We built a three-dimensional irregular network model which can adequately describe reservoir rock pore-throat structures. We carried out numerical simulations to study the NMR T2 distribution of water-saturated rocks....We built a three-dimensional irregular network model which can adequately describe reservoir rock pore-throat structures. We carried out numerical simulations to study the NMR T2 distribution of water-saturated rocks. The results indicate that there is a good correlation between T2 distribution and the pore radius frequency histogram. The total T2 distribution can be partitioned into pore body and pore throat parts. The effect of parameters including throat radius, pore-throat ratio, and coordination number of the micro- pore structure on the T2 distribution can be evaluated individually. The result indicates that： 1 ） with the increase of the pore throat radius, the T2 distribution moves toward longer relaxation times and its peak intensity increases; 2） with the increase of the pore-throat ratio, the T2 distribution moves towards longer T2 with the peak intensity increasing and the overlap between pore body T2 and pore throat T2 decreasing; 3） With the increase of connectivity, the short T2 component increases and peak signal intensity decreases slightly.展开更多
Membrane-based separation processes are new technology combined membrane separation with conventional separation. Hydrophobic porous membranes are often used in these processes. The structure of hydrophobic porous mem...Membrane-based separation processes are new technology combined membrane separation with conventional separation. Hydrophobic porous membranes are often used in these processes. The structure of hydrophobic porous membrane has significant effect on mass transfer process. The permeabilities of five kinds of gas, He, N2, O2, CO2 and water vapor, across six polytetrafluoroethylene(PTFE) flat membranes were tested experimentally. Results indicated that the greater the membrane mean pore size and the wider the pore size distribution are, the higher the gas permeability. A gas permeation model, including the effects of membrane structure parameter and gas properties, was established. A comprehensive characteristic parameter (including porosity, thickness and tortuosity) was found more effective to express the influence of membrane structure in gas permeation process. The predicted permeation coefficients were in good agreement with experimental data.展开更多
A Y-zeolite-containing composite material with micro/mesoporous structure had been synthesized from kaolin by means of the in-situ crystallization method. The obtained samples were investigated by XRD and BET methods....A Y-zeolite-containing composite material with micro/mesoporous structure had been synthesized from kaolin by means of the in-situ crystallization method. The obtained samples were investigated by XRD and BET methods. Evaluation of catalytic activity of both the commercial Y-zeolite and the novel Y-zeolite-containing composite material was carried out in the pulse micro-chromatography platform with two probe molecules of different molecular sizes： VGO feedstock and 1,3,5 tri-isopropyl benzene. It was found that the Y-zeolite-containing composite material was richer in external surface and meso-/macro-pores; the Y-zeolite-containing composite material demonstrated a smaller rate of deactivation compared to the commercial Y-zeolite.展开更多
To promote gas extraction in low-rank high-gas coal beds, the pore structure characteristics of the coal and their effect on gas desorption were studied. The results show that micropores are relatively rare in low-ran...To promote gas extraction in low-rank high-gas coal beds, the pore structure characteristics of the coal and their effect on gas desorption were studied. The results show that micropores are relatively rare in low-rank coal; mesopores are usually semi-open and inkpot-shaped whereas macropores are usually slit-shaped. Gas desorption is relatively easy at high- pressure stages, whereas it is difficult at low-pressure stages because of the ＇bottleneck effect＇ of the semi-open inkpot-shaped mesopores. A ＇two-three-two＇ gas extraction model was established following experimental analysis and engineering practice applied in the Binchang mining area. In this model, gas extraction is divided into three periods： a planning period, a transitional period and a production period. In each period, surface extraction and underground extraction are performed simultaneously, and pressure-relief extraction and conventional extraction are coupled to each other. After applying this model, the gas extraction rate rose to 78.8 %.展开更多
Determination of water saturation is important for reservoir evaluation. When complex pore structures such as fracture and cavity are present in reservoir, Archie equation is no longer suitable. According to different...Determination of water saturation is important for reservoir evaluation. When complex pore structures such as fracture and cavity are present in reservoir, Archie equation is no longer suitable. According to different models of pore structure division, the authors studied water saturation conlputation models. The results show that dual porosity system is divided into four models. The first model is based on dual laterolog, the second is Dual Porosity I , the third is Dual Porosity Ⅱ , and the last one is based on the conductive pore. Besides, the triple porosity system is triple porosity model. Compute water saturation was using all the above five models in volcanic reservoir in Songnan gas field. The triple porosity system is the most suitable model for water saturation computation in complex pore structure volcanic reservoir.展开更多
