[Objective]The aim of this paper was to provide theoretical basis for study on enhancement of surfactants to desorption of PCBs from soil. [Method]The desorption effects of surfactants SDBs,Tween 80,HTAB on PCBs were ...[Objective]The aim of this paper was to provide theoretical basis for study on enhancement of surfactants to desorption of PCBs from soil. [Method]The desorption effects of surfactants SDBs,Tween 80,HTAB on PCBs were studied as well as their distribution in water and soil. Effects of rationing on desorption of PCBs were also analyzed. [Result]The potential of single surfactant to enhance the desorption of PCBs from soil in order was Tween 80 SDBS HTAB. Three surfactants were largely adsorbed on soil and the sorption followed HTABTween 80SDBS. The desorption of PCBs increased significantly and linearly with the increase of aqueous micelle concentration of surfactants. [Conclusion]Enhancing effect of three surfactants on PCBs desorption were obtained,which will provide theoretical basis for further analyzing.展开更多
Adsorption of water on sulfide surfaces and natural floatability of sulfide minerals were studied using density functional theory （DFT） method. All computational models were built in a vacuum environment to eliminat...Adsorption of water on sulfide surfaces and natural floatability of sulfide minerals were studied using density functional theory （DFT） method. All computational models were built in a vacuum environment to eliminate the effects of oxygen and other factors. H2O molecule prefers to stay with pyrite and sphalerite surfaces rather than water, whereas for galena, chalcocite, stibnite, and molybdenite, H2O molecule prefers to stay with water rather than the mineral surfaces. On the other hand, pyrite surface favors N2 more than water, while sphalerite surface cannot adsorb N2. These results show that galena, stibnite, chalcocite, and molybdenite are hydrophobic, while sphalerite is hydrophilic. Although pyrite has certain hydrophilicity, it tends to be aerophilic because the reaction of pyrite with H2O is weaker than pyrite with N2. Thus, pyrite, galena, chalcocite, stibnite and molybdenite all have natural floatability.展开更多
The influencing factors in adsorption such as adsorption time, pulp concentration, bacterial concentration, pH as well as ionic strength were investigated to explore the relationship among them and bacterial adsorptio...The influencing factors in adsorption such as adsorption time, pulp concentration, bacterial concentration, pH as well as ionic strength were investigated to explore the relationship among them and bacterial adsorption. The adsorption was a rapid process for bacterial adhesion to chalcopyrite. The extent of adsorption increased with increasing initial bacterial concentration and pulp concentration. The optimal pH for Acidithiobacillusferrooxidans adsorption onto chalcopyrite surfaces was in the range of pH 1-3. The increase of ionic strength led to decrease in bacterial adsorption, which can be well explained by electric double layer theory. The adsorption behavior appeared to be controlled by both hydrophobic and electrostatic interactions at the interface of bacteria and mineral,展开更多
A stdudy was conducted to determine the seasonal changes of soil respiration and the contribution of root respiration to soil respiration in Betula plaophylla forest in Changbai Mountain from May to September in 2004....A stdudy was conducted to determine the seasonal changes of soil respiration and the contribution of root respiration to soil respiration in Betula plaophylla forest in Changbai Mountain from May to September in 2004. Results indicated that the total soil respiration, root-severed soil respiration and the root respiration followed a similar seasonal trend, with a high rate in summer due to wet and high temperature and a low rate in spring and autumn due to lower temperature. The mean rates of total soil respiration, root-severed soil respiration and root respiration were 4.44, 2.30 and 2.14 μmol.m^-2.s^-1, respectively during the growing season, and they were all exponentially correlated with temperature. Soil respiration rate had a linear correlation with soil volumetric moisture. The Q10 values for total soil respiration, root-severed soil respiration and root respiration were 2,82, 2.59 and 3. 16, respectively. The contribution rate of root respiration to the total soil respiration was between 29.3% and 58.7% during the growing season, indicating that root is a major component of soil respiration. The annual mean rates of total soil respiration, root-severed soil respiration and root respiration were 1.96, 1.08, and 0.87 μmol.m^-2.s^-1, or 741.73 408.71, and 329.24 g.m^-2.a^-1, respectively. Root respiration contributed 44.4% to the annual total soil respiration. The relationship proposed for soil respiration with soil lemperature was useful for understanding and predicting potential changes in Changbai Mountain B. platyphylla forest ecosystem in response to forest management and climate change.展开更多
