The valence states and coordination structures of doped heterometal atoms in two-dimensional(2D)nanomaterials lack predictable regulation strategies.Hence,a robust method is proposed to form unsaturated heteroatom clu...The valence states and coordination structures of doped heterometal atoms in two-dimensional(2D)nanomaterials lack predictable regulation strategies.Hence,a robust method is proposed to form unsaturated heteroatom clusters via the metal-vacancy restraint mechanism,which can precisely regulate the bonding and valence state of heterometal atoms doped in 2D molybdenum disulfide.The unsaturated valence state of heterometal Pt and Ru cluster atoms form a spatial coordination structure with Pt–S and Ru–O–S as catalytically active sites.Among them,the strong binding energy of negatively charged suspended S and O sites for H+,as well as the weak adsorption of positively charged unsaturated heterometal atoms for H*,reduces the energy barrier of the hydrogen evolution reaction proved by theoretical calculation.Whereupon,the electrocatalytic hydrogen evolution performance is markedly improved by the ensemble effect of unsaturated heterometal atoms and highlighted with an overpotential of 84 mV and Tafel slope of 68.5 mV dec^(−1).In brief,this metal vacancy-induced valence state regulation of heterometal can manipulate the coordination structure and catalytic activity of heterometal atoms doped in the 2D atomic lattice but not limited to 2D nanomaterials.展开更多
In the process of ion-adsorption rare earth ore leaching,the migration characteristics of the wetting front in multi-hole injection holes and the influence of wetting front intersection effect on the migration distanc...In the process of ion-adsorption rare earth ore leaching,the migration characteristics of the wetting front in multi-hole injection holes and the influence of wetting front intersection effect on the migration distance of wetting fronts are still unclear.Besides,wetting front migration distance and leaching time are usually required to optimize the leaching process.In this study,wetting front migration tests of ionadsorption rare earth ores during the multi-hole fluid injection(the spacing between injection holes was 10 cm,12 cm and 14 cm)and single-hole fluid injection were completed under the constant water head height.At the pre-intersection stage,the wetting front migration laws of ion-adsorption rare earth ores during the multi-hole fluid injection and single-hole fluid injection were identical.At the postintersection stage,the intersection accelerated the wetting front migration.By using the Darcy’s law,the intersection effect of wetting fronts during the multi-hole liquid injection was transformed into the water head height directly above the intersection.Finally,based on the Green-Ampt model,a wetting front migration model of ion-adsorption rare earth ores during the multi-hole unsaturated liquid injection was established.Error analysis results showed that the proposed model can accurately simulate the infiltration process under experimental conditions.The research results enrich the infiltration law and theory of ion-adsorption rare earth ores during the multi-hole liquid injection,and this study provides a scientific basis for optimizing the liquid injection well pattern parameters of ion-adsorption rare earth in situ leaching in the future.展开更多
BACKGROUND The understanding of bile acid(BA)and unsaturated fatty acid(UFA)profiles,as well as their dysregulation,remains elusive in individuals with type 2 diabetes mellitus(T2DM)coexisting with non-alcoholic fatty...BACKGROUND The understanding of bile acid(BA)and unsaturated fatty acid(UFA)profiles,as well as their dysregulation,remains elusive in individuals with type 2 diabetes mellitus(T2DM)coexisting with non-alcoholic fatty liver disease(NAFLD).Investigating these metabolites could offer valuable insights into the pathophy-siology of NAFLD in T2DM.AIM To identify potential metabolite biomarkers capable of distinguishing between NAFLD and T2DM.METHODS A training model was developed involving 399 participants,comprising 113 healthy controls(HCs),134 individuals with T2DM without NAFLD,and 152 individuals with T2DM and NAFLD.External validation encompassed 172 participants.NAFLD patients were divided based on liver fibrosis scores.The analytical approach employed univariate testing,orthogonal partial least squares-discriminant analysis,logistic regression,receiver operating characteristic curve analysis,and decision curve analysis to pinpoint and assess the diagnostic value of serum biomarkers.RESULTS Compared to HCs,both T2DM and NAFLD groups exhibited diminished levels of specific BAs.In UFAs,particular acids exhibited a positive correlation with NAFLD risk in T2DM,while theω-6:ω-3 UFA ratio demonstrated a negative correlation.Levels ofα-linolenic acid andγ-linolenic acid were linked to significant liver fibrosis in NAFLD.The validation cohort substantiated the predictive efficacy of these biomarkers for assessing NAFLD risk in T2DM patients.CONCLUSION This study underscores the connection between altered BA and UFA profiles and the presence of NAFLD in individuals with T2DM,proposing their potential as biomarkers in the pathogenesis of NAFLD.展开更多
Seepage flow in fractured rock mass due to surface infiltration is a saturated-unsaturated seepage process. Aimed at rock mass with large fracture density, which can be equivalent to continuum, a mathematical model fo...Seepage flow in fractured rock mass due to surface infiltration is a saturated-unsaturated seepage process. Aimed at rock mass with large fracture density, which can be equivalent to continuum, a mathematical model for saturated-unsaturated seepage flow in fractured rock mass due to surface infiltration was established in this paper. The Galerkin finite element method was used in numerical simulation and a finite element program used to calculate saturated-unsaturated seepage flow due to surface infiltration was worked out. A model experiment was employed examine the reasonableness of the program. The results show that the proposed model and program are reasonable. The application of the analysis method in this paper in an engineering project shows that the method is reliable and feasible.展开更多
The aim of the study is to seek a simple and inexpensive method to prevent the permeability rise of unsaturated clay caused by evaporation process and to raise its imperviousness. Taking Chengdu clay as an example, fo...The aim of the study is to seek a simple and inexpensive method to prevent the permeability rise of unsaturated clay caused by evaporation process and to raise its imperviousness. Taking Chengdu clay as an example, four treatment schemes were tried. Na 2CO 3 could reduce conspicuously the permeability of the saturated clay, but could not limit the permeability rise in the alternate wetting and drying process. NaOH had a similar effect to Na 2CO 3. NaCl could not only decrease the saturated hydraulic conductivity, but could also effectively contain the permeability rise caused by evaporation. CH 3COONa had a similar effect to NaCl. The mechanism of Na 2CO 3, NaOH, NaCl and CH 3COONa decreasing the saturated hydraulic conductivity of the clay is that Na + transformed Ca montmorillonites in the original clay into Na montmorillonites and the transformation reduces the sizes of effective pores and the effective porosity of the clay.展开更多
Adiponectin,a specific hormone protein secreted by adipocytes,is a protective factor in the human body and has attracted great attention due to its anti-obesity activity[1,2].The adiponectin gene(ADIPOQ),which is loca...Adiponectin,a specific hormone protein secreted by adipocytes,is a protective factor in the human body and has attracted great attention due to its anti-obesity activity[1,2].The adiponectin gene(ADIPOQ),which is located on human chromosome 3q27,is a single-copy gene.Various single-nucleotide polymorphisms(SNPs)of the human ADIPOQ play an important role in energy balance and are associated with body mass index(BMI)and obesity[3,4].Longchain polyunsaturated fatty acids(LC-PUFAs)have been identified to exert an important role during the first 1,000 days of life on infant growth,neurodevelopment,and visual acuity.Fatty acids,such asα-linoleic acid(ALA,C18:3n-3)and linoleic acid(LA,C18:2n-6),which cannot be synthesized de novo from other lipids,are necessary for biological reactions.Some fatty acids such as docosahexaenoic acid(DHA,C22:6n-3)and eicosapentaenoic acid(EPA,C20:5n-3)can be synthesized in neonates from their precursors(LA and ALA).Because of the very low conversion rates in the neonatal liver,it is crucial to provide adequate LC-PUFAs in the diet from early infancy.展开更多
