The Jiangla'angzong granite in the northern part of the Central Lhasa Terrane is composed of syenogranite and adamellite. LA-ICP-MS zircon U-Pb analyses suggest that syenogranite has a weighted mean 2±6pb/23SU a...The Jiangla'angzong granite in the northern part of the Central Lhasa Terrane is composed of syenogranite and adamellite. LA-ICP-MS zircon U-Pb analyses suggest that syenogranite has a weighted mean 2±6pb/23SU age of 86±1 Ma (mean square weighted deviation=0.37), which is in accordance with the muscovite Ar-Ar age (85±1 Ma) of Cu-Au ore-bearing skarns and the zircon U-Pb age (84±1 Ma) of adamellite. This suggests that the Jiangla'angzong magmatism and Cu-Au mineralization events took place during the Late Cretaceous. The granite contains hornblende, biotite, and pyroxene, and does not contain Al-bearing minerals, such as muscovite, cordierite, and garnet. It has high contents of SiO2 (65.10 -70.91wt%), K20 (3.44-5.17wt%), and total K20+Na20 (7.13-8.15wt%), and moderate contents of A12Oa (14.14-16.45wt%) and CaO (2.33-4.11wt%), with a Reitman index (δ43) of 2.18 to 2.33, and A/ CNK values of 0.88 to 1.02. The P205 contents show a negative correlation with SiO2, whereas Pb contents show a positive correlation with SiO2. Th and Y contents are relatively low and show a negative correlation with the Rb contents. These characteristics suggest that the Jiangla'angzong granite is a high K calc-alkaline metaluminous I-type granite. It is enriched in light rare earth elements (LREE) and large ion lithofile elements (LILE), and depleted in heavy rare earth elements (HREE) and high field strength elements (HFSE), with LREE/HREE ratios of 11.7 to 18.1. The granite has negative Eu anomalies of 0.58 to 0.94 without obvious Ce anomalies (δCe=l.00-1.04). The relatively low initial a7Sr/a6Sr ratios of 0.7106 to 0.7179, positive ε±nt(t) values of 1.0 to 4.1, and two-stage Hf model ages (TDM2) ranging from 889 Ma to 1082 Ma, These geochemical features indicate that the granite derived from a juvenile crust. The (143Nd/144Nd)t values from the Jiangla'angzong granite range from 0.5121 to 0.5123, its eNd(t) values range from -10.17 to -6.10, its (^206pb /^204pb)t values range from 18.683 to 18.746, its (^207pb /^204pb)t values range from 15.695 to 15.700, and its (^208pb /^204pb)t values range from 39.012 to 39.071. These data indicate that the granite was formed by melting of the upper crust with the addition of some mantle materials. We propose that the Jiangla'angzong granite was formed during the post- collision extension of the Qiangtang and Lhasa terranes.展开更多
There are several Pan-African granitoid plutons widely distributed in Shillong Plateau,NE India.Nongpoh(506.7±7 Ma)and Mylliem(480-430 Ma)plutons were chosen for the petrological and geochemical study to constrai...There are several Pan-African granitoid plutons widely distributed in Shillong Plateau,NE India.Nongpoh(506.7±7 Ma)and Mylliem(480-430 Ma)plutons were chosen for the petrological and geochemical study to constrain their petrogenesis.Nongpoh pluton consists of coarse-grained porphyritic quartz-monzogranite(NQM)and Mylliem pluton consists of medium to coarse-grained porphyritic granite(MG).The constituent minerals are K-feldspar,plagioclase,quartz,and biotite in both granitoids with accessory minerals of hornblende,zircon,sphene,and ilmenite.Both NQM and MG are metaluminous to weakly peraluminous(A/CNK=0.82-1.06),exhibit varied ranges of SiO2(NQM:58.4-64.9 wt%;MG:66.9-69.9 wt%),and display a clear compositional gap in the Harker variation diagram.NQM contains higher abundances of CaO,MgO and Fe2O3t and similar K2O and total alkali contents compared to MG.They have distinctive geochemical features typical of highly fractionated I-type granitoids such as higher abundances of K2O,Al2O3,MgO,CaO,Al2O3+CaO>15 wt%and A/CNK<1.1,low P2O5 content,enrichment in LILE,depletion in HFSE and HREE and highly fractionated REE patterns with moderate Eu anomalies,implying magma generation in a post-collisional extension setting and thinning induced asthenosphere upwelling,accompanied by the partial melting of the overlying enriched lithospheric mantle.The multi-element diagram of both NQM and MG shows pronounced negative anomalies at Ba,Nb,Sr,P,Zr,and Ti which implies a major role of crystal fractionation in their petrogenesis.High concentrations of Th,U,and Pb in the granitoid