Mass transfer enhancement of gas absorption by adding a dispersed organic phase has been studied in this work. Various dispersed organic phases （heptanol, octanol, isoamyl alcohol, heptane, octane, and isooctane） we...Mass transfer enhancement of gas absorption by adding a dispersed organic phase has been studied in this work. Various dispersed organic phases （heptanol, octanol, isoamyl alcohol, heptane, octane, and isooctane） were tested respectively in the experiment. According to the theoretical model and experimental data, the overall volumetric mass transfer coefficient and enhancement factor were obtained under different dispersed organic phase volume fraction and stirring speed. The experimental results indicate that gas-liquid mass transfer is enhanced at different level by adding a dispersed organic phase. The best performance of enhancement were achieved with the dispersed organic phase volumetric fraction of 5% and under an intermediate stirring speed of 670 r·min^-1. Among the organic phases tested in the experiment, alcohols show better performance, which gave 20% higher enhance-ment of overall volumetric mass transfer coefficient than adding alkanes.展开更多
Almost half of the oceanic water columns exhibit double-diffusion. The importance of double-diffusion in global oceans’ salt and heat fluxes, water-mass formation and mixing, and circulation is increasingly recognize...Almost half of the oceanic water columns exhibit double-diffusion. The importance of double-diffusion in global oceans’ salt and heat fluxes, water-mass formation and mixing, and circulation is increasingly recognized. However, such an important physical process in the ocean has not been well studied. One of the reasons is the difficulty of parameterizing and quantifying the processes. The paper presented here attempts to quantify the double-diffusive fluxes of salt and heat in the ocean. Previous qualitative analysis by applying the water-mass Turner angle, mTu, to the North Pacific Intermediate Water (NPIW) layer showed a favorable condition for salt-fingering in the upper NPIW due to the overlying warm/salty water above the cold/fresh NPIW core, and a doubly-stable condition in the lower NPIW where potential temperature decreases with depth while salinity increases, inducing double stratification with respect to both potential temperature and salinity. The present study gives a quantitative estimate of double-diffusive fluxes of salt and heat contributed by salt-fingering in the upper NPIW layer.展开更多
The supply of cadmium from soil to plant roots mainly depends on the diffusion process. This work was conducted tostudy the effect of some soil properties on cadmium diffusion coefficient (D) in soil. Measurements we...The supply of cadmium from soil to plant roots mainly depends on the diffusion process. This work was conducted tostudy the effect of some soil properties on cadmium diffusion coefficient (D) in soil. Measurements were made using the Shofield and Graham-Bryce's isotopic labelling method. Cadmium diffusion coefficients varied from 10￣(-7) to 10￣(-9) cm￣2s￣(-1),Higher values were observed in acid sandy soils and lower values in calcareous clay soils. Liming an acid soil resulted in a sub-stantial decrease of D. Addition of cadmium as nitrate salt generally increased D, while addition of sewage sludge and organ-ic matter resulted in a significant decrease of cadmium diffusion. The rhizospheric activity also induced a moderate reduction in D. The relationships between D 10￣(-9)cm￣2s￣(-1)) on the one hand and soil PH, moisture (Mc, g kg￣(-1)), organic matter (OM, gkg￣1 ), clay (Cy, g kg￣(-1)) and cadmium content (Cd, mg kg￣(-1)) on the other were obtained by the multigle regression:D=182. 1-29.g1 pH+0.210Mc-0.303OM+0.011Cy+1.64Cd (R￣2=0.859,n=22 ).展开更多
Two Gaussian air quality dispersion models, the industrial source complex short-term model (ISCST3) with and without modification have been used to simulate the pollutant concentration distribution in urban areas base...Two Gaussian air quality dispersion models, the industrial source complex short-term model (ISCST3) with and without modification have been used to simulate the pollutant concentration distribution in urban areas based on the meteorological data and the emissions distribution of sulfur dioxide. The verified data show that the modified model is more accurate in the urban area of Shijiazhuang. Using the modified model predictions, the control strategies of sulfur dioxide in the urban area have been studied, and the result show that the second long-term (to 2010) strategy can mitigate air pollution significantly and maintain pollution levels within permissible limits.展开更多
Monodispersed manganese ferrite （MnFe2O4） nanocrystals could be successfully synthesized in large quantities via a facile synthetic technique based on the pyrolysis of organometallic compound precursor, in which oct...Monodispersed manganese ferrite （MnFe2O4） nanocrystals could be successfully synthesized in large quantities via a facile synthetic technique based on the pyrolysis of organometallic compound precursor, in which octadecene was used as solvent, and oleic acid and oleylamine were used as capping ligands. MnFe204 nanocrystals were obtained with size in a tunable range of 4- 15 nm and their morphologies could be tuned from spherical to triangle-shaped by varying the surfactants. The phase structure, morphology, and size of the products were characterized in detail by X-ray diffraction （XRD） and transmission electron microscopy （TEM）. Magnetic properties of MnFe2O4 nanocrystals with different morphologies were measured using a superconducting quantum interference device （SQUID）. Both monodisperse MnFe204 nanocrystals with spherical and triangle-shapes are superparamagnetic at room temperature while ferromagnetic at 2 K. The pyrolysis method may provide an effective route to synthesize other spinel ferrites or metal oxides nanocrystals.展开更多