Sediment incipient motion is the first step in sediment resuspension.Previous studies ignored the effect of seepage flow on the mobility of sediment particles and simplified the seabed surface as a rigid boundary.A fl...Sediment incipient motion is the first step in sediment resuspension.Previous studies ignored the effect of seepage flow on the mobility of sediment particles and simplified the seabed surface as a rigid boundary.A flume experiment was designed to innovatively divide the seabed into two parts to control the dynamic response of the seabed and control the seepage conditions.In the experiment,the seabed sediments and the amplitude of internal solitary waves(ISWs)were changed to compare and analyze the impact of seepage flow on the sediment resuspension by shoaling ISWs.Moreover,parametric research and verification were carried out.Results indicate that seepage flow can greatly influence fine sand,promote sediment resuspension,and increase the amount of suspension by two times on average.However,seepage flow had a little effect on the suspension of clayey silt and sandy silt.Besides,seepage force was added to the traditional gravity,drag force,and uplift force,and the parameterization of threshold starting shear stress of coarse-grained sediments was developed.The results of this parameterization were verified,and seepage force was critical to parameterization.The threshold starting shear stress was reduced by 54.6%after increasing the seepage force.The physical mechanism of this process corresponded to the vertical reciprocating transient seepage in and out the seabed interface caused by the wave-induced transient excess pore water pressure.This quantitative study on seepage flow for shear stress of coarse-grained sediments induced by ISWs is critical to geohazard assessment.展开更多
Subterranean estuaries,i.e.,the mixing zone between terrestrial groundwater and recirculated seawater,host a wide range of microbiota.Here,field campaigns were conducted at the mouth of the subterranean estuary at the...Subterranean estuaries,i.e.,the mixing zone between terrestrial groundwater and recirculated seawater,host a wide range of microbiota.Here,field campaigns were conducted at the mouth of the subterranean estuary at the Sanggou Bay(Shandong Province,China)over four consecutive seasons at a seepage face(0−20 cm depth).The diversity of benthic microbiome was characterized via 16S rRNA gene sequencing and metagenomics,combined with physic-chemical parameters,e.g.,organic carbon,total nitrogen and sulfate contents in sediments.During spring,the dominant species were assigned to the phylum Proteobacteria.Important opportunistic species was assigned to Acidobacteria,Actinobacteria and Bacteroidetes.The key components were identified to be species of the genera Pseudoalteromonas,Colwellia and Sphingobium,indicating the involvement of sediment microbiota in the degradation of sedimentary organic carbon,particularly that of pelagic origin,e.g.,phytoplankton detritus and bivalve pseudo-feces.During spring,the microbial community was statistically similar along the depth profiles and among the three sampled stations.Similar spatial distributions were obtained in the remaining seasons.By contrast,the dominant species assemblages varied significantly among seasons,with key genera being Thioprofundum and Nitrosopumilus during summer and autumn and Thioprofundum and Ilumatobacter during winter.Network analysis revealed a seasonal shift in benthic nitrogen and sulfur metabolism associated with these variations in microbial community composition.Overall,our findings suggested that macro elements derived from pelagic inputs,particularly detrital phytoplankton,shaped the microbial community compositions at the seepage face,resulting in significant seasonal variations,while the influence of terrestrial materials transported by groundwater on the sediment microbiota at the seepage face found to be minor.展开更多
Internal erosion is one of the important factors causing geological disasters.The microstructure of soil can change with seepage erosion,resulting in changes in the hydraulic and mechanical properties of the soil.The ...Internal erosion is one of the important factors causing geological disasters.The microstructure of soil can change with seepage erosion,resulting in changes in the hydraulic and mechanical properties of the soil.The evolution of seepage erosion is investigated with X-ray computed tomography(CT)in this study.The change in macropore structure characteristics during the seepage erosion test is quantified and the influence of seepage erosion on soil deformation is analyzed.Moreover,a pore network model(PNM)is established for the specimens and the evolution of the connected pore size characteristics is assessed.The results show that the macropore structure is significantly affected by seepage erosion,especially in terms of the porosity and pore geometry characteristics.The changes in macropore structure characteristics are most obvious in the lower part of the specimen.The influence of seepage erosion on the pore size distribution(PSD)and soil deformation is heterogeneous and closely dependent on the spatial location of the soil.Moreover,seepage erosion enhances macropore connectivity and has a directional impact on macropore orientation.These findings can provide a reference for the theoretical modeling and numerical simulation of the seepage erosion and improve the understanding of the seepage erosion evolution in engineering practice.展开更多
In order to enhance the area throughput of next generation wireless local area network(WLAN)in high density scenarios,orthogonal frequency division multiple access(OFDMA)has been adopted as one of the key technologies...In order to enhance the area throughput of next generation wireless local area network(WLAN)in high density scenarios,orthogonal frequency division multiple access(OFDMA)has been adopted as one of the key technologies in the next generation WLAN communication standards.However,the performance of the existing media access control(MAC)degrades significantly under unsaturated services.Therefore,this paper proposes a multi-user parallel contention channel MAC(MU-MAC)based on unsaturated services,which can effectively reduce the channel access conflict and improve the OFDMA access efficiency of cluster member nodes.On this basis,MU-MAC is enhanced for the spatial clustering group(SCG)formation protocol and support for the unsaturated service characteristics.Further,the optimal access radius when the service is in a non-saturated state is analyzed to make the relevant theoretical analysis more generally,and the expressions for the throughput and area throughput of the proposed protocol are modeled and derived.The simulation results verify the correctness of the theoretical analysis and the efficiency of the protocol performance.The results show that MU-MAC outperforms IEEE 802.11ax and OMAX protocol in area throughput by 40.72%and 104.15%,respectively.展开更多
Groundwater flow through fractured rocks has been recognized as an important issue in many geotechnical engineering practices.Several key aspects of fundamental mechanisms,numerical modeling and engineering applicatio...Groundwater flow through fractured rocks has been recognized as an important issue in many geotechnical engineering practices.Several key aspects of fundamental mechanisms,numerical modeling and engineering applications of flow in fractured rocks are discussed.First,the microscopic mechanisms of fluid flow in fractured rocks,especially under the complex conditions of non-Darcian flow,multiphase flow,rock dissolution,and particle transport,have been revealed through a com-bined effort of visualized experiments and theoretical analysis.Then,laboratory and field methods of characterizing hydraulic properties(e.g.intrinsic permeability,inertial permeability,and unsaturated flow parameters)of fractured rocks in different flow regimes have been proposed.Subsequently,high-performance numerical simulation approaches for large-scale modeling of groundwater flow in frac-tured rocks and aquifers have been developed.Numerical procedures for optimization design of seepage control systems in various settings have also been proposed.Mechanisms of coupled hydro-mechanical processes and control of flow-induced deformation have been discussed.Finally,three case studies are presented to illustrate the applications of the improved theoretical understanding,characterization methods,modeling approaches,and seepage and deformation control strategies to geotechnical engi-neering projects.展开更多