types point to additional involvement of crustal components in their generation.However,MGs with more pronounced positive spikes at U,Th,and Pb compared to NQM in multi-element diagram suggests the involvement of more felsic crustal material.The observed geochemical features of the granitoid types thus suggest that they are genetically unrelated to each other and their parental magmas were modified during magmatic differentiation processes.We suggest that the NQM and MG were formed as a result of fractional crystallization of compositionally diverse hybrid magmas produced due to mingling and mixing of an enriched lithospheric mantle-derived melts with lower crust-and middle crust-derived melts respectively during a period of extension late in the cycle of PanAfrican orogeny.展开更多
The Baleigong granites, located in the western part of the southwestern Tianshan Orogen(Kokshanyan region, China), records late Paleozoic magmatism during the late stages of convergence between the Tarim Block and the...The Baleigong granites, located in the western part of the southwestern Tianshan Orogen(Kokshanyan region, China), records late Paleozoic magmatism during the late stages of convergence between the Tarim Block and the Central Tianshan Arc Terrane. We performed a detailed geochronological and geochemical study of the Baleigong granites to better constrain the nature of collisional processes in the Southwest Tianshan Orogen. The LA-ICP-MS U-Pb zircon isotopic analyses indicate that magmatism commenced in the early Permian(~282 Ma). The granite samples, which are characterized by high contents of SiO2(67.68-69.77 wt%) and Al2O3(13.93-14.76 wt%), are alkali-rich and Mg-poor, corresponding to the high-K calc-alkaline series. The aluminum saturation index(A/CNK) ranges from 0.93 to 1.02, indicating a metaluminous to slightly peraluminous composition. Trace element geochemistry shows depletions in Nb, Ta, and Ti, a moderately negative Eu anomaly(δEu=0.40-0.56), enrichment in LREE, and depletion in HREE((La/Yb)N=7.46-11.78). These geochemical signatures are characteristic of an I-type granite generated from partial melting of a magmatic arc. The I-type nature of the Baleigong granites is also supported by the main mafic minerals being Fe-rich calcic hornblende and biotite. We suggest that the high-K, calc-alkaline I-type granitic magmatism was generated by partial melting of the continental crust, possibly triggered by underplating by basaltic magma. These conditions were likely achieved in a collisional tectonic setting, thus supporting the suggestion that closure of the South Tianshan Ocean was completed prior to the Permian and was followed(in the late Paleozoic) by collision between the Tarim Block and the Central Tianshan Arc Terrane.展开更多
In the western Yangtze Block, widespread Mesoproterozoic to Neoproterozoic rocks are the key to understanding the Precambrian tectonic-magmatic evolution of the region. However, their petrogenesis and tectonic setting...In the western Yangtze Block, widespread Mesoproterozoic to Neoproterozoic rocks are the key to understanding the Precambrian tectonic-magmatic evolution of the region. However, their petrogenesis and tectonic setting are still controversial. In this paper, zircon U-Pb ages, Sm-Nd isotopic and whole-rock geochemical data are reported from selected fresh samples in the southern Dechang county, southwestern China, in order to constrain their emplacement age and magma source, as well as their petrogenesis and tectonic setting. They are mainly composed of biotite monzogranite, monzonitic granite, biotite granodiorites, and quartz diorite. Two ages of 1055 ± 43 Ma and 837.6 ± 3.8 Ma were obtained through zircon U-Pb dating by LA-ICP-MS and LA-MC-ICP-MS, respectively. According to their major element compositions, the Grenville-age granites are peraluminous calc-alkaline series calcic S-type granite. In contrast, the mid-Neoproterozoic granites are metaluminous calc-aikaline series alkalic I-type granite. Furthermore, the S-type granites are enriched in LREEs relative to HREEs with (La/Yb)N ratios of 3.85-18.56 and underwent major fractionation with strongly negative Eu anomalies (Eu/Eu* = 0.38-0.66). In the MORB-normalized trace element variation diagram, all the samples are enriched in Ce and large ion lithophile elements such as Rb, Th, and K, and depleted in high field strength