为拓宽吸波频段,获得高效吸波材料,以纤维素纳米纤维(CNF)为骨架、二维过渡金属碳化物(Ti_(3)C_(2)T_(x))为导电填料,制备了三维多孔气凝胶吸波材料。通过扫描电镜及透射电镜、红外光谱仪、X射线光电子能谱及衍射仪、矢量网络分析仪表...为拓宽吸波频段,获得高效吸波材料,以纤维素纳米纤维(CNF)为骨架、二维过渡金属碳化物(Ti_(3)C_(2)T_(x))为导电填料,制备了三维多孔气凝胶吸波材料。通过扫描电镜及透射电镜、红外光谱仪、X射线光电子能谱及衍射仪、矢量网络分析仪表征了其结构与各项性能。结果表明:基于气凝胶的多孔结构及Ti_(3)C_(2)T_(x)的导电损耗,使得CNF/Ti_(3)C_(2)T_(x)复合气凝胶具有吸波效能,改变Ti_(3)C_(2)T_(x)含量及气凝胶厚度可调节吸波带宽和峰值。根据三维电磁仿真软件CST STUDIO SUITE仿真模拟结果,制备Ti_(3)C_(2)T_(x)质量分数依次为1%、25%、50%的CNF/Ti_(3)C_(2)T_(x)复合气凝胶,在电磁波入射方向按照特征阻抗从大到小叠层构建阻抗阶跃渐变的多层复合结构吸波材料,该材料具有更好的阻抗匹配和衰减损耗性能,反射损耗最小可达-15.9 dB,有效吸收带宽覆盖整个X波段。展开更多
A two-dimensional transition metal carbide/nitride/carbonitride(MXene)and waterborne polyurethane(WPU)were uniformly mixed to form an MXene/WPU coating,which was loaded on polyethylene terephthalate(PET)fabric through...A two-dimensional transition metal carbide/nitride/carbonitride(MXene)and waterborne polyurethane(WPU)were uniformly mixed to form an MXene/WPU coating,which was loaded on polyethylene terephthalate(PET)fabric through blade coating to prepare an MXene/WPU@PET composite fabric with electromagnetic shielding properties.The micro-morphology and composition,surface wettability,tensile properties,electrical conductivity,and electromagnetic shielding properties of the composite fabric were studied.The results showed that the MXene/WPU@PET composite fabric exhibited the cha-racteristics of flexibility and firmness,and a unit area load capacity of MXene/WPU was 1.9 mg/cm^(2),the conductivity 760 S/m,and the electromagnetic shielding effectiveness up to 42 dB(8.2-12.4 GHz);and this convenient and effective method can be used to prepare lightweight and flexible electromagnetic shielding materials,promising broad application prospects in the field of wearable products.展开更多
文摘为拓宽吸波频段,获得高效吸波材料,以纤维素纳米纤维(CNF)为骨架、二维过渡金属碳化物(Ti_(3)C_(2)T_(x))为导电填料,制备了三维多孔气凝胶吸波材料。通过扫描电镜及透射电镜、红外光谱仪、X射线光电子能谱及衍射仪、矢量网络分析仪表征了其结构与各项性能。结果表明:基于气凝胶的多孔结构及Ti_(3)C_(2)T_(x)的导电损耗,使得CNF/Ti_(3)C_(2)T_(x)复合气凝胶具有吸波效能,改变Ti_(3)C_(2)T_(x)含量及气凝胶厚度可调节吸波带宽和峰值。根据三维电磁仿真软件CST STUDIO SUITE仿真模拟结果,制备Ti_(3)C_(2)T_(x)质量分数依次为1%、25%、50%的CNF/Ti_(3)C_(2)T_(x)复合气凝胶,在电磁波入射方向按照特征阻抗从大到小叠层构建阻抗阶跃渐变的多层复合结构吸波材料,该材料具有更好的阻抗匹配和衰减损耗性能,反射损耗最小可达-15.9 dB,有效吸收带宽覆盖整个X波段。
文摘A two-dimensional transition metal carbide/nitride/carbonitride(MXene)and waterborne polyurethane(WPU)were uniformly mixed to form an MXene/WPU coating,which was loaded on polyethylene terephthalate(PET)fabric through blade coating to prepare an MXene/WPU@PET composite fabric with electromagnetic shielding properties.The micro-morphology and composition,surface wettability,tensile properties,electrical conductivity,and electromagnetic shielding properties of the composite fabric were studied.The results showed that the MXene/WPU@PET composite fabric exhibited the cha-racteristics of flexibility and firmness,and a unit area load capacity of MXene/WPU was 1.9 mg/cm^(2),the conductivity 760 S/m,and the electromagnetic shielding effectiveness up to 42 dB(8.2-12.4 GHz);and this convenient and effective method can be used to prepare lightweight and flexible electromagnetic shielding materials,promising broad application prospects in the field of wearable products.