A comparative study of soil respiration was conducted between in a semi-arid steppe community and in a wet meadow community in the Xilin River Basin of Nei Mongol. The seasonal pattern, the climatic controls, and the ...A comparative study of soil respiration was conducted between in a semi-arid steppe community and in a wet meadow community in the Xilin River Basin of Nei Mongol. The seasonal pattern, the climatic controls, and the correlations of soil respiration with plant biomass components, were examined for each community. The main results are reported as follows: (1) The seasonal changes in soil respiration in the two communities had similar dynamic patterns (both being of two peaks), ranging from 312.8 to 1738.9 mg C(.)m(-2).s(-1) and from 354.6 to 2235.6 Mg C.m(-2).s(-1) in the growing season for the steppe plot and the meadow plot respectively. The soil respiration rate of the meadow plot was distinctly higher than that of the steppe plot, with the daily averages being 1349.6 mg C-m(-2).s(-1) and 785.9 mg C-m(-2).s(-1) respectively. (2) The correlation between soil respiration rate and soil moisture was much more significant than with temperature for the steppe community, and being on the contrary for the meadow community, reflecting the different effects of the two climatic factors in different habitats. Based on these regressive relations, the total CO2 efflux rate in the growing season in 2001 was estimated as 142.4 g C/m(2) in the steppe plot, and 236.1 g C/m(2) in the meadow plot. (3) There was no evident relation between the total canopy biomass and CO2 evolution rate, but a significant power function relation between the live canopy biomass and CO2 evolution rate in the meadow plot was detected. In the steppe plot, there existed only a weak relation between soil respiration and either live or total canopy biomass.展开更多
Brine,which is used to produce high-purity magnesia,was purified by XSC-700 to remove boron.Boron adsorption capacity of XSC-700 was investigated by varying the initial boron concentration,temperature,resin/brine rati...Brine,which is used to produce high-purity magnesia,was purified by XSC-700 to remove boron.Boron adsorption capacity of XSC-700 was investigated by varying the initial boron concentration,temperature,resin/brine ratio and stirring speed,while keeping the diameter at constant.The results show that boron adsorption capacity increases with increasing boron concentration,temperature,and decreases with increasing resin/brine ratio.And the stirring speed could slightly affect the boron adsorption capacity.The adsorption kinetics obeys the pseudo-second-order model.Equilibrium data were both examined by Freundlich and Langmuir isotherm equations and it can be well represented by the Freundlich isotherm equation.展开更多
Knowledge of oxygen consumption rates and asphyxiation points in fish is important to determine appropriate stocking and water quality management in aquaculture. The oxygen consumption rate and asphyxiation point in C...Knowledge of oxygen consumption rates and asphyxiation points in fish is important to determine appropriate stocking and water quality management in aquaculture. The oxygen consumption rate and asphyxiation point in Chanodichthys mongolicus were detected under laboratory conditions using an improved respirometer chamber. The results revealed that more accurate estimates can be obtained by adjusting the volume of the respirometer chamber, which may avoid system errors caused by either repeatedly adjusting fish density or selecting different equipment specifications. The oxygen consumption rate and asphyxiation point of C. mongolicus increased with increasing water temperature and decreasing fish size. Changes in the C. mongolicus oxygen consumption rate were divided into three stages at water temperatures of 11-33~C： （I） a low temperature oxygen consumption rate stage when water temperature was 11-19~C, （2） the optimum temperature oxygen consumption rate stage when water temperature was 19-23~C, and （3） a high temperature oxygen consumption rate stage when water temperature was 〉27~C. The temperature quotients （Q10） obtained suggested that C. mongolicus preferred a temperature range of 19-23~C. At 19~C, C. mongolicus exhibited higher oxygen consumption rates during the day when the maximum values were observed at 10：00 and 14：00 than at night when the minimum occurred at 02：00.展开更多
