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新兴交叉学科“工程热化学”助力实现“碳中和”目标
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作者 宋兴飞 孙瑞泽 +2 位作者 姜新东 韩振南 许光文 《中国发展》 2024年第4期1-9,共9页
我国90%以上的碳排放来自有机碳资源和碳酸盐矿物的利用,而这些资源在短期内无法替代。因此,应对“碳中和”挑战的最有效策略是减少这些热化学反应(热诱发/热驱动的化学反应)相关的“超级排放源”。工程热化学(Engineering thermochemis... 我国90%以上的碳排放来自有机碳资源和碳酸盐矿物的利用,而这些资源在短期内无法替代。因此,应对“碳中和”挑战的最有效策略是减少这些热化学反应(热诱发/热驱动的化学反应)相关的“超级排放源”。工程热化学(Engineering thermochemistry,ETC)是一门新兴交叉学科,关注热化学反应及其工程化科学与技术。该文介绍了工程热化学的定义、科学内涵,回顾了工程热化学形成与发展的详细历程,根据其提供的科学方法和原理,分析了可指导且有效的大规模碳减排、碳替代、碳循环途径,展示了工程热化学减少数十亿吨碳排放的方法和依据。 展开更多
关键词 热化学反应工程 工程热化学 新兴交叉学科 碳中和
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热化学反应工程科学与技术发展与展望
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作者 宋兴飞 贾鑫 +2 位作者 安萍 韩振南 许光文 《化工进展》 EI CAS CSCD 北大核心 2024年第7期3513-3533,共21页
“热”诱发、“热”驱动的热化学反应是人类最早认识的化学反应,占据工业化学反应的绝大部分,是能源转化、资源加工、循环经济等的重要反应,涉及发电、供热、冶金、建材、废物消纳等重大工业行业,这些行业是与人类活动相关的CO_(2)排放... “热”诱发、“热”驱动的热化学反应是人类最早认识的化学反应,占据工业化学反应的绝大部分,是能源转化、资源加工、循环经济等的重要反应,涉及发电、供热、冶金、建材、废物消纳等重大工业行业,这些行业是与人类活动相关的CO_(2)排放源的主体,在总碳排放中占比90%以上。在“双碳”目标下,热化学反应科学和技术的创新发展凸显更加特殊和重要的作用,其重要内容之一就是“支撑热化学反应工程化”的科学与技术,即“热化学反应工程”。针对“热”诱导、“热”驱动的化学反应,本文深入归纳和分析其相关科学和技术从古至今的发展特点,凝练形成了五个具有不同科学与技术特点的典型发展时期。总结典型热化学反应相关行业的重要科学与技术的发展及其对社会进步的贡献和影响,阐明“双碳”战略背景下“热化学反应工程”的科技创新机遇和贡献“碳中和”的潜力,揭示了通过碳减排、碳替代和碳循环的技术创新和应用推广,可有效推动我国各种“超级碳排放源”的碳排放强度和碳排放量的大幅降低,实现年60亿吨级二氧化碳的消减。 展开更多
关键词 热诱发 热驱动 热化学反应工程 碳中和 工程热化学
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化学渗透脱挥发分模型在碳基固体原料热化学转化领域应用进展 被引量:1
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作者 郭伟 杨盼曦 +6 位作者 俞尊义 高琨 王晶 张杰 党敏辉 杨伯伦 吴志强 《洁净煤技术》 CAS CSCD 北大核心 2023年第4期65-85,共21页
化学渗透脱挥发分模型(Chemical Percolation Devolatilization,CPD)用于快速升温条件下煤炭脱挥发分的模拟,可以预测不同煤种热解过程中焦油、半焦和轻质气体的实时产率。模型基于晶格模型构建煤炭化学结构,具有煤种适用性广、输入参... 化学渗透脱挥发分模型(Chemical Percolation Devolatilization,CPD)用于快速升温条件下煤炭脱挥发分的模拟,可以预测不同煤种热解过程中焦油、半焦和轻质气体的实时产率。模型基于晶格模型构建煤炭化学结构,具有煤种适用性广、输入参数少的特点,得到广泛关注。首先介绍了CPD模型的发展历程、煤炭模型构建方法和热解反应路径假设与动力学参数计算等,进而综述了CPD模型在煤炭、油页岩和生物质等碳基固体原料热化学转化领域的应用进展。为提高CPD模型在煤炭热转化领域的准确性和适用性,我国学者根据中国煤种结构分析建立了更准确的晶格参数计算方法。通过改进CPD模型中热解反应路径并修正动力学参数使模型更接近真实热解过程,通过对煤颗粒内部温度梯度分布修正及算法改进使得模拟更接近实际热解工况。在油页岩热转化方面,相关学者从油页岩中干酪根化学结构出发,结合油页岩热解特性建立了用于描述其热转化的CPD模型。通过分析生物质的结构特点和反应特性建立了生物质CPD模型,并从化学结构、热解反应路径以及动力学参数等方面进行改进来扩展模型的适用性。CPD模型虽然已得到了广泛应用,但根据煤炭元素分析和工业分析获得拟合参数适用的煤种范围较窄,准确性有待提高,需要进一步通过化学结构表征的方法建立更准确的碳基固体原料结构模型。CPD模型对热解反应过程进行了较大简化,需要根据实际热解反应路径进行修正,包括考虑煤炭热解过程中的二次反应、焦油之间的偶联、反应中自由基变化等问题。现有的CPD模型未考虑煤炭地下热转化过程的应力作用,需要从力-热耦合等复杂反应条件出发进行改进以提高模型的适用性。 展开更多
关键词 化学渗透脱挥发分模型 煤热解 油页岩 生物质 工程热化学
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Modeling and Optimization for Heat Exchanger Networks Synthesis Based on Expert System and Genetic Algorithm 被引量:1
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作者 李志红 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2002年第3期290-297,共8页
A new superstructure form of heat exchanger networks (HEN) isproposed based on expert system system (ES). The new superstructureform is combined with the practical engineering. The differentinvestment cost formula for... A new superstructure form of heat exchanger networks (HEN) isproposed based on expert system system (ES). The new superstructureform is combined with the practical engineering. The differentinvestment cost formula for Different heat exchanger is alsopresented based on ES. The mathematical model for the simultaneousoptimization Of network configuration is established and solved by agenetic algorithm. This method can deal with larger scale HENsynthesis and the optimal HEN configuration is obtainedautomatically. Finally, a case study is presented to Demonstrate theeffectiveness of the method. 展开更多
关键词 heat exchanger network expert system genetic algorithm
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Study on heat transfer for falling liquid film flow with consideration of interfacial evaporation 被引量:1
