A crossed molecular beams, state-to-state scattering study was carried out on the F＋H2→HF＋H reaction at the collision energy of 5.02 kJ/mol, using the highly sensitive H atom Rydberg tagging time-of-flight method. ...A crossed molecular beams, state-to-state scattering study was carried out on the F＋H2→HF＋H reaction at the collision energy of 5.02 kJ/mol, using the highly sensitive H atom Rydberg tagging time-of-flight method. All the peaks in the TOF spectra can be clearly assigned to the ro-vibrational structures of the HF product. The forward scattering of the HF product at v′=3 has been observed. The small forward scattering of the HF product at v′=2 has also been detected. Detailed theoretical analysis is required in order to fully understand the dynamical origin of these forward scattering products at this high collision energy.展开更多
Cellular automata modeling techniques and the characteristics of mixed traffic flow were used to derive the 2-dimensional model presented here for simulation of pedestrian’s crossing dynamics. A conception of “stop...Cellular automata modeling techniques and the characteristics of mixed traffic flow were used to derive the 2-dimensional model presented here for simulation of pedestrian’s crossing dynamics. A conception of “stop point” is introduced to deal with traffic obstacles and resolve conflicts among pedestrians or between pedestrians and the other vehicles on the crosswalk. The model can be easily extended, is very efficient for simulation of pedestrian’s crossing dy- namics, can be integrated into traffic simulation software, and has been proved feasible by simulation experiments.展开更多
The prototypical reaction of F+HD→DF+H was investigated at collision energies from 3.03 meV to 17.97 meV using a crossed molecular beam apparatus with multichannel Rydberg tagging time-of-flight detection.Significant...The prototypical reaction of F+HD→DF+H was investigated at collision energies from 3.03 meV to 17.97 meV using a crossed molecular beam apparatus with multichannel Rydberg tagging time-of-flight detection.Significant contributions from both the BornOppenheimer(BO)forbidden reaction F^(*)(^(2)P_(1/2))+HD→DF+H and the BO-allowed reaction F(^(2)P_(3/2))+HD→DF+H were observed.In the backward scattering direction,the contribution from the BO-forbidden reaction F^(*)(^(2)P_(1/2))+HD was found to be considerably greater than the BO-allowed reaction F(^(2)P_(3/2))+HD,indicating the non-adiabatic effects play an important role in the dynamics of the title reaction at low collision energies.Collision-energy dependence of differential cross sections(DCSs)in the backward scattering direction was found to be monotonously decreased as the collision energy decreases,which does not support the existence of resonance states in this energy range.DCSs of both BO-allowed and BO-forbidden reactions were measured at seven collision energies from 3.03 meV to 17.97 meV.It is quite unexpected that the angular distribution gradually shifts from backward to sideway as the collision energy decreases from 17.97 meV to 3.03 meV,suggesting some unknown mechanisms may exist at low collision energies.展开更多
The nonadiabatic dynamics of methyl nitrate(CH_(3)ONO_(2))is studied with the on-the-fy trajectory surface hopping dynamics at the ADC(2)level.The results confirmed the existence of the ultrafast nonadiabatic decay to...The nonadiabatic dynamics of methyl nitrate(CH_(3)ONO_(2))is studied with the on-the-fy trajectory surface hopping dynamics at the ADC(2)level.The results confirmed the existence of the ultrafast nonadiabatic decay to the electronic ground state.When the dynamics starts from S_(1) and S_(2),the photoproducts are CH_(3)O+NO_(2),consistent with previous results obtained from the experimental studies and theoretical dynamics simulations at more accurate XMS-CASPT2 level.The photolysis products are CH_(3)O+NO_(2) at the ADC(2)level when the dynamics starts from S3,while different photolysis products were obtained in previous experimental and theoretical works.These results demonstrate that the ADC(2)method may still be useful for treating the photolysis mechanism of CH_(3)ONO_(2) at the long-wavelength UV excitation,while great caution should be paid due to its inaccurate performance in the description of the photolysis dynamics at the short-wavelength UV excitation.This gives valuable information to access the accuracy when other alkyl nitrates are treated at the ADC(2)level.展开更多
Landslide surge is a fluid-solid coupling problem involving multidisciplinary intersections such as landslide dynamics, fluid mechanics and mechanics along the way, which has important research value. The construction...Landslide surge is a fluid-solid coupling problem involving multidisciplinary intersections such as landslide dynamics, fluid mechanics and mechanics along the way, which has important research value. The construction of the reservoir will affect the natural geological conditions of the slope of the reservoir area, slope rock under the joint effect of the waves and the reservoir water level changes, which will cause the reservoir bank collapse and even landslides. The occurrence of landslide will cause some loss. In this paper, the types of landslide generation, disaster classification, research methods and existing problems are reviewed. It makes people understand the basic research ideas of landslide surge. Through the analysis and discussion of the different research methods of landslide surges, the shortcomings of these analytical methods are analyzed, which provide important basis for future research and indicate the future research methods and direction.展开更多