Salinization and desertification are closely related to water-salt migration caused by a temperature gradient.Based on the Darcy Law of unsaturated soils,the law of energy conservation and the law of mass conservation...Salinization and desertification are closely related to water-salt migration caused by a temperature gradient.Based on the Darcy Law of unsaturated soils,the law of energy conservation and the law of mass conservation,the thermal-water-salt coupling mathematical model of unsaturated frozen saline soil was established.The model considered the latent heat of phase change,crystallization impedance,crystallization consumption and complete precipitation of solute crystallization in ice.In order to verify the rationality of the model,the unidirectional freezing test of unsaturated saline soil was carried out in an open system with no-pressure water supplement to obtain the spatial distribution of temperature,moisture and salt in the saline soil.Finally,numerical simulations are implemented with the assistance of COMSOL Multiphysics.Validation of the model is illustrated by comparisons between the simulation and experimental data.The results demonstrated that the temperature within saline soil changes with time and can be divided into three stages,namely quick freezing stage,transitional stage and stable stage.The water and salt contents in the freezing zone are layered,with peak values at the freezing front.The coupled model could reveal the heat-mass migration mechanism of unsaturated frozen saline soil and dynamically describe the freezing depth and the movement law of the freezing front,ice and salt crystal formation mechanism,and the change law of thermal conductivity and permeability coefficient.展开更多
Both CT and Avizo software were used to explore the effect of particle gradation on the evolution characteristics of pore structure and seepage paths in weathered crust elution-deposited rare earth ores during leachin...Both CT and Avizo software were used to explore the effect of particle gradation on the evolution characteristics of pore structure and seepage paths in weathered crust elution-deposited rare earth ores during leaching.The results showed that the pore areas in four kinds of ore samples before leaching were mainly concentrated in 10^(4)–10^(7)μm^(2),whose pore quantities accounted for 96.89%,94.94%,90.48%,and 89.45%,respectively,while the corresponding pore volume only accounted for 30.74%,14.55%,7.58%,and 2.84%of the total pore volume.With the decrease of fractal dimension,the average pore throat length increased,but pore throat quantities,the average pore throat radius and coordination number decreased.Compared with that before leaching,the change degree of pore structure during leaching increased with the fractal dimension decreasing.For example,the reduction rate of the average coordination number of ore samples was 14.36%,21.30%,28.00%,and 32.90%,respectively.Seepage simulation results indicated that seepage paths were uniformly distributed before leaching while the streamline density and seepage velocity increased with the fractal dimension decreasing.Besides,the phenomenon of the streamline interruption gradually reduced during leaching while preferential seepage got more obvious with the decrease of the fractal dimension.展开更多
Natural gas hydrate(NGH)is an important future resource for the 21st century and a strategic resource with potential for commercial development in the third energy transition.It is of great significance to accurately ...Natural gas hydrate(NGH)is an important future resource for the 21st century and a strategic resource with potential for commercial development in the third energy transition.It is of great significance to accurately predict the productivity of hydrate-bearing sediments(HBS).The multi-phase seepage parameters of HBS include permeability,porosity,which is closely related to permeability,and hydrate saturation,which has a direct impact on hydrate content.Existing research has shown that these multi-phase seepage parameters have a great impact on HBS productivity.Permeability directly affects the transmission of pressure-drop and discharge of methane gas,porosity and initial hydrate saturation affect the amount of hydrate decomposition and transmission process of pressure-drop,and also indirectly affect temperature variation of the reservoir.Considering the spatial heterogeneity of multi-phase seepage parameters,a depressurization production model with layered heterogeneity is established based on the clayey silt hydrate reservoir at W11 station in the Shenhu Sea area of the South China Sea.Tough+Hydrate software was used to calculate the production model;the process of gas production and seepage parameter evolution under different multi-phase seepage conditions were obtained.A sensitivity analysis of the parameters affecting the reservoir productivity was conducted so that:(a)a HBS model with layered heterogeneity can better describe the transmission process of pressure and thermal compensation mechanism of hydrate reservoir;(b)considering the multi-phase seepage parameter heterogeneity,the influence degrees of the parameters on HBS productivity were permeability,porosity and initial hydrate saturation,in order from large to small,and the influence of permeability was significantly greater than that of other parameters;(c)the production potential of the clayey silt reservoir should not only be determined by hydrate content or seepage capacity,but also by the comprehensive effect of the two;and(d)time scales need to be considered when studying the effects of changes in multi-phase seepage parameters on HBS productivity.展开更多
The seepage mechanism plays a crucial role in low-permeability gas reservoirs.Compared with conventional gas reservoirs,low-permeability sandstone gas reservoirs are characterized by low porosity,low permeability,stro...The seepage mechanism plays a crucial role in low-permeability gas reservoirs.Compared with conventional gas reservoirs,low-permeability sandstone gas reservoirs are characterized by low porosity,low permeability,strong heterogeneity,and high water saturation.Moreover,their percolation mechanisms are more complex.The present work describes a series of experiments conducted considering low-permeability sandstone cores under pressuredepletion conditions(from the Xihu Depression in the East China Sea Basin).It is shown that the threshold pressure gradient of a low-permeability gas reservoir in thick layers is positively correlated with water saturation and negatively correlated with permeability and porosity.The reservoir stress sensitivity is related to permeability and rock composition.Stress sensitivity is generally low when permeability is high or in the early stage of gas reservoir development.It is also shown that in sand conglomerates,especially the more sparsely filled parts,the interstitial materials among the conglomerates can be rapidly dislodged from the skeleton particles under stress.This material can therefore disperse,migrate,and block the pore throat producing serious,stress-sensitive damage.展开更多
