An investigation was carried out concerning the effect of preferential dissolution on the erosion-corrosion for a chromium steel in 1 mol/L NaOH. Preliminary tests using a potentiodynamic technique were performed in o...An investigation was carried out concerning the effect of preferential dissolution on the erosion-corrosion for a chromium steel in 1 mol/L NaOH. Preliminary tests using a potentiodynamic technique were performed in order to establish the presence of preferential dissolution in the alkali solution with and without the alumina particles at different rotation speeds. For purposes of quantifying the observed phenomena a potentiostatic mass loss method was also used. The results show that the active peaks occur at potential between +0.4 and +0.5 V on the polarization curves, which indicates that there is a preferential dissolution for chromium steel under erosion-corrosion conditions and the ferrite phase acts as a sacrificial anode in favor of (Fe,Cr) 7C 3 phase. Addition of particles can promote the preferential dissolution at different rotation speeds. The combined effects of erosion-corrosion results in total mass loss rates to be greater than the sum effects of each process taken alone, thus showing a strong synergism between erosion and corrosion due to preferential dissolution.展开更多
The Tibet Plateau, occupying the main part of Qinghai-Tibet Plateau and having an average altitude of 4 500 m, has geomorphological features that are unique in the world, with soil erosion being one of the main ecolog...The Tibet Plateau, occupying the main part of Qinghai-Tibet Plateau and having an average altitude of 4 500 m, has geomorphological features that are unique in the world, with soil erosion being one of the main ecological problems. Thus the main objectives of the present research were to set up an efficient and simple way of evaluating spatial distribution of soil erosion sensitivity in the Tibet Plateau as well as the responses of soil erosion to changes of natural environmental conditions, and to indicate key regions where soil erosion should be preferentially controlled. Based on the Universal Soil Loss Equation (USLE), the study applied geographic information system (GIS) technology to develop a methodological reference framework, from which soil erosion sensitivity could be evaluated. The impact of precipitation, soil, topography and vegetation on soil erosion was divided into classes of extreme sensitivity, high sensitivity, medium sensitivity, low sensitivity and no sensitivity. With the aid of GIS, the resultant map from overlaying various factors showed that soil erosion sensitivity had great discrepancy in different parts of the region. In the southeastern part of the Tibet Plateau there were mainly three classes of sensitivity, namely, extreme, high and medium sensitivity. However, the other two classes, low and no sensitivity, were dominant in the northwestern part.展开更多
Effects of jet velocity,sand concentration and impingement angle on the surface roughness of Al-brass alloy were investigated after erosion and erosion?corrosion tests.The tests were performed using a jet impingement ...Effects of jet velocity,sand concentration and impingement angle on the surface roughness of Al-brass alloy were investigated after erosion and erosion?corrosion tests.The tests were performed using a jet impingement rig.The eroded surfaces were characterized using2-D and3-D surface profilometery and scanning electron microscopy(SEM).The results showed that there was an increase in the surface roughness of the erosion?corrosion samples as sand concentration was increased to1,5and10g/L at jet velocities of9,6and3m/s,respectively.However,the surface roughness decreased with a further increase in sand concentration.This decrease in the surface roughness was attributed to the higher work hardening of the surface,rebounding or blanketing effect and very high frequency of the impacts at the higher sand concentrations.The surface roughness increased as the jet velocity increased.The results also showed that the change in the surface roughness with impingement angle was not significant at two jet velocities of3and6m/s.However,at a higher jet velocity of9m/s,formation of ripples on the erosion surfaces at oblique angles resulted in a higher surface roughness as compared with the normal impingement angle.展开更多
The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-...The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-) binding properties of Mg-Al LDH-NO_(2) in simulated concrete pore solutions,Cl−and SO_(4)^(2-) diffusion properties of mortars with Mg-Al LDHNO 2 were examined.The steel corrosion and resistance of mortar against SO_(4)^(2-) attack were also evaluated.The results indicate that Mg-Al LDH-NO_(2) can effectively adsorb the Cl−and SO_(4)^(2-) in simulated concrete pore solution,and inhibit the diffusion of Cl−and SO_(4)^(2-) into cement mortars.The presence of SO_(4)^(2-) can greatly affect the uptake amount of Cl−,and there is a coupled effect of Cl−and SO_(4)^(2-) on their penetration into mortar specimens.In addition,Mg-Al LDH-NO_(2) can greatly upgrade the resistance of mortars against SO_(4)^(2-) attack and well prevent the steel from corrosion.However,Cl−will aggravate the SO_(4)^(2-) attack and SO_(4)^(2-) can initially decrease and then increase the steel corrosion.展开更多