Detailed understanding of the mechanism of the combustion relevant multichannel reactions of O(3P) with unsaturated hydrocarbons (UHs) requires the identification of all primary reaction products, the determination of...Detailed understanding of the mechanism of the combustion relevant multichannel reactions of O(3P) with unsaturated hydrocarbons (UHs) requires the identification of all primary reaction products, the determination of their branching ratios and assessment of intersystem crossing (ISC) between triplet and singlet potential energy surfaces (PESs). This can be best achieved combining crossed-molecular-beam (CMB) experiments with universal, soft ionization, mass-spectrometric detection and time-of-flight analysis to high-level ab initio electronic structure calculations of triplet/singlet PESs and RRKM/Master Equation computations of branching ratios (BRs) including ISC. This approach has been recently demonstrated to be successful for O(3P) reactions with the simplest UHs (alkynes, alkenes, dienes) containing two or three carbon atoms. Here, we extend the combined CMB/theoretical approach to the next member in the diene series containing four C atoms, namely 1,2-butadiene (methylallene) to explore how product distributions, branching ratios and ISC vary with increasing molecular complexity going from O(3P))+propadiene to O(3P)+1,2-butadiene. In particular, we focus on the most important, dominant molecular channels, those forming propene+CO (with branching ratio ∽0.5) and ethylidene+ketene (with branching ratio ∽0.15), that lead to chain termination, to be contrasted to radical forming channels (branching ratio ∽0.35) which lead to chain propagation in combustion systems.展开更多
Cross-protection in plants has been widely used to control losses caused by virus diseases in the world. Here, a non-autonomous plant-virus disease model was developed includ- ing cross-protection. Global dynamics of ...Cross-protection in plants has been widely used to control losses caused by virus diseases in the world. Here, a non-autonomous plant-virus disease model was developed includ- ing cross-protection. Global dynamics of the model was discussed. Under the quite weak assumptions, integral form conditions were resolved for permanence of the system and extinction of diseases. Furthermore, we looked into the sufficient conditions that plants could be protected against the detrimental effects of infection by an infection with the mild virus isolates. Last, we performed numerical simulations. Our investigations sug- gested that cross-protection played an important role in controlling the spread of the challenging virus in plants.展开更多
The single cylinder and multi-cylinder pumping dynamics model of a swash plate piston pump were improved.Particular attention has been paid to the design influences of key parts of the valve plate such as relief groov...The single cylinder and multi-cylinder pumping dynamics model of a swash plate piston pump were improved.Particular attention has been paid to the design influences of key parts of the valve plate such as relief groove,pre-compression/ expansion and fluid inertia effect of the unsteady flow.Some important parameters,such as the discharge area,discharge coefficient,fluid bulk modulus,were especially analyzed using numerical methods or by experiment-based estimation.Consequently,the mathematical results of pressure pulsation and flow ripple agree well with experimental results from the test-rig of the flow ripple.Therefore,the cross angle and the pre-compression angle of the valve plate was optimized,based on the pumping dynamics model.Considering both the flow ripple and the cylinder pressure of the pump,the cross angle is set to be 2.2° to 2.7° with a pre-compression angle of 1.7° to 2.2°,so the pumping dynamics character can obtain the best result.展开更多
This paper presents two aggregation strategies in convex intersection region for the distributed mobile sensor network(MSN) with heterogeneous dynamics. First, the authors analyze individual local perception model and...This paper presents two aggregation strategies in convex intersection region for the distributed mobile sensor network(MSN) with heterogeneous dynamics. First, the authors analyze individual local perception model and dynamics model, set the intersection of all the local perceptions as the region of interest(ROI). The MSN consists of sensors with first-order dynamics and second-order dynamics. Then, the authors design a control strategy to ensure that individuals aggregate at a point in the ROI relying on their local perceptions and the locations of neighbors within their communication scope. The authors describe this situation of aggregation as rendezvous. In addition, the authors introduce artificial potential field to make sensors deploy dispersedly in a bounded range near the ROI,which the authors call dispersed deployment. Finally, the authors prove the stability of the proposed strategies and validate the theoretical results by simulations. This research is applied for the cooperative deployment and data collection of mobile platforms with different dynamics under the condition of inaccurate perception.展开更多
基金This work was supported by the Chinese Academy of Sciences, the Ministry of Science and Technology and the National Natural Science Foundation of China.ACKN0WLEDGMENT This work was supported by the Chinese Academy of Sciences, the Ministry of Science and Technology and the National Natural Science Foundation of China.