In practical engineering,the total vertical stress in the soil layer is not constant due to stress diffusion,and varies with time and depth.Therefore,the purpose of this paper is to investigate the effect of stress di...In practical engineering,the total vertical stress in the soil layer is not constant due to stress diffusion,and varies with time and depth.Therefore,the purpose of this paper is to investigate the effect of stress diffusion on the two-dimensional(2D)plane strain consolidation properties of unsaturated soils when the stress varies with time and depth.A series of semi-analytical solutions in terms of excess pore air and water pressures and settlement for 2D plane strain consolidation of unsaturated soils can be derived with the joint use of Laplace transform and Fourier sine series expansion.Then,the inverse Laplace transform of the semi-analytical solution is given in the time domain using a self-programmed code based on Crump’s method.The reliability of the obtained solutions is proved by the degeneration.Finally,the 2D plots of excess pore pressures and the curves of settlement varying with time,considering different physical parameters of unsaturated soil stratum and depth-dependent stress,are depicted and analyzed to study the 2D plane strain consolidation properties of unsaturated soils subjected to the depthdependent stress.展开更多
Coal and gas outburst is a complex dynamic disaster during coal underground mining.Revealing the disaster mechanism is of great signifcance for accurate prediction and prevention of coal and gas outburst.The geo-dynam...Coal and gas outburst is a complex dynamic disaster during coal underground mining.Revealing the disaster mechanism is of great signifcance for accurate prediction and prevention of coal and gas outburst.The geo-dynamic system of coal and gas outburst is proposed.The framework of geo-dynamic system is composed of gassy coal mass,geological dynamic environment and mining disturbance.Equations of stress–damage–seepage interaction for gassy coal mass is constructed to resolve the outburst elimination process by gas extraction with boreholes through layer in foor roadway.The results show the occurrence of outburst is divided into the evolution process of gestation,formation,development and termination of geo-dynamic system.The scale range of outburst occurrence is determined,which provides a spatial basis for the prevention and control of outburst.The formation criterion and instability criterion of coal and gas outburst are established.The formation criterion F1 is defned as the scale of the geo-dynamic system,and the instability criterion F2 is defned as the scale of the outburst geo-body.According to the geo-dynamic system,the elimination mechanism of coal and gas outburst—‘unloading+depressurization’is established,and the gas extraction by boreholes through layer in foor roadway for outburst elimination is given.For the research case,when the gas extraction is 120 days,the gas pressure of the coal seam is reduced to below 0.4 MPa,and the outburst danger is eliminated efectively.展开更多
Unsaturated expansive soil is widely distributed in China and has complex engineering properties.This paper proposes the unified hydraulic effect shear strength theory of unsaturated expansive soil based on the effect...Unsaturated expansive soil is widely distributed in China and has complex engineering properties.This paper proposes the unified hydraulic effect shear strength theory of unsaturated expansive soil based on the effective stress principle,swelling force principle,and soil–water characteristics.Considering the viscoelasticity and structural damage of unsaturated expansive soil during loading,a fractional hardening–damage model of unsaturated expansive soil was established.The model parameters were established on the basis of the proposed calculation method of shear strength and the triaxial shear experiment on unsaturated expansive soil.The proposed model was verified by the experimental data and a traditional damage model.The proposed model can satisfactorily describe the entire process of the strain-hardening law of unsaturated expansive soil.Finally,by investigating the damage variables of the proposed model,it was found that:(a)when the values of confining pressure and matric suction are close,the coupling of confining pressure and matric suction contributes more to the shear strength;(b)there is a damage threshold for unsaturated expansive soil,and is mainly reflected by strength criterion of infinitesimal body;(c)the strain hardening law of unsaturated expansive soil is mainly reflected by fractional derivative operator.展开更多
We provide the capillary pressure curves p_(c)(s)as a function of the effective saturation s based on the theoretical framework of upscaling unsaturated flows in vertically heterogeneous porous layers proposed recentl...We provide the capillary pressure curves p_(c)(s)as a function of the effective saturation s based on the theoretical framework of upscaling unsaturated flows in vertically heterogeneous porous layers proposed recently(Z.Zheng,Journal of Fluid Mechanics,950,A17,2022).Based on the assumption of vertical gravitational-capillary equilibrium,the saturation distribution and profile shape of the invading fluid can be obtained by solving a nonlinear integral-differential equation.The capillary pressure curves p_(c)(s)can then be constructed by systematically varying the injection rate.Together with the relative permeability curves k_(rn)(s)that are already obtained.One can now provide quick estimates on the overall behaviours of interfacial and unsaturated flows in vertically-heterogeneous porous layers.展开更多
Gas breakthrough pressure is a key parameter to evaluate the sealing capacity of caprock,and it also plays important roles in safety and capacity of CO_(2)geological storage.Based on the published experimental results...Gas breakthrough pressure is a key parameter to evaluate the sealing capacity of caprock,and it also plays important roles in safety and capacity of CO_(2)geological storage.Based on the published experimental results,we present numerical simulations on CO_(2)breakthrough pressure in unsaturated low-permeability rock under 9 multiple P-T conditions(which can keep CO_(2)in gaseous,liquid and supercritical states)and thus,a numerical method which can be used to accurately predict CO_(2)breakthrough pressure on rock-core scale is proposed.The simulation results show that CO_(2)breakthrough pressure and breakthrough time are exponential correlated with P-T conditions.Meanwhile,pressure has stronger effects on experimental results than that of temperature.Moreover,we performed sensitivity studies on the pore distribution indexλ(0.6,0.7,0.8,and 0.9)in van Genuchten-Muale model.Results show that with the increase ofλ,CO_(2)breakthrough pressure and breakthrough time both show decreasing trends.In other words,the larger the value ofλis,the better the permeability of the caprock is,and the worse the CO_(2)sealing capacity is.The numerical method established in this study can provide an important reference for the prediction of gas breakthrough pressure on rock-core scale and for related numerical studies.展开更多
基金supported by the National Natural Science Foundation of China(22205209,52202373 and U21A200972)China Postdoctoral Science Foundation(2022M722867)Key Research Project of Higher Education Institutions in Henan Province(23A530001)。
文摘The valence states and coordination structures of doped heterometal atoms in two-dimensional(2D)nanomaterials lack predictable regulation strategies.Hence,a robust method is proposed to form unsaturated heteroatom clusters via the metal-vacancy restraint mechanism,which can precisely regulate the bonding and valence state of heterometal atoms doped in 2D molybdenum disulfide.The unsaturated valence state of heterometal Pt and Ru cluster atoms form a spatial coordination structure with Pt–S and Ru–O–S as catalytically active sites.Among them,the strong binding energy of negatively charged suspended S and O sites for H+,as well as the weak adsorption of positively charged unsaturated heterometal atoms for H*,reduces the energy barrier of the hydrogen evolution reaction proved by theoretical calculation.Whereupon,the electrocatalytic hydrogen evolution performance is markedly improved by the ensemble effect of unsaturated heterometal atoms and highlighted with an overpotential of 84 mV and Tafel slope of 68.5 mV dec^(−1).In brief,this metal vacancy-induced valence state regulation of heterometal can manipulate the coordination structure and catalytic activity of heterometal atoms doped in the 2D atomic lattice but not limited to 2D nanomaterials.