In the present work, we aimed to optimize the preparation technology of dimethyl curcumin niosomes, improve its solubility and assess its stability. The novel anti-androgen dimethyl curcumin niosomes were prepared by ...In the present work, we aimed to optimize the preparation technology of dimethyl curcumin niosomes, improve its solubility and assess its stability. The novel anti-androgen dimethyl curcumin niosomes were prepared by thin-film dispersion-ultrasonic method, and the prescription composition and preparation process were optimized by single-factor investigation method. Certainly, the solubility and quality evaluation of dimethyl curcumin niosomes were also investigated. The average particle size of prepared dimethyl curcumin niosomes was （310.3＋0.9） nm. The highest encapsulation rate was 88.1%± 1.7%, and the drug-loading amount was 4.03%±1.05%. Moreover, the leakage rate was below 2% within 45 d. Collectively, all these findings indicated that the niosomes, as a vector, could significantly improve the solubility and stability of dimethyl curcumin, offering a theoretical basis for dimethyl curcumin as an anticancer drug in medicine application.展开更多
A nuclear accident involving the leaking of radioactive pollutants occurred at the Fukushima Nuclear Power Plant in Japan, following an earthquake and subsequent tsunami on March 11,2011. Using official Japanese data ...A nuclear accident involving the leaking of radioactive pollutants occurred at the Fukushima Nuclear Power Plant in Japan, following an earthquake and subsequent tsunami on March 11,2011. Using official Japanese data on pollutant emissions during the accident, this study simulates the dispersion of nuclear pollutants. The source term of the nuclear leakage of radioactive material is designed using PM2.5 as the tracer of radioactive pollutants, and the study considers dry and wet deposition processes. A coupled-model system is constructed from the air-quality model Models-3/CMAQ and the Weather Research and Forecasting atmospheric model. The transport path and distribution of radioactive pollutants over long and short distances are simulated with different model horizontal resolutions of 30 and 4 km respectively. The long-distance simulation shows that, following the Fukushima nuclear accident, under the effect of westerly winds, radioactive pollutants are transported generally towards the eastern Pacific and reach the American continent after 5 days, but their concentration is only about 10-7 times the concentration near the Fukushima Nuclear Power Plant. The time required for pollutants to reach the United States is basically consistent with measurements made in California on March 18. Because the upper westerly wind is faster than the lower westerly wind, the distribution of pollutants tilts eastward in terms of its vertical structure. The short-distance （local） highresolution simulation indicates that strong winds and precipitation associated with a cyclone can accelerate the deposition, dif- fusion and transport of pollutions, and local cyclonic circulation can change the transport path of pollutants, even resulting in repeated effects of pollution in some areas. Pollutants disperse to southeastern Honshu, Japan, on March 14, 2011, agreeing well with the timing of local observations of increases in the absorbed dose rate. Results also show that radioactive pollutants from the Fukushima nuclear accident are mainly transported and diffuse eastward, resulting in a relatively short-term impact on the Japanese mainland even under the influence of the cyclone system. Therefore, in terms of atmospheric conditions, the location of the Fukusbima Nuclear Power Plant is appropriate and could serve as a reference to site selection and protection of other nuclear facilities.展开更多
An ultra-accurate isogeometric dynamic analysis is presented.The key ingredient of the proposed methodology is the development of isogeometric higher order mass matrix.A new one-step method is proposed for the constru...An ultra-accurate isogeometric dynamic analysis is presented.The key ingredient of the proposed methodology is the development of isogeometric higher order mass matrix.A new one-step method is proposed for the construction of higher order mass matrix.In this approach,an adjustable mass matrix is formulated through introducing a set of mass parameters into the consistent mass matrix under the element mass conservation condition.Then the semi-discrete frequency derived from the free vibration equation with the adjustable mass matrix is served as a measure to optimize the mass parameters.In 1D analysis,it turns out that the present one-step method can perfectly recover the existing reduced bandwidth mass matrix and the higher order mass matrix by choosing different mass parameters.However,the employment of the proposed one-step method to the2D membrane problem yields a remarkable gain of solution accuracy compared with the higher order mass matrix generated by the original two-step method.Subsequently a full-discrete isogeometric transient analysis algorithm is presented by using the Newmark time integration scheme and the higher order mass matrix.The full-discrete frequency is derived to assess the accuracy of space-time discretization.Finally a set of numerical examples are presented to evaluate the accuracy of the proposed method,which show that very favorable solution accuracy is achieved by the present dynamic isogeometric analysis with higher order mass formulation compared with that obtained from the standard consistent mass approach.展开更多
基金Supported by the National Natural Science Foundation of China （20776086）
文摘Mass transfer enhancement of gas absorption by adding a dispersed organic phase has been studied in this work. Various dispersed organic phases （heptanol, octanol, isoamyl alcohol, heptane, octane, and isooctane） were tested respectively in the experiment. According to the theoretical model and experimental data, the overall volumetric mass transfer coefficient and enhancement factor were obtained under different dispersed organic phase volume fraction and stirring speed. The experimental results indicate that gas-liquid mass transfer is enhanced at different level by adding a dispersed organic phase. The best performance of enhancement were achieved with the dispersed organic phase volumetric fraction of 5% and under an intermediate stirring speed of 670 r·min^-1. Among the organic phases tested in the experiment, alcohols show better performance, which gave 20% higher enhance-ment of overall volumetric mass transfer coefficient than adding alkanes.
