according to the test results. 展开更多
关键词 strain coordination quasi-plane-hypothesis external-bonded near-surface mounted fiber reinforced plastic strengthening concrete beam
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Poststack reverse-time migration using a non-reflecting recursive algorithm on surface relief 被引量:3
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作者 张敏 李振春 孙小东 《Applied Geophysics》 SCIE CSCD 2010年第3期239-248,293,共11页
Presently the research based on the accurate seismic imaging methods for surface relief, complex structure, and complicated velocity distributions is of great significance. Reverse-time migration is considered to be o... Presently the research based on the accurate seismic imaging methods for surface relief, complex structure, and complicated velocity distributions is of great significance. Reverse-time migration is considered to be one of highly accurate methods. In this paper, we propose a new non-reflecting recursive algorithm for reverse-time migration by introducing the wave impedance function into the acoustic wave equation and the algorithm for the surface relief case is derived from the coordinate transformation principle. Using the exploding reflector principle and the zero-time imaging condition of poststack reverse- time migration, poststack numerical simulation and reverse-time migration with complex conditions can be realized. The results of synthetic and real data calculations show that the method effectively suppresses unwanted internal reflections and also deals with the seismic imaging problems resulting from surface relief. So, we prove that this method has strong adaptability and practicality. 展开更多
关键词 surface relief non-reflecting recursive algorithm wave impedance coordinate transformation numerical simulation reverse-time migration
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Seismic wavefield modeling in media with fluid-filled fractures and surface topography 被引量:2
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作者 兰海强 张中杰 《Applied Geophysics》 SCIE CSCD 2012年第3期301-312,361,共13页
We present a finite difference (FD) method for the simulation of seismic wave fields in fractured medium with an irregular (non-fiat) free surface which is beneficial for interpreting exploration data acquired in ... We present a finite difference (FD) method for the simulation of seismic wave fields in fractured medium with an irregular (non-fiat) free surface which is beneficial for interpreting exploration data acquired in mountainous regions. Fractures are introduced through the Coates-Schoenberg approach into the FD scheme which leads to local anisotropic properties of the media where fractures are embedded. To implement surface topography, we take advantage of the boundary-conforming grid and map a rectangular grid onto a curved one. We use a stable and explicit second-order accurate finite difference scheme to discretize the elastic wave equations (in a curvilinear coordinate system) in a 2D heterogeneous transversely isotropic medium with a horizontal axis of symmetry (HTI). Efficiency tests performed by different numerical experiments clearly illustrate the influence of an irregular free surface on seismic wave propagation in fractured media which may be significant to mountain seismic exploration. The tests also illustrate that the scattered waves induced by the tips of the fracture are re-scattered by the features of the free surface topography. The scattered waves provoked by the topography are re-scattered by the fractures, especially Rayleigh wave scattering whose amplitudes are much larger than others and making it very difficult to identify effective information from the fractures. 展开更多
关键词 finite difference MODELING FRACTURE irregular free surface curvilinear coordinate
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STUDY OF NON-CONTACT MEASUREMENT OF FREE-FORM SURFACES
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作者 徐玉春 张国雄 +2 位作者 解则晓 冯国馨 王春海 《Transactions of Tianjin University》 EI CAS 2001年第4期226-228,共3页
A non contact three dimensional measurement method is presented in this paper.This system consists of a laser triangulation probe,a probe head and a coordinate measuring machine (CMM).The measurement principle of th... A non contact three dimensional measurement method is presented in this paper.This system consists of a laser triangulation probe,a probe head and a coordinate measuring machine (CMM).The measurement principle of the system is discussed,and a system calibration method employing a reference ball is proposed.The geometric model involving four frames is established to calculate the data points based on the reading of the laser probe and position information from the CMM.A measuring experiment for gesso free form surface using this system is carried out. 展开更多
关键词 free form surface coordinate measuring machine PH10 probe head laser triangulation probe CALIBRATION
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IMPROVEMENTS IN HIDDEN LINE REMOVAL ALGORITHM FOR BI-PARAMETRIC SURFACES
