The novel biodegradable copolymer PDLLA-(MAH-Diol)n-PDLLA with unsaturated bond was synthesized by copolymefizing lactide and prepolymer, which was prepared by the polycondensation of maleic anhydride and poly(ethy...The novel biodegradable copolymer PDLLA-(MAH-Diol)n-PDLLA with unsaturated bond was synthesized by copolymefizing lactide and prepolymer, which was prepared by the polycondensation of maleic anhydride and poly(ethylene glycol), using ptoluene sulphonic acid as catalyst. The new copolymer has improved hydrophilicity and flexibility. The structure and properties of the novel polymers were studied by FTIR, NMR, GPC-MALLS and DSC.展开更多
文摘The novel biodegradable copolymer PDLLA-(MAH-Diol)n-PDLLA with unsaturated bond was synthesized by copolymefizing lactide and prepolymer, which was prepared by the polycondensation of maleic anhydride and poly(ethylene glycol), using ptoluene sulphonic acid as catalyst. The new copolymer has improved hydrophilicity and flexibility. The structure and properties of the novel polymers were studied by FTIR, NMR, GPC-MALLS and DSC.