文摘A crossed molecular beams, state-to-state scattering study was carried out on the F＋H2→HF＋H reaction at the collision energy of 5.02 kJ/mol, using the highly sensitive H atom Rydberg tagging time-of-flight method. All the peaks in the TOF spectra can be clearly assigned to the ro-vibrational structures of the HF product. The forward scattering of the HF product at v′=3 has been observed. The small forward scattering of the HF product at v′=2 has also been detected. Detailed theoretical analysis is required in order to fully understand the dynamical origin of these forward scattering products at this high collision energy.
文摘Cellular automata modeling techniques and the characteristics of mixed traffic flow were used to derive the 2-dimensional model presented here for simulation of pedestrian’s crossing dynamics. A conception of “stop point” is introduced to deal with traffic obstacles and resolve conflicts among pedestrians or between pedestrians and the other vehicles on the crosswalk. The model can be easily extended, is very efficient for simulation of pedestrian’s crossing dy- namics, can be integrated into traffic simulation software, and has been proved feasible by simulation experiments.
基金supported by the National Natural Science Foundation of China(No.21822305,No.21688102,No.22003067)the Chinese Academy of Sciences(No.XDB17000000)。
文摘The prototypical reaction of F+HD→DF+H was investigated at collision energies from 3.03 meV to 17.97 meV using a crossed molecular beam apparatus with multichannel Rydberg tagging time-of-flight detection.Significant contributions from both the BornOppenheimer(BO)forbidden reaction F^(*)(^(2)P_(1/2))+HD→DF+H and the BO-allowed reaction F(^(2)P_(3/2))+HD→DF+H were observed.In the backward scattering direction,the contribution from the BO-forbidden reaction F^(*)(^(2)P_(1/2))+HD was found to be considerably greater than the BO-allowed reaction F(^(2)P_(3/2))+HD,indicating the non-adiabatic effects play an important role in the dynamics of the title reaction at low collision energies.Collision-energy dependence of differential cross sections(DCSs)in the backward scattering direction was found to be monotonously decreased as the collision energy decreases,which does not support the existence of resonance states in this energy range.DCSs of both BO-allowed and BO-forbidden reactions were measured at seven collision energies from 3.03 meV to 17.97 meV.It is quite unexpected that the angular distribution gradually shifts from backward to sideway as the collision energy decreases from 17.97 meV to 3.03 meV,suggesting some unknown mechanisms may exist at low collision energies.
基金supported by the National Natural Science Foundation of China(No.21933011,No.21873112)。
文摘The nonadiabatic dynamics of methyl nitrate(CH_(3)ONO_(2))is studied with the on-the-fy trajectory surface hopping dynamics at the ADC(2)level.The results confirmed the existence of the ultrafast nonadiabatic decay to the electronic ground state.When the dynamics starts from S_(1) and S_(2),the photoproducts are CH_(3)O+NO_(2),consistent with previous results obtained from the experimental studies and theoretical dynamics simulations at more accurate XMS-CASPT2 level.The photolysis products are CH_(3)O+NO_(2) at the ADC(2)level when the dynamics starts from S3,while different photolysis products were obtained in previous experimental and theoretical works.These results demonstrate that the ADC(2)method may still be useful for treating the photolysis mechanism of CH_(3)ONO_(2) at the long-wavelength UV excitation,while great caution should be paid due to its inaccurate performance in the description of the photolysis dynamics at the short-wavelength UV excitation.This gives valuable information to access the accuracy when other alkyl nitrates are treated at the ADC(2)level.
文摘Landslide surge is a fluid-solid coupling problem involving multidisciplinary intersections such as landslide dynamics, fluid mechanics and mechanics along the way, which has important research value. The construction of the reservoir will affect the natural geological conditions of the slope of the reservoir area, slope rock under the joint effect of the waves and the reservoir water level changes, which will cause the reservoir bank collapse and even landslides. The occurrence of landslide will cause some loss. In this paper, the types of landslide generation, disaster classification, research methods and existing problems are reviewed. It makes people understand the basic research ideas of landslide surge. Through the analysis and discussion of the different research methods of landslide surges, the shortcomings of these analytical methods are analyzed, which provide important basis for future research and indicate the future research methods and direction.
