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乙烯裂解C9冷聚合成石油树脂实验研究
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作者 杨霞 李崇 +2 位作者 张力擎 王博 赵桂林 《中文科技期刊数据库(引文版)工程技术》 2024年第6期0174-0177,共4页
以C9馏分,苯乙烯类树脂油,茚类树脂油为原料,按一定的比例配成混合液,并以三氟化硼-乙醚络合物为催化剂,进行冷聚实验合成石油树脂。研究发现:当固定反应液中各活性组分含量的配比不变的情况下,增加反应液中活性组分的总含量,产物石油... 以C9馏分,苯乙烯类树脂油,茚类树脂油为原料,按一定的比例配成混合液,并以三氟化硼-乙醚络合物为催化剂,进行冷聚实验合成石油树脂。研究发现:当固定反应液中各活性组分含量的配比不变的情况下,增加反应液中活性组分的总含量,产物石油树脂的收率、色号及软化点随之增加;增加催化剂的量,石油树脂的收率、色号及软化点也随之增加;随着反应温度的增加,石油树脂的色号和收率随着增加,但是软化点随着反应温度的增加而减小。 展开更多
关键词 C9馏分 冷聚 石油树脂
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用GPC图谱和[η]计算冷聚丁腈橡胶分子量
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作者 曾安群 《合成橡胶工业》 CAS CSCD 北大核心 1993年第4期217-219,共3页
从一个宽分子量分布的冷聚丁腈橡胶(简称丁腈软胶)试样的GPC图谱和[η]获得其M_w和M_n,以这两个分子量为准,将一组窄分子量分布的聚苯乙烯标准试样的分子量和洗出体积建立的校正曲线转换成丁腈软胶的校正曲线,用后一校正曲线即可计算出... 从一个宽分子量分布的冷聚丁腈橡胶(简称丁腈软胶)试样的GPC图谱和[η]获得其M_w和M_n,以这两个分子量为准,将一组窄分子量分布的聚苯乙烯标准试样的分子量和洗出体积建立的校正曲线转换成丁腈软胶的校正曲线,用后一校正曲线即可计算出待测丁腈软胶试样的分子量及其分布。所选条件与文献吻合,平行结果的相对误差小于5%。 展开更多
关键词 冷聚 丁腈橡胶 凝胶渗透色谱
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除环碳九合成冷聚树脂生产工艺研究 被引量:3
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作者 李桂明 葛昌平 +1 位作者 张力擎 邵继洲 《石化技术》 CAS 2018年第9期335-335,338,共2页
对除环碳九生产冷聚树脂的工艺条件进行了实验研究,考察了原料组成对树脂质量的影响,提出了树脂软化点、色号等指标的聚合工艺调控方案供参考。
关键词 碳九 冷聚树脂 软化点
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通用型冷聚丁腈橡胶胶管的配方工艺设计 被引量:1
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作者 赵德平 朱晓峰 《纺织器材》 2006年第B06期15-18,共4页
从通用型冷聚丁腈橡胶和明胶特性分析入手,研究设计了整个配合体系,指出通过系统优化整合后生产的系列通用型棉纺牵伸用胶管使用性能可靠稳定,不仅能够替代通用型热聚丁腈橡胶制造的胶管,还能提高胶管的综合应用性能,使其更适合现代化... 从通用型冷聚丁腈橡胶和明胶特性分析入手,研究设计了整个配合体系,指出通过系统优化整合后生产的系列通用型棉纺牵伸用胶管使用性能可靠稳定,不仅能够替代通用型热聚丁腈橡胶制造的胶管,还能提高胶管的综合应用性能,使其更适合现代化生产要求。 展开更多
关键词 通用型冷聚丁腈橡胶 明胶补强体系 牵伸用胶管 配方工艺设计
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影响C9冷聚树脂聚合反应的工艺研究
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作者 王先武 《化工管理》 2022年第12期144-147,共4页
C9冷聚树脂是经过催化聚合生产所得,因具有良好的热稳定性、相容性、耐水以及耐酸碱性能,因此具有相当广泛的用途。为了获得更加优质的C9冷聚树脂,需要对其工艺进行深入的研究。文章对除环C9组分的来源以及对冷聚反应的影响进行研究,探... C9冷聚树脂是经过催化聚合生产所得,因具有良好的热稳定性、相容性、耐水以及耐酸碱性能,因此具有相当广泛的用途。为了获得更加优质的C9冷聚树脂,需要对其工艺进行深入的研究。文章对除环C9组分的来源以及对冷聚反应的影响进行研究,探讨原料组成的变化对冷聚树脂反应的影响,提出对冷聚树脂产品的软化点及色度的工艺操作管控措施。 展开更多
关键词 除环C9组分 冷聚树脂 软化点 色度 收率
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C9冷聚石油树脂性能影响因素研究
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作者 尚盼 《科技创新导报》 2022年第18期9-12,58,共5页
C9石油树脂是一种用途广泛的热塑性聚合物,被广泛应用于涂料、胶粘剂、橡胶和石墨领域。根据反应机理的不同,可以把C9石油树脂分为C9热聚石油树脂和C9冷聚石油树脂,它的主要原料为乙烯装置副产品——C9馏分,因为原料组成比较复杂,所以... C9石油树脂是一种用途广泛的热塑性聚合物,被广泛应用于涂料、胶粘剂、橡胶和石墨领域。根据反应机理的不同,可以把C9石油树脂分为C9热聚石油树脂和C9冷聚石油树脂,它的主要原料为乙烯装置副产品——C9馏分,因为原料组成比较复杂,所以反应条件也不固定。本文采用自制的甲基茚制备了C9冷聚石油树脂,并研究了反应条件对产品性能的影响,对工业化生产给出指导性意见。 展开更多
关键词 甲基茚 乳化层CPD+MCPD二聚体 C9冷聚石油树脂
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碳五碳九石油树脂装置废水控制与处理
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作者 王伟龙 赵建武 刘英明 《石油石化物资采购》 2020年第21期69-69,共1页
乙烯副产品下游的碳五及碳九类烯烃组分,均以路易斯酸进行链引发、链增长进行阳离子聚合反应,最终以碱液进行链终止,经多级水洗后得到含有溶剂的粗树脂油,再经精馏或闪蒸操作得到去除溶剂和低分子聚合物的树脂成品。
关键词 间戊二烯树脂 碳九冷聚树脂 含氟废水 含铝废水
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Segregation of niobium in laser cladding Inconel 718 superalloy 被引量:9
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作者 龙怡彤 聂璞林 +3 位作者 李铸国 黄坚 李想 徐昕媚 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第2期431-436,共6页