Condensation occurs when the local vapor pressure rises above the saturation vapor pressure at the local temperature in theory. A new measuring apparatus were made to obtain temperature and relative humidity simultane...Condensation occurs when the local vapor pressure rises above the saturation vapor pressure at the local temperature in theory. A new measuring apparatus were made to obtain temperature and relative humidity simultaneously for the purpose of investigating the mechanism of condensation occurred on the fabrics. The experiment conducted at the standard condition of temperature of 20℃ and relative humidity of 65%. The result obtained from experiment showed that condensation could occur under the situation closed to saturation line as the temperature on fabric may be lower than dew point of water vapor in the measuring box depending on the experiment conducted at an ambient environment temperature of 20℃ The range of fabrics studied showed that PTFE laminated fabrics except nylon gingham PTFE laminated fabric facilitates the loss of water vapor and therefore prevent condensation. It is necessary to develop studies from a wide range of fabrics, especially breathable fabrics and under bad experiment condition in order to develop fabrics, which could eliminate condensation, or transport water vapor through the fabric while remaining waterproof.展开更多
Pb2＋ adsorption onto a soil by irrigation of sewage in the Pearl River Delta of South China was examined as a function of the reaction time, solution pH, initial lead concentration, organic matter （humic acid） and ...Pb2＋ adsorption onto a soil by irrigation of sewage in the Pearl River Delta of South China was examined as a function of the reaction time, solution pH, initial lead concentration, organic matter （humic acid） and competitive ions （Cu2＋）. The adsorption of Pb2＋ onto the soil was investigated on batch equilibrium adsorption experiments. Results show that the Pb2＋ adsorption on the soil is relatively rapid in the first 30 min and reaches equilibrium at 2 h, and the kinetics of the adsorption process on the soil is well characterized by the pseudo-second order reaction rate. Langmuir, Freundlich and Temkin isothermal models are fit for the adsorption of Pb2＋ onto the soil, and the maximum amount of Pb2＋ adsorption （Qm） is 7.47 mg/g. The amount of Pb2＋ adsorption increases with increasing the pH at the range of 1.2-4.5 and reaches a plateau at the range of 4.5-12. The presence of humic acid in soil decreases the adsorption of Pb2＋ onto the soil at solution pH of 8 since the negatively charged humic acid with Pb2＋ is difficult to be adsorbed on the negatively charged soil surface. The adsorption of Pb2＋ onto the soil also decreases in the presence of Cu2＋ due to file competition adsorption between Pb2＋ and Cu2＋.展开更多
基金Supported by the National Natural Science Fund (20947003)~~
文摘[Objective]The aim of this paper was to provide theoretical basis for study on enhancement of surfactants to desorption of PCBs from soil. [Method]The desorption effects of surfactants SDBs,Tween 80,HTAB on PCBs were studied as well as their distribution in water and soil. Effects of rationing on desorption of PCBs were also analyzed. [Result]The potential of single surfactant to enhance the desorption of PCBs from soil in order was Tween 80 SDBS HTAB. Three surfactants were largely adsorbed on soil and the sorption followed HTABTween 80SDBS. The desorption of PCBs increased significantly and linearly with the increase of aqueous micelle concentration of surfactants. [Conclusion]Enhancing effect of three surfactants on PCBs desorption were obtained,which will provide theoretical basis for further analyzing.
基金Project(51164001)supported by the National Natural Science Foundation of ChinaProject(NCET-11-0925)supported by New Century Excellent Talents in University,China
文摘Adsorption of water on sulfide surfaces and natural floatability of sulfide minerals were studied using density functional theory （DFT） method. All computational models were built in a vacuum environment to eliminate the effects of oxygen and other factors. H2O molecule prefers to stay with pyrite and sphalerite surfaces rather than water, whereas for galena, chalcocite, stibnite, and molybdenite, H2O molecule prefers to stay with water rather than the mineral surfaces. On the other hand, pyrite surface favors N2 more than water, while sphalerite surface cannot adsorb N2. These results show that galena, stibnite, chalcocite, and molybdenite are hydrophobic, while sphalerite is hydrophilic. Although pyrite has certain hydrophilicity, it tends to be aerophilic because the reaction of pyrite with H2O is weaker than pyrite with N2. Thus, pyrite, galena, chalcocite, stibnite and molybdenite all have natural floatability.