In order to improve the quality of laneways and tunnel excavation by drilling and blasting and by making effective use of explosive energy, a model experiment of rock blasting with a single borehole and a double free-...In order to improve the quality of laneways and tunnel excavation by drilling and blasting and by making effective use of explosive energy, a model experiment of rock blasting with a single borehole and a double free-surface was performed with the objective of studying the effect of parameters such as charge structure, free-surface and rock compressive strength on rock blasting.The model experiments indicate that:1) the smaller the rock compressive strength and density, the more distinctive the cavity expanding action by blasting;2) the powder factor in an air-decoupling charge structure is larger than that in a coupling charge structure, i.e., the explosive energy in an air-decoupling charge structure transferred to the rocks is less than that in a coupling charge structure;3) a free-surface improves the utilizations of explosive energy;4) an air-decoupling charge structure helps to maintain the integrity and stability of wall rock in controlled perimeter blasting, such as in roadways and tunnel excavation by drilling and blasting.展开更多
Porous sol-gel glass of CaO-SiO2-P2O5 system with macropores larger than 100 μm was prepared by adding stearic acid as pore former when the sintering was carried out at 700 ℃ for 3h.The sol-gel porous glass shows an...Porous sol-gel glass of CaO-SiO2-P2O5 system with macropores larger than 100 μm was prepared by adding stearic acid as pore former when the sintering was carried out at 700 ℃ for 3h.The sol-gel porous glass shows an amorphous structure. The diameter of the pore created by pore former varies from 100 to 300 μm, and macroporous glass has a narrow and small pore size distribution in mesoporous scale. The porosity and pore size of macroporous bioactive glass can be controlled.展开更多
The spatial structure characteristics of landform are the foundation of geomorphologic classification and recognition.This paper proposed a new method on quantifying spatial structure characteristics of terrain surfac...The spatial structure characteristics of landform are the foundation of geomorphologic classification and recognition.This paper proposed a new method on quantifying spatial structure characteristics of terrain surface based on improved 3D Lacunarity model.Lacunarity curve and its numerical integration are used in this model to improve traditional classification result that different morphological types may share the close value of indexes based on global statistical analysis.Experiments at four test areas with different landform types show that improved 3D Lacunarity model can effectively distinguish different morphological types per texture analysis.Higher sensitivity in distinguishing the tiny differences of texture characteristics of terrain surface shows that the quantification method by 3D Lacu-narity model and its numerical integration presented in this paper could contribute to improving the accuracy of land-form classifications and relative studies.展开更多
Permeability is one of the key issues in the design of molds and in the molding process for composite manufacture. As a disordered fibrous assembly, 2.5- dimension （2.5 D） woven reinforcement materials have complex ...Permeability is one of the key issues in the design of molds and in the molding process for composite manufacture. As a disordered fibrous assembly, 2.5- dimension （2.5 D） woven reinforcement materials have complex structure. It poses a challenge to the study of pore structure and the establishment of the theoretical permeability model. Toward addressing this problem, a powerful tool called fractal theory emerged. According to the analysis of 2.5 D woven reinforcement material stmcture using fractal theory, it is found that the structure has an obvious fractal character. Therefore, a permeability fractal model of 2.5D woven reinforcement material was established by cormbining the Hagen-Poiseulle equation with Darcy law according to the capillary vessel fractal model in this paper. The permeability was expressed as a function of the fractal dimension and microstructure parameter of the porous media in this model. The theoretical model is verified by experimental tests and the measurement data are in good agreement with the results obtained from the fractal medel .展开更多
