通常，太阳光中只有紫外光部分（高能量）才能用于把水分解成H2和O2的光催化电解反应，这类反应一般发生在由单晶、金红石型钛白氧化钛阴极和铂电极组成的光化学电池中。目前，日本东京大学（University of Tokyo）化学系统工程系教授Ka...通常，太阳光中只有紫外光部分（高能量）才能用于把水分解成H2和O2的光催化电解反应，这类反应一般发生在由单晶、金红石型钛白氧化钛阴极和铂电极组成的光化学电池中。目前，日本东京大学（University of Tokyo）化学系统工程系教授Kazunari Domen开发出一种新型非均相催化剂，使水可以在可见光照射下（波长大于400nm）光解成H2和O2。展开更多
The applicability of the density rule of Pathwardhan and Kumer and the rule based on the linear isopiestic relation is studied by comparison with experimental density data in the literature. Predicted and measured val...The applicability of the density rule of Pathwardhan and Kumer and the rule based on the linear isopiestic relation is studied by comparison with experimental density data in the literature. Predicted and measured values for 18 electrolyte mixtures are compared. The two rules are good for mixtures with and without common ions, including those containing associating ions. The deviations of the rule based on the linear isopiestic relation are slightly higher for the mixtures involving very strong ion complexes, but the predictions are still quite satisfactory.The density rule of Pathwardhan and Kumer is more accurate for these mixtures. However, it is not applicable for mixtures containing non-electrolytes. The rule based on the linear isopiestic relation is extended to mixtures involving non-electrolytes. The predictions for the mixtures containing both electrolytes and non-electrolytes and the non-electrolyte mixtures are accurate. All these results indicate that this rule is a widely applicable approach.展开更多
Biology is a rich source of great ideas that can inspire us to find successful ways to solve the challenging problems in engineering practices including those in the chemical industry. Bio-inspired chemical engineerin...Biology is a rich source of great ideas that can inspire us to find successful ways to solve the challenging problems in engineering practices including those in the chemical industry. Bio-inspired chemical engineering(Bio Ch E)may be recognized as a significant branch of chemical engineering. It may consist of, but not limited to, the following three aspects: 1) Chemical engineering principles and unit operations in biological systems; 2) Process engineering principles for producing existing or developing new chemical products through living ‘devices';and 3) Chemical engineering processes and equipment that are designed and constructed through mimicking(does not have to reproduce one hundred percent) the biological systems including their physical–chemical and mechanical structures to deliver uniquely beneficial performances. This may also include the bio-inspired sensors for process monitoring. In this paper, the above aspects are defined and discussed which establishes the scope of BioChE.展开更多
With the Industry 4.0 era coming, modern chemical plants will be gradually transformed into smart factories, which sets higher requirements for fault detection and diagnosis(FDD) to enhance operation safety intelligen...With the Industry 4.0 era coming, modern chemical plants will be gradually transformed into smart factories, which sets higher requirements for fault detection and diagnosis(FDD) to enhance operation safety intelligence. In a typical chemical process, there are hundreds of process variables. Feature selection is a key to the efficiency and effectiveness of FDD. Even though artificial immune system has advantages in adaptation and independency on a large number of fault samples, antibody library construction used to be based on experience. It is not only time consuming, but also lack of scientific foundation in fault feature selection, which may deteriorate the FDD performance of the AIS. In this paper, a fault antibody feature selection optimization(FAFSO) algorithm is proposed based on genetic algorithm to optimize the fault antibody features and the antibody libraries' thresholds simultaneously. The performance of the proposed FAFSO algorithms is illustrated through the Tennessee Eastman benchmark problem.展开更多
Building envelopes include facades and roof, which have the most interaction and exchange with outside and natural environment. In the future, meeting buildings various complicated needs with new technological advance...Building envelopes include facades and roof, which have the most interaction and exchange with outside and natural environment. In the future, meeting buildings various complicated needs with new technological advances necessitates a change and evolution in building envelopes. Controlling the energy consumption of the buildings is mostly through controlling the energy performance of the building envelopes. New technologies lead to the intelligent facades and envelopes. The envelope can be designed to be a part of the whole building＇s metabolism （energy production, storage and consumption） and morphology. The envelope would be a controlled part of the building which is managed through the central control system of the building, which connects it to other parts. It caused building envelope design to be changed fundamentally, so that there is a need to interact with engineering disciplines including computer engineering, mechanical engineering, material engineering and so on. All of these caused building envelope to get closer to biological and living systems. The physical restrictions which affect buildings system and living systems are the same. So they cause the same forces to shape the structure and form of the systems and the same rules to interact with the environment. The restrictions of material and energy resources caused living systems to be energy efficient and consuming less material. But the most important difference between living systems and building systems is in maximum use of different resources. As living systems use information maximally, the building system technology is based on using maximum energy. Now, there are many reasons and restrictions that building envelopes cannot act like living systems. But technological developments and contributing more disciplines in design and construction of building envelopes caused the future way of these envelopes get close to living systems for their energy