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作者 张金涛 王补宣 +1 位作者 彭晓峰 杜建华 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2001年第2期145-149,共5页
The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial eveiporative h... The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial eveiporative heat transfer in the turbulent model would lower the predicted convective heat transfer coefficient. Predictions of the new model resulted in a prominent deviation from that predictions of the normal model in the case of large mass flow rate and low wall heat flux. This deviation will be decreased with increasing wall heat flux, such that it will be asymptotic zero at very high wall heat flux. Predictions of the new model agreed well with the current experimental measurements. This study has verified that the Reynolds number is not the sole crucial parameter for heat transfer of falling liquid film flow, and wall heat flux will be another important independent parameter. This result is consistent with our previous studies. 展开更多
关键词 falling liquid film convective heat transfer turbulent model
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Heat Integration for Different Separation Processes
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作者 崔明珠 冯霄 张早校 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1999年第2期126-131,共6页
The distribution of heat duties among individual separation subsystems and other aspects of heat integration in such systems are reviewed. Heat integration for different separation processes is investigated, using the... The distribution of heat duties among individual separation subsystems and other aspects of heat integration in such systems are reviewed. Heat integration for different separation processes is investigated, using the pinch point method. Such a study will provide theoretical guide lines for the proper choice of a desirable separation process. 展开更多
关键词 SEPARATION heat duty pinch analysis heat integration
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A New General Equation of State 被引量:1
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作者 云志 秦金平 +1 位作者 史美仁 时钧 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1999年第2期161-165,共5页
A new general equation of state is presented, which can be used to express not only common cubic equations of state, but also quartic equations of state and so on. Main advantage of the new equation over the previous ... A new general equation of state is presented, which can be used to express not only common cubic equations of state, but also quartic equations of state and so on. Main advantage of the new equation over the previous general equations is that it is in simple form, and is easy to manipulate mathematically. 展开更多
关键词 equation of state general equation cubic equation quartic equation
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A Numerical Study on Fully Developed Fluid Flow and Heat Transfer in a Spiral Finned Tube
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作者 张建文 张政 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1999年第1期56-66,共11页
In this paper, the standard k-ε two-equation model is adopted to numerically simulate fully developed fluid flow and heat transfer in a spiral finned tube within a cracking furnace for ethylene manufacturing. By vari... In this paper, the standard k-ε two-equation model is adopted to numerically simulate fully developed fluid flow and heat transfer in a spiral finned tube within a cracking furnace for ethylene manufacturing. By variable transformation, the original 3-D problem is converted into a 2-D problem in spiral coordinates. The algorithm of SIMPLEC is used to study the fully developed fluid flow and heat transfer in the spiral finned tube at constant periphery temperature and constant axial heat flux. The computed results agree pretty well with the experimental data obtained from the industry. Further studies on the fluid flows and temperature profiles at different Reynolds numbers within straight and spiral finned tubes are conducted and the mechanisms involved are explored. It is found that with the spiral finned tube, pressure drop increases to a great extent whereas heat transfer tends to be decreased. 展开更多