Inconel 718 superalloy is widely used in the aerospace and turbine industry. Segregation of niobium appears in the laser cladding Inconel 718 superalloy and consequently influences the phase transformation during the ... Inconel 718 superalloy is widely used in the aerospace and turbine industry. Segregation of niobium appears in the laser cladding Inconel 718 superalloy and consequently influences the phase transformation during the rapid solidification. In order to control the microstructure and improve the mechanical properties of the deposited coating, the the influence of solidification conditions on the segregation of niobium and the resultant formation of Nb-rich Laves phase was studied using the microstructure observation and EDS analysis. The results show that the cooling rate has considerable influence on the microstructure of the deposited coating. High cooling rate is beneficial for suppressing the segregation of Nb and reducing the formation of Laves phase, which is believed to be detrimental to the performance of the Inconel 718 alloy. 展开更多
关键词 Inconel 718 superalloy segregation of niobium laser cladding cooling rate
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ULTRASOUND INDUCED AND LASER ENHANCED COLD FUSION CHEMISTRY
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作者 T. V. Prevenslik (2/E Greenery Court, Discovery Bay, Hong Kong) 《Nuclear Science and Techniques》 SCIE CAS CSCD 1995年第4期198-203,共6页
The standard model of sonoluminescence suggests that the Coulomb barrier to deuterium fusion may be overcome by high bubble gas temperatures caused by compression heating if the bubble diameter remains spherical durin... The standard model of sonoluminescence suggests that the Coulomb barrier to deuterium fusion may be overcome by high bubble gas temperatures caused by compression heating if the bubble diameter remains spherical during bubble collapse.However, in the more likely collapse geometry of a pancake shape, the temperature rise in the bubbles is negligible. But the collapsing pancake bubble is found to significantly increase the frequency of the infrared energy available in the vibrational state of the water molecules at ambient temperature. For a collapse to liquid density, ultraviolet radiation at about 10eV is found. Although the ultraviolet radiation is of a low intensity, higher intensities may be possible if the bubble collapse is enhanced by visible and infrared lasers. Neither hot nor cold fusion is predicted in bubble collapse,but the ultraviolet energy at about 10eV developed in the bubble is sufficient to provide the basis for a new field of chemistry called ultrasound induced and laser enhanced cold fusion chemistry. 展开更多
关键词 Cold fusion ULTRASOUND ULTRAVIOLET THEORY
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Physics of Cold Fusion by TSC Theory
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《Journal of Physical Science and Application》 2013年第3期191-198,共8页