基金supported by “Fondazione Cassa Risparmio Perugia” (Project 2015.0331.021 Scientific & Technological Research)EC COST Action CM1404 (Chemistry of Smart Energy Carriers and Technologies– SMARTCATS)+1 种基金the Università degli Studi di Perugia (“Fondo Ricerca di Base 2017”)Italian MIUR and Università degli Studi di Perugia within the program“Department of Excellence-2018-2022-project AMIS”
文摘Detailed understanding of the mechanism of the combustion relevant multichannel reactions of O(3P) with unsaturated hydrocarbons (UHs) requires the identification of all primary reaction products, the determination of their branching ratios and assessment of intersystem crossing (ISC) between triplet and singlet potential energy surfaces (PESs). This can be best achieved combining crossed-molecular-beam (CMB) experiments with universal, soft ionization, mass-spectrometric detection and time-of-flight analysis to high-level ab initio electronic structure calculations of triplet/singlet PESs and RRKM/Master Equation computations of branching ratios (BRs) including ISC. This approach has been recently demonstrated to be successful for O(3P) reactions with the simplest UHs (alkynes, alkenes, dienes) containing two or three carbon atoms. Here, we extend the combined CMB/theoretical approach to the next member in the diene series containing four C atoms, namely 1,2-butadiene (methylallene) to explore how product distributions, branching ratios and ISC vary with increasing molecular complexity going from O(3P))+propadiene to O(3P)+1,2-butadiene. In particular, we focus on the most important, dominant molecular channels, those forming propene+CO (with branching ratio ∽0.5) and ethylidene+ketene (with branching ratio ∽0.15), that lead to chain termination, to be contrasted to radical forming channels (branching ratio ∽0.35) which lead to chain propagation in combustion systems.
基金The research has been supported by the National Natural Science Foundation of China （11561004）, the Development for Local Colleges and Universities Foundation of China - the Applied Mathematics Innovative Team Building, and the Bidding Project of Gannan Normal University （16zb02）.
文摘Cross-protection in plants has been widely used to control losses caused by virus diseases in the world. Here, a non-autonomous plant-virus disease model was developed includ- ing cross-protection. Global dynamics of the model was discussed. Under the quite weak assumptions, integral form conditions were resolved for permanence of the system and extinction of diseases. Furthermore, we looked into the sufficient conditions that plants could be protected against the detrimental effects of infection by an infection with the mild virus isolates. Last, we performed numerical simulations. Our investigations sug- gested that cross-protection played an important role in controlling the spread of the challenging virus in plants.
基金Project supported by the National Key Technologies Supporting Program of China during the 11th Five-Year Plan Period (Nos. 2006BAF01B01, 2006BAF01B04, and 2007AA03Z211)the National Natural Science Foundation of China (No. 50877070)the Technological Research and Development Programs of the Min-istry of Chinese Railways (No. 2009J006-L)
文摘The single cylinder and multi-cylinder pumping dynamics model of a swash plate piston pump were improved.Particular attention has been paid to the design influences of key parts of the valve plate such as relief groove,pre-compression/ expansion and fluid inertia effect of the unsteady flow.Some important parameters,such as the discharge area,discharge coefficient,fluid bulk modulus,were especially analyzed using numerical methods or by experiment-based estimation.Consequently,the mathematical results of pressure pulsation and flow ripple agree well with experimental results from the test-rig of the flow ripple.Therefore,the cross angle and the pre-compression angle of the valve plate was optimized,based on the pumping dynamics model.Considering both the flow ripple and the cylinder pressure of the pump,the cross angle is set to be 2.2° to 2.7° with a pre-compression angle of 1.7° to 2.2°,so the pumping dynamics character can obtain the best result.
基金supported by the National Natural Science Foundation of China under Grant No.61203078the Foundation for Innovative Research Groups of the National Natural Science Foundation of China under Grant No.61321002+3 种基金the Projects of Major International(Regional)Joint Research Program NSFC under Grant No.61120106010the Beijing Education Committee Cooperation Building Foundation Projectthe Program for Changjiang Scholars and Innovative Research Team in University under Grant No.IRT1208the Chang Jiang Scholars Program,and the Beijing Outstanding Ph.D.Program Mentor under Grant No.20131000704
文摘This paper presents two aggregation strategies in convex intersection region for the distributed mobile sensor network(MSN) with heterogeneous dynamics. First, the authors analyze individual local perception model and dynamics model, set the intersection of all the local perceptions as the region of interest(ROI). The MSN consists of sensors with first-order dynamics and second-order dynamics. Then, the authors design a control strategy to ensure that individuals aggregate at a point in the ROI relying on their local perceptions and the locations of neighbors within their communication scope. The authors describe this situation of aggregation as rendezvous. In addition, the authors introduce artificial potential field to make sensors deploy dispersedly in a bounded range near the ROI,which the authors call dispersed deployment. Finally, the authors prove the stability of the proposed strategies and validate the theoretical results by simulations. This research is applied for the cooperative deployment and data collection of mobile platforms with different dynamics under the condition of inaccurate perception.
