The purification and separation of durene from the mixture containing durene isomers were studied.Since the boiling points of tetramethyl benzene isomers are very close but their melting points are of great difference...The purification and separation of durene from the mixture containing durene isomers were studied.Since the boiling points of tetramethyl benzene isomers are very close but their melting points are of great differences,static melt crystallization was applied to separate and purify durene from its isomers.Crystallization experiments were carried out under various operating conditions.The effects of cooling rate,crystallization temperature,sweating temperature and sweating time on the yield and purity of crystal were investigated.Orthogonal experimental design method was adopted to analyze the factors that may affect the yield of durene.Under the optimal crystallization conditions,the purity of durene could reach as high as 99.06%with the yield of 75.3%through one crystallization process.By fitting purification data based on sweating time in isothermal operations,the purification rate coefficient was obtained.展开更多
The excited state characters of HY103 have been studied by means of time-resolved photon emission （time-correlated single photon counting） and time dependent density functional theory calculations. The experimental ...The excited state characters of HY103 have been studied by means of time-resolved photon emission （time-correlated single photon counting） and time dependent density functional theory calculations. The experimental and theoretical results demonstrate that HY103 dyes undergo an efficient one-bond-flip motion after photoexicitation at room temperature, which leads to a very short lifetime of the normM fluorescence state, and a weak fluorescence emission around 670 am. However, when HY103 are excited in amorphous glasses at 77 K, the normal fluorescence emission is prolonged to nanoseconds time scale about 2 ns, and the fluorescence emission is enhanced. Furthermore, a new emission state is produced, which is characterized as a volume-conserved twisted （VCT） state. This is the first observation of a VCT state. The experiment indicates that the VCT motion of excited state of π-conjugated molecules in restricted environment can form a stable emission state, and the excited state character of π-conjugated molecules in restricted environment is complex.展开更多
The multifractality of energy and thermal dissipation of fully developed intermittent turbulence is investigated in the urban canopy layer under unstable conditions by the singularity spectrum for the fractal dimensio...The multifractality of energy and thermal dissipation of fully developed intermittent turbulence is investigated in the urban canopy layer under unstable conditions by the singularity spectrum for the fractal dimensions of sets of singularities characterizing multifractals. In order to obtain high-order moment properties of smallscale turbulent dissipation in the inertial range, an ultrasonic anemometer with a high sampling frequency of 100 Hz was used. The authors found that the turbulent signal could be singular everywhere. Moreover, the singular exponents of energy and thermal dissipation rates are most frequently encountered at around 0.2, which is significantly smaller than the singular exponents for a wind tunnel at a moderate Reynolds number. The evidence indicates a higher intermittency of turbulence in the urban canopy layer at a high Reynolds number, which is demonstrated by the data with high temporal resolution. Furthermore, the temperature field is more intermittent than the velocity field. In addition, a large amount of samples could be used for verification of the results.展开更多
The macroscopic anomalies before and after the May 12,2008 Wenchuan M8. 0 earthquake were collected and analyzed in this paper. The credible anomalies occurring from February 1 to June 10,2008 were treated as macrosco...The macroscopic anomalies before and after the May 12,2008 Wenchuan M8. 0 earthquake were collected and analyzed in this paper. The credible anomalies occurring from February 1 to June 10,2008 were treated as macroscopic anomalies,and their space-time distribution was studied. The research indicates that in time distribution,the number of macroscopic anomalies peaked before the earthquake,and these peak values appeared twice after the earthquake. In space distribution,the distribution of macroscopic anomalies before the earthquake was the same as that after the earthquake. In this paper,the mechanism of occurrence of macroscopic anomalies and the role of macroscopic anomalies in forecasting earthquake were also discussed.展开更多
Detecting traffic anomalies is essential for diagnosing attacks. HighSp eed Backbone Net works （HSBN） require Traffic Anomaly Detection Systems （TADS） which are accurate （high detec tion and low false positive ra...Detecting traffic anomalies is essential for diagnosing attacks. HighSp eed Backbone Net works （HSBN） require Traffic Anomaly Detection Systems （TADS） which are accurate （high detec tion and low false positive rates） and efficient. The proposed approach utilizes entropy as traffic distributions metric over some traffic dimensions. An efficient algorithm, having low computational and space complexity, is used to estimate entro py. Entropy values over all dimensions are展开更多