Adsorption process is acknowledged as an effective option for phenolic wastewater treatment. In this work, the activated carbon （AC） samples after thermal modification were prepared by using muffle furnace. The phen...Adsorption process is acknowledged as an effective option for phenolic wastewater treatment. In this work, the activated carbon （AC） samples after thermal modification were prepared by using muffle furnace. The phenol ad- sorption kinetics and equilibrium measurements were carried out under static conditions at temperature ranging from 25 to 55 ~C. The test results show that the thermal modification can enhance phenol adsorption on AC samples. The porous structure and surface chemistry analyses indicate that the decay in pore morphology and decrease of total oxygen-containing functional groups are found for the thermal modified AC samples. Thus, it can be further inferred that the decrease of total oxygen-containing functional groups on the modified AC sam- ples is the main reason for the enhanced phenol adsorption capacity. For both the raw sample and the optimum modified AC sample at 900 ~C, the pseudo-second order kinetics and Langmuir models are found to fit the exper- imental data very well. The maximum phenol adsorption capacity of the optimum modified AC sample can reach 144,93 mg.g ~ which is higher than that of the raw sample, i.e. 119.53 mg.g 1. Adsorption thermodynamics analysis confirms that the phenol adsorption on the optimum modified AC sample is an exothermic process and mainly via physical adsorption.展开更多
According to the law of conservation in the state of turbulent flow, the differential equation describing the airflow temperature distribution in drifting tunnel is derived, By theoretical analysis and field measureme...According to the law of conservation in the state of turbulent flow, the differential equation describing the airflow temperature distribution in drifting tunnel is derived, By theoretical analysis and field measurement of the airflow and thermal process in mine, theoretical analysis and systematic flow are developed. By PHONENICS program, the numerical simulation is processed, and the changing rule of airflow temperature with various parameters in drifting tunnel is derived. The airflow temperature in drifting tunnel decreases as the airflow velocity increases in a way of negative power exponent, and elevates linearly as the temperature of the incoming airflow elevates.展开更多
In recent years,the Yanchang shale-oil formations of the Ordos Basin are rich in reserves with complex lithology and structure characteristics,low porosity and low permeability,and weak anomalies for oil and water dis...In recent years,the Yanchang shale-oil formations of the Ordos Basin are rich in reserves with complex lithology and structure characteristics,low porosity and low permeability,and weak anomalies for oil and water discriminations,have been the key targets of unconventional oil/gas resource exploration and development in the relevant areas.The joint acoustic-electrical(AE)properties can be used to interpret reservoir lithology,mineralogy,pore structure,and fluid saturation.To conduct tests of thin section analysis,X-ray diff raction,and ultrasonic and electrical experiments at diff erent pressures and saturation degrees,cores from the shale-oil formations in the Q area of the basin are collected.The variations in AE properties with respect to clay content,porosity,pressure(microfracture),and saturation are analyzed.The experimental results indicate that the rock physics behaviors of sandstones with diff erent clay contents vary significantly.The AE properties of clean sandstones are basically dependent on the microfractures(pressure),while for muddy sandstones,the clay content is an important factor affecting the responses.The target reservoir consists of interbedded sandstone and shale layers.The AE equivalent medium equations and the Gurevich theory are applied to establish the joint models for the diff erent lithologies and simulate the variations in AE properties with respect to fluid type,pore structure,and mineral components.The three-dimensional joint templates of clean and muddy sandstones,as well as shale,are developed based on the elastic and electrical attributes and then calibrated using the experimental and well-log data.The reservoir properties are estimated with the templates and validated by the log data.The results indicate that the joint templates based on lithology characteristics can eff ectively characterize the properties of interbedded sandstone and shale layers.Furthermore,the combined application of AE data provides more beneficial information for the assessment of rock properties,leading to precise estimates that conform with the actual formation conditions.展开更多
The oil-pressboard insulation is a typical composite insulation system widely used in the design and manufactory of large power apparatus. The implement of oil-pressboard insulation may lead to surface electrification...The oil-pressboard insulation is a typical composite insulation system widely used in the design and manufactory of large power apparatus. The implement of oil-pressboard insulation may lead to surface electrification and discharge at the interface under certain condition. It is of significant importance to take an insight into the phenomenon occurring at the interface. Through experiment, the pressboard is found as a porous material. The interface changes abruptly from bulk pressboard to the bulk oil as a result of the porous structure. A new model is proposed which divides the interface into bulk oil region, transition region, and bulk pressboard region. The width of the transition region is decided according to the microtome figure. The effective permittivity of the transition region is calculated using a new model based on fractal theory. The model is validated and compared with previous calculation model. The effect of the existence of transition region on the electric field distribution is discussed.展开更多