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作者 李卫国 唐月红 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 1998年第2期93-97,共5页
A hidden line removal algorithm for bi parametric surfaces is presented and illustrated by some experimental results. The enclosure test is done using area coordinates. A technique of moving box of encirclement is p... A hidden line removal algorithm for bi parametric surfaces is presented and illustrated by some experimental results. The enclosure test is done using area coordinates. A technique of moving box of encirclement is presented. It is found that the algorithm is of general purpose, requires minimal computer storage, has high accuracy and simplicity, and is very easy to be implemented on a computer. 展开更多
关键词 computational geometry computer graphics computer aided design hidden line removal area coordinates bi parametric surfaces
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Surfacer在曲面重构中应用研究
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作者 刘德平 陈建军 兰素萍 《机械设计与制造》 北大核心 2006年第9期125-127,共3页
针对典型样件分析了由样件点云到曲面实体生成的处理方法,重点讨论了曲面点云的处理、定位操作,实现了轮廓曲线的生成和曲面的重构,通过曲面的延伸和修剪处理,完成由点云到曲面实体的重构,对曲面和点云信息进行了误差比较,最后得出结论。
关键词 曲面 三坐标测量 surfaceR CAD/CAM
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Oxidation of formic acid on stepped Au(997) surface
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作者 邬宗芳 姜志全 +3 位作者 金岳康 熊锋 孙光辉 黄伟新 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2016年第10期1738-1746,共9页
The adsorption and reaction of formic acid (HCOOH) on clean and atomic oxygen‐covered Au(997) surfaces were studied by temperature‐programmed desorption/reaction spectroscopy (TPRS) and X‐ray photoelectron sp... The adsorption and reaction of formic acid (HCOOH) on clean and atomic oxygen‐covered Au(997) surfaces were studied by temperature‐programmed desorption/reaction spectroscopy (TPRS) and X‐ray photoelectron spectroscopy (XPS). At 105 K, HCOOH molecularly adsorbs on clean Au(997) and interacts more strongly with low‐coordinated Au atoms at (111) step sites than with those at (111) terrace sites. On an atomic oxygen‐covered Au(997) surface, HCOOH reacts with oxygen at‐oms to form HCOO and OH at 105 K. Upon subsequent heating, surface reactions occur among ad‐sorbed HCOO, OH, and atomic oxygen and produce CO2, H2O, and HCOOH between 250 and 400 K. The Au(111) steps bind surface adsorbates more strongly than the Au(111) terraces and exhibit larger barriers for HCOO(a) oxidation reactions. The surface reactions also depend on the relative coverages of co‐existing surface species. Our results elucidate the elementary surface reactions between formic acid and oxygen adatoms on Au surfaces and highlight the effects of the coordina‐tion number of the Au atoms on the Au catalysis. 展开更多
关键词 Gold catalysis surface chemistry Model catalyst Geometric structure coordination number
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SCATTERING OF CIRCULAR CAVITY IN RIGHT-ANGLE PLANAR SPACE TO STEADY SH-WAVE 被引量:1
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作者 史文谱 刘殿魁 +2 位作者 宋永涛 褚京莲 胡爱琴 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2006年第12期1619-1626,共8页
Complex function method and multi-polar coordinate transformation technology are used here to study scattering of circular cavity in right-angle planar space to SH-wave with out-of-plane loading on the horizontal stra... Complex function method and multi-polar coordinate transformation technology are used here to study scattering of circular cavity in right-angle planar space to SH-wave with out-of-plane loading on the horizontal straight boundary. At first, Green function of right-angle planar space which has no circular cavity is constructed; then the scattering solution which satisfies the free stress conditions of the two right-angle boundaries with the circular cavity existing in the space is formulated. Therefore, the total displacement field can be constructed using overlapping principle. An infinite algebraic equations of unknown coefficients existing in the scattering solution field can be gained using multi-polar coordinate and the free stress condition at the boundary of the circular cavity. It can be solved by using limit items in the infinite series which can give a high computation precision. An example is given to illustrate the variations of the tangential stress at the boundary of the circular cavity due to different dimensionless wave numbers, the location of the circular cavity, the loading center and the distributing range of the out-of-plane loading. The results show the efficiency and effectiveness of the mothod introduced here. 展开更多
关键词 SCATTERING SH-wave circular cavity dynamic stress right-angle planar space multi-polar coordinate
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The quantum nonthermal radiation and horizon surface gravity of an arbitrarily accelerating black hole with electric charge and magnetic charge
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作者 谢志堃 潘伟珍 杨学军 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第3期567-571,共5页