The polarization curves of mild steel in de-aerated 0.5 mol NaHCO 3+0.5 mol Na 2CO 3 solution with and without erodent particles of 300 g/L of 100 μm alumina have been measured using a rotating cylinder electrode (RC...The polarization curves of mild steel in de-aerated 0.5 mol NaHCO 3+0.5 mol Na 2CO 3 solution with and without erodent particles of 300 g/L of 100 μm alumina have been measured using a rotating cylinder electrode (RCE) apparatus over the range of rotation speeds from 0 to 4 000 r/min. The results show that the mild steel in the de-aerated slurry exhibits classical active/passive polarization behavior. The speed of cylinder rotation has a great effect in the presence of particles on the active dissolution current density. The erosion-corrosion process is severely erosion-dominated for the mild steel. However, the poor corrosion resistance of the mild steel in such turbulent slurries is also significant, especially at lower than 4 m/s.展开更多
The damage process of concrete exposed to sodium sulfate attack and drying-wetting cycles was investigated. The water to binder(W/B) ratio and the concentration of sulfate solution were taken as variable parameters. T...The damage process of concrete exposed to sodium sulfate attack and drying-wetting cycles was investigated. The water to binder(W/B) ratio and the concentration of sulfate solution were taken as variable parameters. Through the experiment, visual change, relative dynamic modulus of elasticity(RDME) and the surface damage layer thickness of concrete were measured.Furthermore, SEM and thermal analysis were used to investigate the changing of microstructure and corrosion products of concrete.The test results show that the ultrasonic velocity is related to the damage layer of concrete. It approves that an increase in damage layer thickness reduces the compactness and the ultrasonic velocity. The deterioration degree of concrete could be estimated effectively by measuring the surface damage layer and the RDME of concrete. It is also found that the content of gypsum in concrete is less than that of ettringite in test, and some gypsum is checked only after a certain corrosion extent. When the concrete is with high W/B ratio or exposed to high concentration of sulfate solution, the content of ettringite first increases and then decreases with corrosion time. However, the content of gypsum increases at a steady rate. The content of corrosion products does not correspond well with the observations of RDME change, and extensive amount of corrosion products can be formed before obvious damage occurs.展开更多
16Mn steel, 1Cr18Ni9 stainless steel, thermal sprayed Al2O3-TiO2 ceramic coating and nylon1010-5 %Al2O3 coating were tested with an erosion -corrosion tester.The effects of pH values and slurry velocities on the erosi...16Mn steel, 1Cr18Ni9 stainless steel, thermal sprayed Al2O3-TiO2 ceramic coating and nylon1010-5 %Al2O3 coating were tested with an erosion -corrosion tester.The effects of pH values and slurry velocities on the erosion-corrosion behavior of the materials tested were determined. The erosion-corrosion behavior of the materials tested changes with pH values and presents different change tendencies. The erosion-corrosion rates of the materials are increased with slurry velocities. The erosion-corrosion mechanisms for the steels and the coatings are considerably different.展开更多
文摘An investigation was carried out concerning the effect of preferential dissolution on the erosion-corrosion for a chromium steel in 1 mol/L NaOH. Preliminary tests using a potentiodynamic technique were performed in order to establish the presence of preferential dissolution in the alkali solution with and without the alumina particles at different rotation speeds. For purposes of quantifying the observed phenomena a potentiostatic mass loss method was also used. The results show that the active peaks occur at potential between +0.4 and +0.5 V on the polarization curves, which indicates that there is a preferential dissolution for chromium steel under erosion-corrosion conditions and the ferrite phase acts as a sacrificial anode in favor of (Fe,Cr) 7C 3 phase. Addition of particles can promote the preferential dissolution at different rotation speeds. The combined effects of erosion-corrosion results in total mass loss rates to be greater than the sum effects of each process taken alone, thus showing a strong synergism between erosion and corrosion due to preferential dissolution.
基金Project supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (No. KZCX3-SW-339-04).
文摘The Tibet Plateau, occupying the main part of Qinghai-Tibet Plateau and having an average altitude of 4 500 m, has geomorphological features that are unique in the world, with soil erosion being one of the main ecological problems. Thus the main objectives of the present research were to set up an efficient and simple way of evaluating spatial distribution of soil erosion sensitivity in the Tibet Plateau as well as the responses of soil erosion to changes of natural environmental conditions, and to indicate key regions where soil erosion should be preferentially controlled. Based on the Universal Soil Loss Equation (USLE), the study applied geographic information system (GIS) technology to develop a methodological reference framework, from which soil erosion sensitivity could be evaluated. The impact of precipitation, soil, topography and vegetation on soil erosion was divided into classes of extreme sensitivity, high sensitivity, medium sensitivity, low sensitivity and no sensitivity. With the aid of GIS, the resultant map from overlaying various factors showed that soil erosion sensitivity had great discrepancy in different parts of the region. In the southeastern part of the Tibet Plateau there were mainly three classes of sensitivity, namely, extreme, high and medium sensitivity. However, the other two classes, low and no sensitivity, were dominant in the northwestern part.