Conversion-type anode materials hold great potential for Li+storage applications owing to their high specific capacity,while large volume expansion and poor electrical conductivity limit their rate and cycling perform...Conversion-type anode materials hold great potential for Li+storage applications owing to their high specific capacity,while large volume expansion and poor electrical conductivity limit their rate and cycling performances.Herein,a bimetal ZnMn-based metal-organic framework(ZnMn-MOF)is engineered for in situ conversion of MnO-encapsulated porous carbon(MnO/PC)composite.The templating and activation effects of coordinated Zn endow the converted PC matrix with a highly porous structure.This enhances the compatibility of PC matrix with MnO particles,resulting in the full encapsulation of MnO particles in the PC matrix.More significantly,the PC matrix provides enough void space to buffer the volume change,which fully wraps the MnO without crack or fracture during repeated cycling.As a result,MnO/PC shows high charge storage capability,extraordinary rate performance,and long-term cycling stability at the same time.Thus MnO/PC exhibits high delithiation capacities of 768mA h g^(-1)at 0.1Ag^(-1)and 487mA h g^(-1)at a high rate of 0.7Ag^(-1),combined with an unattenuated cycling performance after 500 cycles at 0.3Ag^(-1).More significantly,MnO/PC demonstrates a well-matched performance with the capacitive activated carbon electrode in a Li-ion capacitor(LIC)full cell.LIC demonstrates a high specific energy of 153.6W h kg^(-1)at 210W kg^(-1),combined with a specific energy of 71.8W h kg^(-1)at a high specific power of 63.0kW kg^(-1).展开更多
The pore structures and controlling factors of several different Paleozoic shales from Southern China and their kerogens were studied using nitrogen adsorption and scanning electron microscopy methods. The results ind...The pore structures and controlling factors of several different Paleozoic shales from Southern China and their kerogens were studied using nitrogen adsorption and scanning electron microscopy methods. The results indicate that： 1） The specific surface area is 2.22-3.52 m2/g and has no correlation with the TOC content of the Permian Dalong Formation shales, nanopores are extremely undeveloped in the Dalong Formation kerogens, which have specific surface areas of 20.35-27.49 me/g; 2） the specific surface area of the Silurian Longmaxi Formation shales is in the range of 17.83-29.49 m2/g and is positively correlated with TOC content, the kerogens from the Longmaxi Formation have well-developed nanopores, with round or elliptical shapes, and the specific surface areas of these kerogens are as high as 279.84-300.3 m2/g; 3） for the Niutitang Formation shales, the specific surface area is 20.12-29.49 m2/grock and increases significantly with increasing TOC and smectite content. The Niuti- tang Formation kerogens develop a certain amount of nanopores with a specific surface area of 161.2 m2/g. Oil shale was also examined for comparison, and was found to have a specific surface area of 19.99 m2/g. Nanopores are rare in the Youganwo Formation kerogen, which has a specific surface area of only 5.54 m2/g, suggesting that the specific surface area of oil shale is due mainly to the presence of smectite and other clay minerals. The specific surface area and the number of pores present in shales are closely related to TOC, kerogen type and maturity, smectite content, and other factors. Low-maturity kerogen has very few nanopores and therefore has a very low specific surface area, whereas nanopores are abundant in mature to over- mature kerogen, leading to high specific surface areas. The Longmaxi Formation kerogen has more developed nanopores and a higher specific surface area than the Niutitang Formation kerogen, which may be due to differences in the kerogen type and maceral components. A high content of smectite may also contribute to shale surface area. The pore volume and specific sur- face area of low-maturity kerogens are mainly attributable to pores with diameters above 10 nm. By contrast, the pore volume of mature kerogens consists predominantly of pores with diameters above 10 nm with some contribution from about 4 nm diameter pores, while the specific surface area is due mainly to pores with diameters of less than 4 nm. Through a comparative study of the specific surface area and pore structure characteristics of different shales and their kerogens, we conclude that the Longmaxi Formation shales and Niutitang Formation shales have greater sorption capacities than the Dalong Formation shales.展开更多
文摘We built a three-dimensional irregular network model which can adequately describe reservoir rock pore-throat structures. We carried out numerical simulations to study the NMR T2 distribution of water-saturated rocks. The results indicate that there is a good correlation between T2 distribution and the pore radius frequency histogram. The total T2 distribution can be partitioned into pore body and pore throat parts. The effect of parameters including throat radius, pore-throat ratio, and coordination number of the micro- pore structure on the T2 distribution can be evaluated individually. The result indicates that： 1 ） with the increase of the pore throat radius, the T2 distribution moves toward longer relaxation times and its peak intensity increases; 2） with the increase of the pore-throat ratio, the T2 distribution moves towards longer T2 with the peak intensity increasing and the overlap between pore body T2 and pore throat T2 decreasing; 3） With the increase of connectivity, the short T2 component increases and peak signal intensity decreases slightly.
