In this work,hybrid material CNTs@MIL-101(Cr) was synthesized in 2 h using multi-walled carbon nanotubes(MWCNTs) as the crystal growth accelerator with hydrothermal method.The characteristic differences between the cr...In this work,hybrid material CNTs@MIL-101(Cr) was synthesized in 2 h using multi-walled carbon nanotubes(MWCNTs) as the crystal growth accelerator with hydrothermal method.The characteristic differences between the crystals of CNTs@MIL-101(Cr) and MIL-101 were investigated by N_2 adsorption–desorption isotherms,X-ray diffraction(XRD),scanning electron microscope(SEM) and thermogravimetric analyzer(TGA).The results showed that MWCNTs embedding in the hybrid material provide more mesoporous volumes than that of MIL-101.Moreover,the fast synthesized crystals of CNTs@MIL-101(Cr) still preserve the octahedral shape like MIL-101 and have a larger size ranging from 1.5 to 2.0 μm which were approximately three times larger than that of MIL-101.In the proposed mechanism,the roles of MWCNTs played in the crystallization were discussed where MWCNTs can be seen as coaxial cylindrical tubes composed of multi-layer graphenes and the place where nucleation and crystal growth processes occur at the tubes' out surface.Then,a crystal seeding layer bonding with the MWCNTs may be easily formed which accelerates the growth rate of MIL-101 crystals.Thus,larger crystals of CNTs@MIL-101(Cr) were formed due to the faster crystal growth rate of MIL-101.展开更多
This study tried to apply biomass fuel to clean burner combustion under high load conditions by water addition. A newly developed injector mixes fuel rapidly with water inside of the injector with support of atomizing...This study tried to apply biomass fuel to clean burner combustion under high load conditions by water addition. A newly developed injector mixes fuel rapidly with water inside of the injector with support of atomizing air. The mixture composed of three-fluid is injected as spray into a flame stabilizer of burner. Investigation of emission performance of this injector shows that the internally rapid mixing type of injector is hopeful technique to introduce water into burner combustion. Combustion by this injector emits exceedingly less particulate matters at high load. NOx emission is strongly dependent on water flow rate.展开更多
An ejector of low NO~ burner was designed for a gas instantaneous water heater in this work. The flowing and mixing process of the ejector was investigated by computational fluid dynamics （CFD） approach. A comprehen...An ejector of low NO~ burner was designed for a gas instantaneous water heater in this work. The flowing and mixing process of the ejector was investigated by computational fluid dynamics （CFD） approach. A comprehensive study was conducted to understand the effects of the geometrical parameters on the static pressure of air and methane, and mole fraction uniformity of methane at the outlet of ejector. The distribution chamber was applied to balance the pressure and improve the mixing process of methane and air in front of the fire hole. A distribution orifice plate with seven distribution orifices was introduced at the outlet of the ejector to improve the flow organization. It is found that the nozzle exit position of 5 mm and nozzle diameter d 〉1.3 mm should be used to improve the flow organization and realize the well premixed combustion for this designed ejector.展开更多
基金Supported by the National Natural Science Foundation of China(21006053)
文摘In this work,hybrid material CNTs@MIL-101(Cr) was synthesized in 2 h using multi-walled carbon nanotubes(MWCNTs) as the crystal growth accelerator with hydrothermal method.The characteristic differences between the crystals of CNTs@MIL-101(Cr) and MIL-101 were investigated by N_2 adsorption–desorption isotherms,X-ray diffraction(XRD),scanning electron microscope(SEM) and thermogravimetric analyzer(TGA).The results showed that MWCNTs embedding in the hybrid material provide more mesoporous volumes than that of MIL-101.Moreover,the fast synthesized crystals of CNTs@MIL-101(Cr) still preserve the octahedral shape like MIL-101 and have a larger size ranging from 1.5 to 2.0 μm which were approximately three times larger than that of MIL-101.In the proposed mechanism,the roles of MWCNTs played in the crystallization were discussed where MWCNTs can be seen as coaxial cylindrical tubes composed of multi-layer graphenes and the place where nucleation and crystal growth processes occur at the tubes' out surface.Then,a crystal seeding layer bonding with the MWCNTs may be easily formed which accelerates the growth rate of MIL-101 crystals.Thus,larger crystals of CNTs@MIL-101(Cr) were formed due to the faster crystal growth rate of MIL-101.
文摘This study tried to apply biomass fuel to clean burner combustion under high load conditions by water addition. A newly developed injector mixes fuel rapidly with water inside of the injector with support of atomizing air. The mixture composed of three-fluid is injected as spray into a flame stabilizer of burner. Investigation of emission performance of this injector shows that the internally rapid mixing type of injector is hopeful technique to introduce water into burner combustion. Combustion by this injector emits exceedingly less particulate matters at high load. NOx emission is strongly dependent on water flow rate.
基金Project(NR2013K04) supported by Beijing Key Lab of Heating,Gas Supply,Ventilating and Air Conditioning Engineering,ChinaProject(20130909) supported by the Higher School Science and Technology Development Fund of Tianjin,China
文摘An ejector of low NO~ burner was designed for a gas instantaneous water heater in this work. The flowing and mixing process of the ejector was investigated by computational fluid dynamics （CFD） approach. A comprehensive study was conducted to understand the effects of the geometrical parameters on the static pressure of air and methane, and mole fraction uniformity of methane at the outlet of ejector. The distribution chamber was applied to balance the pressure and improve the mixing process of methane and air in front of the fire hole. A distribution orifice plate with seven distribution orifices was introduced at the outlet of the ejector to improve the flow organization. It is found that the nozzle exit position of 5 mm and nozzle diameter d 〉1.3 mm should be used to improve the flow organization and realize the well premixed combustion for this designed ejector.
