Zinc-modified Pt/SAPO-11 catalysts were prepared by incipient wetness impregnation and assessed in the hydroisomerization of n-octane.Their physicochemical properties were investigated using powder X-ray diffraction,s...Zinc-modified Pt/SAPO-11 catalysts were prepared by incipient wetness impregnation and assessed in the hydroisomerization of n-octane.Their physicochemical properties were investigated using powder X-ray diffraction,scanning electron microscopy,nitrogen adsorption-desorption,pyridine-adsorbed infrared spectroscopy,temperature-programmed desorption of NH3,temperature-programmed reduction of hydrogen,temperature-programmed desorption of hydrogen,transmission electron microscopy,and X-ray photoelectron spectroscopy.The addition of zinc resulted in high dispersion of platinum.Zinc acted as a competitive adsorbent,changed the location of platinum.The catalyst with a zinc loading of 0.5%gave the highest selectivity to dimethylhexanes,but the conversion was lower than those achieved with the other catalysts.Dimethylhexanes have large molecular diameters,and therefore their diffusion may be difficult.This weakens the catalytic activity of the zinc-modified catalysts and lowers the n-octane conversion.展开更多
Lateral diffusion of diblock copolymer residing on the interfaces between two immiscible liquids is investigated at single molecular level. Fluorescence correlation spectroscopy was used to study the diffusion of fluo...Lateral diffusion of diblock copolymer residing on the interfaces between two immiscible liquids is investigated at single molecular level. Fluorescence correlation spectroscopy was used to study the diffusion of fluorescence-labeled diblock copolymer,polystyrene-b-polyisoprene, at the interface formed between two immiscible liquids. The interfaces are formed between N,N-dimethylformamide(DMF) and a few immiscible liquids, n-alkane and polyisoprene. Interfacial diffusion coefficient of the diblock copolymer probe is found to decrease monotonously with the increase of the molecular length of the interface constituting liquids. The decrease of diffusion coefficient follows the prediction by Einstein relation using the viscosity of the constituting liquids as the variables only for interfaces between DMF and very small n-alkanes. For interfaces formed between DMF and bigger alkanes and especially between DMF and polyisoprene, the diffusion coefficient is much higher than the calculated value,indicating that the probe molecule starts to probe the much less viscous interfacial region because the interfacial width gets larger,whose thickness is comparable to the molecule size of the liquids.展开更多
基金supported by the National Natural Science Foundation of China(21676300)~~
文摘Zinc-modified Pt/SAPO-11 catalysts were prepared by incipient wetness impregnation and assessed in the hydroisomerization of n-octane.Their physicochemical properties were investigated using powder X-ray diffraction,scanning electron microscopy,nitrogen adsorption-desorption,pyridine-adsorbed infrared spectroscopy,temperature-programmed desorption of NH3,temperature-programmed reduction of hydrogen,temperature-programmed desorption of hydrogen,transmission electron microscopy,and X-ray photoelectron spectroscopy.The addition of zinc resulted in high dispersion of platinum.Zinc acted as a competitive adsorbent,changed the location of platinum.The catalyst with a zinc loading of 0.5%gave the highest selectivity to dimethylhexanes,but the conversion was lower than those achieved with the other catalysts.Dimethylhexanes have large molecular diameters,and therefore their diffusion may be difficult.This weakens the catalytic activity of the zinc-modified catalysts and lowers the n-octane conversion.
基金supported by the National Natural Science Foundation of China (51573197, 21544012)the Instrumentation Developments Funding of Chinese Academy of Sciences
文摘Lateral diffusion of diblock copolymer residing on the interfaces between two immiscible liquids is investigated at single molecular level. Fluorescence correlation spectroscopy was used to study the diffusion of fluorescence-labeled diblock copolymer,polystyrene-b-polyisoprene, at the interface formed between two immiscible liquids. The interfaces are formed between N,N-dimethylformamide(DMF) and a few immiscible liquids, n-alkane and polyisoprene. Interfacial diffusion coefficient of the diblock copolymer probe is found to decrease monotonously with the increase of the molecular length of the interface constituting liquids. The decrease of diffusion coefficient follows the prediction by Einstein relation using the viscosity of the constituting liquids as the variables only for interfaces between DMF and very small n-alkanes. For interfaces formed between DMF and bigger alkanes and especially between DMF and polyisoprene, the diffusion coefficient is much higher than the calculated value,indicating that the probe molecule starts to probe the much less viscous interfacial region because the interfacial width gets larger,whose thickness is comparable to the molecule size of the liquids.