基金Supported by the 863 Hi-Tech. Research and Development Program of China (No. 2002AA649280, No. 2002AA304030),National Natural Science Foundation of China (No. 20206002), Beijing NOVA program (H013610250112), University Doctor Science Foundation of China
文摘Membrane-based separation processes are new technology combined membrane separation with conventional separation. Hydrophobic porous membranes are often used in these processes. The structure of hydrophobic porous membrane has significant effect on mass transfer process. The permeabilities of five kinds of gas, He, N2, O2, CO2 and water vapor, across six polytetrafluoroethylene(PTFE) flat membranes were tested experimentally. Results indicated that the greater the membrane mean pore size and the wider the pore size distribution are, the higher the gas permeability. A gas permeation model, including the effects of membrane structure parameter and gas properties, was established. A comprehensive characteristic parameter (including porosity, thickness and tortuosity) was found more effective to express the influence of membrane structure in gas permeation process. The predicted permeation coefficients were in good agreement with experimental data.
文摘A Y-zeolite-containing composite material with micro/mesoporous structure had been synthesized from kaolin by means of the in-situ crystallization method. The obtained samples were investigated by XRD and BET methods. Evaluation of catalytic activity of both the commercial Y-zeolite and the novel Y-zeolite-containing composite material was carried out in the pulse micro-chromatography platform with two probe molecules of different molecular sizes： VGO feedstock and 1,3,5 tri-isopropyl benzene. It was found that the Y-zeolite-containing composite material was richer in external surface and meso-/macro-pores; the Y-zeolite-containing composite material demonstrated a smaller rate of deactivation compared to the commercial Y-zeolite.
基金Acknowledgments The research was supported by the National Basic Research Programme of China （973 Project） （2011CB201205）, National Natural Science Foundation of China （51474211）, and the National Key Technology R＆D Program （2012BAK04B07）.
文摘To promote gas extraction in low-rank high-gas coal beds, the pore structure characteristics of the coal and their effect on gas desorption were studied. The results show that micropores are relatively rare in low-rank coal; mesopores are usually semi-open and inkpot-shaped whereas macropores are usually slit-shaped. Gas desorption is relatively easy at high- pressure stages, whereas it is difficult at low-pressure stages because of the ＇bottleneck effect＇ of the semi-open inkpot-shaped mesopores. A ＇two-three-two＇ gas extraction model was established following experimental analysis and engineering practice applied in the Binchang mining area. In this model, gas extraction is divided into three periods： a planning period, a transitional period and a production period. In each period, surface extraction and underground extraction are performed simultaneously, and pressure-relief extraction and conventional extraction are coupled to each other. After applying this model, the gas extraction rate rose to 78.8 %.