基金This research was funded by the National Natural Science Foundation of China(Grant No.52174113)the Young Jinggang Scholars Award Program in Jiangxi Province,China(Grant No.QNJG2018051)the“Thousand Talents”of Jiangxi Province,China(Grant No.jxsq2019201043).
文摘In the process of ion-adsorption rare earth ore leaching,the migration characteristics of the wetting front in multi-hole injection holes and the influence of wetting front intersection effect on the migration distance of wetting fronts are still unclear.Besides,wetting front migration distance and leaching time are usually required to optimize the leaching process.In this study,wetting front migration tests of ionadsorption rare earth ores during the multi-hole fluid injection(the spacing between injection holes was 10 cm,12 cm and 14 cm)and single-hole fluid injection were completed under the constant water head height.At the pre-intersection stage,the wetting front migration laws of ion-adsorption rare earth ores during the multi-hole fluid injection and single-hole fluid injection were identical.At the postintersection stage,the intersection accelerated the wetting front migration.By using the Darcy’s law,the intersection effect of wetting fronts during the multi-hole liquid injection was transformed into the water head height directly above the intersection.Finally,based on the Green-Ampt model,a wetting front migration model of ion-adsorption rare earth ores during the multi-hole unsaturated liquid injection was established.Error analysis results showed that the proposed model can accurately simulate the infiltration process under experimental conditions.The research results enrich the infiltration law and theory of ion-adsorption rare earth ores during the multi-hole liquid injection,and this study provides a scientific basis for optimizing the liquid injection well pattern parameters of ion-adsorption rare earth in situ leaching in the future.
基金Supported by the Scientific Research Projects of Jiangsu Provincial Health and Health Commission,No.ZDB2020034 and No.M2021056.
文摘BACKGROUND The understanding of bile acid(BA)and unsaturated fatty acid(UFA)profiles,as well as their dysregulation,remains elusive in individuals with type 2 diabetes mellitus(T2DM)coexisting with non-alcoholic fatty liver disease(NAFLD).Investigating these metabolites could offer valuable insights into the pathophy-siology of NAFLD in T2DM.AIM To identify potential metabolite biomarkers capable of distinguishing between NAFLD and T2DM.METHODS A training model was developed involving 399 participants,comprising 113 healthy controls(HCs),134 individuals with T2DM without NAFLD,and 152 individuals with T2DM and NAFLD.External validation encompassed 172 participants.NAFLD patients were divided based on liver fibrosis scores.The analytical approach employed univariate testing,orthogonal partial least squares-discriminant analysis,logistic regression,receiver operating characteristic curve analysis,and decision curve analysis to pinpoint and assess the diagnostic value of serum biomarkers.RESULTS Compared to HCs,both T2DM and NAFLD groups exhibited diminished levels of specific BAs.In UFAs,particular acids exhibited a positive correlation with NAFLD risk in T2DM,while theω-6:ω-3 UFA ratio demonstrated a negative correlation.Levels ofα-linolenic acid andγ-linolenic acid were linked to significant liver fibrosis in NAFLD.The validation cohort substantiated the predictive efficacy of these biomarkers for assessing NAFLD risk in T2DM patients.CONCLUSION This study underscores the connection between altered BA and UFA profiles and the presence of NAFLD in individuals with T2DM,proposing their potential as biomarkers in the pathogenesis of NAFLD.
文摘Seepage flow in fractured rock mass due to surface infiltration is a saturated-unsaturated seepage process. Aimed at rock mass with large fracture density, which can be equivalent to continuum, a mathematical model for saturated-unsaturated seepage flow in fractured rock mass due to surface infiltration was established in this paper. The Galerkin finite element method was used in numerical simulation and a finite element program used to calculate saturated-unsaturated seepage flow due to surface infiltration was worked out. A model experiment was employed examine the reasonableness of the program. The results show that the proposed model and program are reasonable. The application of the analysis method in this paper in an engineering project shows that the method is reliable and feasible.
文摘The aim of the study is to seek a simple and inexpensive method to prevent the permeability rise of unsaturated clay caused by evaporation process and to raise its imperviousness. Taking Chengdu clay as an example, four treatment schemes were tried. Na 2CO 3 could reduce conspicuously the permeability of the saturated clay, but could not limit the permeability rise in the alternate wetting and drying process. NaOH had a similar effect to Na 2CO 3. NaCl could not only decrease the saturated hydraulic conductivity, but could also effectively contain the permeability rise caused by evaporation. CH 3COONa had a similar effect to NaCl. The mechanism of Na 2CO 3, NaOH, NaCl and CH 3COONa decreasing the saturated hydraulic conductivity of the clay is that Na + transformed Ca montmorillonites in the original clay into Na montmorillonites and the transformation reduces the sizes of effective pores and the effective porosity of the clay.
文摘Adiponectin,a specific hormone protein secreted by adipocytes,is a protective factor in the human body and has attracted great attention due to its anti-obesity activity[1,2].The adiponectin gene(ADIPOQ),which is located on human chromosome 3q27,is a single-copy gene.Various single-nucleotide polymorphisms(SNPs)of the human ADIPOQ play an important role in energy balance and are associated with body mass index(BMI)and obesity[3,4].Longchain polyunsaturated fatty acids(LC-PUFAs)have been identified to exert an important role during the first 1,000 days of life on infant growth,neurodevelopment,and visual acuity.Fatty acids,such asα-linoleic acid(ALA,C18:3n-3)and linoleic acid(LA,C18:2n-6),which cannot be synthesized de novo from other lipids,are necessary for biological reactions.Some fatty acids such as docosahexaenoic acid(DHA,C22:6n-3)and eicosapentaenoic acid(EPA,C20:5n-3)can be synthesized in neonates from their precursors(LA and ALA).Because of the very low conversion rates in the neonatal liver,it is crucial to provide adequate LC-PUFAs in the diet from early infancy.
