The water distribution system of one residential district in Tianjin is taken as an example to analyze the changes of water quality.Partial least squares(PLS) regression model,in which the turbidity and Fe are regarde...The water distribution system of one residential district in Tianjin is taken as an example to analyze the changes of water quality.Partial least squares(PLS) regression model,in which the turbidity and Fe are regarded as control objectives,is used to establish the statistical model.The experimental results indicate that the PLS regression model has good predicted results of water quality compared with the monitored data.The percentages of absolute relative error(below 15%,20%,30%) are 44.4%,66.7%,100%(turbidity) and 33.3%,44.4%,77.8%(Fe) on the 4th sampling point;77.8%,88.9%,88.9%(turbidity) and 44.4%,55.6%,66.7%(Fe) on the 5th sampling point.展开更多
Mobility and bioavailability of lead （Pb） could be affected considerably by soil physicochemical properties; however, less is known about the effect of Pb levels and aging time. This study was conducted to evaluate ...Mobility and bioavailability of lead （Pb） could be affected considerably by soil physicochemical properties; however, less is known about the effect of Pb levels and aging time. This study was conducted to evaluate the effects of Pb levels and wetting-drying （WD） cycles on distribution and bioavailability of Pb in three semi-arid zone soils treated with different levels of Pb（NO3）2. Wetting-drying cycles simulated the actual field irrigation in the semi-arid soils. A soil with a long history of Pb contamination was also taken as a reference soil. The soils were spiked with various levels of Pb and incubated under WD cycles for 160 d. Sequential extractions and batch sorption experiments were performed to assess the fractionation of Pb in the spiked soils. Redistribution index （Uts） and reduced partitioning parameter （IR） were applied to semi-quantify the distribution of Pb in the spiked soils. A small amount of Pb sorbed was desorbed by the soils, indicating a strong and irreversible binding of Pb in the studied soils. Contribution of carbonate-bound （Car） and residual （Res） Pb fl＇actions to the total Pb of the soils was more than 97%. The Car, soluble plus exchangeable （SE）, and organic matter-bound （OMB） fractions of Pb were transferred to the Res fraction under the WD cycles. The IR and Uts values were influenced by Pb loading levels and WD; therefore, the Pb lability and/or redistribution pattern could semi-quantitatively be assessed via these parameters. At the end of the experiment, the Ia and Uts values for the Pb salt-spiked soils did not show the quasi- equilibrium state. The lability of Pb in the soils decreased with increasing incubation time and showed a strong dependence on Pb levels and soil chemical composition. WD cycles significantly affected the overall lability of Pb in soils through influencing the redistribution of Pb among solid-phase components.展开更多
基金Supported by National Natural Science Foundation of China (No.50478086)Tianjin Special Scientific Innovation Foundation (No.06FZZDSH00900)
文摘The water distribution system of one residential district in Tianjin is taken as an example to analyze the changes of water quality.Partial least squares(PLS) regression model,in which the turbidity and Fe are regarded as control objectives,is used to establish the statistical model.The experimental results indicate that the PLS regression model has good predicted results of water quality compared with the monitored data.The percentages of absolute relative error(below 15%,20%,30%) are 44.4%,66.7%,100%(turbidity) and 33.3%,44.4%,77.8%(Fe) on the 4th sampling point;77.8%,88.9%,88.9%(turbidity) and 44.4%,55.6%,66.7%(Fe) on the 5th sampling point.
基金Supported by the National Science Foundation of Iran and Urmia University,Iran
文摘Mobility and bioavailability of lead （Pb） could be affected considerably by soil physicochemical properties; however, less is known about the effect of Pb levels and aging time. This study was conducted to evaluate the effects of Pb levels and wetting-drying （WD） cycles on distribution and bioavailability of Pb in three semi-arid zone soils treated with different levels of Pb（NO3）2. Wetting-drying cycles simulated the actual field irrigation in the semi-arid soils. A soil with a long history of Pb contamination was also taken as a reference soil. The soils were spiked with various levels of Pb and incubated under WD cycles for 160 d. Sequential extractions and batch sorption experiments were performed to assess the fractionation of Pb in the spiked soils. Redistribution index （Uts） and reduced partitioning parameter （IR） were applied to semi-quantify the distribution of Pb in the spiked soils. A small amount of Pb sorbed was desorbed by the soils, indicating a strong and irreversible binding of Pb in the studied soils. Contribution of carbonate-bound （Car） and residual （Res） Pb fl＇actions to the total Pb of the soils was more than 97%. The Car, soluble plus exchangeable （SE）, and organic matter-bound （OMB） fractions of Pb were transferred to the Res fraction under the WD cycles. The IR and Uts values were influenced by Pb loading levels and WD; therefore, the Pb lability and/or redistribution pattern could semi-quantitatively be assessed via these parameters. At the end of the experiment, the Ia and Uts values for the Pb salt-spiked soils did not show the quasi- equilibrium state. The lability of Pb in the soils decreased with increasing incubation time and showed a strong dependence on Pb levels and soil chemical composition. WD cycles significantly affected the overall lability of Pb in soils through influencing the redistribution of Pb among solid-phase components.