基金Supported by the National Natural Science Foundation of China(No.41174096)
文摘Determination of water saturation is important for reservoir evaluation. When complex pore structures such as fracture and cavity are present in reservoir, Archie equation is no longer suitable. According to different models of pore structure division, the authors studied water saturation conlputation models. The results show that dual porosity system is divided into four models. The first model is based on dual laterolog, the second is Dual Porosity I , the third is Dual Porosity Ⅱ , and the last one is based on the conductive pore. Besides, the triple porosity system is triple porosity model. Compute water saturation was using all the above five models in volcanic reservoir in Songnan gas field. The triple porosity system is the most suitable model for water saturation computation in complex pore structure volcanic reservoir.
文摘In order to improve the quality of laneways and tunnel excavation by drilling and blasting and by making effective use of explosive energy, a model experiment of rock blasting with a single borehole and a double free-surface was performed with the objective of studying the effect of parameters such as charge structure, free-surface and rock compressive strength on rock blasting.The model experiments indicate that:1) the smaller the rock compressive strength and density, the more distinctive the cavity expanding action by blasting;2) the powder factor in an air-decoupling charge structure is larger than that in a coupling charge structure, i.e., the explosive energy in an air-decoupling charge structure transferred to the rocks is less than that in a coupling charge structure;3) a free-surface improves the utilizations of explosive energy;4) an air-decoupling charge structure helps to maintain the integrity and stability of wall rock in controlled perimeter blasting, such as in roadways and tunnel excavation by drilling and blasting.
基金Project(50174059) supported by the National Natural Science Foundation of China
文摘Porous sol-gel glass of CaO-SiO2-P2O5 system with macropores larger than 100 μm was prepared by adding stearic acid as pore former when the sintering was carried out at 700 ℃ for 3h.The sol-gel porous glass shows an amorphous structure. The diameter of the pore created by pore former varies from 100 to 300 μm, and macroporous glass has a narrow and small pore size distribution in mesoporous scale. The porosity and pore size of macroporous bioactive glass can be controlled.
基金Under the auspices of National Natural Science Foundation of China (No.40930531,41171320,41001301)
文摘The spatial structure characteristics of landform are the foundation of geomorphologic classification and recognition.This paper proposed a new method on quantifying spatial structure characteristics of terrain surface based on improved 3D Lacunarity model.Lacunarity curve and its numerical integration are used in this model to improve traditional classification result that different morphological types may share the close value of indexes based on global statistical analysis.Experiments at four test areas with different landform types show that improved 3D Lacunarity model can effectively distinguish different morphological types per texture analysis.Higher sensitivity in distinguishing the tiny differences of texture characteristics of terrain surface shows that the quantification method by 3D Lacu-narity model and its numerical integration presented in this paper could contribute to improving the accuracy of land-form classifications and relative studies.
基金Science and Technology Support Program of Jiangsu Province of China(No.BE2008017)
文摘Permeability is one of the key issues in the design of molds and in the molding process for composite manufacture. As a disordered fibrous assembly, 2.5- dimension （2.5 D） woven reinforcement materials have complex structure. It poses a challenge to the study of pore structure and the establishment of the theoretical permeability model. Toward addressing this problem, a powerful tool called fractal theory emerged. According to the analysis of 2.5 D woven reinforcement material stmcture using fractal theory, it is found that the structure has an obvious fractal character. Therefore, a permeability fractal model of 2.5D woven reinforcement material was established by cormbining the Hagen-Poiseulle equation with Darcy law according to the capillary vessel fractal model in this paper. The permeability was expressed as a function of the fractal dimension and microstructure parameter of the porous media in this model. The theoretical model is verified by experimental tests and the measurement data are in good agreement with the results obtained from the fractal medel .