elements such as Nb, and Ti, with negative Sr and Ti anomalies. The I-type granites are enriched in LREEs with slight negative Eu anomalies (Eu/Eu*= 0.83-0.93). They are characterized by the enrichment of highly incompatible elements (such as K, Rb, Ba, Th) and LREEs, relative to MORB. Neodymium isotopic data show that the S-type granites display 143Nd/144Nd values of 0.51241-0.51256, and have eNa (t = 1055 Ma) values of (-3.29) to (-3.81). Calculated tDM ages yield values from 1.87 to 1.91 Ga with the tDM.2stg ages of 1.86 to 1.9 Ga. The I-type granites have 143Nd/144Nd ratios between 0.51192 and 0.51195, corresponding to initial eNd (t = 837 Ma) values of 1.22 to 5.63. Calculated tDM ages yield values from 1.0 to 1.38 Ga and the tDM.2stg ages yield values from 0.99 to 1.06 Ga. The S-type granites are distinguished as syn-collision granite, whereas the I-type granites were formed as arc magmas according to the Rb-(Yb+Ta) and R1-R2 tectonic discrimination diagrams. To conclude, there are two types of spatially associated granite, the Mesoproterozoic S-type granite which were derived from re- melting of upper crustal mudstone and/or clastics and resulted from the convergence of two continental plates, and the mid-Neoproterozoic I-type granite which formed in continental arc and resulted from mantle-derived magma mixed crust material, in the western Yangtze Block. Furthermore, we suggest that collision between the Yangtze and Cathaysia blocks occurred at about 1055 Ma, and caused the S- type granite. The I-type granite related to the subduction of oceanic lithosphere eastward underneath the Yangtze Block in the mid-Neoproterozoic.展开更多
The Kejie pluton is located in the north of the Changning-Menglian suture zone. The rock types are mainly biotite-granite. Zircon LA-ICP-MS U-Pb dating indicates that the Kejie pluton emplaced at about 80-77 Ma, Late ...The Kejie pluton is located in the north of the Changning-Menglian suture zone. The rock types are mainly biotite-granite. Zircon LA-ICP-MS U-Pb dating indicates that the Kejie pluton emplaced at about 80-77 Ma, Late Cretaceous. The Kejie pluton samples are characterized by high SiO2 (71.68%-72.47%), K2O (4.73%-5.54%), total alkali (K2O + Na2O = 8.21%-8.53%), K2O/Na2O ratios (1.36-1.94) and low P2O5 (0.13%-0.17%), with A/CNK of 1.025-1.055; enriched in U, Th, and K, depleted in Ba, Nb, St, Ti, P and Eu. They are highly fractionated, slightly peraluminous 1-type granite. The two samples of the Kejie pluton give a large variation of εHf(t) values (-5.04 to 1.96) and Hf isotope crustal model ages of 1.16-1.5 Ga. Zircon Hf isotopes and zircon saturation temperatures of whole-rock (801℃-823℃) show that the mantle-derived materials maybe have played a vital role in the generation of the Kejie pluton. The Kejie pluton was most likely generated in a setting associated with the eastward subduction of the neo-Tethys ocean, where intrusion of mantle wedge basaltic magmas in the crust caused the anatexis of the latter, forming hybrid melts, which subsequently experienced high-degree fractional crystallization.展开更多
The Mabeng granitic intrusion, which occurs in the northwestern T-S gold ore field, presents intruive contact with the country rocks. The facies zoining in it is obvious and its mineral components are relatively simpl...The Mabeng granitic intrusion, which occurs in the northwestern T-S gold ore field, presents intruive contact with the country rocks. The facies zoining in it is obvious and its mineral components are relatively simple. Its petrochemic characteristics demonstrate that it is hornblende-biotite granite with aluminium-alkali oversaturation, meanwhile its petrogeochemical features show a high gold content with a concentrational coefficient 12. 2. Its REE suggests that its internal different facies are the differentiational products of magma from the same source. All of those support the suggestion that the intrusion is originaly magmatic genesis and belongs io the I-type of granite. The original magma of the body comes from the deep crust or the upper mantle and is highly auriferous.展开更多