This paper reviews the author's recent works on the basic physics of cold fusion by the TSC (tetrahedral symmetric condensate) theory. Models of TSC formation conditions in condensed matter are first proposed. Seco... This paper reviews the author's recent works on the basic physics of cold fusion by the TSC (tetrahedral symmetric condensate) theory. Models of TSC formation conditions in condensed matter are first proposed. Secondly formulas for cold fusion rates per D(H)-cluster are explained with typical quantitative results. The 4D/TSC fusion and the 4H/TSC WS fusion are underlying mechanisms, respectively for the D (deuterium)-system and the H (protium)-system. 展开更多
关键词 Cold fusion condensed matter TSC theory D(H)-cluster 4D fusion 4H WS fusion.
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Model for Interaction Between Photon and Cold Atom in QED Cavity
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作者 ZHANGLi WANGCheng +2 位作者 LIYan-Min RUANSheng-Ping XUANLi 《Communications in Theoretical Physics》 SCIE CAS CSCD 2004年第6期941-948,共8页
A model has been established for the interaction between a single-mode optical field and a 2-energy-level cold atom with exact analytic solutions given. The processes of momentum and energy exchanges between the optic... A model has been established for the interaction between a single-mode optical field and a 2-energy-level cold atom with exact analytic solutions given. The processes of momentum and energy exchanges between the optical field and the cold atom due to the interaction between them are discussed in detail, and a formula has been given for the variation of momentum and energy exchange volumes with time t in dress state while both the effects of photon recoil and Doppler effect are taken into consideration. 展开更多
关键词 QED in cavity dress state cold atom effect of doppler Bose-Einstein condensation
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New Process of Cold Fusion
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作者 C.P.L. Karl von Thule Elena Dvoryashina 《Journal of Energy and Power Engineering》 2017年第10期643-645,共3页
The author's Process of Cold Fusion firstly was announced at the International Conference on Emerging Nuclear Energy Systems in 2007, after that it was presented at the International Conference on Emerging Nuclear En... The author's Process of Cold Fusion firstly was announced at the International Conference on Emerging Nuclear Energy Systems in 2007, after that it was presented at the International Conference on Emerging Nuclear Energy Systems in 2009. The product has already been applied since June, 2007. It was developed as a large Module of 300 cm x 40 cm, producing energy at 600 megawatts per hour, with unique waste of about 300 cubic meters of pure drinkable instant water a day. There is also a Portable Module, producing about 1 megawatt per hour, having in waste about 1 cubic meter of pure drinkable instant water a day. The important details: (1) we have the ability to stop the Module at any time; (2) the civil applications of this process is mentioned at the articles, published on the website of the European Scientific Parliament in the year of 2010; (3) the diverse modules became the object of special protocols, signed with a number of countries all over the world. 展开更多
关键词 Nuclear energy for humanity useful electricity HEAT pure instant water.