基金Supported by the National Natural Science Foundation of China(41302132)Training Programmes of Innovation and Entrepreneurship for Undergraduates of Yunnan Province(Grant No.201510674042)the Introduced Talents Foundation of Kunming University of Science and Technology(KKSY201205160)
文摘Adsorption process is acknowledged as an effective option for phenolic wastewater treatment. In this work, the activated carbon （AC） samples after thermal modification were prepared by using muffle furnace. The phenol ad- sorption kinetics and equilibrium measurements were carried out under static conditions at temperature ranging from 25 to 55 ~C. The test results show that the thermal modification can enhance phenol adsorption on AC samples. The porous structure and surface chemistry analyses indicate that the decay in pore morphology and decrease of total oxygen-containing functional groups are found for the thermal modified AC samples. Thus, it can be further inferred that the decrease of total oxygen-containing functional groups on the modified AC sam- ples is the main reason for the enhanced phenol adsorption capacity. For both the raw sample and the optimum modified AC sample at 900 ~C, the pseudo-second order kinetics and Langmuir models are found to fit the exper- imental data very well. The maximum phenol adsorption capacity of the optimum modified AC sample can reach 144,93 mg.g ~ which is higher than that of the raw sample, i.e. 119.53 mg.g 1. Adsorption thermodynamics analysis confirms that the phenol adsorption on the optimum modified AC sample is an exothermic process and mainly via physical adsorption.
文摘According to the law of conservation in the state of turbulent flow, the differential equation describing the airflow temperature distribution in drifting tunnel is derived, By theoretical analysis and field measurement of the airflow and thermal process in mine, theoretical analysis and systematic flow are developed. By PHONENICS program, the numerical simulation is processed, and the changing rule of airflow temperature with various parameters in drifting tunnel is derived. The airflow temperature in drifting tunnel decreases as the airflow velocity increases in a way of negative power exponent, and elevates linearly as the temperature of the incoming airflow elevates.
基金supported by the National Natural Science Foundation of China (Nos.41974123,42174161)the Jiangsu Innovation and Entrepreneurship Plan and the Jiangsu Province Science Fund for Distinguished Young Scholars (grant no.BK20200021).
文摘In recent years,the Yanchang shale-oil formations of the Ordos Basin are rich in reserves with complex lithology and structure characteristics,low porosity and low permeability,and weak anomalies for oil and water discriminations,have been the key targets of unconventional oil/gas resource exploration and development in the relevant areas.The joint acoustic-electrical(AE)properties can be used to interpret reservoir lithology,mineralogy,pore structure,and fluid saturation.To conduct tests of thin section analysis,X-ray diff raction,and ultrasonic and electrical experiments at diff erent pressures and saturation degrees,cores from the shale-oil formations in the Q area of the basin are collected.The variations in AE properties with respect to clay content,porosity,pressure(microfracture),and saturation are analyzed.The experimental results indicate that the rock physics behaviors of sandstones with diff erent clay contents vary significantly.The AE properties of clean sandstones are basically dependent on the microfractures(pressure),while for muddy sandstones,the clay content is an important factor affecting the responses.The target reservoir consists of interbedded sandstone and shale layers.The AE equivalent medium equations and the Gurevich theory are applied to establish the joint models for the diff erent lithologies and simulate the variations in AE properties with respect to fluid type,pore structure,and mineral components.The three-dimensional joint templates of clean and muddy sandstones,as well as shale,are developed based on the elastic and electrical attributes and then calibrated using the experimental and well-log data.The reservoir properties are estimated with the templates and validated by the log data.The results indicate that the joint templates based on lithology characteristics can eff ectively characterize the properties of interbedded sandstone and shale layers.Furthermore,the combined application of AE data provides more beneficial information for the assessment of rock properties,leading to precise estimates that conform with the actual formation conditions.
基金Project(2009CB724504)supported by the National Basic Research Program of China
文摘The oil-pressboard insulation is a typical composite insulation system widely used in the design and manufactory of large power apparatus. The implement of oil-pressboard insulation may lead to surface electrification and discharge at the interface under certain condition. It is of significant importance to take an insight into the phenomenon occurring at the interface. Through experiment, the pressboard is found as a porous material. The interface changes abruptly from bulk pressboard to the bulk oil as a result of the porous structure. A new model is proposed which divides the interface into bulk oil region, transition region, and bulk pressboard region. The width of the transition region is decided according to the microtome figure. The effective permittivity of the transition region is calculated using a new model based on fractal theory. The model is validated and compared with previous calculation model. The effect of the existence of transition region on the electric field distribution is discussed.