关键词 fluid flow and heat transfer numerical simulation finned tube spiral finned tube spiral coordinates system
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Numerical simulation of spray performance based on the Euler-Lagrange Approach 被引量:4
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作者 Yujia Tao Xiulan Huai +1 位作者 Ziyi Guo Ran Yin 《Journal of Thermal Science》 SCIE EI CAS CSCD 2009年第1期91-96,共6页
Numerical simulations have been carried out to investigate the liquid atomization and spray process using the Discrete Phase Model of the commercial CFD code combined with the Wall-Film boundary conditions. The effect... Numerical simulations have been carried out to investigate the liquid atomization and spray process using the Discrete Phase Model of the commercial CFD code combined with the Wall-Film boundary conditions. The effects of spray parameters on droplets Santer mean diameter (SMD), droplet collision speed, the thickness of liquid-film, the surface temperature and its uniformity were analyzed in the present study. The simulation results and the experimental data obtained in the available literature agree within 13.8%, The computational results show that the spray pressure is the main factor to realize the atomization. Increasing the mass flux and the spray pressure, the droplet collision speed increases while the corresponding maximum film thickness on the heated surface declines. The surface temperature changes indistinctively with the increase of the spray distance, but the temperature distribution tends to be uniform. 展开更多
关键词 liquid atomization discrete phase model Wall-film numerical simulation
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Periodical shedding of cloud cavitation from a single hydrofoil in high-speed cryogenic channel flow
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作者 Yutaka ITO Koichi SETO Takao NAGASAKI 《Journal of Thermal Science》 SCIE EI CAS CSCD 2009年第1期58-64,共7页
In order to explain criteria for periodical shedding of the cloud cavitation, flow patterns of cavitation around a piano-convex hydrofoil were observed using a cryogenic cavitation tunnel of a blowdown type. Two hydro... In order to explain criteria for periodical shedding of the cloud cavitation, flow patterns of cavitation around a piano-convex hydrofoil were observed using a cryogenic cavitation tunnel of a blowdown type. Two hydrofoils of similarity of 20 and 60 mm in chord length with two test sections of 20 and 60 mm in width were prepared. Working fluids were water at ambient temperature, hot water and liquid nitrogen. The parameter range was varied between 0.3 and 1.4 for cavitation number, 9 and 17 m/sec for inlet flow velocity, and -8° and 8° for the flow incidence angle, respectively. At incidence angle 8°, that is, the convex surface being suction surface, periodical shedding of the whole cloud cavitation was observed on the convex surface under the specific condition with cavitation number and inlet flow velocity, respectively, 0.5, 9 m/sec for liquid nitrogen at 192℃ and 1.4, 11 m/sec for water at 88℃, whereas under the supercavitation condition, it was not observable. Periodical shedding of cloud cavitation occurs only in the case that there are both the adverse pressure gradient and the slow flow region on the hydrofoil. 展开更多
关键词 cloud cavitation CRYOGEN visualization HYDROFOIL
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