efficiency. Some of living systems characteristics which the future building envelopes would have partially or benefit for the design process or construction are self-organization, evolution principles, hierarchical levels, processing energy, reaction to environmental stimuli and self-adjustment. Self-organization is achieved in some design software and in building material production for creating formal patterns. Evolution principles provide infrastructure for soft wares for optimization purposes and form creation. Hierarchical levels refer to giving hierarchical structure to the building envelopes through layering and designing different scales. Processing energy （metabolism） would be achieved through photovoltaic and solar collectors to produce energy and in passive systems for energy storage and distribution. Controlling solar radiation absorption and transmittance would help energy transfer from outside to building and vice versa. Reaction to environmental stimuli which is one of the most important characteristics of future building envelopes would use different types of active and passive sensors to create envelope mechanical reactions through material properties or collect data for processing in the control center to determine the right reaction. The reaction would be through different strategies such as changing properties and moving. Reaction could be passive or active. Self-adjustment can be achieved by control systems and processing units. All of these mean intelligent envelopes are essential parts of future buildings. Though it is now started with new design soft wares based on biological principles to optimize different parameters affecting the envelope function or to create the most efficient form.展开更多
Energy chemistry systems engineering （ECSE）, the applica- tion of the principles of system engineering in the field of energy chemistry, is a rapidly developing cutting-edge inter- discipline. It is used for various...Energy chemistry systems engineering （ECSE）, the applica- tion of the principles of system engineering in the field of energy chemistry, is a rapidly developing cutting-edge inter- discipline. It is used for various processes and systems in the domain of energy chemistry, dealing with problems of the efficient conversion, comprehensive utilization and comple- mentary integration of material and energy with the theories, methods and techniques of system engineering.展开更多
This paper aims to provide a brief introduction to recent advances in numerical algorithms and methods in the emerging computational geoscience filed with general simulation characteristics of modeling multiple chemic...This paper aims to provide a brief introduction to recent advances in numerical algorithms and methods in the emerging computational geoscience filed with general simulation characteristics of modeling multiple chemical and physical processes that take place in ore-generating systems within the Earth's crust. Due to significant differences between Earth systems and engineering systems, the existing numerical algorithms and methods, which are designed for simulating realistic problems in the engineering fields, may not be straightforwardly used to simulate ore-generating problems without significant improvements. Thus, extensive and systematic studies have been conducted, in recent years, to develop new numerical algorithms and methods for simulating different aspects of ore-generating problems. Not only can the outcomes of these studies provide new simulation tools for better understanding the controlled dynamic mechanisms that take place in ore-generating systems, but also they have enriched the research contents of computational mechanics in the broad sense.展开更多
文摘通常，太阳光中只有紫外光部分（高能量）才能用于把水分解成H2和O2的光催化电解反应，这类反应一般发生在由单晶、金红石型钛白氧化钛阴极和铂电极组成的光化学电池中。目前，日本东京大学（University of Tokyo）化学系统工程系教授Kazunari Domen开发出一种新型非均相催化剂，使水可以在可见光照射下（波长大于400nm）光解成H2和O2。
基金Supported by the Science Foundation of University of Petroleum (No. ZX9903), the Open Science Foundation of the State Key Laboratory of Heavy Oil Processing (No. 200005), and the National Natural Science Foundation of China (No. 20006010).
文摘The applicability of the density rule of Pathwardhan and Kumer and the rule based on the linear isopiestic relation is studied by comparison with experimental density data in the literature. Predicted and measured values for 18 electrolyte mixtures are compared. The two rules are good for mixtures with and without common ions, including those containing associating ions. The deviations of the rule based on the linear isopiestic relation are slightly higher for the mixtures involving very strong ion complexes, but the predictions are still quite satisfactory.The density rule of Pathwardhan and Kumer is more accurate for these mixtures. However, it is not applicable for mixtures containing non-electrolytes. The rule based on the linear isopiestic relation is extended to mixtures involving non-electrolytes. The predictions for the mixtures containing both electrolytes and non-electrolytes and the non-electrolyte mixtures are accurate. All these results indicate that this rule is a widely applicable approach.
文摘Biology is a rich source of great ideas that can inspire us to find successful ways to solve the challenging problems in engineering practices including those in the chemical industry. Bio-inspired chemical engineering(Bio Ch E)may be recognized as a significant branch of chemical engineering. It may consist of, but not limited to, the following three aspects: 1) Chemical engineering principles and unit operations in biological systems; 2) Process engineering principles for producing existing or developing new chemical products through living ‘devices';and 3) Chemical engineering processes and equipment that are designed and constructed through mimicking(does not have to reproduce one hundred percent) the biological systems including their physical–chemical and mechanical structures to deliver uniquely beneficial performances. This may also include the bio-inspired sensors for process monitoring. In this paper, the above aspects are defined and discussed which establishes the scope of BioChE.
