The variation regularity of coke strength was investigated in terms of the genetic factors and petrographic parameters of coal in collaboration with the technical properties of coal. A concept of inert holding ratio o...The variation regularity of coke strength was investigated in terms of the genetic factors and petrographic parameters of coal in collaboration with the technical properties of coal. A concept of inert holding ratio of coal was proposed. There is an optimal inert holding ratio for different ranks of coals for making coke with highest combined strength. The additive property of inert holding ratio under normal conditions was demonstrated with actual examples of coal blending.Thus it is possible to predict the combined strength of coke through reflectance, content of inert components and caking index diagram system.展开更多
This study examines the use of intact samples as an alternative to powder in conventional batch sorption studies to determine the distribution coefficient(K_d).Stable cesium(^(133)Cs) and strontium(^(87)Sr) were used ...This study examines the use of intact samples as an alternative to powder in conventional batch sorption studies to determine the distribution coefficient(K_d).Stable cesium(^(133)Cs) and strontium(^(87)Sr) were used under specified geochemical conditions to compare the Kdvalues of powder and block pumice tuff samples. The aim of the study was to infer any Kddifference under laboratory and field conditions. Kdvalues for block samples were found to be less than one order of magnitude lower than powder materials for both Cs and Sr on fresh tuff, and more than one order of magnitude lower in oxidized tuff. Destruction of micropores in oxidized tuff was estimated to be mainly responsible for reducing Kdvalues in oxidized tuff. However, approximately one order of magnitude difference in Kdvalues indicates that homogenously prepared intact samples can be used for sorption coefficient measurement at closer to in situ conditions. Pore size distribution analysis using mercury intrusion porosimetry revealed that lower Kdvalues on block samples result from lower surface area available as sorption sites due to inaccessible closed pores in the intact solid.展开更多
文摘The variation regularity of coke strength was investigated in terms of the genetic factors and petrographic parameters of coal in collaboration with the technical properties of coal. A concept of inert holding ratio of coal was proposed. There is an optimal inert holding ratio for different ranks of coals for making coke with highest combined strength. The additive property of inert holding ratio under normal conditions was demonstrated with actual examples of coal blending.Thus it is possible to predict the combined strength of coke through reflectance, content of inert components and caking index diagram system.
文摘This study examines the use of intact samples as an alternative to powder in conventional batch sorption studies to determine the distribution coefficient(K_d).Stable cesium(^(133)Cs) and strontium(^(87)Sr) were used under specified geochemical conditions to compare the Kdvalues of powder and block pumice tuff samples. The aim of the study was to infer any Kddifference under laboratory and field conditions. Kdvalues for block samples were found to be less than one order of magnitude lower than powder materials for both Cs and Sr on fresh tuff, and more than one order of magnitude lower in oxidized tuff. Destruction of micropores in oxidized tuff was estimated to be mainly responsible for reducing Kdvalues in oxidized tuff. However, approximately one order of magnitude difference in Kdvalues indicates that homogenously prepared intact samples can be used for sorption coefficient measurement at closer to in situ conditions. Pore size distribution analysis using mercury intrusion porosimetry revealed that lower Kdvalues on block samples result from lower surface area available as sorption sites due to inaccessible closed pores in the intact solid.