The Mayo-Darley massif is an anorogenic complex of the Cameroon Line that has a mantle origin.Tin-bearing rocks were analyzed by ICP-AES and INAA analytical methods.The purpose of this work was to provide new geochemi...The Mayo-Darley massif is an anorogenic complex of the Cameroon Line that has a mantle origin.Tin-bearing rocks were analyzed by ICP-AES and INAA analytical methods.The purpose of this work was to provide new geochemical data for the Mayo-Darley tin formation and to understand its petrogenesis and the origin of tin mineralization.The Mayo-Darley tin deposit is made up of tin-granite,and tin-greisen,greisenification was developed on the borders of quartz dykes.These rocks belong to the alkaline series and were classified into acid(SiO2-=61.6%–73.8%;65.4%–98%respectively)and basic(42.9%–47%SiO_(2))rocks.They showed enrichment in HSFE,LILE,Ga/Al and chondrite normalized REE patterns indicating LREE enrichment relative to HREE with a negative Eu anomaly,only sample SB8 of tin-granite showed Eu/Eu*=1.11.Rocks display metaluminous,peralkaline,peraluminous,ferroan,high-K calc-alkaline to shoshonitic,alkalic to calcic affinity,and crystallized at800°C.The chemistry of this deposit reflects the primary composition of granite,quartz monzonite,gabbro,and foid gabbro.This complex experienced multi-stage sub-solidus hydrothermal fluid reactions and shows variable alteration of feldspars alkali mobility.The rocks are classified as A1-type granite,overlap with the OIB field,and were derived from a within-plate setting,similar to mantle non plumederived magmas.The origin of tin mineralization in MayoDarley has a complex evolution,tin mineralization was derived from hydrothermal and hydrogenous metal-rich deposits and shows Sn–Hf–Zr and Sn–Tl–Nb association.These new data confirm the complexity of the Mayo-Darley tin complex and elucidate the origin of tin mineralization.展开更多
基金financially supported by the National Key Research and Development Program of China (Grant No.2016YFC0600308, SQ2018YFC060162)the China Geological Survey Project (Grant No.DD20160015,DD20160026)+1 种基金the International Scientific Plan of the Qinghai Xizang (Tibet) Plateau of Chengdu Center, China Geological Surveythe Natural Science Foundation of China (Grant No.41702080, 41702086)
文摘The Jiangla'angzong granite in the northern part of the Central Lhasa Terrane is composed of syenogranite and adamellite. LA-ICP-MS zircon U-Pb analyses suggest that syenogranite has a weighted mean 2±6pb/23SU age of 86±1 Ma (mean square weighted deviation=0.37), which is in accordance with the muscovite Ar-Ar age (85±1 Ma) of Cu-Au ore-bearing skarns and the zircon U-Pb age (84±1 Ma) of adamellite. This suggests that the Jiangla'angzong magmatism and Cu-Au mineralization events took place during the Late Cretaceous. The granite contains hornblende, biotite, and pyroxene, and does not contain Al-bearing minerals, such as muscovite, cordierite, and garnet. It has high contents of SiO2 (65.10 -70.91wt%), K20 (3.44-5.17wt%), and total K20+Na20 (7.13-8.15wt%), and moderate contents of A12Oa (14.14-16.45wt%) and CaO (2.33-4.11wt%), with a Reitman index (δ43) of 2.18 to 2.33, and A/ CNK values of 0.88 to 1.02. The P205 contents show a negative correlation with SiO2, whereas Pb contents show a positive correlation with SiO2. Th and Y contents are relatively low and show a negative correlation with the Rb contents. These characteristics suggest that the Jiangla'angzong granite is a high K calc-alkaline metaluminous I-type granite. It is enriched in light rare earth elements (LREE) and large ion lithofile elements (LILE), and depleted in heavy rare earth elements (HREE) and high field strength elements (HFSE), with LREE/HREE ratios of 11.7 to 18.1. The granite has negative Eu anomalies of 0.58 to 0.94 without obvious Ce anomalies (δCe=l.00-1.04). The relatively low initial a7Sr/a6Sr ratios of 0.7106 to 0.7179, positive ε±nt(t) values of 1.0 to 4.1, and two-stage Hf model ages (TDM2) ranging from 889 Ma to 1082 Ma, These geochemical features indicate that the granite derived from a juvenile crust. The (143Nd/144Nd)t values from the Jiangla'angzong granite range from 0.5121 to 0.5123, its eNd(t) values range from -10.17 to -6.10, its (^206pb /^204pb)t values range from 18.683 to 18.746, its (^207pb /^204pb)t values range from 15.695 to 15.700, and its (^208pb /^204pb)t values range from 39.012 to 39.071. These data indicate that the granite was formed by melting of the upper crust with the addition of some mantle materials. We propose that the Jiangla'angzong granite was formed during the post- collision extension of the Qiangtang and Lhasa terranes.
