Divalent β-diketiminate lanthanide complexes LYbR（THF）（L=｛（2,6-Me2C6H3）NC（Me）｝2CH;R=C9H7（1）,CH3C5H4（2）,OC6H2-But2-2,6-Me-4（32））were synthesized by reducing the mixed-ligand trivalen（t） β-diketimina...Divalent β-diketiminate lanthanide complexes LYbR（THF）（L=｛（2,6-Me2C6H3）NC（Me）｝2CH;R=C9H7（1）,CH3C5H4（2）,OC6H2-But2-2,6-Me-4（32））were synthesized by reducing the mixed-ligand trivalen（t） β-diketiminate ytterbium chlorides synthesized in situ with Na-K alloy.These divalent lanthanide complexes exhibit good catalytic activity for the ring opening polymerization of ε-caprolactone.展开更多
The first example of homochiral two dimensional neutral cobalt? 3 amino (S) tyrosine (ATYR) coordination polymer, bis(3 amino (S) tyrosinato )cobalt? 1 was synthesized under the hydrothermal reaction of Co(ClO4)2 ...The first example of homochiral two dimensional neutral cobalt? 3 amino (S) tyrosine (ATYR) coordination polymer, bis(3 amino (S) tyrosinato )cobalt? 1 was synthesized under the hydrothermal reaction of Co(ClO4)2 ·6H2O with ATYR in which 1 displays modest second harmonic generation response. CCDC: 214275.展开更多
文摘Divalent β-diketiminate lanthanide complexes LYbR（THF）（L=｛（2,6-Me2C6H3）NC（Me）｝2CH;R=C9H7（1）,CH3C5H4（2）,OC6H2-But2-2,6-Me-4（32））were synthesized by reducing the mixed-ligand trivalen（t） β-diketiminate ytterbium chlorides synthesized in situ with Na-K alloy.These divalent lanthanide complexes exhibit good catalytic activity for the ring opening polymerization of ε-caprolactone.
文摘The first example of homochiral two dimensional neutral cobalt? 3 amino (S) tyrosine (ATYR) coordination polymer, bis(3 amino (S) tyrosinato )cobalt? 1 was synthesized under the hydrothermal reaction of Co(ClO4)2 ·6H2O with ATYR in which 1 displays modest second harmonic generation response. CCDC: 214275.