基金Supported by the Natural Science Foundation of Jiangsu Province(No.BK20210527)the Open Research Fund of Key Laboratory of Coastal Science and Integrated Management,Ministry of Natural Resources(No.2021COSIMQ002)+1 种基金the National Natural Science Foundation of China(Nos.42107158,41831280)the Fundamental Research Funds for the Central Universities(No.2021QN1096)。
文摘Sediment incipient motion is the first step in sediment resuspension.Previous studies ignored the effect of seepage flow on the mobility of sediment particles and simplified the seabed surface as a rigid boundary.A flume experiment was designed to innovatively divide the seabed into two parts to control the dynamic response of the seabed and control the seepage conditions.In the experiment,the seabed sediments and the amplitude of internal solitary waves(ISWs)were changed to compare and analyze the impact of seepage flow on the sediment resuspension by shoaling ISWs.Moreover,parametric research and verification were carried out.Results indicate that seepage flow can greatly influence fine sand,promote sediment resuspension,and increase the amount of suspension by two times on average.However,seepage flow had a little effect on the suspension of clayey silt and sandy silt.Besides,seepage force was added to the traditional gravity,drag force,and uplift force,and the parameterization of threshold starting shear stress of coarse-grained sediments was developed.The results of this parameterization were verified,and seepage force was critical to parameterization.The threshold starting shear stress was reduced by 54.6%after increasing the seepage force.The physical mechanism of this process corresponded to the vertical reciprocating transient seepage in and out the seabed interface caused by the wave-induced transient excess pore water pressure.This quantitative study on seepage flow for shear stress of coarse-grained sediments induced by ISWs is critical to geohazard assessment.
基金The National Natural Science Foundation of China under contract No.41706081.
文摘Subterranean estuaries,i.e.,the mixing zone between terrestrial groundwater and recirculated seawater,host a wide range of microbiota.Here,field campaigns were conducted at the mouth of the subterranean estuary at the Sanggou Bay(Shandong Province,China)over four consecutive seasons at a seepage face(0−20 cm depth).The diversity of benthic microbiome was characterized via 16S rRNA gene sequencing and metagenomics,combined with physic-chemical parameters,e.g.,organic carbon,total nitrogen and sulfate contents in sediments.During spring,the dominant species were assigned to the phylum Proteobacteria.Important opportunistic species was assigned to Acidobacteria,Actinobacteria and Bacteroidetes.The key components were identified to be species of the genera Pseudoalteromonas,Colwellia and Sphingobium,indicating the involvement of sediment microbiota in the degradation of sedimentary organic carbon,particularly that of pelagic origin,e.g.,phytoplankton detritus and bivalve pseudo-feces.During spring,the microbial community was statistically similar along the depth profiles and among the three sampled stations.Similar spatial distributions were obtained in the remaining seasons.By contrast,the dominant species assemblages varied significantly among seasons,with key genera being Thioprofundum and Nitrosopumilus during summer and autumn and Thioprofundum and Ilumatobacter during winter.Network analysis revealed a seasonal shift in benthic nitrogen and sulfur metabolism associated with these variations in microbial community composition.Overall,our findings suggested that macro elements derived from pelagic inputs,particularly detrital phytoplankton,shaped the microbial community compositions at the seepage face,resulting in significant seasonal variations,while the influence of terrestrial materials transported by groundwater on the sediment microbiota at the seepage face found to be minor.
基金the National Natural Science Foundation of China(No.41972297)the Natural Science Foundation of Hebei Province(No.D2021202002).
文摘Internal erosion is one of the important factors causing geological disasters.The microstructure of soil can change with seepage erosion,resulting in changes in the hydraulic and mechanical properties of the soil.The evolution of seepage erosion is investigated with X-ray computed tomography(CT)in this study.The change in macropore structure characteristics during the seepage erosion test is quantified and the influence of seepage erosion on soil deformation is analyzed.Moreover,a pore network model(PNM)is established for the specimens and the evolution of the connected pore size characteristics is assessed.The results show that the macropore structure is significantly affected by seepage erosion,especially in terms of the porosity and pore geometry characteristics.The changes in macropore structure characteristics are most obvious in the lower part of the specimen.The influence of seepage erosion on the pore size distribution(PSD)and soil deformation is heterogeneous and closely dependent on the spatial location of the soil.Moreover,seepage erosion enhances macropore connectivity and has a directional impact on macropore orientation.These findings can provide a reference for the theoretical modeling and numerical simulation of the seepage erosion and improve the understanding of the seepage erosion evolution in engineering practice.
基金supported by the 13th Five-Year National Key Research and Development Plan of China (2016YFD0300609)the Outstanding Science and Technology Innovation Talents Program of Henan province (184200510008)+4 种基金Modern Agricultural Technology System Project of Henan Province (S2010-01G04)the National Key Research and Development Program of China (2017YFD0301105)the National Natural Science Foundations of CHINA (Grant No. 61501373, No. 61771390, No. 61771392, No. 61871322, and No. 61271279)the Henan Province Key Scientific and Technological Project (182102110291 and 222102110234)Natural Science Foundation of Henan Province (232300420186)
文摘In order to enhance the area throughput of next generation wireless local area network(WLAN)in high density scenarios,orthogonal frequency division multiple access(OFDMA)has been adopted as one of the key technologies in the next generation WLAN communication standards.However,the performance of the existing media access control(MAC)degrades significantly under unsaturated services.Therefore,this paper proposes a multi-user parallel contention channel MAC(MU-MAC)based on unsaturated services,which can effectively reduce the channel access conflict and improve the OFDMA access efficiency of cluster member nodes.On this basis,MU-MAC is enhanced for the spatial clustering group(SCG)formation protocol and support for the unsaturated service characteristics.Further,the optimal access radius when the service is in a non-saturated state is analyzed to make the relevant theoretical analysis more generally,and the expressions for the throughput and area throughput of the proposed protocol are modeled and derived.The simulation results verify the correctness of the theoretical analysis and the efficiency of the protocol performance.The results show that MU-MAC outperforms IEEE 802.11ax and OMAX protocol in area throughput by 40.72%and 104.15%,respectively.
基金The financial supports from the National Natural Science Foundation of China(Grant Nos.51988101,51925906 and 52122905)are gratefully acknowledged.