基金financially supported by the Department of Science and Technology,Govt.of India under the Inspire Research Fellowship Programme(File No.:DST/Inspire Fellowship/2016/IF160812)。
文摘There are several Pan-African granitoid plutons widely distributed in Shillong Plateau,NE India.Nongpoh(506.7±7 Ma)and Mylliem(480-430 Ma)plutons were chosen for the petrological and geochemical study to constrain their petrogenesis.Nongpoh pluton consists of coarse-grained porphyritic quartz-monzogranite(NQM)and Mylliem pluton consists of medium to coarse-grained porphyritic granite(MG).The constituent minerals are K-feldspar,plagioclase,quartz,and biotite in both granitoids with accessory minerals of hornblende,zircon,sphene,and ilmenite.Both NQM and MG are metaluminous to weakly peraluminous(A/CNK=0.82-1.06),exhibit varied ranges of SiO2(NQM:58.4-64.9 wt%;MG:66.9-69.9 wt%),and display a clear compositional gap in the Harker variation diagram.NQM contains higher abundances of CaO,MgO and Fe2O3t and similar K2O and total alkali contents compared to MG.They have distinctive geochemical features typical of highly fractionated I-type granitoids such as higher abundances of K2O,Al2O3,MgO,CaO,Al2O3+CaO>15 wt%and A/CNK<1.1,low P2O5 content,enrichment in LILE,depletion in HFSE and HREE and highly fractionated REE patterns with moderate Eu anomalies,implying magma generation in a post-collisional extension setting and thinning induced asthenosphere upwelling,accompanied by the partial melting of the overlying enriched lithospheric mantle.The multi-element diagram of both NQM and MG shows pronounced negative anomalies at Ba,Nb,Sr,P,Zr,and Ti which implies a major role of crystal fractionation in their petrogenesis.High concentrations of Th,U,and Pb in the granitoid types point to additional involvement of crustal components in their generation.However,MGs with more pronounced positive spikes at U,Th,and Pb compared to NQM in multi-element diagram suggests the involvement of more felsic crustal material.The observed geochemical features of the granitoid types thus suggest that they are genetically unrelated to each other and their parental magmas were modified during magmatic differentiation processes.We suggest that the NQM and MG were formed as a result of fractional crystallization of compositionally diverse hybrid magmas produced due to mingling and mixing of an enriched lithospheric mantle-derived melts with lower crust-and middle crust-derived melts respectively during a period of extension late in the cycle of PanAfrican orogeny.