基金a result of my short visit to the Physical Oceanography Laboratory of Ocean University of ChinaQingdao with support from the Foundation for Open Projects of the Key Lab.of Physical Oceanography,the Ministry of Education,China(No.200401).
文摘Almost half of the oceanic water columns exhibit double-diffusion. The importance of double-diffusion in global oceans’ salt and heat fluxes, water-mass formation and mixing, and circulation is increasingly recognized. However, such an important physical process in the ocean has not been well studied. One of the reasons is the difficulty of parameterizing and quantifying the processes. The paper presented here attempts to quantify the double-diffusive fluxes of salt and heat in the ocean. Previous qualitative analysis by applying the water-mass Turner angle, mTu, to the North Pacific Intermediate Water (NPIW) layer showed a favorable condition for salt-fingering in the upper NPIW due to the overlying warm/salty water above the cold/fresh NPIW core, and a doubly-stable condition in the lower NPIW where potential temperature decreases with depth while salinity increases, inducing double stratification with respect to both potential temperature and salinity. The present study gives a quantitative estimate of double-diffusive fluxes of salt and heat contributed by salt-fingering in the upper NPIW layer.
文摘The supply of cadmium from soil to plant roots mainly depends on the diffusion process. This work was conducted tostudy the effect of some soil properties on cadmium diffusion coefficient (D) in soil. Measurements were made using the Shofield and Graham-Bryce's isotopic labelling method. Cadmium diffusion coefficients varied from 10￣(-7) to 10￣(-9) cm￣2s￣(-1),Higher values were observed in acid sandy soils and lower values in calcareous clay soils. Liming an acid soil resulted in a sub-stantial decrease of D. Addition of cadmium as nitrate salt generally increased D, while addition of sewage sludge and organ-ic matter resulted in a significant decrease of cadmium diffusion. The rhizospheric activity also induced a moderate reduction in D. The relationships between D 10￣(-9)cm￣2s￣(-1)) on the one hand and soil PH, moisture (Mc, g kg￣(-1)), organic matter (OM, gkg￣1 ), clay (Cy, g kg￣(-1)) and cadmium content (Cd, mg kg￣(-1)) on the other were obtained by the multigle regression:D=182. 1-29.g1 pH+0.210Mc-0.303OM+0.011Cy+1.64Cd (R￣2=0.859,n=22 ).
文摘Two Gaussian air quality dispersion models, the industrial source complex short-term model (ISCST3) with and without modification have been used to simulate the pollutant concentration distribution in urban areas based on the meteorological data and the emissions distribution of sulfur dioxide. The verified data show that the modified model is more accurate in the urban area of Shijiazhuang. Using the modified model predictions, the control strategies of sulfur dioxide in the urban area have been studied, and the result show that the second long-term (to 2010) strategy can mitigate air pollution significantly and maintain pollution levels within permissible limits.
基金Project(2010QZZD008) supported by the Prospect Key Projects of Fundamental Research Funds for the Central UniversitiesProject(2007FJ3008) supported by the Hunan Provincial Key Science and Technology Program of China
文摘Monodispersed manganese ferrite （MnFe2O4） nanocrystals could be successfully synthesized in large quantities via a facile synthetic technique based on the pyrolysis of organometallic compound precursor, in which octadecene was used as solvent, and oleic acid and oleylamine were used as capping ligands. MnFe204 nanocrystals were obtained with size in a tunable range of 4- 15 nm and their morphologies could be tuned from spherical to triangle-shaped by varying the surfactants. The phase structure, morphology, and size of the products were characterized in detail by X-ray diffraction （XRD） and transmission electron microscopy （TEM）. Magnetic properties of MnFe2O4 nanocrystals with different morphologies were measured using a superconducting quantum interference device （SQUID）. Both monodisperse MnFe204 nanocrystals with spherical and triangle-shapes are superparamagnetic at room temperature while ferromagnetic at 2 K. The pyrolysis method may provide an effective route to synthesize other spinel ferrites or metal oxides nanocrystals.
