To investigate the potential use of two Japanese regional clayey soils, named Ariake clay and Akaboku soil, as soil barrier materials, a series of laboratory diffusion tests are presented. Using an available computer ...To investigate the potential use of two Japanese regional clayey soils, named Ariake clay and Akaboku soil, as soil barrier materials, a series of laboratory diffusion tests are presented. Using an available computer program Pollute V6.3, the effective diffusion coefficients of K^+ of the soils were back-calculated from the diffusion tests. It is found that the Ariake clay has a larger effective diffusion coefficient than the Akaboku soil, indicating that the Ariake clay may provide a better diffusion barrier. A comparison of the effective diffusion coefficients between the single-salt solution condition and the multi-salt solution condition indicates that soils have higher effective diffusion coefficients under the former condition. It is suggested to use miscible solution close to landfill leachates for determining effective diffusion coefficients of specified chemical species for a practical design.展开更多
The main objective of this study was to establish optimal incineration conditions through the analysis of pollutant formation mechanisms involved in the combustion process of a retort incinerator. Calorific values of ...The main objective of this study was to establish optimal incineration conditions through the analysis of pollutant formation mechanisms involved in the combustion process of a retort incinerator. Calorific values of several types of municipal solid wastes were determined and related to specific incinerability indexes. The incinerability testing concerning this study was conducted on residues with an incinerability index (II) of 123. The samples were tested under different conditions: with and without chamber preheating, varying the percentage of inlet air (25, 50 and 75% of the system capacity), measuring the temperatures of the primary and secondary chambers, and gauging the CO and NO stack emissions with an electrochemical cell. With comparative purposes in mind, samples with indexes ofI = 112, I = 123, I = 130 and I = 132 were also tested to assess the influence of the II on pollutant emissions.展开更多
Domestic wastes have become an importer topic of environmental protection research. From the social cost of treating domestic wastes, this article analyzes present environmental pollution caused by neglected externali...Domestic wastes have become an importer topic of environmental protection research. From the social cost of treating domestic wastes, this article analyzes present environmental pollution caused by neglected externality when we discharge domestic wastes in the method of analysis on the difference between marginal personal cost and marginal social cost; It also proves the necessity and the importance of levying pollution tax and proposes the measures of eontrolling environmental potlution caused by domestic wastes.展开更多
In order to determine the quantity of laboratories doing waste minimization practice related with the USEPA (United State Environmental Protection Agency) pollution hierarchy, an initial diagnostic about waste manag...In order to determine the quantity of laboratories doing waste minimization practice related with the USEPA (United State Environmental Protection Agency) pollution hierarchy, an initial diagnostic about waste management at laboratories was conducted. The data gathered were used to start a training to laboratory personnel training about EPA-PH (Environmental Protection Agency-Pollution Hierarchy). After training new diagnostics were performed. The applications of waste minimization practices in the laboratories were analyzed before and after the training. The most poorly practices performed year by year during the study period were "substitute nonhazardous materials", "chemical treatment" and "distillation". "Redistribute surplus chemical" was performed in 22 labs, 30 labs and 48 labs during years 2010, 2011 and 2013 respectively as the most common practice. This study showed that training about pollution prevention hierarchy increased the number of laboratories doing waste minimization practices, prioritizing reduction and prevention from the source.展开更多
The objectives of this work were to determine the potential mineralization of various organic pollutants that are likely found in compostable materials during composting, and to evaluate the participation of the micro...The objectives of this work were to determine the potential mineralization of various organic pollutants that are likely found in compostable materials during composting, and to evaluate the participation of the microflora of the thermophilic and maturation composting phases in pollutant mineralization. Four composts were used: a biowaste compost (BioW), a municipal solid waste compost (MSW), a green waste compost (GW) and a co-compost of green waste and sludge (GW+S). In each composting plant, two samples were withdrawn: one in the thermophilic phase (fresh compost) and one in the maturation phase (mature compost) to have the microflora of thermophilic and maturation phases active, respectively. The mineralization of 5 organic pollutants, 3 polycyclic aromatic hydrocarbons (PAHs) (i.e., phenanthrene, fluoranthene and benzo(a)pyrene), 1 herbicide (dicamba) and 1 polychlorinated biphenyl (PCB, congener 52), was measured in a laboratory setting during incubations at 60 ~C in fresh composts and at 28 ~C in mature composts. All molecules were 14C-labeled, which allowed the mineralization of the molecules to be measured by trapping of produced 14CO2 in NaOH. Their volatilization was also measured by trapping molecules on glass wool impregnated with paraffin oil. Mineralization of the organic molecules was only observed when the maturation microflora was present in the mature composts or when it was inoculated into the fresh compost. Phenanthrene mineralization of up to 60% in the fresh GW^S compost was the only exception. Mineralization of PAH decreased when the complexity of the PAH molecules increased. Mineralization of phenanthrene and fluoranthene reached 50%-70% in all mature composts. Benzo(a)pyrene was mineralized (30%) only in the MSW mature compost. Dicamba was moderately mineralized (30%-40%). Finally, no PCB mineralization was detected, but 20% of the PCB had volatilized after 12 d at 60 ℃. No clear difference was observed in the degrading capacity of the different composts, and the major difference was the larger mineralizing capacity of the maturation microflora compared with the thermophilic microflora.展开更多
文摘To investigate the potential use of two Japanese regional clayey soils, named Ariake clay and Akaboku soil, as soil barrier materials, a series of laboratory diffusion tests are presented. Using an available computer program Pollute V6.3, the effective diffusion coefficients of K^+ of the soils were back-calculated from the diffusion tests. It is found that the Ariake clay has a larger effective diffusion coefficient than the Akaboku soil, indicating that the Ariake clay may provide a better diffusion barrier. A comparison of the effective diffusion coefficients between the single-salt solution condition and the multi-salt solution condition indicates that soils have higher effective diffusion coefficients under the former condition. It is suggested to use miscible solution close to landfill leachates for determining effective diffusion coefficients of specified chemical species for a practical design.
