In order to better understand the prevailing mechanism of CO2 storage in coal and estimate CO2 sequestration capacity of a coal seam and enhanced coalbed methane recovery （ECBM） with CO2 injection into coal, we inve...In order to better understand the prevailing mechanism of CO2 storage in coal and estimate CO2 sequestration capacity of a coal seam and enhanced coalbed methane recovery （ECBM） with CO2 injection into coal, we investigated the preferential adsorption of CH4 and CO2 on coals. Adsorption of pure CO2, CH4 and their binary mixtures on high-rank coals from Qinshui Basin in China were employed to study the preferential adsorption behaviour. Multiple regression equations were presented to predict CH4 equi- librium concentration from equilibrium pressure and its initial-composition in feed gas. The results show that preferential adsorption of CO2 on coals over the entire pressure range under competitive sorption conditions was observed, however, preferential adsorption of CH4 over CO2 on low-volatile bituminous coal from higher CH4-compostion in source gas was found at up to 1O MPa pressure. Preferential adsorp- tion of CO2 increases with increase of CH4 concentration in source gas, and decreases with increasing pressure. Although there was no systematic investigation of the effect of coal rank on preferential adsorp- tion, there are obvious differences in preferential adsorption of gas between low-volatile bituminous coal and anthracite. The obtained preferential adsorption gives rise to the assumption that CO2 sequestration in coal beds with subsequent CO2-ECBM might be an ootion in Qinshui Basins, China.展开更多
Flow field in multilayer gob area, which formed in small hiden-depth, multi-coal layer groups, close distance, hard coal layer, and hard roof, possesses characteristics such as complex, changeable and unstable. Dynami...Flow field in multilayer gob area, which formed in small hiden-depth, multi-coal layer groups, close distance, hard coal layer, and hard roof, possesses characteristics such as complex, changeable and unstable. Dynamic balance theory of local flow field in multilayer gob area was built based on the realistic requirement that the serious threat on current mining coal layer by large-scale spontaneous combustion fire on close spontaneous combustion coal layer group of Datong Coal mining area at the ＇di-hard＇ conditions was caused by small coal pit mining. The kernel was in dynamic balance between flow field pressures of working face and local flow field in multilayer gob area was kept by transformation. Corresponding technology and set of devices were developed.展开更多
Based on the concept of “element” and the fundamental thermodynamic principle,the relationships of the residual properties,the property changes of mixing,excess properties,fugacity coefficients and activity coeffici...Based on the concept of “element” and the fundamental thermodynamic principle,the relationships of the residual properties,the property changes of mixing,excess properties,fugacity coefficients and activity coefficients between the hypothetical solution of elemental species and the equilibrated solution of actual species were established.The hypothetical solution of elemental species provides a way of reducing the dimensionality of problem, simplifying the analysis and visualizing the phase behavior.展开更多
This work is concerned about multiscale models of compact bone. We focus on the lacuna-canalicular system. The interstitial fluid and the ions in it are regarded as sol- vent and others are treated as solute. The syst...This work is concerned about multiscale models of compact bone. We focus on the lacuna-canalicular system. The interstitial fluid and the ions in it are regarded as sol- vent and others are treated as solute. The system has the characteristic of solvation process as well as non-equilibrium dynamics. The differential geometry theory of sur- faces is adopted. We use this theory to separate the macroscopic domain of solvent from the microscopic domain of solute. We also use it to couple continuum and discrete descriptions. The energy functionals are constructed and then the variational principle is applied to the energy functionals so as to derive desirable governing equations. We consider both long-range polar interactions and short-range nonpolar interactions. The solution of governing equations leads to the minimization of the total energy.展开更多
基金supported by the National Natural Science Foundation of China(Nos.51174127 and 21176145)the Natural Science Foundation of Shandong Province(No.ZR2011DM005)the Open Research Fund Program of Key Laboratory of Mine Disaster Prevention and Control(Shandong University of Science and Technology)(No.MDPC0806)
文摘In order to better understand the prevailing mechanism of CO2 storage in coal and estimate CO2 sequestration capacity of a coal seam and enhanced coalbed methane recovery （ECBM） with CO2 injection into coal, we investigated the preferential adsorption of CH4 and CO2 on coals. Adsorption of pure CO2, CH4 and their binary mixtures on high-rank coals from Qinshui Basin in China were employed to study the preferential adsorption behaviour. Multiple regression equations were presented to predict CH4 equi- librium concentration from equilibrium pressure and its initial-composition in feed gas. The results show that preferential adsorption of CO2 on coals over the entire pressure range under competitive sorption conditions was observed, however, preferential adsorption of CH4 over CO2 on low-volatile bituminous coal from higher CH4-compostion in source gas was found at up to 1O MPa pressure. Preferential adsorp- tion of CO2 increases with increase of CH4 concentration in source gas, and decreases with increasing pressure. Although there was no systematic investigation of the effect of coal rank on preferential adsorp- tion, there are obvious differences in preferential adsorption of gas between low-volatile bituminous coal and anthracite. The obtained preferential adsorption gives rise to the assumption that CO2 sequestration in coal beds with subsequent CO2-ECBM might be an ootion in Qinshui Basins, China.
基金Supported by the Key Projects of the National Natural Science Foundation of China （50834002）
文摘Flow field in multilayer gob area, which formed in small hiden-depth, multi-coal layer groups, close distance, hard coal layer, and hard roof, possesses characteristics such as complex, changeable and unstable. Dynamic balance theory of local flow field in multilayer gob area was built based on the realistic requirement that the serious threat on current mining coal layer by large-scale spontaneous combustion fire on close spontaneous combustion coal layer group of Datong Coal mining area at the ＇di-hard＇ conditions was caused by small coal pit mining. The kernel was in dynamic balance between flow field pressures of working face and local flow field in multilayer gob area was kept by transformation. Corresponding technology and set of devices were developed.
基金Supported by the National Natural Science Foundation of China (No. 29976035) and the Natural Science Foundation of Fujian Province (No. B9810011).
文摘Based on the concept of “element” and the fundamental thermodynamic principle,the relationships of the residual properties,the property changes of mixing,excess properties,fugacity coefficients and activity coefficients between the hypothetical solution of elemental species and the equilibrated solution of actual species were established.The hypothetical solution of elemental species provides a way of reducing the dimensionality of problem, simplifying the analysis and visualizing the phase behavior.
文摘This work is concerned about multiscale models of compact bone. We focus on the lacuna-canalicular system. The interstitial fluid and the ions in it are regarded as sol- vent and others are treated as solute. The system has the characteristic of solvation process as well as non-equilibrium dynamics. The differential geometry theory of sur- faces is adopted. We use this theory to separate the macroscopic domain of solvent from the microscopic domain of solute. We also use it to couple continuum and discrete descriptions. The energy functionals are constructed and then the variational principle is applied to the energy functionals so as to derive desirable governing equations. We consider both long-range polar interactions and short-range nonpolar interactions. The solution of governing equations leads to the minimization of the total energy.