基金Projects (41073060,21007009,50874032) supported by the National Natural Science Foundation of ChinaProject (B604) supported by Shanghai Leading Academic Discipline Project,ChinaProject (10CG34) supported by Shanghai Municipal Education Commission and Shanghai Education Development Foundation,China
文摘The influencing factors in adsorption such as adsorption time, pulp concentration, bacterial concentration, pH as well as ionic strength were investigated to explore the relationship among them and bacterial adsorption. The adsorption was a rapid process for bacterial adhesion to chalcopyrite. The extent of adsorption increased with increasing initial bacterial concentration and pulp concentration. The optimal pH for Acidithiobacillusferrooxidans adsorption onto chalcopyrite surfaces was in the range of pH 1-3. The increase of ionic strength led to decrease in bacterial adsorption, which can be well explained by electric double layer theory. The adsorption behavior appeared to be controlled by both hydrophobic and electrostatic interactions at the interface of bacteria and mineral,
基金supported by the Knowledge Inno-vation Project of the Chinese Academy of Sciences (KZCX2-YW-416)the National Natural Science Foundation (90411020)
文摘A stdudy was conducted to determine the seasonal changes of soil respiration and the contribution of root respiration to soil respiration in Betula plaophylla forest in Changbai Mountain from May to September in 2004. Results indicated that the total soil respiration, root-severed soil respiration and the root respiration followed a similar seasonal trend, with a high rate in summer due to wet and high temperature and a low rate in spring and autumn due to lower temperature. The mean rates of total soil respiration, root-severed soil respiration and root respiration were 4.44, 2.30 and 2.14 μmol.m^-2.s^-1, respectively during the growing season, and they were all exponentially correlated with temperature. Soil respiration rate had a linear correlation with soil volumetric moisture. The Q10 values for total soil respiration, root-severed soil respiration and root respiration were 2,82, 2.59 and 3. 16, respectively. The contribution rate of root respiration to the total soil respiration was between 29.3% and 58.7% during the growing season, indicating that root is a major component of soil respiration. The annual mean rates of total soil respiration, root-severed soil respiration and root respiration were 1.96, 1.08, and 0.87 μmol.m^-2.s^-1, or 741.73 408.71, and 329.24 g.m^-2.a^-1, respectively. Root respiration contributed 44.4% to the annual total soil respiration. The relationship proposed for soil respiration with soil lemperature was useful for understanding and predicting potential changes in Changbai Mountain B. platyphylla forest ecosystem in response to forest management and climate change.
文摘A comparative study of soil respiration was conducted between in a semi-arid steppe community and in a wet meadow community in the Xilin River Basin of Nei Mongol. The seasonal pattern, the climatic controls, and the correlations of soil respiration with plant biomass components, were examined for each community. The main results are reported as follows: (1) The seasonal changes in soil respiration in the two communities had similar dynamic patterns (both being of two peaks), ranging from 312.8 to 1738.9 mg C(.)m(-2).s(-1) and from 354.6 to 2235.6 Mg C.m(-2).s(-1) in the growing season for the steppe plot and the meadow plot respectively. The soil respiration rate of the meadow plot was distinctly higher than that of the steppe plot, with the daily averages being 1349.6 mg C-m(-2).s(-1) and 785.9 mg C-m(-2).s(-1) respectively. (2) The correlation between soil respiration rate and soil moisture was much more significant than with temperature for the steppe community, and being on the contrary for the meadow community, reflecting the different effects of the two climatic factors in different habitats. Based on these regressive relations, the total CO2 efflux rate in the growing season in 2001 was estimated as 142.4 g C/m(2) in the steppe plot, and 236.1 g C/m(2) in the meadow plot. (3) There was no evident relation between the total canopy biomass and CO2 evolution rate, but a significant power function relation between the live canopy biomass and CO2 evolution rate in the meadow plot was detected. In the steppe plot, there existed only a weak relation between soil respiration and either live or total canopy biomass.