文摘The main objective of this study was to establish optimal incineration conditions through the analysis of pollutant formation mechanisms involved in the combustion process of a retort incinerator. Calorific values of several types of municipal solid wastes were determined and related to specific incinerability indexes. The incinerability testing concerning this study was conducted on residues with an incinerability index (II) of 123. The samples were tested under different conditions: with and without chamber preheating, varying the percentage of inlet air (25, 50 and 75% of the system capacity), measuring the temperatures of the primary and secondary chambers, and gauging the CO and NO stack emissions with an electrochemical cell. With comparative purposes in mind, samples with indexes ofI = 112, I = 123, I = 130 and I = 132 were also tested to assess the influence of the II on pollutant emissions.
基金Supported by the National Social Science Foundation of China (05BJY021) National Natural Science Foundation of China (70371049).
文摘Domestic wastes have become an importer topic of environmental protection research. From the social cost of treating domestic wastes, this article analyzes present environmental pollution caused by neglected externality when we discharge domestic wastes in the method of analysis on the difference between marginal personal cost and marginal social cost; It also proves the necessity and the importance of levying pollution tax and proposes the measures of eontrolling environmental potlution caused by domestic wastes.
文摘In order to determine the quantity of laboratories doing waste minimization practice related with the USEPA (United State Environmental Protection Agency) pollution hierarchy, an initial diagnostic about waste management at laboratories was conducted. The data gathered were used to start a training to laboratory personnel training about EPA-PH (Environmental Protection Agency-Pollution Hierarchy). After training new diagnostics were performed. The applications of waste minimization practices in the laboratories were analyzed before and after the training. The most poorly practices performed year by year during the study period were "substitute nonhazardous materials", "chemical treatment" and "distillation". "Redistribute surplus chemical" was performed in 22 labs, 30 labs and 48 labs during years 2010, 2011 and 2013 respectively as the most common practice. This study showed that training about pollution prevention hierarchy increased the number of laboratories doing waste minimization practices, prioritizing reduction and prevention from the source.
基金Supported by the Veolia Group,France,and the INRA,France
文摘The objectives of this work were to determine the potential mineralization of various organic pollutants that are likely found in compostable materials during composting, and to evaluate the participation of the microflora of the thermophilic and maturation composting phases in pollutant mineralization. Four composts were used: a biowaste compost (BioW), a municipal solid waste compost (MSW), a green waste compost (GW) and a co-compost of green waste and sludge (GW+S). In each composting plant, two samples were withdrawn: one in the thermophilic phase (fresh compost) and one in the maturation phase (mature compost) to have the microflora of thermophilic and maturation phases active, respectively. The mineralization of 5 organic pollutants, 3 polycyclic aromatic hydrocarbons (PAHs) (i.e., phenanthrene, fluoranthene and benzo(a)pyrene), 1 herbicide (dicamba) and 1 polychlorinated biphenyl (PCB, congener 52), was measured in a laboratory setting during incubations at 60 ~C in fresh composts and at 28 ~C in mature composts. All molecules were 14C-labeled, which allowed the mineralization of the molecules to be measured by trapping of produced 14CO2 in NaOH. Their volatilization was also measured by trapping molecules on glass wool impregnated with paraffin oil. Mineralization of the organic molecules was only observed when the maturation microflora was present in the mature composts or when it was inoculated into the fresh compost. Phenanthrene mineralization of up to 60% in the fresh GW^S compost was the only exception. Mineralization of PAH decreased when the complexity of the PAH molecules increased. Mineralization of phenanthrene and fluoranthene reached 50%-70% in all mature composts. Benzo(a)pyrene was mineralized (30%) only in the MSW mature compost. Dicamba was moderately mineralized (30%-40%). Finally, no PCB mineralization was detected, but 20% of the PCB had volatilized after 12 d at 60 ℃. No clear difference was observed in the degrading capacity of the different composts, and the major difference was the larger mineralizing capacity of the maturation microflora compared with the thermophilic microflora.