Anisotropy correction is necessary during the processing of converted PS- wave seismic data to achieve accurate structural imaging, reservoir prediction, and fracture detection. To effectively eliminate the adverse ef...Anisotropy correction is necessary during the processing of converted PS- wave seismic data to achieve accurate structural imaging, reservoir prediction, and fracture detection. To effectively eliminate the adverse effects of S-wave splitting and to improve PS- wave imaging quality, we tested methods for pre-stack migration imaging and anisotropic correction of PS-wave data. We based this on the propagation rules of seismic waves in a horizontal transverse isotropy medium, which is a fractured medium model that reflects likely subsurface conditions in the field. We used the radial （R） and transverse （T） components of PS-wave data to separate the fast and slow S-wave components, after which their propagation moveout was effectively extracted. Meanwhile, corrections for the energies and propagation moveouts of the R and T components were implemented using mathematical rotation. The PS-wave imaging quality was distinctly improved, and we demonstrated the reliability of our methods through numerical simulations. Applying our methods to three-dimensional and three-component seismic field data from the Xinchang-Hexingchang region of the Western Sichuan Depression in China, we obtained high-quality seismic imaging with continuous reflection wave groups, distinct structural features, and specific stratigraphic contact relationships. This study provides an effective and reliable approach for data processing that will improve the exploration of complex, hidden lithologic gas reservoirs.展开更多
A time-series similarity measurement method based on wavelet and matrix transform was proposed,and its anti-noise ability,sensitivity and accuracy were discussed. The time-series sequences were compressed into wavelet...A time-series similarity measurement method based on wavelet and matrix transform was proposed,and its anti-noise ability,sensitivity and accuracy were discussed. The time-series sequences were compressed into wavelet subspace,and sample feature vector and orthogonal basics of sample time-series sequences were obtained by K-L transform. Then the inner product transform was carried out to project analyzed time-series sequence into orthogonal basics to gain analyzed feature vectors. The similarity was calculated between sample feature vector and analyzed feature vector by the Euclid distance. Taking fault wave of power electronic devices for example,the experimental results show that the proposed method has low dimension of feature vector,the anti-noise ability of proposed method is 30 times as large as that of plain wavelet method,the sensitivity of proposed method is 1/3 as large as that of plain wavelet method,and the accuracy of proposed method is higher than that of the wavelet singular value decomposition method. The proposed method can be applied in similarity matching and indexing for lager time series databases.展开更多
基金the Society of Vertebrate Paleontology Patterson Memorial Grant for fieldwork National Geographic Society Young Explorers Grant,United States Fulbright Program, Geological Society of Americathe Evolving Earth Foundation+1 种基金the National Basic Research Program of China(GrantNo.2012CB821900)the National Natural Science Foundationo f China(GrantNo.40730210)~~
基金supported by the Major Basic Research Projects of MST of China(2006CB806400)the Basic Work Program of MST of China(2006FY120300-15)the National Natural Science Foundation of China(40532010)~~
基金Supported by the National Natural Science Foundation of China(21176172)Top Talents Program of Yunnan Province,China(2011HA010)
文摘The purification and separation of durene from the mixture containing durene isomers were studied.Since the boiling points of tetramethyl benzene isomers are very close but their melting points are of great differences,static melt crystallization was applied to separate and purify durene from its isomers.Crystallization experiments were carried out under various operating conditions.The effects of cooling rate,crystallization temperature,sweating temperature and sweating time on the yield and purity of crystal were investigated.Orthogonal experimental design method was adopted to analyze the factors that may affect the yield of durene.Under the optimal crystallization conditions,the purity of durene could reach as high as 99.06%with the yield of 75.3%through one crystallization process.By fitting purification data based on sweating time in isothermal operations,the purification rate coefficient was obtained.
文摘The excited state characters of HY103 have been studied by means of time-resolved photon emission （time-correlated single photon counting） and time dependent density functional theory calculations. The experimental and theoretical results demonstrate that HY103 dyes undergo an efficient one-bond-flip motion after photoexicitation at room temperature, which leads to a very short lifetime of the normM fluorescence state, and a weak fluorescence emission around 670 am. However, when HY103 are excited in amorphous glasses at 77 K, the normal fluorescence emission is prolonged to nanoseconds time scale about 2 ns, and the fluorescence emission is enhanced. Furthermore, a new emission state is produced, which is characterized as a volume-conserved twisted （VCT） state. This is the first observation of a VCT state. The experiment indicates that the VCT motion of excited state of π-conjugated molecules in restricted environment can form a stable emission state, and the excited state character of π-conjugated molecules in restricted environment is complex.
