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镁铝碱式碳酸盐阻燃剂的热分析及吸热值优化 被引量:2
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作者 任庆利 陈寿田 +1 位作者 罗强 吴洪才 《西安交通大学学报》 EI CAS CSCD 北大核心 2002年第4期353-356,384,共5页
研究了镁铝碱式碳酸盐阻燃剂([Mg_6Al_2(OH)_(16)CO_3] 4H_2O)的热分析及差示扫描量热法(DSC)吸热值的优化.讨论了不同的铝源(分别以AlCl_3、NaAlO_2为铝源)、不同的镁铝摩尔比对... 研究了镁铝碱式碳酸盐阻燃剂([Mg_6Al_2(OH)_(16)CO_3] 4H_2O)的热分析及差示扫描量热法(DSC)吸热值的优化.讨论了不同的铝源(分别以AlCl_3、NaAlO_2为铝源)、不同的镁铝摩尔比对所得镁铝碱式碳酸盐复合阻燃剂的相结构、热分解温度和DSC吸热值的影响.结果表明:原料中铝源的选取对其热分解温度有决定性的影响;在一定范围内,合理的镁铝比可优化DSC吸热值,得到热性能优异的镁铝碱式碳酸盐复合阻燃剂. 展开更多
关键词 镁铝碱式碳酸盐 阻燃剂 热分析 吸热值 优化
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人工神经网络预测镁铝水滑石纳米晶的差示扫描量热法的吸热值 被引量:1
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作者 任庆利 罗强 《硅酸盐学报》 EI CAS CSCD 北大核心 2005年第8期1002-1005,1011,共5页
常压下采用液相法制备了高纯度的镁铝水滑石纳米晶体试样。基于镁铝水滑石的差示扫描量热法(differentialscanningcalorimetry,DSC)吸热值和水滑石纳米晶体的制备工艺因素(包括:反应时间,反应温度,以及原料NaOH,MgCl2,Na2CO3,和NaAlO2... 常压下采用液相法制备了高纯度的镁铝水滑石纳米晶体试样。基于镁铝水滑石的差示扫描量热法(differentialscanningcalorimetry,DSC)吸热值和水滑石纳米晶体的制备工艺因素(包括:反应时间,反应温度,以及原料NaOH,MgCl2,Na2CO3,和NaAlO2的添加浓度)之间的非线性关系,建立三层结构的反向误差传播(back-propagation,BP)网络。为克服由于BP神经网络隐含层的存在,增加训练的工作量,以及当输入的参变量较多时,导致误差曲面过于复杂,出现数据冗余的缺点,尝试了采用主成分分析,对输入变景首先进行预处理。同时,在迭代公式中附加动量项和变换收敛步长,以加快网络训练速度,提高模型的预测能力与相对准确性。计算结果表明:使用改进的BP神经网络模型,对镁铝水滑石纳米晶体的DSC吸热值有较好的预测能力。 展开更多
关键词 镁铝水滑石 差示扫描量热法吸热值 反向传播 神经网络
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镁铝复合阻燃剂热分析研究 被引量:5
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作者 李克民 舒永爱 杨凤兰 《化学世界》 CAS CSCD 1996年第4期181-184,共4页
适当改变镁铝摩尔比等工艺条件,所制得的镁铝复合阻燃剂具有不同的热分解温度,其DSC吸热值也各异。文章对镁铝复合阻燃剂的热分解过程加以分析,指出了不同制备工艺条件对所制成的样品热分解行为的影响,认为镁铝复合阻燃剂的热分... 适当改变镁铝摩尔比等工艺条件,所制得的镁铝复合阻燃剂具有不同的热分解温度,其DSC吸热值也各异。文章对镁铝复合阻燃剂的热分解过程加以分析,指出了不同制备工艺条件对所制成的样品热分解行为的影响,认为镁铝复合阻燃剂的热分解温度可根据实际需要,人为地加以控制。 展开更多
关键词 热分解温度 复合阻燃剂 DSC吸热值
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Phosphate Adsorption and Surface Charge Characteristics and Their Relations to Mineralogy of Some Soils from Southern China
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作者 ZHANG MINGKUI M. J. WILSON +1 位作者 HE ZHENLI L. CLARK and D. M. L. DUTHIE (Department of Soil Science and Agricultural Chemistry, Zhejiang Agricultural University, Hanyzhou 310029 China) (Soils and Soil Microbiolopy Division, Macaulay Land Use Research Institu 《Pedosphere》 SCIE CAS CSCD 1998年第4期297-304,共8页
The phosphate adsorption and surface charge characteristics of the tropical and subtropical soils derived from different parent materials in China were determined, and their relations to soil mineralogy were analysed.... The phosphate adsorption and surface charge characteristics of the tropical and subtropical soils derived from different parent materials in China were determined, and their relations to soil mineralogy were analysed.The results showed that all soil phosphate adsorption curves were well fitted by Freundlich equation and Langmuir equation. The maximum buffering capacity of P ranged from 66 to 9880 mg kg-1, with an increasing order of purple soil, skeletal soil, red soil, lateritic red soil, yellow soil and latosol; and the highest value was 149 times the lowest value, which indicated great differences among these soils in phosphate adsorption and supplying characteristics. The pHo (zero point of charge) values obtained by salt titrationpotential titration varied from 3.03 to 5.49, and the highest value was found in the latosol derived from basalt whereas the lowest value was found in the purple soil. The correlation analysis indicated that the main minerals responsible for phosphate adsorption in the soils were gibbsite, amorphous iron oxide and kaolinite; and the pHo was mainly controlled by kaolinite, gibbsite and oxides. 展开更多
关键词 MINERALOGY pH_0 phosphate adsorption tropical and subtropical soils
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Numerical Simulation of Two-Phase Closed Thermosyphon
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作者 G.V. Kuznetsov M.A. Al-Ani M.A. Sheremet 《Journal of Energy and Power Engineering》 2011年第3期227-232,共6页
Heat transfer and hydrodynamics of two phase closed thermosyphon (TPCT) is studied using finite difference method of Stream function and vorticity. The mathematical model is formed for both vapor phase and liquid fi... Heat transfer and hydrodynamics of two phase closed thermosyphon (TPCT) is studied using finite difference method of Stream function and vorticity. The mathematical model is formed for both vapor phase and liquid film in a non-dimensional form. The momentum and energy equations as parabolic equations have been solved by means of the locally one-dimensional scheme of A.A. Samarskii. The Poisson equation for the stream function has been approximated on the basis of the discrete scheme "cross". The obtained system of algebraic equations has been solved by the successive over relaxation method. The effect of the Rayleigh number on the velocity and temperature fields in the domain of interest and on the average Nusselt number at the solid-fluid interfaces is investigated. It was found that increase in the Rayleigh number leads to the increment of both the average Nusselt number and the stream function in the vapor zone. 展开更多
关键词 Mathematical simulation two-phase thermosyphon conjugate heat transfer hydrodynamics.
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