文摘Groundwater flow through fractured rocks has been recognized as an important issue in many geotechnical engineering practices.Several key aspects of fundamental mechanisms,numerical modeling and engineering applications of flow in fractured rocks are discussed.First,the microscopic mechanisms of fluid flow in fractured rocks,especially under the complex conditions of non-Darcian flow,multiphase flow,rock dissolution,and particle transport,have been revealed through a com-bined effort of visualized experiments and theoretical analysis.Then,laboratory and field methods of characterizing hydraulic properties(e.g.intrinsic permeability,inertial permeability,and unsaturated flow parameters)of fractured rocks in different flow regimes have been proposed.Subsequently,high-performance numerical simulation approaches for large-scale modeling of groundwater flow in frac-tured rocks and aquifers have been developed.Numerical procedures for optimization design of seepage control systems in various settings have also been proposed.Mechanisms of coupled hydro-mechanical processes and control of flow-induced deformation have been discussed.Finally,three case studies are presented to illustrate the applications of the improved theoretical understanding,characterization methods,modeling approaches,and seepage and deformation control strategies to geotechnical engi-neering projects.
基金supported by the Special Funds for Guiding Local Scientific and Technological Development by The Central Government(22ZY1QA005)the Science and Technology Program of Gansu Province"Outstanding Doctoral Students Project"(22JR5RA325)+3 种基金"Innovation Star"Funding Project for Outstanding Graduate Students of Gansu Province(2022CXZX-528)the Science and Technology Project of Gansu Province(21YF5GA050)Education Department of Gansu Province Industrial Support Plan Project(2021CYZC-28)Transport Department of Gansu Province Science and Technology R&D Projects(No.2021-12).
文摘Salinization and desertification are closely related to water-salt migration caused by a temperature gradient.Based on the Darcy Law of unsaturated soils,the law of energy conservation and the law of mass conservation,the thermal-water-salt coupling mathematical model of unsaturated frozen saline soil was established.The model considered the latent heat of phase change,crystallization impedance,crystallization consumption and complete precipitation of solute crystallization in ice.In order to verify the rationality of the model,the unidirectional freezing test of unsaturated saline soil was carried out in an open system with no-pressure water supplement to obtain the spatial distribution of temperature,moisture and salt in the saline soil.Finally,numerical simulations are implemented with the assistance of COMSOL Multiphysics.Validation of the model is illustrated by comparisons between the simulation and experimental data.The results demonstrated that the temperature within saline soil changes with time and can be divided into three stages,namely quick freezing stage,transitional stage and stable stage.The water and salt contents in the freezing zone are layered,with peak values at the freezing front.The coupled model could reveal the heat-mass migration mechanism of unsaturated frozen saline soil and dynamically describe the freezing depth and the movement law of the freezing front,ice and salt crystal formation mechanism,and the change law of thermal conductivity and permeability coefficient.
基金the National Natural Science Foundation of China(Nos.52174258,92162109,52222405 and 52004184).
文摘Both CT and Avizo software were used to explore the effect of particle gradation on the evolution characteristics of pore structure and seepage paths in weathered crust elution-deposited rare earth ores during leaching.The results showed that the pore areas in four kinds of ore samples before leaching were mainly concentrated in 10^(4)–10^(7)μm^(2),whose pore quantities accounted for 96.89%,94.94%,90.48%,and 89.45%,respectively,while the corresponding pore volume only accounted for 30.74%,14.55%,7.58%,and 2.84%of the total pore volume.With the decrease of fractal dimension,the average pore throat length increased,but pore throat quantities,the average pore throat radius and coordination number decreased.Compared with that before leaching,the change degree of pore structure during leaching increased with the fractal dimension decreasing.For example,the reduction rate of the average coordination number of ore samples was 14.36%,21.30%,28.00%,and 32.90%,respectively.Seepage simulation results indicated that seepage paths were uniformly distributed before leaching while the streamline density and seepage velocity increased with the fractal dimension decreasing.Besides,the phenomenon of the streamline interruption gradually reduced during leaching while preferential seepage got more obvious with the decrease of the fractal dimension.
基金supported by the National Natural Science Foundation of China(Grant Nos.42276224,and 42206230)the Jilin Scientific and Technological Development Program(Grant No.20190303083SF)+2 种基金the International Cooperation Key Laboratory of Underground Energy Development and Geological Restoration(Grant No.YDZJ202102CXJD014)the Interdisciplinary Integration and Innovation Project of JLU(Grant No.JLUXKJC2021ZZ18)the Graduate Innovation Fund of Jilin University(Grant No.2023CX100)。
文摘Natural gas hydrate(NGH)is an important future resource for the 21st century and a strategic resource with potential for commercial development in the third energy transition.It is of great significance to accurately predict the productivity of hydrate-bearing sediments(HBS).The multi-phase seepage parameters of HBS include permeability,porosity,which is closely related to permeability,and hydrate saturation,which has a direct impact on hydrate content.Existing research has shown that these multi-phase seepage parameters have a great impact on HBS productivity.Permeability directly affects the transmission of pressure-drop and discharge of methane gas,porosity and initial hydrate saturation affect the amount of hydrate decomposition and transmission process of pressure-drop,and also indirectly affect temperature variation of the reservoir.Considering the spatial heterogeneity of multi-phase seepage parameters,a depressurization production model with layered heterogeneity is established based on the clayey silt hydrate reservoir at W11 station in the Shenhu Sea area of the South China Sea.Tough+Hydrate software was used to calculate the production model;the process of gas production and seepage parameter evolution under different multi-phase seepage conditions were obtained.A sensitivity analysis of the parameters affecting the reservoir productivity was conducted so that:(a)a HBS model with layered heterogeneity can better describe the transmission process of pressure and thermal compensation mechanism of hydrate reservoir;(b)considering the multi-phase seepage parameter heterogeneity,the influence degrees of the parameters on HBS productivity were permeability,porosity and initial hydrate saturation,in order from large to small,and the influence of permeability was significantly greater than that of other parameters;(c)the production potential of the clayey silt reservoir should not only be determined by hydrate content or seepage capacity,but also by the comprehensive effect of the two;and(d)time scales need to be considered when studying the effects of changes in multi-phase seepage parameters on HBS productivity.
基金carried out at the National Natural Science Foundation of China(Nos.41672129,U19B200129)http://www.nsfc.gov.cn/and the National Science and technology Major Projects of China(No.2016ZX05027-004).
文摘The seepage mechanism plays a crucial role in low-permeability gas reservoirs.Compared with conventional gas reservoirs,low-permeability sandstone gas reservoirs are characterized by low porosity,low permeability,strong heterogeneity,and high water saturation.Moreover,their percolation mechanisms are more complex.The present work describes a series of experiments conducted considering low-permeability sandstone cores under pressuredepletion conditions(from the Xihu Depression in the East China Sea Basin).It is shown that the threshold pressure gradient of a low-permeability gas reservoir in thick layers is positively correlated with water saturation and negatively correlated with permeability and porosity.The reservoir stress sensitivity is related to permeability and rock composition.Stress sensitivity is generally low when permeability is high or in the early stage of gas reservoir development.It is also shown that in sand conglomerates,especially the more sparsely filled parts,the interstitial materials among the conglomerates can be rapidly dislodged from the skeleton particles under stress.This material can therefore disperse,migrate,and block the pore throat producing serious,stress-sensitive damage.