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New Process of Cold Fusion
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作者 C.P.L. Karl yon THULE 《Journal of Energy and Power Engineering》 2013年第11期2115-2118,共4页
The author's process of cold fusion, was announced to International Conference on Emerging Nuclear Energy Systems in 2007, then exposed to International Conference on Emerging Nuclear Energy Systems in 2009, and has ... The author's process of cold fusion, was announced to International Conference on Emerging Nuclear Energy Systems in 2007, then exposed to International Conference on Emerging Nuclear Energy Systems in 2009, and has been applied since June, 2007 in a non-member border country of the European Union, for safety reasons, the product, of a large module of 300 cm x 40 cm, using energy of mass of 600 megawatts per hour, and unique waste, 300 cubic meters of pure water a day, instantly drinkable. The presentation which the author shall make, will contain, if it is possible, several demonstrations of a portable module, producing one megawatt per hour, and in waste one cubic meter of water per day: the authors are able to stop the module at any time. The civil applications of this process, the author developed in the articles published on the site of the European Scientific Parliament 2010, and diverse modules were the object of a protocol signed by large Asian country. 展开更多
关键词 Cold fusion ENERGY WATER POWER European Scientific Parliament.
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Combining the Radiative, Conductive and Convective Heat Flows in and around a Skylight
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作者 Martin Falt Ron Zevenhoven 《Journal of Energy and Power Engineering》 2012年第9期1423-1428,共6页
Normal skylights bring light into the spaces located below them. By the use of IR (infrared radiation) transmissive polymer films and IR-emitting and absorbing gases, an advanced version of the skylight may supply p... Normal skylights bring light into the spaces located below them. By the use of IR (infrared radiation) transmissive polymer films and IR-emitting and absorbing gases, an advanced version of the skylight may supply passive cooling and thermal insulation to the room located below it. This novel radiative skylight can, in its cooling mode, lead heat from the room below, to the cool skies located above the skylight. When cooling is no longer needed or attainable, the skylight will in its cooling mode provide the room with an optimal amount of thermal resistance. This article is a progress reporting on the modeling of the skylight. The main work is done to combine the different heat transfer methods into one single model by the use of the commercial program Comsol 4.1. The results show that a cooling effect of 100 W/ma is achievable when the skylight is compared with a similar skylight containing only air. 展开更多
关键词 Radiative cooling heat transfer in participating media skylight.
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Energy Spectrum of Two-Component Bose-Einstein Condensates in Optical Lattices 被引量:1
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作者 HANJiu-Rong LIUJin-Ming +1 位作者 JINGHui WANGYu-Zhu 《Communications in Theoretical Physics》 SCIE CAS CSCD 2005年第5期809-813,共5页
With the method of Green's function, we investigate the energy spectra of two-component ultracold bosonic atoms in optical lattices. We End that there are two energy bands for each component. The critical conditio... With the method of Green's function, we investigate the energy spectra of two-component ultracold bosonic atoms in optical lattices. We End that there are two energy bands for each component. The critical condition of the superfluid-Mott insulator phase transition is determined by the energy band structure. We also find that the nearest neighboring and on-site interactions fail to change the structure of energy bands, but shift the energy bands only. According to the conditions of the phase transitions, three stable superfluid and Mott insulating phases can be found by adjusting the experiment parameters. We also discuss the possibility of observing these new phases and their transitions in further experiments. 展开更多
关键词 energy spectrum phase transition Bose-Einstein condensates optical lattice
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Study on Dibehenyl Fumarate-Vinyl Acetate Copolymer for Lowering Cold Filter Plugging Point of Diesel Fuel
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作者 Du Tao Wang Shujun +1 位作者 Liu Hongyan Zhang Ying 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2010年第4期52-56,共5页