基金financially supported by the National Natural Science Foundation of China (Grant Nos.U1403292, 41472196, 41502085, and 41902214)the National Key Technology Research and Development Program of the Ministry of Science and Technology of China (2015BAB05B04, 2018YFC0604005)the China Geological Survey Bureau (JYYWF20183702, JYYWF20180602)
文摘The Baleigong granites, located in the western part of the southwestern Tianshan Orogen(Kokshanyan region, China), records late Paleozoic magmatism during the late stages of convergence between the Tarim Block and the Central Tianshan Arc Terrane. We performed a detailed geochronological and geochemical study of the Baleigong granites to better constrain the nature of collisional processes in the Southwest Tianshan Orogen. The LA-ICP-MS U-Pb zircon isotopic analyses indicate that magmatism commenced in the early Permian(~282 Ma). The granite samples, which are characterized by high contents of SiO2(67.68-69.77 wt%) and Al2O3(13.93-14.76 wt%), are alkali-rich and Mg-poor, corresponding to the high-K calc-alkaline series. The aluminum saturation index(A/CNK) ranges from 0.93 to 1.02, indicating a metaluminous to slightly peraluminous composition. Trace element geochemistry shows depletions in Nb, Ta, and Ti, a moderately negative Eu anomaly(δEu=0.40-0.56), enrichment in LREE, and depletion in HREE((La/Yb)N=7.46-11.78). These geochemical signatures are characteristic of an I-type granite generated from partial melting of a magmatic arc. The I-type nature of the Baleigong granites is also supported by the main mafic minerals being Fe-rich calcic hornblende and biotite. We suggest that the high-K, calc-alkaline I-type granitic magmatism was generated by partial melting of the continental crust, possibly triggered by underplating by basaltic magma. These conditions were likely achieved in a collisional tectonic setting, thus supporting the suggestion that closure of the South Tianshan Ocean was completed prior to the Permian and was followed(in the late Paleozoic) by collision between the Tarim Block and the Central Tianshan Arc Terrane.
基金supported by the China Geological Survey project(1212011120623)
文摘In the western Yangtze Block, widespread Mesoproterozoic to Neoproterozoic rocks are the key to understanding the Precambrian tectonic-magmatic evolution of the region. However, their petrogenesis and tectonic setting are still controversial. In this paper, zircon U-Pb ages, Sm-Nd isotopic and whole-rock geochemical data are reported from selected fresh samples in the southern Dechang county, southwestern China, in order to constrain their emplacement age and magma source, as well as their petrogenesis and tectonic setting. They are mainly composed of biotite monzogranite, monzonitic granite, biotite granodiorites, and quartz diorite. Two ages of 1055 ± 43 Ma and 837.6 ± 3.8 Ma were obtained through zircon U-Pb dating by LA-ICP-MS and LA-MC-ICP-MS, respectively. According to their major element compositions, the Grenville-age granites are peraluminous calc-alkaline series calcic S-type granite. In contrast, the mid-Neoproterozoic granites are metaluminous calc-aikaline series alkalic I-type granite. Furthermore, the S-type granites are enriched in LREEs relative to HREEs with (La/Yb)N ratios of 3.85-18.56 and underwent major fractionation with strongly negative Eu anomalies (Eu/Eu* = 0.38-0.66). In the MORB-normalized trace element variation diagram, all the samples are enriched in Ce and large ion lithophile elements such as Rb, Th, and K, and depleted in high field strength elements such as Nb, and Ti, with negative Sr and Ti anomalies. The I-type granites are enriched in LREEs with slight negative Eu anomalies (Eu/Eu*= 0.83-0.93). They are characterized by the enrichment of highly incompatible elements (such as K, Rb, Ba, Th) and LREEs, relative to MORB. Neodymium isotopic data show that the S-type granites display 143Nd/144Nd values of 0.51241-0.51256, and have eNa (t = 1055 Ma) values of (-3.29) to (-3.81). Calculated tDM ages yield values from 1.87 to 1.91 Ga with the tDM.2stg ages of 1.86 to 1.9 Ga. The I-type granites have 143Nd/144Nd ratios between 0.51192 and 0.51195, corresponding to initial eNd (t = 837 Ma) values of 1.22 to 5.63. Calculated tDM ages yield values from 1.0 to 1.38 Ga and the tDM.2stg ages yield values from 0.99 to 1.06 Ga. The S-type granites are distinguished as syn-collision granite, whereas the I-type granites were formed as arc magmas according to the Rb-(Yb+Ta) and R1-R2 tectonic discrimination diagrams. To conclude, there are two types of spatially associated granite, the Mesoproterozoic S-type granite which were derived from re- melting of upper crustal mudstone and/or clastics and resulted from the convergence of two continental plates, and the mid-Neoproterozoic I-type granite which formed in continental arc and resulted from mantle-derived magma mixed crust material, in the western Yangtze Block. Furthermore, we suggest that collision between the Yangtze and Cathaysia blocks occurred at about 1055 Ma, and caused the S- type granite. The I-type granite related to the subduction of oceanic lithosphere eastward underneath the Yangtze Block in the mid-Neoproterozoic.