基金supported by the National Natural Science Foundation of China(21905148)China Postdoctoral Science Foundation(2019T120567 and 2017M612184)+2 种基金the 1000-Talents Planthe World-Class Discipline Programthe Taishan Scholars Advantageous and Distinctive Discipline Program of Shandong province for supporting the research team of energy storage materials.
文摘Conversion-type anode materials hold great potential for Li+storage applications owing to their high specific capacity,while large volume expansion and poor electrical conductivity limit their rate and cycling performances.Herein,a bimetal ZnMn-based metal-organic framework(ZnMn-MOF)is engineered for in situ conversion of MnO-encapsulated porous carbon(MnO/PC)composite.The templating and activation effects of coordinated Zn endow the converted PC matrix with a highly porous structure.This enhances the compatibility of PC matrix with MnO particles,resulting in the full encapsulation of MnO particles in the PC matrix.More significantly,the PC matrix provides enough void space to buffer the volume change,which fully wraps the MnO without crack or fracture during repeated cycling.As a result,MnO/PC shows high charge storage capability,extraordinary rate performance,and long-term cycling stability at the same time.Thus MnO/PC exhibits high delithiation capacities of 768mA h g^(-1)at 0.1Ag^(-1)and 487mA h g^(-1)at a high rate of 0.7Ag^(-1),combined with an unattenuated cycling performance after 500 cycles at 0.3Ag^(-1).More significantly,MnO/PC demonstrates a well-matched performance with the capacitive activated carbon electrode in a Li-ion capacitor(LIC)full cell.LIC demonstrates a high specific energy of 153.6W h kg^(-1)at 210W kg^(-1),combined with a specific energy of 71.8W h kg^(-1)at a high specific power of 63.0kW kg^(-1).
基金supported by National Basic Research Program of China(Grant No.2012CB214704)Major National Science and Techno-logy Project(Grant No.2011ZX05008-002-20)National Natural Science Foundation of China(Grant No.4123058)
文摘The pore structures and controlling factors of several different Paleozoic shales from Southern China and their kerogens were studied using nitrogen adsorption and scanning electron microscopy methods. The results indicate that： 1） The specific surface area is 2.22-3.52 m2/g and has no correlation with the TOC content of the Permian Dalong Formation shales, nanopores are extremely undeveloped in the Dalong Formation kerogens, which have specific surface areas of 20.35-27.49 me/g; 2） the specific surface area of the Silurian Longmaxi Formation shales is in the range of 17.83-29.49 m2/g and is positively correlated with TOC content, the kerogens from the Longmaxi Formation have well-developed nanopores, with round or elliptical shapes, and the specific surface areas of these kerogens are as high as 279.84-300.3 m2/g; 3） for the Niutitang Formation shales, the specific surface area is 20.12-29.49 m2/grock and increases significantly with increasing TOC and smectite content. The Niuti- tang Formation kerogens develop a certain amount of nanopores with a specific surface area of 161.2 m2/g. Oil shale was also examined for comparison, and was found to have a specific surface area of 19.99 m2/g. Nanopores are rare in the Youganwo Formation kerogen, which has a specific surface area of only 5.54 m2/g, suggesting that the specific surface area of oil shale is due mainly to the presence of smectite and other clay minerals. The specific surface area and the number of pores present in shales are closely related to TOC, kerogen type and maturity, smectite content, and other factors. Low-maturity kerogen has very few nanopores and therefore has a very low specific surface area, whereas nanopores are abundant in mature to over- mature kerogen, leading to high specific surface areas. The Longmaxi Formation kerogen has more developed nanopores and a higher specific surface area than the Niutitang Formation kerogen, which may be due to differences in the kerogen type and maceral components. A high content of smectite may also contribute to shale surface area. The pore volume and specific sur- face area of low-maturity kerogens are mainly attributable to pores with diameters above 10 nm. By contrast, the pore volume of mature kerogens consists predominantly of pores with diameters above 10 nm with some contribution from about 4 nm diameter pores, while the specific surface area is due mainly to pores with diameters of less than 4 nm. Through a comparative study of the specific surface area and pore structure characteristics of different shales and their kerogens, we conclude that the Longmaxi Formation shales and Niutitang Formation shales have greater sorption capacities than the Dalong Formation shales.