基金The National Natural Science Foundation of China(Grant No.31271002)Jiangsu Provincial Department of Education Funded Projects(Grant No.14KJB350001)
文摘In the present work, we aimed to optimize the preparation technology of dimethyl curcumin niosomes, improve its solubility and assess its stability. The novel anti-androgen dimethyl curcumin niosomes were prepared by thin-film dispersion-ultrasonic method, and the prescription composition and preparation process were optimized by single-factor investigation method. Certainly, the solubility and quality evaluation of dimethyl curcumin niosomes were also investigated. The average particle size of prepared dimethyl curcumin niosomes was （310.3＋0.9） nm. The highest encapsulation rate was 88.1%± 1.7%, and the drug-loading amount was 4.03%±1.05%. Moreover, the leakage rate was below 2% within 45 d. Collectively, all these findings indicated that the niosomes, as a vector, could significantly improve the solubility and stability of dimethyl curcumin, offering a theoretical basis for dimethyl curcumin as an anticancer drug in medicine application.
基金supported by the Special Funds of Public Welfare of China (Grant No. GYHY201306061)the National Natural Science Foundation of China (Grant Nos. 41230421, 41105065 & 41275128)
文摘A nuclear accident involving the leaking of radioactive pollutants occurred at the Fukushima Nuclear Power Plant in Japan, following an earthquake and subsequent tsunami on March 11,2011. Using official Japanese data on pollutant emissions during the accident, this study simulates the dispersion of nuclear pollutants. The source term of the nuclear leakage of radioactive material is designed using PM2.5 as the tracer of radioactive pollutants, and the study considers dry and wet deposition processes. A coupled-model system is constructed from the air-quality model Models-3/CMAQ and the Weather Research and Forecasting atmospheric model. The transport path and distribution of radioactive pollutants over long and short distances are simulated with different model horizontal resolutions of 30 and 4 km respectively. The long-distance simulation shows that, following the Fukushima nuclear accident, under the effect of westerly winds, radioactive pollutants are transported generally towards the eastern Pacific and reach the American continent after 5 days, but their concentration is only about 10-7 times the concentration near the Fukushima Nuclear Power Plant. The time required for pollutants to reach the United States is basically consistent with measurements made in California on March 18. Because the upper westerly wind is faster than the lower westerly wind, the distribution of pollutants tilts eastward in terms of its vertical structure. The short-distance （local） highresolution simulation indicates that strong winds and precipitation associated with a cyclone can accelerate the deposition, dif- fusion and transport of pollutions, and local cyclonic circulation can change the transport path of pollutants, even resulting in repeated effects of pollution in some areas. Pollutants disperse to southeastern Honshu, Japan, on March 14, 2011, agreeing well with the timing of local observations of increases in the absorbed dose rate. Results also show that radioactive pollutants from the Fukushima nuclear accident are mainly transported and diffuse eastward, resulting in a relatively short-term impact on the Japanese mainland even under the influence of the cyclone system. Therefore, in terms of atmospheric conditions, the location of the Fukusbima Nuclear Power Plant is appropriate and could serve as a reference to site selection and protection of other nuclear facilities.
基金supported by the National Natural Science Foundation of China(Grant No.11222221)
文摘An ultra-accurate isogeometric dynamic analysis is presented.The key ingredient of the proposed methodology is the development of isogeometric higher order mass matrix.A new one-step method is proposed for the construction of higher order mass matrix.In this approach,an adjustable mass matrix is formulated through introducing a set of mass parameters into the consistent mass matrix under the element mass conservation condition.Then the semi-discrete frequency derived from the free vibration equation with the adjustable mass matrix is served as a measure to optimize the mass parameters.In 1D analysis,it turns out that the present one-step method can perfectly recover the existing reduced bandwidth mass matrix and the higher order mass matrix by choosing different mass parameters.However,the employment of the proposed one-step method to the2D membrane problem yields a remarkable gain of solution accuracy compared with the higher order mass matrix generated by the original two-step method.Subsequently a full-discrete isogeometric transient analysis algorithm is presented by using the Newmark time integration scheme and the higher order mass matrix.The full-discrete frequency is derived to assess the accuracy of space-time discretization.Finally a set of numerical examples are presented to evaluate the accuracy of the proposed method,which show that very favorable solution accuracy is achieved by the present dynamic isogeometric analysis with higher order mass formulation compared with that obtained from the standard consistent mass approach.