基金Supported by the National Natural Science Foundation of China(61433001)
文摘With the Industry 4.0 era coming, modern chemical plants will be gradually transformed into smart factories, which sets higher requirements for fault detection and diagnosis(FDD) to enhance operation safety intelligence. In a typical chemical process, there are hundreds of process variables. Feature selection is a key to the efficiency and effectiveness of FDD. Even though artificial immune system has advantages in adaptation and independency on a large number of fault samples, antibody library construction used to be based on experience. It is not only time consuming, but also lack of scientific foundation in fault feature selection, which may deteriorate the FDD performance of the AIS. In this paper, a fault antibody feature selection optimization(FAFSO) algorithm is proposed based on genetic algorithm to optimize the fault antibody features and the antibody libraries' thresholds simultaneously. The performance of the proposed FAFSO algorithms is illustrated through the Tennessee Eastman benchmark problem.
文摘Building envelopes include facades and roof, which have the most interaction and exchange with outside and natural environment. In the future, meeting buildings various complicated needs with new technological advances necessitates a change and evolution in building envelopes. Controlling the energy consumption of the buildings is mostly through controlling the energy performance of the building envelopes. New technologies lead to the intelligent facades and envelopes. The envelope can be designed to be a part of the whole building＇s metabolism （energy production, storage and consumption） and morphology. The envelope would be a controlled part of the building which is managed through the central control system of the building, which connects it to other parts. It caused building envelope design to be changed fundamentally, so that there is a need to interact with engineering disciplines including computer engineering, mechanical engineering, material engineering and so on. All of these caused building envelope to get closer to biological and living systems. The physical restrictions which affect buildings system and living systems are the same. So they cause the same forces to shape the structure and form of the systems and the same rules to interact with the environment. The restrictions of material and energy resources caused living systems to be energy efficient and consuming less material. But the most important difference between living systems and building systems is in maximum use of different resources. As living systems use information maximally, the building system technology is based on using maximum energy. Now, there are many reasons and restrictions that building envelopes cannot act like living systems. But technological developments and contributing more disciplines in design and construction of building envelopes caused the future way of these envelopes get close to living systems for their energy efficiency. Some of living systems characteristics which the future building envelopes would have partially or benefit for the design process or construction are self-organization, evolution principles, hierarchical levels, processing energy, reaction to environmental stimuli and self-adjustment. Self-organization is achieved in some design software and in building material production for creating formal patterns. Evolution principles provide infrastructure for soft wares for optimization purposes and form creation. Hierarchical levels refer to giving hierarchical structure to the building envelopes through layering and designing different scales. Processing energy （metabolism） would be achieved through photovoltaic and solar collectors to produce energy and in passive systems for energy storage and distribution. Controlling solar radiation absorption and transmittance would help energy transfer from outside to building and vice versa. Reaction to environmental stimuli which is one of the most important characteristics of future building envelopes would use different types of active and passive sensors to create envelope mechanical reactions through material properties or collect data for processing in the control center to determine the right reaction. The reaction would be through different strategies such as changing properties and moving. Reaction could be passive or active. Self-adjustment can be achieved by control systems and processing units. All of these mean intelligent envelopes are essential parts of future buildings. Though it is now started with new design soft wares based on biological principles to optimize different parameters affecting the envelope function or to create the most efficient form.
基金supported by the National Natural Science Foundation of China(51206137)
文摘Energy chemistry systems engineering （ECSE）, the applica- tion of the principles of system engineering in the field of energy chemistry, is a rapidly developing cutting-edge inter- discipline. It is used for various processes and systems in the domain of energy chemistry, dealing with problems of the efficient conversion, comprehensive utilization and comple- mentary integration of material and energy with the theories, methods and techniques of system engineering.
基金supported by the National Natural Science Foundation of China(Grant Nos.11272359,10872219 and 10672190)
文摘This paper aims to provide a brief introduction to recent advances in numerical algorithms and methods in the emerging computational geoscience filed with general simulation characteristics of modeling multiple chemical and physical processes that take place in ore-generating systems within the Earth's crust. Due to significant differences between Earth systems and engineering systems, the existing numerical algorithms and methods, which are designed for simulating realistic problems in the engineering fields, may not be straightforwardly used to simulate ore-generating problems without significant improvements. Thus, extensive and systematic studies have been conducted, in recent years, to develop new numerical algorithms and methods for simulating different aspects of ore-generating problems. Not only can the outcomes of these studies provide new simulation tools for better understanding the controlled dynamic mechanisms that take place in ore-generating systems, but also they have enriched the research contents of computational mechanics in the broad sense.
