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树核星形聚丙烯酰胺的制备及其稀溶液性质 被引量:11
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作者 方申文 段明 +1 位作者 蒋春勇 张健 《石油化工》 CAS CSCD 北大核心 2009年第3期278-283,共6页
以叔胺化树枝状聚酰胺基胺为核,通过光引发自由基聚合制备了具有不同支臂数(4,8,16)的树核星形聚丙烯酰胺(DSPAM)。研究DSPAM在NaCl水溶液中的稀溶液性质时发现,特性黏数([η])相同时,DSPAM的Huggins系数(KH)比线型聚丙烯酰胺大,溶剂化D... 以叔胺化树枝状聚酰胺基胺为核,通过光引发自由基聚合制备了具有不同支臂数(4,8,16)的树核星形聚丙烯酰胺(DSPAM)。研究DSPAM在NaCl水溶液中的稀溶液性质时发现,特性黏数([η])相同时,DSPAM的Huggins系数(KH)比线型聚丙烯酰胺大,溶剂化DSPAM的分子体积也较大;随溶液中NaCl浓度的增加,不同支臂数DSPAM的[η]、扩张因子(α)和体积相关参数(VE)增大,KH呈无规律性波动,形状因子(υ)变化较小;α和VE在不同的NaCl浓度下均随DSPAM支臂数的增多而减小,支臂数为16时DSPAM的υ最接近2.5,此时DSPAM分子的在溶液中的构象也最接近球状。用原子力显微镜观察支臂数为16的DSPAM在水中的微观结构基本呈现球状。 展开更多
关键词 树核星形聚丙烯酰胺 特性黏数 扩张因子 体积相关系数 形状因子
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Seasonal and inter-annual variation of surface roughness length and bulk transfer coefficients in a semiarid area 被引量:12
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作者 FENG JianWu LIU HuiZhi +2 位作者 WANG Lei DU Qun SHI LiQing 《Science China Earth Sciences》 SCIE EI CAS 2012年第2期254-261,共8页
Here we report a multiyear study on the surface roughness length and bulk transfer coefficients over the degraded grassland and cropland surfaces in a semiarid area of China. Eddy covariance measurement and the meteor... Here we report a multiyear study on the surface roughness length and bulk transfer coefficients over the degraded grassland and cropland surfaces in a semiarid area of China. Eddy covariance measurement and the meteorological profile observation data were used to analyze characteristics of these parameters on the diurnal, seasonal, and annual scales. Significant seasonal and annual variations of the aerodynamic roughness length are observed over the two surfaces. A large variation of kB-1 is measured during the day. Both kB-1 and the bulk transfer coefficients exhibit significant seasonal and annual variations. During the growing season (May to October), average Cd and Ch are 3.1×10-3 and 2.5×10-3 over the degrade grassland surface, and 4.7×10-3 and 3.1×10-3 over the cropland surface respectively. During the non-growing season, average Cd and Ch are 2.3×10-3 and 2.0×10-3 over the degrade grassland surface, and 2.9×10-3 and 2.2×10-3 over the cropland surface respectively. 展开更多
关键词 semiarid area surface roughness length bulk transfer coefficients eddy covariance method
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