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基于机械—化学方法硅表面芳香烃重氮盐单层膜的制备 被引量:2
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作者 史立秋 孙涛 +1 位作者 闫永达 董申 《机械工程学报》 EI CAS CSCD 北大核心 2009年第7期249-253,共5页
基于金刚石刀具建立能在溶液中加工微小结构的微加工系统,在一端为硝基的四氟化硼芳烃重氮盐溶液(NO2C6H4N2BF4)中用该系统切削硅片,利用机械与化学结合的方法使得芳香烃分子和切削过的硅片之间以共价键连接,实现硅表面的"成形并... 基于金刚石刀具建立能在溶液中加工微小结构的微加工系统,在一端为硝基的四氟化硼芳烃重氮盐溶液(NO2C6H4N2BF4)中用该系统切削硅片,利用机械与化学结合的方法使得芳香烃分子和切削过的硅片之间以共价键连接,实现硅表面的"成形并功能化"的一步完成,为纳米尺度功能化结构的构筑提供一定的试验基础。用扫描电子显微镜(Scanning electronic microscopy,SEM)表征不同切削力下的微结构表面形貌图,为下一步在溶液中"成形并功能化"硅表面提供好的基底。用X射线光电子能谱(X-ray photoelectron spectroscopy,XPS)和原子力显微镜(Atomic force microscopy,AFM)分别研究组装时间和切削速度对切削处生成自组装单层膜(Self-assembly monolayer,SAMs)质量的影响,总结出本试验条件下切削力为20mN,组装时间为12h左右,切削速度为500nm/s的时候组装膜表面质量较好。并用AFM对自组装膜的纳米摩擦性能进行检测,证明组装前后硅基底表面的化学组成发生了变化,组装后SAMs表面的摩擦力较大。 展开更多
关键词 机械-化学方法芳香烃重氮盐硅单层膜
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Stiffness identification of four-point-elastic-support rigid plate 被引量:2
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作者 彭利平 刘初升 +1 位作者 武继达 王帅 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第1期159-167,共9页
As the stiffness of the elastic support varies with the physical-chemical erosion and mechanical friction, model catastrophe of a single degree-of-freedom(DOF) isolation system may occur. A 3-DOF four-point-elastic-su... As the stiffness of the elastic support varies with the physical-chemical erosion and mechanical friction, model catastrophe of a single degree-of-freedom(DOF) isolation system may occur. A 3-DOF four-point-elastic-support rigid plate(FERP) structure is presented to describe the catastrophic isolation system. Based on the newly-established structure, theoretical derivation for stiffness matrix calculation by free response(SMCby FR) and the method of stiffness identification by stiffness matrix disassembly(SIby SMD)are proposed. By integrating the SMCby FR and the SIby SMD and defining the stiffness assurance criterion(SAC), the procedures for stiffness identification of a FERP structure(SIFERP) are summarized. Then, a numerical example is adopted for the SIFERP validation, in which the simulated tested free response data are generated by the numerical methods, and operation for filtering noise is conducted to imitate the practical application. Results in the numerical example demonstrate the feasibility and accuracy of the developed SIFERP for stiffness identification. 展开更多
关键词 stiffness identification four-point-elastic-support rigid plate free response stiffness matrix disassembly
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Preparation of Aryldiazonium Salt Monolayers on Si(100) Surface by Chemomechanical Method
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作者 史立秋 张林 +3 位作者 手峰 闫永达 孙涛 董申 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2011年第6期741-744,I0004,共5页
Functionalizing and patterning of the silicon surface can be realized simultaneously by the chemomechanical method. The oxide-coated crystalline silicon (100) surface is scratched with a diamond tool in the presence... Functionalizing and patterning of the silicon surface can be realized simultaneously by the chemomechanical method. The oxide-coated crystalline silicon (100) surface is scratched with a diamond tool in the presence of aryldiazonium salt (C6H5N2BF4). Scratching activates the silicon surface by removing the passivation oxide layer to expose fresh Si atoms. The sur- face morphologies before and after chemomechanical reaction are characterized with atomic force microscopy. Time-of-flight secondary ion mass spectroscopy confirms the presence of C6H5 and provides evidence for the formation of self-assembled monolayer (SAM) on silicon surface via Si-C covalent bonds by scratching the silicon in the presence of C6H5N2BF4. C6H5 groups further bond with surface Si atoms via Si-C covalent bonds as confirmed from infrared spectroscopy results. We propose that chemomechanical reaction, which occurred during scratching the silicon surface, produce C6H5 groups from aryldiazonium salt. The relevant adhesion of SAM is measured. It is found that SAM can reduce the adhesion of silicon. The monolayer can be used as anti-adhesion monolayer for micro/nanoelectromechanical systems components under different environments and operating conditions. 展开更多
关键词 Chemomechanical SILICON MONOLAYER Aryldiazonium salt
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中小型精制植物油厂生产建置综述 被引量:1
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作者 尹平安 《渭南师专学报(自然科学版)》 1998年第5期20-22,共3页
油脂是一种高分子的天然有机化合物,它和蛋白质以及糖类都是人类合理营养的基础.随着经济建设的飞速发展,人民生活水平的不断提高,对油脂不仅在数量上而且在质量上的要求越来越高,精炼油的市场越来越广阔,本文就精制油的炼制方法... 油脂是一种高分子的天然有机化合物,它和蛋白质以及糖类都是人类合理营养的基础.随着经济建设的飞速发展,人民生活水平的不断提高,对油脂不仅在数量上而且在质量上的要求越来越高,精炼油的市场越来越广阔,本文就精制油的炼制方法、生产工艺。 展开更多
关键词 油脂 机械方法 化学方法 机械-物理化学方法 生产工艺 主要设备
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Construction of Mechanized Claw as a Teaching Method in Engineering
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作者 Gabriel Souza da Silva Andre Felipe Souza da Cruz +2 位作者 Filipe Cavalcanti Fernande~ Alberto Chequer Novais Neto Wellington da Silva Fonseca 《Journal of Mechanics Engineering and Automation》 2015年第2期107-111,共5页
The labor market requires, increasingly, an updated and more professional preparation, mainly due to the rapid pace of scientific technical advancement means in the industry. From this point, it is important to encour... The labor market requires, increasingly, an updated and more professional preparation, mainly due to the rapid pace of scientific technical advancement means in the industry. From this point, it is important to encourage the development of the basic techniques of control systems, electronics and communication in order to produce knowledge in the mechatronic field and so apply them to industry. Considering the relevance of this subject, the students of Federal University of Para-Campus Tucumi through the Research Group of Electrical and Mechanical Systems apply their knowledge in multidisciplinary engineering fields in order to generate knowledge from creative techniques using low cost materials, together with the encouragement of social and environmental responsibility which is very important nowadays. At the same time, targeting the needs of the labor market, this work aims to foster in students the skills and requirements through team projects and innovative methods. Therefore, this paper presents a mechanical manipulator, where their operating characteristics are based on industrial robots in the literature, powered by DC (direct current) motors and fully developed from reusable materials. By adding a developed control from the Arduino, prototyping platform with an electronic strategic offers through the internet the long-distance control convenience. 展开更多
关键词 ARDUINO mechanized claw low cost industry.
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