Using a new tortoise coordinate transformation,we discuss the quantum nonthermal radiation characteristics near an event horizon by studying the Hamilton-Jacobi equation of a scalar particle in curved space-time,and o... Using a new tortoise coordinate transformation,we discuss the quantum nonthermal radiation characteristics near an event horizon by studying the Hamilton-Jacobi equation of a scalar particle in curved space-time,and obtain the event horizon surface gravity and the Hawking temperature on that event horizon.The results show that there is a crossing of particle energy near the event horizon.We derive the maximum overlap of the positive and negative energy levels.It is also found that the Hawking temperature of a black hole depends not only on the time,but also on the angle.There is a problem of dimension in the usual tortoise coordinate,so the present results obtained by using a correct-dimension new tortoise coordinate transformation may be more reasonable. 展开更多
关键词 tortoise coordinate transformation black hole quantum nonthermal radiation event horizon surface gravity
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Elastic reverse-time migration in irregular tunnel environment based on polar coordinates
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作者 Qu Ying-Ming Zhou Chang +3 位作者 Worral Qurmet Li Zhen-Chun Wang Chang-Bo Sun Jun-Zhi 《Applied Geophysics》 SCIE CSCD 2020年第2期253-266,316,共15页
When seismic exploration is conducted in a special geological environment such as a tunnel space,the traditional imaging method in the Cartesian coordinate system cannot accurately discretize the air column in that en... When seismic exploration is conducted in a special geological environment such as a tunnel space,the traditional imaging method in the Cartesian coordinate system cannot accurately discretize the air column in that environment.Thus,obtaining Thus,obtaining highquality imaging results is diffi cult.Therefore,an elastic-wave reverse-time migration method based on the polar coordinate system is proposed.In this method,three boundary conditions exist:outer,inner,and corner boundaries.In the outer boundary,the polar-coordinated absorbing boundary in the radial direction is used to suppress the artifi cial-boundary refl ection.The free-surface boundary condition is adopted in the tunnel space at the inner boundary.In the angular boundaries,we use two diff erent boundary conditions for two cases.The air column in the tunnel space is usually not an irregular circle.Therefore,the irregular tunnelspace geological body in the polar coordinate system is meshed into curvilinear grids and transformed into a regular one in an auxiliary polar coordinate system using the mapping method.Finally,elastic reverse-time migration technology is applied into the auxiliary polar coordinate system.In the numerical examples,two typical models are used to test the proposed method,which verify that the proposed method can obtain accurate images from the datasets in the tunnel space. 展开更多
关键词 Polar coordinate system Irregular tunnel ELASTIC Reverse-time migration Free surface
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Evaluation of a global eddy-permitting hybrid coordinate ocean model
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作者 CHEN Yue-Liang YAN Chang-Xiang +1 位作者 ZHU Jiang LI Yi-Neng 《Atmospheric and Oceanic Science Letters》 CSCD 2018年第4期345-351,共7页
A historical run(1993–2014)of a global,eddy-permitting,hybrid coordinate ocean model(HYCOM)is evaluated against observations.The authors evaluate several metrics in the model,including the spatial distribution of sea... A historical run(1993–2014)of a global,eddy-permitting,hybrid coordinate ocean model(HYCOM)is evaluated against observations.The authors evaluate several metrics in the model,including the spatial distribution of sea surface temperature(SST),the zonally averaged seasonal cycle of SST,the variability of the sea level anomaly(SLA),the zonally and meridionally averaged temperature and salinity,and the equatorial undercurrent.It is found that the simulated seasonal cycle of SST is 0.2–0.8 stronger than observed at midlatitudes.The modeled SST is 0.29°C warmer than the observed for the global ocean.the structure of the subsurface temperature and salinity is similar to the observed.moreover,the variability of SLA exhibits the same pattern as observed.The modeled equatorial undercurrent in the pacific ocean is weaker than observed,but stronger than the ecco reanalysis product.overall,the model can reproduce the large-scale ocean states,and is suitable for analyses seeking to better understand the dynamics and thermodynamics of the upper ocean,as well as ocean variability. 展开更多
关键词 Eddy-permitting hybrid coordinate ocean model sea surface temperature sea level anomaly temperature and salinity
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CAD-DIRECTED INSPECTION PLANNING FOR FREEFORM SURFACE USING CONTACT PROBES