In the practice of petroleum industry, adding cold flow improver (CFI) to lower the fuel's cold filter plugging point (CFPP) is an effective and economic way for improving the cold flow performance of diesel fuel... In the practice of petroleum industry, adding cold flow improver (CFI) to lower the fuel's cold filter plugging point (CFPP) is an effective and economic way for improving the cold flow performance of diesel fuel. This paper described the synthesis and evaluation of the performance of dibehenyl fumarate-vinyl acetate (FV) copolymer for improving the cold flow performance of the tested diesel fuels. The carbon distribution in n-alkanes of the tested diesel samples were analyzed by gas phase chromatography. The structure of the copolymer was confirmed by the 1H NMR spectroscopy. The wax crystals morphologies with and without adding the FV additive were investigated by means of polarizing microscope. The test results indicated that the FV additive could depress CFPP of the tested diesel samples by 2℃ and 4℃, respectively, when dosage of the additive was 0.08 m%. The additive can modify the size and shape of the wax crystals and inhibit the formation of larger wax crystal lattices. 展开更多
关键词 diesel fuel cold flow improver cold filter plugging point COPOLYMER wax crystal
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Study of Cold Fusion Reactions Using Collective Clusterization Approach
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作者 Gurjit Kaur Kirandeep Sandhu Manoj K.Sharma 《Communications in Theoretical Physics》 SCIE CAS CSCD 2017年第10期505-517,共13页
Within the framework of the dynamical cluster decay model (DCM), the in evaporation cross-sections (σ1n) of cold fusion reactions (Pb and Bi targets) are calculated for ZCN = 104-113 superheavy nuclei. The calc... Within the framework of the dynamical cluster decay model (DCM), the in evaporation cross-sections (σ1n) of cold fusion reactions (Pb and Bi targets) are calculated for ZCN = 104-113 superheavy nuclei. The calculations are carried out in the fixed range of excitation energy ECN = 15 ± 1 MeV, so that the comparative analysis of reaction dynamics can be worked out. First of all, the fission barriers (Bf ) and neutron separation energies (S1n) are estimated to account the decreasing cross-sections of cold fusion reactions. In addition to this, the importance of hot optimum orientations of β24-deformed nuclei over cold one is explored at fixed angular momentum and neck-length parameters. The hot optimum orientations support all the target-projectile (t,p) combinations, which are explored experimentally in the cold fusion reactions. Some new target-projectile combinations are also predicted for future exploration. Further, the In cross-sections are addressed for ZCN = 104-113 superheavy nuclei at comparable excitation energies which show the decent agrement with experimental data upto ZCN = 109 nuclei. Finally, to understand the dynamics of higher-Z superheavy nuclei, the cross-sections are also calculated at maximum available energies around the Coulomb barrier and the effect of non-sticking moment of inertia (INS) is also investigated at these energies. 展开更多
关键词 cold fusion reactions ln-decay cross-sections fragment mass distribution
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Fundamental Analysis of Helium-Gas Coolant Leakage Rate Through First-Wall Cracks in Tokamak Fusion Reactors
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作者 Tony C.Min 《Journal of Thermal Science》 SCIE EI CAS CSCD 1993年第1期12-17,共6页
A fundamental analysis of helium-gas coolant leakage rate through first-wall cracks in Tokamak fusion reactors was made. Criteria for ascertaining the correct flow models were thoroughly investigated. After testing th... A fundamental analysis of helium-gas coolant leakage rate through first-wall cracks in Tokamak fusion reactors was made. Criteria for ascertaining the correct flow models were thoroughly investigated. After testing the criteria, it was determined that the correct model is the compressible choked flow for the helium-gas coolant under the normal operating conditions in the Tokamak fusion reactors. The upper bound leakage rates through metallic wall for two crack sizes were calculated. The calculated maximum numbers of allowable cracks through metallic and silicon-carbon composite wall were also reported. The experimental data of specimen S-23 (the small crack size), checked with the predicted or calculated leakage rate. But the experimental data of specimen S-4 (the large crack size, which is only 4.4 times larger than the crack size of specimen S-23) were two orders of magnitude higher than the calculated value. This is probably due to the many through-cracks undetected and therefore, not reported in the experiment, and not due to the difference in crack sizes. It should be noted that since there are only two test data points, it is recommended that more testing or experimental data will be needed. The results of two previous investigations about the calculated leakage values, their equations used, and their flow models employed were also reviewed. It is concluded that the correct model for the analysis is the compressible choked flow, and that helium can be as an effective coolant for fusion power reactors. Several recommendations are also made. Specifically, more experiments for helium, and similar analysis and experiments for lithium and water coolant are needed; and should be encouraged. 展开更多
关键词 coolant leakage rate Tokamak fusion reactor flow model.