基金Project(2008BAB35B04) supported by the National Key Technology R&D Program of China
文摘Brine,which is used to produce high-purity magnesia,was purified by XSC-700 to remove boron.Boron adsorption capacity of XSC-700 was investigated by varying the initial boron concentration,temperature,resin/brine ratio and stirring speed,while keeping the diameter at constant.The results show that boron adsorption capacity increases with increasing boron concentration,temperature,and decreases with increasing resin/brine ratio.And the stirring speed could slightly affect the boron adsorption capacity.The adsorption kinetics obeys the pseudo-second-order model.Equilibrium data were both examined by Freundlich and Langmuir isotherm equations and it can be well represented by the Freundlich isotherm equation.
基金Supported by the Central-Level Non-Profit Scientific Research Institutes Special Funds(Nos.2014A07XK04,HSY201403)the Harbin Science and Technology Project(No.2012AA6CN037)the National Key Technology Research and Development Program of China(No.2012BAD25B09)
文摘Knowledge of oxygen consumption rates and asphyxiation points in fish is important to determine appropriate stocking and water quality management in aquaculture. The oxygen consumption rate and asphyxiation point in Chanodichthys mongolicus were detected under laboratory conditions using an improved respirometer chamber. The results revealed that more accurate estimates can be obtained by adjusting the volume of the respirometer chamber, which may avoid system errors caused by either repeatedly adjusting fish density or selecting different equipment specifications. The oxygen consumption rate and asphyxiation point of C. mongolicus increased with increasing water temperature and decreasing fish size. Changes in the C. mongolicus oxygen consumption rate were divided into three stages at water temperatures of 11-33~C： （I） a low temperature oxygen consumption rate stage when water temperature was 11-19~C, （2） the optimum temperature oxygen consumption rate stage when water temperature was 19-23~C, and （3） a high temperature oxygen consumption rate stage when water temperature was 〉27~C. The temperature quotients （Q10） obtained suggested that C. mongolicus preferred a temperature range of 19-23~C. At 19~C, C. mongolicus exhibited higher oxygen consumption rates during the day when the maximum values were observed at 10：00 and 14：00 than at night when the minimum occurred at 02：00.
文摘Condensation occurs when the local vapor pressure rises above the saturation vapor pressure at the local temperature in theory. A new measuring apparatus were made to obtain temperature and relative humidity simultaneously for the purpose of investigating the mechanism of condensation occurred on the fabrics. The experiment conducted at the standard condition of temperature of 20℃ and relative humidity of 65%. The result obtained from experiment showed that condensation could occur under the situation closed to saturation line as the temperature on fabric may be lower than dew point of water vapor in the measuring box depending on the experiment conducted at an ambient environment temperature of 20℃ The range of fabrics studied showed that PTFE laminated fabrics except nylon gingham PTFE laminated fabric facilitates the loss of water vapor and therefore prevent condensation. It is necessary to develop studies from a wide range of fabrics, especially breathable fabrics and under bad experiment condition in order to develop fabrics, which could eliminate condensation, or transport water vapor through the fabric while remaining waterproof.
基金Project(SK201109) supported by the Basic Scientific Study Funding from Institute of Hydrogeology and Environmental Geology,Chinese Academy of Geological SciencesProject(2010CB428806-2) supported by the National Basic Research Program of China
文摘Pb2＋ adsorption onto a soil by irrigation of sewage in the Pearl River Delta of South China was examined as a function of the reaction time, solution pH, initial lead concentration, organic matter （humic acid） and competitive ions （Cu2＋）. The adsorption of Pb2＋ onto the soil was investigated on batch equilibrium adsorption experiments. Results show that the Pb2＋ adsorption on the soil is relatively rapid in the first 30 min and reaches equilibrium at 2 h, and the kinetics of the adsorption process on the soil is well characterized by the pseudo-second order reaction rate. Langmuir, Freundlich and Temkin isothermal models are fit for the adsorption of Pb2＋ onto the soil, and the maximum amount of Pb2＋ adsorption （Qm） is 7.47 mg/g. The amount of Pb2＋ adsorption increases with increasing the pH at the range of 1.2-4.5 and reaches a plateau at the range of 4.5-12. The presence of humic acid in soil decreases the adsorption of Pb2＋ onto the soil at solution pH of 8 since the negatively charged humic acid with Pb2＋ is difficult to be adsorbed on the negatively charged soil surface. The adsorption of Pb2＋ onto the soil also decreases in the presence of Cu2＋ due to file competition adsorption between Pb2＋ and Cu2＋.