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作者 Chen Manyi Li Bin Duan Zhengcheng 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2005年第4期579-581,共3页
A methodology for CAD-directed measurement of freeform surface using a coordinate measuring machine equipped with a touch-trigger probe is presented, mainly including adaptive sampling of measurement points and regist... A methodology for CAD-directed measurement of freeform surface using a coordinate measuring machine equipped with a touch-trigger probe is presented, mainly including adaptive sampling of measurement points and registration of freeform surface. The proposed sampling method follows four steps: Freeform surface is fitted by bi-cubic B-spline; Curvedness measure of the surface is computed; Given a number of sampling points, an iterative algorithm is constructed for selecting a set of measurement points by employing the curvedness information; The measurement points is regularized for tradeoff between maximizing the measurement accuracy and minimizing the sampling time and cost. The aforesaid algorithm is demonstrated in term of a marine propeller blade. An offset surface registration method is presented to improve alignment accuracy of freeform objects, and Monte Carlo simulation is conducted to verify the effectiveness of the method. 展开更多
关键词 Freeform surface Inspection coordinate measurement Contact probe
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A Semi-Analytical Approach to Green's Functions for Problems in Multiply-Connected Regions on a Spherical Surface
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作者 V.N. Borodin 《Journal of Mathematics and System Science》 2013年第12期597-601,共5页
This work aims at potential fields generated by point sources in conductive perforated fragments of spherical shells. Such fields are interpreted as profiles of Green's functions of relevant boundary-value problems s... This work aims at potential fields generated by point sources in conductive perforated fragments of spherical shells. Such fields are interpreted as profiles of Green's functions of relevant boundary-value problems stated in multiply-connected regions for Laplace equation written in geographical coordinates. Those are efficiently computed by a modification of the method of functional equations, with closed analytical forms preliminary obtained for Green's functions for the corresponding simply-connected regions. 展开更多
关键词 Green's function Laplace equation spherical coordinates surfaces with apertures.
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VISION-BASED MEASUREMENT OF FREE-FORM SURFACES
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作者 Luo Feilu Zhou Jiwei +2 位作者 Ni Guoqi Tao Zemin Yang Qiaoling(Department of Mechantronics and Instrumentation, NUDT, Changsha, 410073) 《国防科技大学学报》 EI CAS CSCD 北大核心 1995年第3期13-19,32,共8页
VISION-BASEDMEASUREMENTOFFREE-FORMSURFACESLuoFeilu;ZhouJiwei;NiGuoqi;TaoZemin;YangQiaoling(DepartmentofMecha... VISION-BASEDMEASUREMENTOFFREE-FORMSURFACESLuoFeilu;ZhouJiwei;NiGuoqi;TaoZemin;YangQiaoling(DepartmentofMechantronicsandInstru... 展开更多
关键词 自由曲面 测量 视觉
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Revealing the effect of electrolyte coordination structures on the intercalation chemistry of batteries
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作者 Chao Wang Xianjin Li +6 位作者 Guiming Zhong Caixia Meng Shiwen Li Guohui Zhang Yanxiao Ning Xianfeng Li Qiang Fu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第6期149-156,I0006,共9页
In-depth understanding of the electrolyte-dependent intercalation chemistry in batteries through direct operando/in situ characterizations is crucial for the development of the high-performance batteries.Herein,taking... In-depth understanding of the electrolyte-dependent intercalation chemistry in batteries through direct operando/in situ characterizations is crucial for the development of the high-performance batteries.Herein,taking the Al/graphite battery as a model system,the effect of electrolyte coordination structure on the intercalation processes has been investigated over the batteries with either 1-hexyl-3-methylimidazolium chloride(HMICl)-AlCl_(3) or 1-ethyl-3-methylimidazolium chloride(EMICl)-AlCl_(3) ionic liquid electrolyte using operando X-ray photoelectron spectroscopy(XPS)and X-ray diffraction.With a weaker anion-cation interaction in HMI-based electrolyte,the XPS-derived atomic ratio between cointercalated N and intercalated Al is 0.9,which is lower than 1.6 for EMI-based electrolyte.Attributed to the additional de-solvation process,the batteries with the HMI-based electrolyte show a lower ionic diffusion rate,capacity,and cycling performance,which agree with the operando characterization results.Our findings highlight the critical role of the electrolyte coordination structure on the(co-)intercalation chemistry. 展开更多
关键词 Operando surface characterization Electrolyte coordination structure De-solvation Intercalation chemistry
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