基金supported by the National Natural Science Foundation of China(Grant Nos.11472272 and 91215302)the Special Fund for Meteorological Research in the Public Interest(Grant No.GYHY201206041)
文摘The multifractality of energy and thermal dissipation of fully developed intermittent turbulence is investigated in the urban canopy layer under unstable conditions by the singularity spectrum for the fractal dimensions of sets of singularities characterizing multifractals. In order to obtain high-order moment properties of smallscale turbulent dissipation in the inertial range, an ultrasonic anemometer with a high sampling frequency of 100 Hz was used. The authors found that the turbulent signal could be singular everywhere. Moreover, the singular exponents of energy and thermal dissipation rates are most frequently encountered at around 0.2, which is significantly smaller than the singular exponents for a wind tunnel at a moderate Reynolds number. The evidence indicates a higher intermittency of turbulence in the urban canopy layer at a high Reynolds number, which is demonstrated by the data with high temporal resolution. Furthermore, the temperature field is more intermittent than the velocity field. In addition, a large amount of samples could be used for verification of the results.
基金sponsored by the National KeyTechnology R&D Program (2006BAC01B03-04-04)
文摘The macroscopic anomalies before and after the May 12,2008 Wenchuan M8. 0 earthquake were collected and analyzed in this paper. The credible anomalies occurring from February 1 to June 10,2008 were treated as macroscopic anomalies,and their space-time distribution was studied. The research indicates that in time distribution,the number of macroscopic anomalies peaked before the earthquake,and these peak values appeared twice after the earthquake. In space distribution,the distribution of macroscopic anomalies before the earthquake was the same as that after the earthquake. In this paper,the mechanism of occurrence of macroscopic anomalies and the role of macroscopic anomalies in forecasting earthquake were also discussed.
基金supported by the National High-Tech Research and Development Plan of China under Grant No.2011AA010702
文摘Detecting traffic anomalies is essential for diagnosing attacks. HighSp eed Backbone Net works （HSBN） require Traffic Anomaly Detection Systems （TADS） which are accurate （high detec tion and low false positive rates） and efficient. The proposed approach utilizes entropy as traffic distributions metric over some traffic dimensions. An efficient algorithm, having low computational and space complexity, is used to estimate entro py. Entropy values over all dimensions are
基金supported by the National Natural Science Foundation of China(Grant No.41574099)the National Key Science and Technology Special Projects(grant No.2016ZX05002004-005)
文摘Anisotropy correction is necessary during the processing of converted PS- wave seismic data to achieve accurate structural imaging, reservoir prediction, and fracture detection. To effectively eliminate the adverse effects of S-wave splitting and to improve PS- wave imaging quality, we tested methods for pre-stack migration imaging and anisotropic correction of PS-wave data. We based this on the propagation rules of seismic waves in a horizontal transverse isotropy medium, which is a fractured medium model that reflects likely subsurface conditions in the field. We used the radial （R） and transverse （T） components of PS-wave data to separate the fast and slow S-wave components, after which their propagation moveout was effectively extracted. Meanwhile, corrections for the energies and propagation moveouts of the R and T components were implemented using mathematical rotation. The PS-wave imaging quality was distinctly improved, and we demonstrated the reliability of our methods through numerical simulations. Applying our methods to three-dimensional and three-component seismic field data from the Xinchang-Hexingchang region of the Western Sichuan Depression in China, we obtained high-quality seismic imaging with continuous reflection wave groups, distinct structural features, and specific stratigraphic contact relationships. This study provides an effective and reliable approach for data processing that will improve the exploration of complex, hidden lithologic gas reservoirs.
基金Projects(60634020, 60904077, 60874069) supported by the National Natural Science Foundation of ChinaProject(JC200903180555A) supported by the Foundation Project of Shenzhen City Science and Technology Plan of China
文摘A time-series similarity measurement method based on wavelet and matrix transform was proposed,and its anti-noise ability,sensitivity and accuracy were discussed. The time-series sequences were compressed into wavelet subspace,and sample feature vector and orthogonal basics of sample time-series sequences were obtained by K-L transform. Then the inner product transform was carried out to project analyzed time-series sequence into orthogonal basics to gain analyzed feature vectors. The similarity was calculated between sample feature vector and analyzed feature vector by the Euclid distance. Taking fault wave of power electronic devices for example,the experimental results show that the proposed method has low dimension of feature vector,the anti-noise ability of proposed method is 30 times as large as that of plain wavelet method,the sensitivity of proposed method is 1/3 as large as that of plain wavelet method,and the accuracy of proposed method is higher than that of the wavelet singular value decomposition method. The proposed method can be applied in similarity matching and indexing for lager time series databases.