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High Heat Flux Burnout in Subcooled Flow Boiling
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作者 G.P.Celata M.Cumo 《Journal of Thermal Science》 SCIE EI CAS CSCD 1995年第3期151-161,共11页
The paper reports the results of an experimental research carried out at the Heat Transfer Division of the Energy Department, C.R. Casaccia, on the thermal hydraulic characterisation of subcooled flow boiling CHF unde... The paper reports the results of an experimental research carried out at the Heat Transfer Division of the Energy Department, C.R. Casaccia, on the thermal hydraulic characterisation of subcooled flow boiling CHF under typical conditions of thermonuclear fusion reactors, i.e. high liquid velocity and subcooling.The experiment was carried out exploring the following parameters: channel diameter (from 2.5 to 8.0 mm), heated length (10 and 15 cm), liquid velocity (from 2 to 40 m/s), exit pressure (from atmospheric to 5.0 MPa), inlet temperature (from 30 to 80℃), channel orientation (vertical and horizontal). A Inaximum CHF value of 60.6 MW/m2 has been obtained under the following conditions: Tin = 30°, p= 2.5 MPa, u = 40 m/s, D = 2.5 mm (smooth channel)Turbulence promoters (helically coiled wires) have been employed to further enhance the CHF attainable with subcooled flow boiling. Helically coiled wires allow an increase of 50% of the maximum CHF obtained with smooth channels. 展开更多
关键词 subcooled flow boiling high heat flux fusion reactor burnout.
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Heat Transfer in Internal Channel of a Blade:Effects of Rotation in a Trailing Edge Cooling System 被引量:1
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作者 Luca Andrei Antonio Andreini +1 位作者 Leonardo Bonanni Bruno Facchini 《Journal of Thermal Science》 SCIE EI CAS CSCD 2012年第3期236-249,共14页
The aerothermal performance of a trailing edge (TE) internal cooling system of a high pressure gas turbine blade was evaluated under stationary and rotating conditions. The investigated geometry consists of a 30:1 ... The aerothermal performance of a trailing edge (TE) internal cooling system of a high pressure gas turbine blade was evaluated under stationary and rotating conditions. The investigated geometry consists of a 30:1 scaled model reproducing a typical wedge shaped discharge duct with one row of enlarged pedestals. The airflow pattern inside the device simulates a highly loaded rotor blade cooling scheme with a 90 [deg] turning flow from the radial hub inlet to the tangential TE outlet. Two different tip configurations were tested, the first one with a completely closed section, the second one with a 5 holes outlet surfaces discharging at ambient pressure. In order to assess rotation effects, a rotating test rig, composed of a rotating ann holding both the PMMA TE model and the instru mentation, was purposely developed and manufactured. A thin Inconel heating foil and wide band Thermochromic Liquid Crystals are used to perform steady state heat transfer measurements on the blade pres sure side. A rotary joint ensures the pneumatic connection between the blower and the rotating apparatus; more over several slip rings are used for both instrumentation power supply and thermocouple connection. A parallel CFD analysis involving steadystate RANS modeling was conducted to allow an insight of the flow field inside the redirecting channel and the interpedestal ducts to better interpret the developing vortical structures. LowReynolds grid clustering permits to integrate up to the wall both the momentum and the thermal boundary layer. Calculations were performed by means of an inhouse developed pressure based solver exploiting the kco SST turbulence model implemented in the framework of the opensource finite volume discretization toolbox OpenFOAM~. Analyzed flow conditions correspond to Reynolds number of 20000 in the hub inlet section and angular speed varies to obtain rotation numbers in the range from 0 to 0.3. The orientation of the rotation axis is orthogonal to the heated surface as to resemble a 90 [deg] blade metal angle. Results are reported in terms of de tailed heat transfer coefficient 2D maps on the suction side surface as well as spanwise profiles inside the pedestal ducts. 展开更多
关键词 heat transfer trailing edge PEDESTAL rotation number OpenFOAM~ CFD TLC thermography
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