基金financially supported by the Programme of the China Geological Survey (No.1212011120608, No.1212011220907)the National Key Projects for Basic Research of China (No.2009CB421002, No.2011CB403102)+2 种基金NSF of China (No. 40672044)Program for Changjiang Scholars, Innovative Research Team in University (No.IRT1083)111 project (No.B07011)
文摘The Kejie pluton is located in the north of the Changning-Menglian suture zone. The rock types are mainly biotite-granite. Zircon LA-ICP-MS U-Pb dating indicates that the Kejie pluton emplaced at about 80-77 Ma, Late Cretaceous. The Kejie pluton samples are characterized by high SiO2 (71.68%-72.47%), K2O (4.73%-5.54%), total alkali (K2O + Na2O = 8.21%-8.53%), K2O/Na2O ratios (1.36-1.94) and low P2O5 (0.13%-0.17%), with A/CNK of 1.025-1.055; enriched in U, Th, and K, depleted in Ba, Nb, St, Ti, P and Eu. They are highly fractionated, slightly peraluminous 1-type granite. The two samples of the Kejie pluton give a large variation of εHf(t) values (-5.04 to 1.96) and Hf isotope crustal model ages of 1.16-1.5 Ga. Zircon Hf isotopes and zircon saturation temperatures of whole-rock (801℃-823℃) show that the mantle-derived materials maybe have played a vital role in the generation of the Kejie pluton. The Kejie pluton was most likely generated in a setting associated with the eastward subduction of the neo-Tethys ocean, where intrusion of mantle wedge basaltic magmas in the crust caused the anatexis of the latter, forming hybrid melts, which subsequently experienced high-degree fractional crystallization.
文摘The Mabeng granitic intrusion, which occurs in the northwestern T-S gold ore field, presents intruive contact with the country rocks. The facies zoining in it is obvious and its mineral components are relatively simple. Its petrochemic characteristics demonstrate that it is hornblende-biotite granite with aluminium-alkali oversaturation, meanwhile its petrogeochemical features show a high gold content with a concentrational coefficient 12. 2. Its REE suggests that its internal different facies are the differentiational products of magma from the same source. All of those support the suggestion that the intrusion is originaly magmatic genesis and belongs io the I-type of granite. The original magma of the body comes from the deep crust or the upper mantle and is highly auriferous.
文摘The Mayo-Darley massif is an anorogenic complex of the Cameroon Line that has a mantle origin.Tin-bearing rocks were analyzed by ICP-AES and INAA analytical methods.The purpose of this work was to provide new geochemical data for the Mayo-Darley tin formation and to understand its petrogenesis and the origin of tin mineralization.The Mayo-Darley tin deposit is made up of tin-granite,and tin-greisen,greisenification was developed on the borders of quartz dykes.These rocks belong to the alkaline series and were classified into acid(SiO2-=61.6%–73.8%;65.4%–98%respectively)and basic(42.9%–47%SiO_(2))rocks.They showed enrichment in HSFE,LILE,Ga/Al and chondrite normalized REE patterns indicating LREE enrichment relative to HREE with a negative Eu anomaly,only sample SB8 of tin-granite showed Eu/Eu*=1.11.Rocks display metaluminous,peralkaline,peraluminous,ferroan,high-K calc-alkaline to shoshonitic,alkalic to calcic affinity,and crystallized at800°C.The chemistry of this deposit reflects the primary composition of granite,quartz monzonite,gabbro,and foid gabbro.This complex experienced multi-stage sub-solidus hydrothermal fluid reactions and shows variable alteration of feldspars alkali mobility.The rocks are classified as A1-type granite,overlap with the OIB field,and were derived from a within-plate setting,similar to mantle non plumederived magmas.The origin of tin mineralization in MayoDarley has a complex evolution,tin mineralization was derived from hydrothermal and hydrogenous metal-rich deposits and shows Sn–Hf–Zr and Sn–Tl–Nb association.These new data confirm the complexity of the Mayo-Darley tin complex and elucidate the origin of tin mineralization.