文摘Effects of jet velocity,sand concentration and impingement angle on the surface roughness of Al-brass alloy were investigated after erosion and erosion?corrosion tests.The tests were performed using a jet impingement rig.The eroded surfaces were characterized using2-D and3-D surface profilometery and scanning electron microscopy(SEM).The results showed that there was an increase in the surface roughness of the erosion?corrosion samples as sand concentration was increased to1,5and10g/L at jet velocities of9,6and3m/s,respectively.However,the surface roughness decreased with a further increase in sand concentration.This decrease in the surface roughness was attributed to the higher work hardening of the surface,rebounding or blanketing effect and very high frequency of the impacts at the higher sand concentrations.The surface roughness increased as the jet velocity increased.The results also showed that the change in the surface roughness with impingement angle was not significant at two jet velocities of3and6m/s.However,at a higher jet velocity of9m/s,formation of ripples on the erosion surfaces at oblique angles resulted in a higher surface roughness as compared with the normal impingement angle.
基金Project(51478164)supported by the National Natural Science Foundation of ChinaProject(BK20181306)supported by Natural Science Foundation of Jiangsu Province,China。
文摘The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-) binding properties of Mg-Al LDH-NO_(2) in simulated concrete pore solutions,Cl−and SO_(4)^(2-) diffusion properties of mortars with Mg-Al LDHNO 2 were examined.The steel corrosion and resistance of mortar against SO_(4)^(2-) attack were also evaluated.The results indicate that Mg-Al LDH-NO_(2) can effectively adsorb the Cl−and SO_(4)^(2-) in simulated concrete pore solution,and inhibit the diffusion of Cl−and SO_(4)^(2-) into cement mortars.The presence of SO_(4)^(2-) can greatly affect the uptake amount of Cl−,and there is a coupled effect of Cl−and SO_(4)^(2-) on their penetration into mortar specimens.In addition,Mg-Al LDH-NO_(2) can greatly upgrade the resistance of mortars against SO_(4)^(2-) attack and well prevent the steel from corrosion.However,Cl−will aggravate the SO_(4)^(2-) attack and SO_(4)^(2-) can initially decrease and then increase the steel corrosion.
文摘The polarization curves of mild steel in de-aerated 0.5 mol NaHCO 3+0.5 mol Na 2CO 3 solution with and without erodent particles of 300 g/L of 100 μm alumina have been measured using a rotating cylinder electrode (RCE) apparatus over the range of rotation speeds from 0 to 4 000 r/min. The results show that the mild steel in the de-aerated slurry exhibits classical active/passive polarization behavior. The speed of cylinder rotation has a great effect in the presence of particles on the active dissolution current density. The erosion-corrosion process is severely erosion-dominated for the mild steel. However, the poor corrosion resistance of the mild steel in such turbulent slurries is also significant, especially at lower than 4 m/s.
基金Project(51278403)supported by the National Natural Science Foundation of China
文摘The damage process of concrete exposed to sodium sulfate attack and drying-wetting cycles was investigated. The water to binder(W/B) ratio and the concentration of sulfate solution were taken as variable parameters. Through the experiment, visual change, relative dynamic modulus of elasticity(RDME) and the surface damage layer thickness of concrete were measured.Furthermore, SEM and thermal analysis were used to investigate the changing of microstructure and corrosion products of concrete.The test results show that the ultrasonic velocity is related to the damage layer of concrete. It approves that an increase in damage layer thickness reduces the compactness and the ultrasonic velocity. The deterioration degree of concrete could be estimated effectively by measuring the surface damage layer and the RDME of concrete. It is also found that the content of gypsum in concrete is less than that of ettringite in test, and some gypsum is checked only after a certain corrosion extent. When the concrete is with high W/B ratio or exposed to high concentration of sulfate solution, the content of ettringite first increases and then decreases with corrosion time. However, the content of gypsum increases at a steady rate. The content of corrosion products does not correspond well with the observations of RDME change, and extensive amount of corrosion products can be formed before obvious damage occurs.
文摘16Mn steel, 1Cr18Ni9 stainless steel, thermal sprayed Al2O3-TiO2 ceramic coating and nylon1010-5 %Al2O3 coating were tested with an erosion -corrosion tester.The effects of pH values and slurry velocities on the erosion-corrosion behavior of the materials tested were determined. The erosion-corrosion behavior of the materials tested changes with pH values and presents different change tendencies. The erosion-corrosion rates of the materials are increased with slurry velocities. The erosion-corrosion mechanisms for the steels and the coatings are considerably different.