基金supported by the National Natural Science Foundation of China(Grant Nos.12172211 and 41630633)the National Key Research and Development Project of China(Grant No.2019YFC1509800).
文摘In practical engineering,the total vertical stress in the soil layer is not constant due to stress diffusion,and varies with time and depth.Therefore,the purpose of this paper is to investigate the effect of stress diffusion on the two-dimensional(2D)plane strain consolidation properties of unsaturated soils when the stress varies with time and depth.A series of semi-analytical solutions in terms of excess pore air and water pressures and settlement for 2D plane strain consolidation of unsaturated soils can be derived with the joint use of Laplace transform and Fourier sine series expansion.Then,the inverse Laplace transform of the semi-analytical solution is given in the time domain using a self-programmed code based on Crump’s method.The reliability of the obtained solutions is proved by the degeneration.Finally,the 2D plots of excess pore pressures and the curves of settlement varying with time,considering different physical parameters of unsaturated soil stratum and depth-dependent stress,are depicted and analyzed to study the 2D plane strain consolidation properties of unsaturated soils subjected to the depthdependent stress.
基金supported by the National Natural Science Foundation of China(52004117,52174117 and 51674132)the Postdoctoral Science Foundation of China(2021T140290 and 2020M680975)the Discipline Innovation Team of Liaoning Technical University(LNTU20TD-03 and LNTU20TD-30).
文摘Coal and gas outburst is a complex dynamic disaster during coal underground mining.Revealing the disaster mechanism is of great signifcance for accurate prediction and prevention of coal and gas outburst.The geo-dynamic system of coal and gas outburst is proposed.The framework of geo-dynamic system is composed of gassy coal mass,geological dynamic environment and mining disturbance.Equations of stress–damage–seepage interaction for gassy coal mass is constructed to resolve the outburst elimination process by gas extraction with boreholes through layer in foor roadway.The results show the occurrence of outburst is divided into the evolution process of gestation,formation,development and termination of geo-dynamic system.The scale range of outburst occurrence is determined,which provides a spatial basis for the prevention and control of outburst.The formation criterion and instability criterion of coal and gas outburst are established.The formation criterion F1 is defned as the scale of the geo-dynamic system,and the instability criterion F2 is defned as the scale of the outburst geo-body.According to the geo-dynamic system,the elimination mechanism of coal and gas outburst—‘unloading+depressurization’is established,and the gas extraction by boreholes through layer in foor roadway for outburst elimination is given.For the research case,when the gas extraction is 120 days,the gas pressure of the coal seam is reduced to below 0.4 MPa,and the outburst danger is eliminated efectively.
基金financially supported by Sichuan Huaxi Group Co.,ltd.(No.HXKX2019/015,No.HXKX2019/019,No.HXKX2018/030)the Open Fund of Sichuan Provincial Engineering Research Center of City Solid Waste Energy and Building Materials Conversion and Utilization Technology(No.GF2022ZC009)the Open Fund of Sichuan Engineering Research Center for Mechanical Properties and Engineering Technology of Unsaturated Soils(No.SC-FBHT2022-04)。
文摘Unsaturated expansive soil is widely distributed in China and has complex engineering properties.This paper proposes the unified hydraulic effect shear strength theory of unsaturated expansive soil based on the effective stress principle,swelling force principle,and soil–water characteristics.Considering the viscoelasticity and structural damage of unsaturated expansive soil during loading,a fractional hardening–damage model of unsaturated expansive soil was established.The model parameters were established on the basis of the proposed calculation method of shear strength and the triaxial shear experiment on unsaturated expansive soil.The proposed model was verified by the experimental data and a traditional damage model.The proposed model can satisfactorily describe the entire process of the strain-hardening law of unsaturated expansive soil.Finally,by investigating the damage variables of the proposed model,it was found that:(a)when the values of confining pressure and matric suction are close,the coupling of confining pressure and matric suction contributes more to the shear strength;(b)there is a damage threshold for unsaturated expansive soil,and is mainly reflected by strength criterion of infinitesimal body;(c)the strain hardening law of unsaturated expansive soil is mainly reflected by fractional derivative operator.
基金by the Program for Professor of Special Appointment(Eastern Scholar,No.TP2020009)at Shanghai Institutions of Higher Learning。
文摘We provide the capillary pressure curves p_(c)(s)as a function of the effective saturation s based on the theoretical framework of upscaling unsaturated flows in vertically heterogeneous porous layers proposed recently(Z.Zheng,Journal of Fluid Mechanics,950,A17,2022).Based on the assumption of vertical gravitational-capillary equilibrium,the saturation distribution and profile shape of the invading fluid can be obtained by solving a nonlinear integral-differential equation.The capillary pressure curves p_(c)(s)can then be constructed by systematically varying the injection rate.Together with the relative permeability curves k_(rn)(s)that are already obtained.One can now provide quick estimates on the overall behaviours of interfacial and unsaturated flows in vertically-heterogeneous porous layers.
基金supported by Open Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering,Institute of Rock and Soil Mechanics,Chinese Academy of Sciences(Grant No.SKLGME021010)funded by the National Natural Science Foundation of China(Grant No.41702251 and 42141010)the MOE Key Laboratory of Groundwater Circulation and Environmental Evolution。
文摘Gas breakthrough pressure is a key parameter to evaluate the sealing capacity of caprock,and it also plays important roles in safety and capacity of CO_(2)geological storage.Based on the published experimental results,we present numerical simulations on CO_(2)breakthrough pressure in unsaturated low-permeability rock under 9 multiple P-T conditions(which can keep CO_(2)in gaseous,liquid and supercritical states)and thus,a numerical method which can be used to accurately predict CO_(2)breakthrough pressure on rock-core scale is proposed.The simulation results show that CO_(2)breakthrough pressure and breakthrough time are exponential correlated with P-T conditions.Meanwhile,pressure has stronger effects on experimental results than that of temperature.Moreover,we performed sensitivity studies on the pore distribution indexλ(0.6,0.7,0.8,and 0.9)in van Genuchten-Muale model.Results show that with the increase ofλ,CO_(2)breakthrough pressure and breakthrough time both show decreasing trends.In other words,the larger the value ofλis,the better the permeability of the caprock is,and the worse the CO_(2)sealing capacity is.The numerical method established in this study can provide an important reference for the prediction of gas breakthrough pressure on rock-core scale and for related numerical studies.
